Characterization of the chemical structures of natural and synthetic aluminosilicate gels and sols by infrared spectroscopy     

Victor C. Farmer  Anthony R. Fraser  J.Mervyn Tait 《Geochimica et cosmochimica acta》1979,43(9):1417-1420

Infrared spectra in the 300–1400 cm^?1 region indicate that the non-crystalline products of interaction between hydroxyaluminium species and orthosilicic acid in dilute aqueous solutions of pH < 5 differ markedly in structure from those formed in near-neutral and alkaline solutions of pH > 6. The compound formed in acid solution has an infrared spectrum similar to imogolite, and is termed proto-imogolite; like imogolite, it contains orthosilicate groups and 6-coordinated aluminium, and has an ideal Si:Al ratio of around 0.5, but it can incorporate some excess alumina or silica and it does not have the regular tubular structure of imogolite. Compounds formed in alkaline solutions that are not too dilute have infrared spectra resembling the feldspathoid group of minerals and are termed hydrous feldspathoids. They incorporate a condensed tetrahedral framework with an Si:Al ratio greater than one, but can also contain 6-coordinated aluminium.Natural allophanes of the proto-imogolite and hydrous feldspathoid types exist. The allophane of weathered pumice, however, contains a condensed silicate anion that incorporates little tetrahedral aluminium. Proto-imogolite forms stable sols at pH < 5 and must play an important role in the transport of aluminium in acidic natural waters containing dissolved silica.  相似文献   

Petrology of the Skien basaltic rocks,southwestern Oslo Region,Norway     

Tom Victor Segalstad 《Lithos》1979,12(3):221-239

The pile of Permian continental basaltic rocks near Skien has a minimum thickness of 1 500 m, dipping 40^g towards NE, consisting of several thin lava flows. Most flows are porphyric, though both tuffs and aphyric flows occur to a lesser extent. Amygdules are abundant and a characteristic feature. The flows in the lower 2/3 of the basalt pile are mainly classified as melanite-ankaramite; some in the middle part as melanite-nephelinite; and the upper 1/3 of the flows as basanite. The basaltic rocks evolved from an assumed olivine-nephelinitic magma at great depths principally by clinopyroxene crystal fractionation accompanied by later olivine and maybe melilite reactions at moderate pressure in minor shallower magma chambers.  相似文献   

Experimental study of silica diffusion during metasomatic reactions in the presence of water at 550°C and 1000 bars     

Jean-Pierre Ildefonse  Victor Gabis 《Geochimica et cosmochimica acta》1976,40(3):297-303

Metasomatic reactions between quartz and incompatible oxides or hydroxides were experimentally studied at 550°C and 1000 bars water pressure. Two porous pellets of the initial reagents pressed one against the other were used. Reaction rims in the millimeter range develop at the initial boundary in the oxide pellet. All the experiments show that an important transfer of silica occurs by diffusion in the stationary intergranular solution.The chemical transfer of silica through the intergranular fluid is quantitatively determined by studying the kinetics of growth of the forsterite rim in the system quartz-brucite. The kinetics limiting stage being silica transfer, the experiments allow the determination of the diffusion coefficient of silica through the solution. At 550°C and 1000 bars, a value of 2.4 × 10^?1cm² s¹ is found.This high value shows the importance of chemical diffusion in the intergranular fluid of rocks during metamorphic processes.  相似文献   

Continuous spatially distributed simulation of surface and subsurface hydrological processes in a small semiarid catchment     

Marco Maneta  Susanne Schnabel  Victor Jetten 《水文研究》2008,22(13):2196-2214

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Late Quaternary moisture export across Central America and to Greenland: evidence for tropical rainfall variability from Costa Rican stalagmites     

Matthew S. Lachniet  Leah Johnson  Yemane Asmerom  Stephen J. Burns  Victor Polyak  William P. Patterson  Lindsay Burt  April Azouz 《Quaternary Science Reviews》2009,28(27-28):3348-3360

We present a high-resolution terrestrial archive of Central American rainfall over the period 100–24 and 8.1–6.5 ka, based on δ¹⁸O time series from U-series dated stalagmites collected from a cave on the Pacific Coast of Costa Rica. Our results indicate substantial δ¹⁸O variability on millennial to orbital time scales that is interpreted to reflect rainfall variations over the cave site. Correlations with other paleoclimate proxy records suggest that the rainfall variations are forced by sea surface temperatures (SST) in the Atlantic and Pacific Oceans in a fashion analogous to the modern climate cycle. Higher rainfall is associated with periods of a warm tropical North Atlantic Ocean and large SST gradients between the Atlantic and Pacific Oceans. Rainfall variability is likely linked to the intensity and/or latitudinal position of the intertropical convergence zone (ITCZ). Periods of higher rainfall in Costa Rica are also associated with an enhanced sea surface salinity gradient on either side of the isthmus, suggesting greater freshwater export from the Atlantic Basin when the ITCZ is stronger and/or in a more northerly position. Further, wet periods in Central America coincide with high deuterium excess values in Greenland ice, suggesting a direct link between low latitude SSTs, tropical rainfall, and moisture delivery to Greenland. Our results indicate that a stronger tropical hydrological cycle during warm periods and large inter-ocean SST gradients enhanced the delivery of low latitude moisture to Greenland.  相似文献   

