Decomposition reactions of magnesium sulfate hydrates and phase equilibria in the MgSO₄-H₂O and Na-Mg-Cl-SO₄-H₂O systems with implications for Mars     

Michael Steiger  Kirsten Linnow  Dorothee Ehrhardt  Mandy Rohde 《Geochimica et cosmochimica acta》2011,75(12):3600-3626

We report new measurements of equilibrium relative humidities for stable and metastable hydration-dehydration equilibria involving several magnesium sulfates in the MgSO₄·nH₂O series. We also report a comprehensive thermodynamic treatment of the system including solution properties and experimental data from the published literature, i.e. solubilities, heat capacities and additional decomposition humidities. While for some magnesium sulfate hydrates solubility data in the binary system MgSO₄-H₂O are sparse, there is a reasonable database of solubility measurements of these hydrates in the ternary MgCl₂-MgSO₄-H₂O and the quaternary reciprocal Na⁺-Mg²⁺-Cl⁻-SO₄²⁻-H₂O systems. To make these data suitable for the determination of solubility products, we parameterized a Pitzer ion interaction model for the calculation of activity coefficients and water activities in mixed solutions of these systems and report the ion interaction parameters for the Na⁺-Mg²⁺-Cl⁻-SO₄²⁻-H₂O system. The model predicted solubilities in the reciprocal system are in very good agreement with experimental data. Using all available experimental data and the solution model an updated phase diagram of the MgSO₄-H₂O system covering the whole temperature range from about 170 to 473 K is established. This treatment includes MgSO₄·H₂O (kieserite), MgSO₄·4H₂O (starkeyite), MgSO₄·5H₂O (pentahydrite), MgSO₄·6H₂O (hexahydrite), MgSO₄·7H₂O (epsomite) and MgSO₄·11H₂O (meridianiite). It is shown that only kieserite, hexahydrite, epsomite and meridianiite show fields of stable existence while starkeyite and pentahydrite are always metastable. Due to sluggish kinetics of kieserite formation, however, there is a rather extended field of metastable existence of starkeyite which makes this solid a major product in dehydration reactions. The model predicted behavior of the magnesium sulfates is in excellent agreement with observations reported in the literature under terrestrial temperature and relative humidity conditions. We also discuss the implications of the new phase diagram for sulfates on Mars.  相似文献   

A framework for addressing health disparities in vulnerable populations with the help of Esri Community Analyst     

Camelia Maria Kantor  Veronica Constantin 《GeoJournal》2017,82(1):1-8

Increasingly, health outcomes are tied to nutritional opportunities based on the availability of foods and cultural patterns of consumption. This paper demonstrates how Esri Community Analyst can help in identifying at-risk communities. The methodology that results argues a means by which national data made available by Esri in a “one-stop shop” can be utilized in a simplified, user-friendly way to identify specific populations with higher prevalence of certain diseases and areas where nutritional needs are likely unmet. For demonstration purposes, this paper presents a case study for South Carolina, USA.  相似文献   

Effects of ionizing radiation on the survival of bacterial spores in artificial martian regolith     

Ralf Moeller  Manfred Rohde  Günther Reitz 《Icarus》2010,206(2):783-582

Bacterial spores of Bacillus subtilis were used as a model system to study the effects of ionizing radiation on the survivability of spores uncovered and covered with artificial martian regolith. Spore survival after X-ray exposure was mainly depending on the role of non-homologous end-joining (NHEJ) as the major DNA double-strand break repair pathway during germination, the involvement of major small, acid-soluble spore proteins (SASP) as DNA radioprotectants and the coverage by martian regolith, whereas spores covered with martian regolith were significantly more sensitive to X-rays than uncovered spores, which is mainly due to the interaction of X-rays with artificial martian regolith resulting in the formation of secondary electrons and reactive oxygen species.  相似文献   

Late Quaternary multiple incised valley systems: An unusually well‐preserved stratigraphic record of two interglacial valley‐fill successions from the Arno Plain (northern Tuscany,Italy)          下载免费PDF全文

Veronica Rossi  Alessandro Amorosi  Giovanni Sarti  Sara Mariotti 《Sedimentology》2017,64(7):1901-1928

