Monte Carlo simulation of mixing in Ca3Fe2Ge3O12–Ca4Ge4O12 garnets and implications for the thermodynamic stability of pyrope–majorite solid solution     

Victor L. Vinograd  Bjoern Winkler  Daniel J. Wilson  Andrew Putnis  Julian D. Gale 《Physics and Chemistry of Minerals》2006,33(8-9):533-544

Static lattice energy calculations, based on empirical pair potentials, were performed for a large set of structures differing in the arrangement of octahedral cations within the garnet 2 × 2 × 2 supercell. The compositions of these structures varied between Ca₃Fe₂Ge₃O₁₂ and Ca₄Ge₄O₁₂. The energies were cluster expanded using pair and quaternary terms. The derived ordering constants were used to constrain Monte Carlo simulations of temperature-dependent mixing properties in the ranges of 1,073–3,673 K and 0–10 GPa. The free energies of mixing were calculated using the method of thermodynamic integration. The calculations predict a wide miscibility gap between Fe-rich (cubic) and Fe-pure (tetragonal) garnets consistent with recent experimental observations of Iezzi et al. (Phys Chem Miner 32:197–207, 2005). It is shown that the miscibility gap arises due to a very strong cation ordering at the Fe-pure composition, driven by the charge difference between Ca²⁺ and Ge⁴⁺ cations. The structural and thermodynamic analogies between Ca–Ge and Mg–Si systems suggest that a similar miscibility gap should exist between pyrope and Mg–Si-majorite.  相似文献   

Late Holocene linkages between decade–century scale climate variability and productivity at Lake Tanganyika, Africa     

Andrew S. Cohen  Kiram E. Lezzar  Julia Cole  David Dettman  Geoffrey S. Ellis  Meagan Eagle Gonneea  Pierre-Denis Plisnier  Victor Langenberg  Maarten Blaauw  Derrick Zilifi 《Journal of Paleolimnology》2006,36(2):189-209

Microlaminated sediment cores from the Kalya slope region of Lake Tanganyika provide a near-annually resolved paleoclimate record between ∼∼2,840 and 1,420 cal. yr B.P. demonstrating strong linkages between climate variability and lacustrine productivity. Laminae couplets comprise dark, terrigenous-dominated half couplets, interpreted as low density underflows deposited from riverine sources during the rainy season, alternating with light, planktonic diatomaceous ooze, with little terrigenous component, interpreted as windy/dry season deposits. Laminated portions of the studied cores consist of conspicuous dark and light colored bundles of laminae couplets. Light and dark bundles alternate at decadal time scales. Within dark bundles, both light and dark half couplets are significantly thinner than within light bundles, implying slower sediment accumulation rates during both seasons over those intervals.Time series analyses of laminae thickness patterns demonstrate significant periodicities at interannual–centennial time scales. Longer time scale periodicities (multidecadal to centennial scale) of light and dark half couplet thicknesses are coherent and in some cases are similar to solar cycle periods on these time scales. Although laminae thickness cycles do not strongly covary with the actual Δ¹⁴C record for this same time period, two large Δ¹⁴C anomalies are associated with substantial decreases in both light and dark laminae thickness. In contrast to the multidecadal– centennial time scale, significant annual to decadal periodicities, which are broadly consistent with ENSO/PDO forcing and their impact on East African climate, are not coherent between light and dark half couplets. The coherency of light–dark couplets at decadal–centennial time scales, but not at shorter time scales, is consistent with a model of a long-term relationship between precipitation (recorded in wet season dark laminae thickness) and productivity (light laminae thickness), which is not manifest at shorter time scales. We hypothesize that this coupling results from long-term recharging of internal nutrient loading during wet periods (higher erosion of soil P) and reduced loading during drought intervals. The relationship is not expressed on short time scales during which the dominant control on productivity is wind-driven, dry season upwelling, which is uncorrelated with wet-season precipitation. Our record greatly extends the temporal record of this quasi-periodic behavior throughout the late Holocene and provides the first evidence linking decade- to century-scale episodes of enhanced productivity to enhanced precipitation levels and nutrient recharge in a productive tropical lake.  相似文献   

The Port Mouton Shear Zone: intersection of a regional fault with a crystallizing granitoid pluton   总被引：2，自引：0，他引：2  