Meteorites at Meridiani Planum provide evidence for significant amounts of surface and near‐surface water on early Mars     

Alberto G. FAIRÉN  James M. DOHM  Victor R. BAKER  Shane D. THOMPSON  William C. MAHANEY  Kenneth E. HERKENHOFF  J. Alexis P. RODRÍGUEZ  Alfonso F. DAVILA  Dirk SCHULZE‐MAKUCH  M. Ramy EL MAARRY  Esther R. UCEDA  Ricardo AMILS  Hirdy MIYAMOTO  Kyeong J. KIM  Robert C. ANDERSON  Christopher P. McKAY 《Meteoritics & planetary science》2011,46(12):1832-1841

Abstract– Six large iron meteorites have been discovered in the Meridiani Planum region of Mars by the Mars Exploration Rover Opportunity in a nearly 25 km‐long traverse. Herein, we review and synthesize the available data to propose that the discovery and characteristics of the six meteorites could be explained as the result of their impact into a soft and wet surface, sometime during the Noachian or the Hesperian, subsequently to be exposed at the Martian surface through differential erosion. As recorded by its sediments and chemical deposits, Meridiani has been interpreted to have undergone a watery past, including a shallow sea, a playa, an environment of fluctuating ground water, and/or an icy landscape. Meteorites could have been encased upon impact and/or subsequently buried, and kept underground for a long time, shielded from the atmosphere. The meteorites apparently underwent significant chemical weathering due to aqueous alteration, as indicated by cavernous features that suggest differential acidic corrosion removing less resistant material and softer inclusions. During the Amazonian, the almost complete disappearance of surface water and desiccation of the landscape, followed by induration of the sediments and subsequent differential erosion and degradation of Meridiani sediments, including at least 10–80 m of deflation in the last 3–3.5 Gy, would have exposed the buried meteorites. We conclude that the iron meteorites support the hypothesis that Mars once had a denser atmosphere and considerable amounts of water and/or water ice at and/or near the surface.  相似文献   

Measuring and managing changes in estuaries and lagoons: morphological and eco-toxicological aspects   总被引：1，自引：0，他引：1  

Zonta R  Guerzoni S  Pérez-Ruzafa A  de Jonge VN 《Marine pollution bulletin》2007,55(10-12):403-406

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Distribution of arsenic and mercury in subtropical coastal beachrock,Gulf of Mannar,India   总被引：1，自引：0，他引：1  

J Dajkumar Sahayam  N Chandrasekar  S Krishna Kumar  G Victor Rajamanickam 《Journal of Earth System Science》2010,119(1):129-135

An assessment of coastal pollution was made on the basis of trace element concentrations (arsenic — As, mercury — Hg) in the Gulf of Mannar. The beachrock samples were collected along the coastal tracts between Rameswaram and Kanyakumari. The samples were dried and digested to determine the As and Hg using atomic absorption spectrophotometer (AAS-air-acetylene and nitrous oxide method). The As and Hg accumulation status of the beachrock was assessed using geo-accumulation index values (I _geo). The accumulation of As and Hg in the beachrock ranges from 2.75 to 20.72 μg g⁻¹ and from 0.06 to 0.31 μg g⁻¹, respectively. The As and Hg concentrations in the beachrocks are compared with crustal average values and average of other region sediments. The possible source of the contamination is from atmospheric deposition and anthropogenic activities.  相似文献   

Reply to “Rip Current Misunderstandings”     

Victor A. Gensini  Walker S. Ashley 《Natural Hazards》2010,55(2):163-165

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Phytoplankton diversity in a tropical bay,North Borneo,Malaysia as revealed by light microscopy and Next-Generation Sequencing     

Brian Wei Khong Chong  Sandric Chee Yew Leong  Victor S. Kuwahara  Teruaki Yoshida 《海洋学报(英文版)》2022,41(12):142-151

Assessments of phytoplankton diversity in Sabah waters, North Borneo, have primarily relied on morphology-based identification, which has inherent biases and can be time-consuming. Next-Generation Sequencing (NGS) technology has been shown to be capable of overcoming several limitations of morphology-based methods. Samples were collected from the Sepanggar Bay over the course of the year 2018 in different monsoon seasons. Morphology-based identification and NGS sequencing of the V8–V9 region of the 18S LSU rDNA were used to investigate the diversity of the phytoplankton community. Microscopy and NGS showed complementary results with more diatom taxa detected by microscopy whereas NGS detected smaller and rarer taxa. The harmful algal genera in the study site comprised of Skeletonema, Margalefidinium, Pyrodinium, Takayama, and Alexandrium as detected by NGS. This study showed that that an integrative approach of both morphological and molecular techniques could provide more comprehensive information about the phytoplankton community as the approach captured quantitative variability as well as the diversity of phytoplankton species.  相似文献