Laboratory kinetics of C₂H radical reactions with ethane, propane, and n-butane at T = 96-296 K: implications for Titan     

James E. Murphy  Stephen R. Leone 《Icarus》2003,163(1):175-181

The kinetics of the reactions of C₂H radical with ethane (k₁), propane (k₂), and n-butane (k₃) are studied over the temperature range of T = 96-296 K with a pulsed Laval nozzle apparatus that utilizes a pulsed laser photolysis-chemiluminescence technique. The C₂H decay profiles in the presence of both the alkane reactant and O₂ are monitored by the CH(A²Δ) chemiluminescence tracer method. The results, together with available literature data, yield the following Arrhenius expressions: k₁(T) = (0.51 ± 0.06) × 10⁻¹⁰ exp[(−76 ± 30)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-800 K), k₂(T) = (0.98 ± 0.32) × 10⁻¹⁰exp[(−71 ± 60)K/T] cm³ molecule⁻¹ s⁻¹ (T = 96-361 K), and k₃(T) = (1.23 ± 0.26) × 10⁻¹⁰ cm³ molecule⁻¹ s⁻¹ (T = 96-297 K). At T = 296 K, k₁ is measured as a function of total pressure and has little or no pressure dependence. The results from this work support a direct hydrogen abstraction mechanism for the title reactions. Implications to the atmospheric chemistry of Titan are discussed.  相似文献   

The effects of topographically-controlled thermal tides in the martian upper atmosphere as seen by the MGS accelerometer     

Paul Withers  S.W Bougher 《Icarus》2003,164(1):14-32

Mars Global Surveyor accelerometer observations of the martian upper atmosphere revealed large variations in density with longitude during northern hemisphere spring at altitudes of 130-160 km, all latitudes, and mid-afternoon local solar times (LSTs). This zonal structure is due to tides from the surface. The zonal structure is stable on timescales of weeks, decays with increasing altitude above 130 km, and is dominated by wave-3 (average amplitude 22% of mean density) and wave-2 (18%) harmonics. The phases of these harmonics are constant with both altitude and latitude, though their amplitudes change significantly with latitude. Near the South Pole, the phase of the wave-2 harmonic changes by 90° with a change of half a martian solar day while the wave-3 phase stays constant, suggesting diurnal and semidiurnal behaviour, respectively. We use a simple application of classical tidal theory to identify the dominant tidal modes and obtain results consistent with those of General Circulation Models. Our method is less rigorous, but simpler, than the General Circulation Models and hence complements them. Topography has a strong influence on the zonal structure.  相似文献   

Ghosts of the Milky Way: a search for topology in new quasar catalogues     

S. J. Weatherley  S. J. Warren  S. M. Croom  R. J. Smith  B. J. Boyle  T. Shanks  L. Miller  M. P. Baltovic 《Monthly notices of the Royal Astronomical Society》2003,342(1):L9-L13

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Planar deformation features and impact glass in inclusions from the Vredefort Granophyre,South Africa     

P. C. Buchanan  W. U. Reimold 《Meteoritics & planetary science》2002,37(6):807-822

Abstract— The Vredefort Granophyre represents impact melt that was injected downward into fractures in the floor of the Vredefort impact structure, South Africa. This unit contains inclusions of country rock that were derived from different locations within the impact structure and are predominantly composed of quartzite, feldspathic quartzite, arkose, and granitic material with minor proportions of shale and epidiorite. Two of the least recrystallized inclusions contain quartz with single or multiple sets of planar deformation features. Quartz grains in other inclusions display a vermicular texture, which is reminiscent of checkerboard feldspar. Feldspars range from large, twinned crystals in some inclusions to fine‐grained aggregates that apparently are the product of decomposition of larger primary crystals. In rare inclusions, a mafic mineral, probably biotite or amphibole, has been transformed to very fine‐grained aggregates of secondary phases that include small euhedral crystals of Fe‐rich spinel. These data indicate that inclusions within the Vredefort Granophyre were exposed to shock pressures ranging from <5 to 8–30 GPa. Many of these inclusions contain small, rounded melt pockets composed of a groundmass of devitrified or metamorphosed glass containing microlites of a variety of minerals, including K‐feldspar, quartz, augite, low‐Ca pyroxene, and magnetite. The composition of this devitrified glass varies from inclusion to inclusion, but is generally consistent with a mixture of quartz and feldspar with minor proportions of mafic minerals. In the case of granitoid inclusions, melt pockets commonly occur at the boundaries between feldspar and quartz grains. In metasedimentary inclusions, some of these melt pockets contain remnants of partially melted feldspar grains. These melt pockets may have formed by eutectic melting caused by inclusion of these fragments in the hot (650 to 1610 °C) impact melt that crystallized to form the Vredefort Granophyre.  相似文献   

CORROSION RESISTANCE OF INTERFERENCE FILM ON STAINLESS STEEL     

张经磊  侯保荣 《中国海洋湖沼学报》1997,15(4):363-368

IwrRODUcrlONStainlessstalhasbeenusedwidelyasbuildingrnateria1,especiallyasdecoratingrnate-rialinbuildings.Ordinarystainlesssteehasonlyonemonot0noussilverywhitCcolourwhichsomeimesdoesnotrnatchwithitSsurmundingenvironment.lnordert0improveitSdereratingperfonnaneeandexpanditsuse,muchresearchhasbeenconductedsincethe4O'st0trytoformabright,uniform,highcorrosi0nandwearresistantco1ourfilmonastainlesssteesurface.Duringtheeariystage,anirnmersionedhodwasused,i.e.inimrs-ingthestainlesssteelinahots0luti…  相似文献   