Un‐fragmented stratigraphic records of late Quaternary multiple incised valley systems are rarely preserved in the subsurface of alluvial‐delta plains due to older valley reoccupation. The identification of a well‐preserved incised valley fill succession beneath the southern interfluve of the Last Glacial Maximum Arno palaeovalley (northern Italy) represents an exceptional opportunity to examine in detail evolutionary trends of a Mediterranean system over multiple glacial–interglacial cycles. Through sedimentological and quantitative meiofauna (benthic foraminifera and ostracods) analyses of two reference cores (80 m and 100 m long) and stratigraphic correlations, a mid‐Pleistocene palaeovalley, 5 km wide and 50 m deep, was reconstructed. Whereas valley filling is chronologically constrained to the penultimate interglacial (Marine Isotope Stage 7) by four electron spin resonance ages on bivalve shells (Cerastoderma glaucum), its incision is tentatively correlated with the Marine Isotope Stage 8 sea‐level fall. Above basal fluvial‐channel gravels, the incised valley fill is formed by a mud‐prone succession, up to 44 m thick, formed by a lower floodplain unit and an upper unit with brackish meiofauna that reflects the development of a wave‐dominated estuary. Subtle meiofauna changes towards less confined conditions record two marine flooding episodes, chronologically linked to the internal Marine Isotope Stage 7 climate‐eustatic variability. After the maximum transgressive phase, recorded by coastal sands, the interfluves were flooded around 200 ka (latest Marine Isotope Stage 7). The subsequent shift in river incision patterns, possibly driven by neotectonic activity, prevented valley reoccupation guiding the northward formation of the Last Glacial Maximum palaeovalley. The applied multivariate approach allowed the sedimentological characterization of the Marine Isotope Stage 7 and Marine Isotope Stage 1 palaeovalley fills, including shape, size and facies architecture, which revealed a consistent river‐coastal system response over two non‐consecutive glacial–interglacial cycles (Marine Isotope Stages 8 to 7 and Marine Isotope Stages 2 to 1). The recurring stacking pattern of facies documents a predominant control exerted on stratigraphy by Milankovitch and sub‐Milankovitch glacio‐eustatic oscillations across the late Quaternary period.  相似文献   

Lake Shala: Water chemistry,mineralogy and geochemistry of sediments in an Ethiopian Rift lake     

Dr. Albrecht Baumann  Doz. Dr. Ulrich Förstner  Dr. Rudolf Rohde 《International Journal of Earth Sciences》1975,64(1):593-609

Lake Shala, the deepest lake in the internal Galla lakes basin of the Ethiopian Rift, fills a depression in Pleistocene volcanic rocks. Its sodium-bicarbonate (-chloride) water (salinity 16 g/l) is remarkably low in earth alkalines and sulphate. Stratification is indicated by different ion concentrations in the surface and bottom waters and by a thermocline in a water depth of 50–70 m. Hot soda springs emerging on the shores of Lakes Shala and Langano are believed to be derived from a hot saline underground reservoir recharged by meteoric waters. The ion composition of the hot spring waters is uniform and matches that in the Galla Lakes except for total salinities. Anomalous heavy metal concentrations are lacking in lake and hot spring waters. Sediments of Lake Shala belong to an extremely fine-grained group of deposits. They are poorly sorted and the lateral distribution of the grain sizes does not follow the normal scheme for aquatic depositional environments. A belt, 50–100 m below lake level containing the finest-grained sediments, separates the shallow periphery of the lake bottom from the deep center, both characterized by coarser-grained deposits. The sediments consist of a large portion of glassy components. A poorly cristallized smectite is most abundant in the clay mineral group. The components of the sand fraction are quartz, feldspar, glass particles and occasionally calcite. Nickel, cobalt and lead are depleted in the Lake Shala sediments compared with the averages of shales. Iron, manganese and zinc are relatively high. Silver, cadmium and some of the rare earth elements are enriched by factors of > 5.  相似文献   

A synthesis of sociological and biological perspectives on sustainable land use in Namaqualand   总被引：1，自引：0，他引：1  

B. Cousins  M.T. Hoffman  N. Allsopp  R.F. Rohde 《Journal of Arid Environments》2007,70(4):834

A transdisciplinary synthesis, grouped into four main themes, of the key papers in this Special Issue on Namaqualand is provided. Perspectives on current environmental, economic and social issues in the region are interpreted in the context of the past and are used to inform future trajectories of change and development needs within the region. Firstly, in terms of the climatic and biophysical environment, Namaqualand's rich biodiversity is not uniformly distributed and is explained in terms of the spatially heterogeneous geological, pedological and topographical gradients that characterize the region. Spatial and temporal variation in rainfall over long time frames would also have promoted speciation within isolated, poorly-dispersed, leaf succulent populations. Future climate models propose a decrease in rainfall across the region with an associated reduction in livestock production. The second theme provides an historical perspective on changing land use practices in Namaqualand over the last 2000 years. It suggests that they have frequently been influenced by events originating far from the region such as colonial expansion, apartheid legislation and globalization. Local people, particularly marginalised communal farmers have had to adapt to these outside influences within an increasingly confined landscape that has progressively eroded their mobility and restricted their ability to utilise the spatial and temporal variability inherent in semi-arid environments. The third theme shows how livelihood diversification has been one of the key ways in which local people from communal areas have adapted to change. While farming makes up a relatively small part of the income of most households it enhances the resilience of livelihoods in the region. The fourth theme is concerned with land reform, conservation and restoration in Namaqualand. While a significant amount of land has been transferred to previously-marginalised groups, equitable access to these resources is lacking. An exclusively commercial orientation within the extension and development programmes of the Department of Agriculture further hampers the effectiveness of land reform as a tool for reducing levels of poverty in the majority of households in the region. Conservation initiatives could enhance livelihood options in Namaqualand but are viewed by some as being in competition with the state's land reform programme and are too recent to reflect significant regional benefits at this stage. While restoration is possible in severely degraded lands, the costs and operational difficulties in these event-driven, semi-arid systems are emphasised. Finally, this synthesis suggests that the important exogenous drivers of change in the 21st century are likely to be climate, biodiversity conservation initiatives, land redistribution and continued processes of de-agrarianisation as a result of macro-economic change. A focus on building institutions, encouraging livestock mobility within a significantly expanded commons and supporting livelihood diversification are some of the approaches necessary to address the development needs of Namaqualand.  相似文献   