D. Barrie Clarke  Krista L. McCuish  Ron H. Vernon  Victor Maksaev  Brent V. Miller   《Lithos》2002,61(3-4):141-159

The peraluminous tonalite–monzogranite Port Mouton Pluton is a petrological, geochemical, structural, and geochronological anomaly among the many Late Devonian granitoid intrusions of the Meguma Lithotectonic Zone of southern Nova Scotia. The most remarkable structural feature of this pluton is a 4-km-wide zone of strongly foliated (040/subvertical) monzogranites culminating in a narrow (10–30 m), straight, zone of compositionally banded rocks that extends for at least 3 km along strike. The banded monzogranites consist of alternating melanocratic and leucocratic compositions that are complementary to the overall composition of that part of the pluton, suggesting an origin by mineral–melt and mineral–mineral sorting. Biotite and feldspar are strongly foliated in the plane of the compositional bands. These compositional variations and foliations originated by a process of segregation flow during shearing of the main magma with a crystallinity of 55–75%. Subsequent minor brittle fracturing of feldspars, twinning of microcline, development of blocky sub-grains in quartz, and kinking of micas demonstrate overprinting by a high-temperature deformation straddling the monzogranite solidus. Small folds and late sigmoidal dykes indicate dextral movement on the shear zone. This Port Mouton Shear Zone (PMSZ) is approximately co-linear with the only outcrops of Late Devonian mafic intrusions in the area, two of which are syn-plutonic with well-developed mingling textures in the marginal tonalite of the Port Mouton Pluton. Also closely co-linear with the mafic intrusions are a granitoid dyke that extends well beyond the outer contact of the Port Mouton Pluton, a swarm of large aligned angular xenolithic slabs, a zone of thin wispy schlieren banding, a large Be-bearing pegmatite, and a breccia pipe with abundant garnetiferous metapelitic xenoliths. In various ways, the shear zone may control all of these features. The Port Mouton Shear Zone is parallel to many other NE-trending faults and shear zones in the northern Appalachians, probably related to the docking of the Meguma Zone along the Cobequid–Chedabucto Fault system.  相似文献   

Image analysis applied to quantitative evaluation of chromatic impact generated by open-pit quarries and mines     

Victor Pinto  Xavier Font  Miquel Salgot  Jose Tapias  Tomas Mañá 《Environmental Geology》2002,41(5):495-503

One of the most important environmental impacts resulting from opencast mining, and especially quarries, is the visual impact. Evaluation of this impact considers two aspects: first, the area occupied by the quarry as seen by an observer from a specific place, and, second, the chromatic contrast existing between landscape and exploitation. In this study we develop a methodology to assess the chromatic impact in an objective and comparable form. To assess this impact we developed a method based on image analysis that allows us to obtain from a picture or image its equivalent as a function of chromatic impact, according to the sensibility of the human eye to different wavelengths. The methodology was applied to the Martinenca limestone quarry (Alcanar, Tarragona) and to Cerro Kori Kollo mine, La Joya district (Bolivia).  相似文献   

加卸载响应比(LURR)理论的实验研究   总被引：13，自引：1，他引：13  

余怀忠  尹祥础  夏蒙棼  梁乃刚  李敏  许昭永  彭克银  Wu Zhishen  Qi Li 《中国地震》2003,19(1):58-66

利用大尺度岩石试件破坏声发射实验，对加卸载响应比(Load/Unload Response Ratio)理论进行了实验研究。实验采用的加载条件力求能够模拟地下岩石的复杂受力过程。在加载过程中，岩石试件内部出现的损伤用声发射技术进行了记录。实验数据经过分析之后所得的结论与加卸载响应比理论预测的结果相符合。把加卸载响应比值Y的变化情况与声发射事件定位的过程相对比，也可以进一步看出岩石材料内部的损伤发展过程与加卸载响应比Y值的变化具有一致性。而高Y值的异常情况出现，又是在材料发生最终破坏之前，所以，可以用加卸载响应比理论定量地分析岩石试件损伤演化情况，从而对岩石材料的破坏及地震做出预测。实验结果再一次验证了加卸载响应比理论。  相似文献   

Use of principal components analysis in petrology: an example from the Martinsville igneous complex, Virginia, U.S.A.     

