Two-dimensional pH distributions and dynamics in bioturbated marine sediments   总被引：2，自引：0，他引：2  

Qingzhi Zhu  Yanzhen Fan 《Geochimica et cosmochimica acta》2006,70(19):4933-4949

The seafloor is the site of intense biogeochemical and mineral dissolution-precipitation reactions which generate strong gradients in pH near the sediment-overlying water interface. These gradients are usually measured in one-dimension vertically with depth. Two-dimensional pH distributions in marine sediments were examined at high resolution (65 × 65 μm pixel) and analytical precision over areas of ∼150 to 225 cm² using a newly developed pH planar fluorosensor. Dramatic three-dimensional gradients, complex heterogeneity, and dynamic changes of pH occur in the surficial zone of deposits inhabited by macrofauna. pH can vary by ±2 units horizontally as well as vertically over millimeter scales. pH minima zones often form in association with redoxclines within a few millimeters of inner burrow walls, and become more pronounced with time if burrows remain stable and irrigated for extended periods. Microenvironmental pH minima also form locally around decaying biomass and relict burrow tracks, and dissipate with time (∼5 d). H⁺ concentrations and fluxes in sandy mud show complex acid-base reaction distributions with net H⁺ fluxes around burrows up to ∼12 nmol cm⁻² d⁻¹ and maximum net reaction rates varying between −90 (consumption) to 120 (production) μM d⁻¹ (∼90 nmol cm⁻¹ d⁻¹ burrow length). Acid producing zones that surround irrigated burrows are largely balanced by acid titration zones along inner burrow walls and outer radial boundaries. The geometry and scaling of pH microenvironments are functions of diagenetic reaction rates and three-dimensional transport patterns determined by sediment properties, such as diffusive tortuosity, and by benthic community characteristics such as the abundance, mobility, and size of infauna. Previously, undocumented biogeochemical phenomena such as low pH regions associated with in-filled relict biogenic structures and burrowing tracks are readily demonstrated by two-dimensional and time-dependent images of pH and sedimentary structure.  相似文献   

Increasing critical sensitivity of the Load/Unload Response Ratio before large earthquakes with identified stress accumulation pattern   总被引：2，自引：0，他引：2  

Huai-zhong Yu  Zheng-kang Shen  Yong-ge Wan  Qing-yong Zhu  Xiang-chu Yin   《Tectonophysics》2006,428(1-4):87-94

The Load/Unload Response Ratio (LURR) method is proposed for short-to-intermediate-term earthquake prediction [Yin, X.C., Chen, X.Z., Song, Z.P., Yin, C., 1995. A New Approach to Earthquake Prediction — The Load/Unload Response Ratio (LURR) Theory, Pure Appl. Geophys., 145, 701–715]. This method is based on measuring the ratio between Benioff strains released during the time periods of loading and unloading, corresponding to the Coulomb Failure Stress change induced by Earth tides on optimally oriented faults. According to the method, the LURR time series usually climb to an anomalously high peak prior to occurrence of a large earthquake. Previous studies have indicated that the size of critical seismogenic region selected for LURR measurements has great influence on the evaluation of LURR. In this study, we replace the circular region usually adopted in LURR practice with an area within which the tectonic stress change would mostly affect the Coulomb stress on a potential seismogenic fault of a future event. The Coulomb stress change before a hypothetical earthquake is calculated based on a simple back-slip dislocation model of the event. This new algorithm, by combining the LURR method with our choice of identified area with increased Coulomb stress, is devised to improve the sensitivity of LURR to measure criticality of stress accumulation before a large earthquake. Retrospective tests of this algorithm on four large earthquakes occurred in California over the last two decades show remarkable enhancement of the LURR precursory anomalies. For some strong events of lesser magnitudes occurred in the same neighborhoods and during the same time periods, significant anomalies are found if circular areas are used, and are not found if increased Coulomb stress areas are used for LURR data selection. The unique feature of this algorithm may provide stronger constraints on forecasts of the size and location of future large events.  相似文献   

Indium Enrichment in the Meng'entaolegai Ag-Pb-Zn Deposit, Inner Mongolia, China   总被引：3，自引：0，他引：3  

Qian Zhang    Xiaoqing Zhu    Yuliang He  Junjie Jiang  Dapeng Wang 《Resource Geology》2006,56(3):337-346