Book review     

D. W. Connell  Thomas M. Baugh 《Estuaries and Coasts》1992,15(2):255-255

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Isolation of resonance in acoustic backscatter from elastic targetsusing adaptive estimation schemes     

Azimi-Sadjadi  M.R. Wilbur  J. Dobeck  G.J. 《Oceanic Engineering, IEEE Journal of》1995,20(4):346-353

It has been shown that at certain frequencies the acoustic backscatter from elastic targets exhibits certain resonance behavior which closely relates to the physical properties of the target such as dimension, thickness, and composition. The purpose of this paper is to develop an automated approach for identifying the presence of resonance in the acoustic backscatter from an unknown underwater target by isolating the resonance part from the specular contribution. An adaptive transversal filter structure is used to estimate the specular part of the backscatter and consequently the error signal would provide an estimate of the resonance part. An important aspect of this scheme lies in the fact that it does not require an underlying model for the elastic return. The adaptation rule is based upon fast recursive least squares (RLS) learning. The approach taken in this paper is general in the sense that it can be applied to targets of unknown geometry and thickness and, further, does not require any a priori information about the target and/or the environment. Test results on acoustic data are presented which indicate the effectiveness of the proposed approach  相似文献   

Radial velocity searches for other planetary systems:Current status and future prospects     

W. D. Cochran  A. P. Hatzes 《Astrophysics and Space Science》1996,241(1):43-60

Measurement of variations in the radial velocities of stars due to the reflex orbital motion of the star around the planetary-system barycenter constitutes a powerful method of searching for substellar or planetary mass companions. After several years of patient data acquisition, radial-velocity searches for planetary systems around other stars are now beginning to bear fruit. In late 1995 and early 1996, three candidate systems were announced with Jovian-mass planets around solar-type stars. The current paradigm for low-mass star formation suggests that planetary systems should be able to form in the circumstellar disks surrounding young stellar objects. These newly discovered systems, and other discoveries which will soon follow them, will test critically our understanding of the processes of star- and planet-formation. We review the techniques used in these radial-velocity searches and their results to date. We then discuss planned improvements in the surveys, and the prospects for the next 20 years.  相似文献   

AN ILLUSTRATIVE STUDY ON LOCAL LANDSCAPEAND ITS LONG-TERM CHANGES BASED ON IKONOS AND HISTORICAL AERIAL PHOTO   总被引：2，自引：0，他引：2  

RUANRen-zong ErieCELLISt 《中国地理科学(英文版)》2004,14(2):162-169

Nowadays, the research works on landscape at fine scales using high-resolution images are uncommon.This research is based on the analysis of the combination of remote sensing data (1KONOS imagery acquired in 2002 and historical aerial photo taken in 1942). In the paper, the ecotopes in Qiujiadou and Xishao villages in Yixing City of Jiangsu Province in 1942 and 2002 were compared and landscape changes as well as the causes of the considerable changes were analyzed. It was found that the ecotope changes were at greater level in some aspects such as water surface and perennial vegetation coverage etc. This study at fine scale is globally significant for the rural areas, especially for the subsistence agricultural land, which occupies larger percentage in the earth. And it analyzes the structure of landscape based on a new landscape classification system--stratifications method.  相似文献   

The MPE X-ray test facility PANTER: Calibration of hard X-ray (15–50 kev) optics     

M. J. Freyberg  H. Bräuninger  W. Burkert  G. D. Hartner  O. Citterio  F. Mazzoleni  G. Pareschi  D. Spiga  S. Romaine  P. Gorenstein  B. D. Ramsey 《Experimental Astronomy》2005,20(1-3):405-412

The Max-Planck-Institut für extraterrestrische Physik (MPE) in Garching, Germany, uses its large X-ray beam line facility PANTER for testing X-ray astronomical instrumentation. A number of telescopes, gratings, filters, and detectors, e.g. for astronomical satellite missions like Exosat, ROSAT, Chandra (LETG), BeppoSAX, SOHO (CDS), XMM-Newton, ABRIXAS, Swift (XRT), have been successfully calibrated in the soft X-ray energy range (< 15keV). Moreover, measurements with mirror test samples for new missions like ROSITA and XEUS have been carried out at PANTER. Here we report on an extension of the energy range, enabling calibrations of hard X-ray optics over the energy range 15–50 keV. Several future X-ray astronomy missions (e.g., Simbol-X, Constellation-X, XEUS) have been proposed, which make use of hard X-ray optics based on multilayer coatings. Such optics are currently being developed by the Osservatorio Astronomico di Brera (OAB), Milano, Italy, and the Harvard-Smithsonian Center for Astrophysics (CfA), Cambridge, MA, USA. These optics have been tested at the PANTER facility with a broad energy band beam (up to 50 keV) using the XMM-Newton EPIC-pn flight spare CCD camera with its good intrinsic energy resolution, and also with monochromatic X-rays between C-K (0.277 keV) and Cu-Kα (8.04 keV). PACS: 95.55.Ka, 95.55.Aq, 41 50.+h, 07.85.Fv  相似文献