P. C. Ragland  J. F. Conley  W. C. Parker  J. A. Von Orman 《Mineralogy and Petrology》1997,60(3-4):165-184

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外资：发展中国家城市化的新动力：珠江三角洲个案研究   总被引：106，自引：9，他引：106  

薛凤旋  杨春 《地理学报》1997,52(3):193-206

城市化的研究历来都偏重于内力的营造，例如区域经济的不同发展步伐，乡村－市的人口流动，政府的地区性经济政策以及新城市的建设等。在资本、人力、技术和市场走向“全球化”的情况下，新的国际分工自１９８０年以来已成为一些发展中国家和地区的人口及经济活动急剧增长与集中的主要动力。本文对这一类型城市化的特点和空间形态作出了概括性的描述。  相似文献   

Cuyania: An Exotic Block to Gondwana — Introduction     

Graciela I. Vujovich  Luis A.D. Fernandes  Victor A. Ramos 《Gondwana Research》2004,7(4):1005-1007

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Conditions of pocket formation in the Oktyabrskaya tourmaline-rich gem pegmatite (the Malkhan field, Central Transbaikalia, Russia)     

Igor S. Peretyazhko  Victor Ye. Zagorsky  Sergey Z. Smirnov  Mikhail Y. Mikhailov 《Chemical Geology》2004,210(1-4):91-111

Coexisting melt (MI), fluid-melt (FMI) and fluid (FI) inclusions in quartz from the Oktaybrskaya pegmatite, central Transbaikalia, have been studied and the thermodynamic modeling of PVTX-properties of aqueous orthoboric-acid fluids has been carried out to define the conditions of pocket formation. At room temperature, FMI in early pocket quartz and in quartz from the coarse-grained quartz–oligoclase host pegmatite contain crystalline aggregates and an orthoboric-acid fluid. The portion of FMI in inclusion assemblages decreases and the volume of fluid in inclusions increases from the early to the late growth zones in the pocket quartz. No FMI have been found in the late growth zones. Significant variations of solid/fluid ratios in the neighboring FMI result from heterogeneous entrapment of coexisting melts and fluids by a host mineral. Raman spectroscopy, SEM EDS and EMPA indicate that the crystalline aggregates in FMI are dominated by mica minerals of the boron-rich muscovite–nanpingite CsAl₂[AlSi₃O₁₀](OH,F)₂ series as well as lepidolite. Topaz, quartz, potassium feldspar and several unidentified minerals occur in much lower amounts. Fluid isolations in FMI and FI have similar total salinity (4–8 wt.% NaCl eq.) and H₃BO₃ contents (12–16 wt.%). The melt inclusions in host-pegmatite quartz homogenize at 570–600 °C. The silicate crystalline aggregates in large inclusions in pocket quartz completely melt at 615 °C. However, even after those inclusions were significantly overheated at 650±10 °C and 2.5 kbar during 24 h they remained non-homogeneous and displayed two types: (i) glass+unmelted crystals and (ii) fluid+glass. The FMI glasses contain 1.94–2.73 wt.% F, 2.51 wt.% B₂O₃, 3.64–5.20 wt.% Cs₂O, 0.54 wt.% Li₂O, 0.57 wt.% Ta₂O₅, 0.10 wt.% Nb₂O₅, 0.12 wt.% BeO. The H₂O content of the glass could exceed 12 wt.%. Such compositions suggest that the residual melts of the latest magmatic stage were strongly enriched in H₂O, B, F, Cs and contained elevated concentrations of Li, Be, Ta, and Nb. FMI microthermometry showed that those melts could have crystallized at 615–550 °C.

Crystallization of quartz–feldspar pegmatite matrix leads to the formation of H₂O-, B- and F-enriched residual melts and associated fluids (prototypes of pockets). Fluids of different compositions and residual melts of different liquidus–solidus P–T-conditions would form pockets with various internal fluid pressures. During crystallization, those melts release more aqueous fluids resulting in a further increase of the fluid pressure in pockets. A significant overpressure and a possible pressure gradient between the neighboring pockets would induce fracturing of pockets and “fluid explosions”. The fracturing commonly results in the crushing of pocket walls, formation of new fractures connecting adjacent pockets, heterogenization and mixing of pocket fluids. Such newly formed fluids would interact with a primary pegmatite matrix along the fractures and cause autometasomatic alteration, recrystallization, leaching and formation of “primary–secondary” pockets.  相似文献   

The Singapore River thematic zone: sustainable tourism in an urban context   总被引：5，自引：0，他引：5  

Victor R Savage  Shirlena Huang  T C Chang 《The Geographical journal》2004,170(3):212-225

This paper explores the concept of sustainable tourism and how it applies to urban destinations such as Singapore. As tourism is an important industry in Singapore, in terms of employment, business activity and an income generator, the Singapore Tourism Board is continuously looking at potential avenues to make Singapore a competitive destination. We examine the use of thematic zones in Singapore as a strategy to achieve its ambition of becoming a tourism capital of the world. By focusing on a case study of the Singapore River thematic zone (one of the 11 thematic zones identified by the Singapore Tourism Board), we assess the viability of thematic zones in ensuring sustainable urban tourism. The paper closes with some theoretical reflections and policy implications arising from our key findings.  相似文献