Abstract. The Meng'entaolegai In-rich Ag-Pb-Zn deposit is located in the eastern part of Inner Mongolia. It is one of the In-richest deposits in China. Large amounts of quartz and sulfide minerals constitute a hydrothermal quartz-sulfide vein deposit within a Hercynian acidic granite massif, which occupies an area of about 400 km². Thirty-six orebodies, controlled strictly by the E-W trend faults, are found in the orefield of 6 km in length from east to west and 200 to 1,000 m in width from south to north. The ore minerals are mainly galena, sphalerite and pyrite, and subordinate chalcopyrite, arsenopyrite, cassiterite and stannite with many Ag-minerals. The gangue minerals are mainly quartz, calcite, sericite and chlorite. Economic components of the deposit are dominated by Pb andZn (reserves of Pb and Zn are 0.17 Mt and 0.37 Mt, and their grades are 1 % and 2.3 %, respectively), with Ag, Sn, In and Cd (1,800 t Ag, >2,000 t Sn, >500 t In and 1,800 t Cd) as by-products. Indium is highly enriched in ores and its contents are 9 to 295 ppm in ores and 85 to 2,660 ppm in sphalerite. Analytical results show that the ore-forming fluid of this deposit contains 0.8–3.5 ppm In and 4–36 ppm Sn, and the two elements show a very good positive correlation with a correlation coefficient of 0.8672, while the correlation between In and Zn in the ore-forming fluids, with a correlation coefficient of 0.5723, is not as good as that between In and Sn. This indicates that indium has an affinity with tin in the ore-forming fluids. The authors think that this is probably the main reason why those In-rich deposits spread over the world are simultaneously enriched in tin.  相似文献   

城乡边缘带时空离心推移的约束及其方法     

龚兆先  温春阳  周永章 《热带地理》2006,26(2):129-133

分析了城乡边缘带时空离心推移的驱动力,认为必须而且可以对离心推移进行适当约束,以促进城乡边缘带的可持续发展;分析了离心推移的约束机制及约束的基本方式,提出了约束的主要原则和主要方法。  相似文献   

萨拉乌苏河流域萨拉乌苏组沙丘砂沉积特征   总被引：7，自引：1，他引：7  

欧先交  李保生  靳鹤龄  吴正  温小浩  董光荣  曾兰华  欧阳椿陶  杨艺  刘宇飞 《地理学报》2006,61(9):965-975

萨拉乌苏河流域米浪沟湾剖面萨拉乌苏组含7层古流动沙丘砂、4层古固定-半固定沙丘砂.对这些沙丘砂的沉积构造观察以及粒度、扫描电镜和常量化学元素分析结果表明：（1）这些沙丘砂具有与现代沙丘砂相似的风成沉积构造特征;（2）粒度及其参数——Mz、σ、Sk和Kg,以及主要化学组分SiO2、Al2O3和TOFE也与现代沙丘砂相近;（3）Mz-σ、SiO2-Al2O3＋TOFE散点图和概率累积曲线显示这些沙丘砂与萨拉乌苏组中的河湖相、古土壤差别明显,而与现代沙丘砂一致;（4）石英砂颗粒具有良好的磨圆以及碟形坑、新月形坑、麻坑、上翻解理薄片、硅质沉淀和硅质裂纹等表面结构特征,反映其曾受持久的风力搬运作用.沉积构造、粒度、石英砂颗粒表面结构和化学元素等多个方面具备了与现代沙丘砂类似的风成特征,证明这些沙丘砂的成因是风成的.  相似文献   

高校自然地理实践教学改革探讨   总被引：7，自引：0，他引：7  

文星跃  董廷旭 《福建地理》2006,21(2):135-137

从现代自然地理学综合性和应用性的特点出发,结合自然地理教学现状,分析了自然地理实践教学改革的必要性。阐述了加强实践教学应遵循的基本原则。提出了改革的主要途径,即调整课程内容,优化自然地理课程体系;创新实践教学手段和方法;营造良好的学术氛围和加强横向科研合作。  相似文献   

Comparison of methods to model the gravitational gradients from topographic data bases   总被引：7，自引：0，他引：7  

Christopher Jekeli  Lizhi Zhu 《Geophysical Journal International》2006,166(3):999-1014

A number of methods have been developed over the last few decades to model the gravitational gradients using digital elevation data. All methods are based on second-order derivatives of the Newtonian mass integral for the gravitational potential. Foremost are algorithms that divide the topographic masses into prisms or more general polyhedra and sum the corresponding gradient contributions. Other methods are designed for computational speed and make use of the fast Fourier transform (FFT), require a regular rectangular grid of data, and yield gradients on the entire grid, but only at constant altitude. We add to these the ordinary numerical integration (in horizontal coordinates) of the gradient integrals. In total we compare two prism, two FFT and two ordinary numerical integration methods using 1" elevation data in two topographic regimes (rough and moderate terrain). Prism methods depend on the type of finite elements that are generated with the elevation data; in particular, alternative triangulations can yield significant differences in the gradients (up to tens of Eötvös). The FFT methods depend on a series development of the topographic heights, requiring terms up to 14th order in rough terrain; and, one popular method has significant bias errors (e.g. 13 Eötvös in the vertical–vertical gradient) embedded in its practical realization. The straightforward numerical integrations, whether on a rectangular or triangulated grid, yield sub-Eötvös differences in the gradients when compared to the other methods (except near the edges of the integration area) and they are as efficient computationally as the finite element methods.  相似文献   