Multitemporal UAV surveys for landslide mapping and characterization   总被引：1，自引：0，他引：1  

Guglielmo Rossi  Luca Tanteri  Veronica Tofani  Pietro Vannocci  Sandro Moretti  Nicola Casagli 《Landslides》2018,15(5):1045-1052

This paper presents the preliminary results of the IPL project 196 “Development and applications of a multi-sensor drone for geohazards monitoring and mapping.” The objective of the project is to test the applicability of a multi-sensor drone for the mapping and monitoring of different types of geohazards. The Department of Earth Sciences of the University of Florence has developed a new type of drone airframe. Several survey campaigns were performed in the village of Ricasoli, in the Upper Arno river Valley (Tuscany, Italy) with the drone equipped with an optical camera to understand the possibility of this rising technology to map and characterize landslides. The aerial images were combined and analyzed using Structure-from-Motion (SfM) software. The collected data allowed an accurate reconstruction and mapping of the detected landslides. Comparative analysis of the obtained DTMs also permitted the detection of some slope portions being prone to failure and to evaluate the area and volume of the involved mass.  相似文献   

A review of the impacts of salmonid farming on marine coastal ecosystems in the southeast Pacific   总被引：2，自引：0，他引：2  

Buschmann  Alejandro H.; Riquelme  Veronica A.; Hernandez-Gonzalez  Maria C.; Varela  Daniel; Jimenez  Jaime E.; Henriquez  Luis A.; Vergara  Pedro A.; Guinez  Ricardo; Filun  Luis 《ICES Journal of Marine Science》2006,63(7):1338-1345

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Eutrophication and the rate of net nitrification in a coastal marine ecosystem     

Veronica M. Berounsky  Scott W. Nixon 《Estuarine, Coastal and Shelf Science》1985,20(6):773-781

Rates of net nitrification were calculated for four large (13 m³) estuarine-based microcosms that had been subjected to inorganic nutrient enrichment. Calculated rates were based on two years of weekly nitrate and nitrite measurements and ranged from a maximum of 0·55 μmol NO₂₊₃⁻ produced l⁻¹ day⁻¹ in the control tank (no enrichment) to over 13 μmol NO₂₊₃⁻ produced l⁻¹ day⁻¹ in the most enriched tank (receiving 18·6 μmol NH₄ l⁻¹ day⁻¹). Almost all NO₂₊₃⁻ production was pelagic, little was benthic. Net NO₃⁻ production or net NO₂⁻ production dominated the net nitrification rates during different seasons. Good correlations were found between various oxidation rates and substrate concentrations. The calculated net nitrite production rates were 10 to 1000 times higher than previously reported rates for open ocean systems, demonstrating the potential importance of nitrification to estuarine systems.  相似文献   

A sample preparation guide for clay-rich carbonaceous chondrites     

Bennett J. K. Wilson  Veronica E. Di Cecco  Laurence A. J. Garvie  Kimberly T. Tait  Michael G. Daly 《Meteoritics & planetary science》2024,59(3):560-567

The matrix of the C2-ungrouped Tarda meteorite contains abundant smectite minerals that swell and crumble when exposed to polar liquids, causing the sample to rapidly slake. This phenomenon presents a serious challenge when polishing the meteorite, as common polishing liquids used on carbonaceous chondrites, such as water, ethanol, ethylene glycol, and isopropyl alcohol, are polar and will cause the sample to swell, making it unsuitable for some analyses. Hexane and mineral oil are nonpolar liquids that were found to not induce swelling on highly expansive montmorillonite-clay analog material and were effectively integrated into a polishing procedure for Tarda. Here, we detail a procedure for mounting, cutting, and polishing the Tarda meteorite to prepare a surface that is suitable for a variety of sensitive techniques, such as electron microprobe analysis. This work offers a practical methodology for the preparation of other clay-rich samples, which may include the recently returned Ryugu and Bennu materials.  相似文献