Dissolved trace elements in river water: spatial distribution and the influencing factor, a study for the Pearl River Delta Economic Zone, China   总被引：1，自引：0，他引：1  

T. P. Ouyang  Z. Y. Zhu  Y. Q. Kuang  N. S. Huang  J. J. Tan  G. Z. Guo  L. S. Gu  B. Sun 《Environmental Geology》2006,49(5):733-742

Twenty-nine water samples were collected from different river channels of the Pearl River Delta Economic Zone, China. An inductively coupled plasma-mass spectromonitor (ICP-MS) was used to measure concentrations of the trace elements in these samples. The results suggest that the average concentrations of rare earth elements in river water show an increasing trend from the West River, the North River, the rivers of the Pearl River Delta, and the Shenzhen River to the East River. Relatively high concentrations of heavy metals appear in the East River, the rivers of the Pearl River Delta and the Shenzhen River, while the West River and the North River have relatively low heavy metal concentrations. Trace element concentrations in samples collected near urban or industrial areas are much higher than those of samples collected from distant areas, away from urban and industrial areas. After natural conditions, human activities have significant influence on the trace element concentrations in river water. This trace element concentration’s spatial distribution in the river water from the Pearl River Delta Economic Zone is actually an integrated effect of natural conditions and human activity.  相似文献   

Energy transfer among Pb, Ce and Mn in fluorescent calcite from Kuerle, Xinjiang, China     

Aierken Sidike  X.-M. Wang  Alifu Sawuti  H.-J. Zhu  I. Kusachi  N. Yamashita 《Physics and Chemistry of Minerals》2006,33(8-9):559-566

Natural calcite from Kuerle, Xinjiang, China, shows orange-red fluorescence when exposed to short-wave ultraviolet (UV) light (Hg 253.7 nm). Photoluminescence (PL) emission and excitation spectra of the calcite are observed at room temperature in detail. The PL emission spectrum under 208 nm excitation consists of three bands: two UV bands at 325 and 355 nm and an orange-red band at 620 nm. The three bands are ascribed to Pb²⁺, Ce³⁺ and Mn²⁺, respectively, as activators. The Pb²⁺ excitation band is observed at 243 nm, and the Ce³⁺ excitation band at 295 nm. The Pb²⁺ excitation band is also observed by monitoring the Ce³⁺ fluorescence, and the Pb²⁺ and Ce³⁺ excitation bands, in addition to six Mn²⁺ excitation bands, are also observed by monitoring the Mn²⁺ fluorescence. These indicate that four types of the energy transfer can occur in calcite through the following processes: (1) Pb²⁺ → Ce³⁺, (2) Pb²⁺ → Mn²⁺, (3) Ce³⁺ → Mn²⁺ and (4) Pb²⁺ → Ce³⁺ → Mn²⁺.  相似文献   

塔里木盆地东河砂岩沉积和储层特征及综合分析   总被引：21，自引：0，他引：21  

贾进华  张宝民  朱世海  朱运成  李占银 《古地理学报》2006,8(3):339-352

东河砂岩是一套海侵初期的沉积产物，东河砂岩不是一个等时沉积体，相当于晚泥盆世晚期至早石炭世早期沉积，具体沉积时间各地有差异。由于东河砂岩是覆盖广泛的海侵初期沉积，因此具有海侵初期填平补齐的特征，其沉积相决定于海侵的速度、沉积物的供给和海侵前的古地貌。塔北地区受塔北古隆起的阻挡，海水在古隆起周围滞留时间较长，又有较粗粒的物源供给，其沉积产物主要是滨岸海滩沉积；塔中地区由于地形复杂，沉积类型也比较复杂，底部砾岩段有河流相沉积，而块状砂岩段和砂砾岩段有河口湾和滨岸海滩沉积，不同段在成分、分选性和粒级上有较大的差异；而其它低平地区主要是海侵期快速的滨岸和陆架沉积。受沉积因素影响，东河砂岩有效储层的分布具有地域性；除沉积因素外，低的地温梯度和短期的深埋藏是优质储层发育的重要控制因素。  相似文献