Vein graphite deposits: geological settings,origin, and economic significance   总被引：1，自引：0，他引：1  

F. J. Luque  J-M. Huizenga  E. Crespo-Feo  H. Wada  L. Ortega  J. F. Barrenechea 《Mineralium Deposita》2014,49(2):261-277

Graphite deposits result from the metamorphism of sedimentary rocks rich in carbonaceous matter or from precipitation from carbon-bearing fluids (or melts). The latter process forms vein deposits which are structurally controlled and usually occur in granulites or igneous rocks. The origin of carbon, the mechanisms of transport, and the factors controlling graphite deposition are discussed in relation to their geological settings. Carbon in granulite-hosted graphite veins derives from sublithospheric sources or from decarbonation reactions of carbonate-bearing lithologies, and it is transported mainly in CO₂-rich fluids from which it can precipitate. Graphite precipitation can occur by cooling, water removal by retrograde hydration reactions, or reduction when the CO₂-rich fluid passes through relatively low-fO₂ rocks. In igneous settings, carbon is derived from assimilation of crustal materials rich in organic matter, which causes immiscibility and the formation of carbon-rich fluids or melts. Carbon in these igneous-hosted deposits is transported as CO₂ and/or CH₄ and eventually precipitates as graphite by cooling and/or by hydration reactions affecting the host rock. Independently of the geological setting, vein graphite is characterized by its high purity and crystallinity, which are required for applications in advanced technologies. In addition, recent discovery of highly crystalline graphite precipitation from carbon-bearing fluids at moderate temperatures in vein deposits might provide an alternative method for the manufacture of synthetic graphite suitable for these new applications.  相似文献   

Geochemistry and petrogenesis of carbonatites from South Nam Xe,Lai Chau area,northwest Vietnam     

Thuy Nguyen Thi  Hideki Wada  Tsuyoshi Ishikawa  Taketo Shimano 《Mineralogy and Petrology》2014,108(3):371-390

This paper presents a study of the petrography, mineral chemistry, geochemistry, and Sr–Nd–Pb–C–O isotope systematics of carbonatite dykes and associated rocks from the northeastern part of the Song Da intracontinental rift in South Nam Xe (northwest Vietnam) aimed at constraining the origin of the carbonatite magmas. The carbonatites are characterized by SiO₂ < 12.18 wt.% and by wide ranges in FeO, MgO and CaO content that define them as calciocarbonatite and ferrocarbonatite. On U–Th–Pb isochron diagrams, whole rocks and mineral separates from the ferrocarbonatites form linear arrays corresponding to ages of 30.2–31.6 Ma (Rupelian, Oligocene). The South Nam Xe carbonatites are extremely enriched in Sr, Ba, and light rare earth elements (LREE), and depleted in high field strength elements (HFSE) (e.g. Ti, Nb, Ta, Zr and Hf). The age–corrected Sr–Nd–Pb isotope ratios and C isotope data are relatively uniform (⁸⁷Sr/⁸⁶Sr_(t) = 0.708193–0.708349; ¹⁴³Nd/¹⁴⁴Nd_(t) = 0.512250–0.512267; ε_Nd(t) = ?6.46 to ?6.80; ²⁰⁶Pb/²⁰⁴Pb_(t) = 18.26–18.79; ²⁰⁷Pb/²⁰⁴Pb_(t) = 15.62–15.64; ²⁰⁸Pb/²⁰⁴Pb_(t) = 38.80–39.38; δ¹³C_V-PDB = –2.7?‰ to ?4.1?‰). These isotopic compositions indicate source contamination that occurred before the production of the carbonatite magmas, and did not change noticeably during or after emplacement. The variation in oxygen isotopes is consistent with the change in mineral compositions and trace element abundances: the lower δ¹⁸O values (9.1–11.0?‰) coupled with Sr-rich, Mn-poor calcite, and igneous textures such as triple junctions among calcite grain boundaries, define a magmatic origin. However, the elevated δ¹⁸O values of the ferrocarbonatites (12.0–13.3?‰) coupled with a volatile-bearing mineral assemblages (including REE fluorcarbonates, sulfates, sulfides and fluorite) may be due to interaction with meteoric water during low-temperature alteration. High δ¹³C values and Sr–Pb ratios, and low Rb/Sr (0.00014–0.00301), Sm/Nd (0.089–0.141) and ¹⁴³Nd/¹⁴⁴Nd ratios, coupled with very high Sr-Nd concentrations, suggest the involvement of an enriched mantle component, which probably resulted from metasomatism due to the migration of subducted material. Because of the lack of tectonic data and the limited number of samples studied, this conclusion is still ambiguous and requires further study.  相似文献   

Numerical simulation of impact cratering on granular material   总被引：1，自引：0，他引：1  

Koji Wada  Hiroki Senshu 《Icarus》2006,180(2):528-545

A new numerical code based on the Distinct Element Method (DEM) is developed to study the impact cratering processes on granular material. This code has a potential advantage to simulate the cratering process on granular material, since the movement of discrete particles can be treated. To show the physical plausibility of this code, we conduct 3-D numerical simulations of vertical impact into granular material targets that consist of 384,000 particles, and compare the results with those from experimental studies. It is shown that the excavation stage of cratering derived from experimental studies is represented well by our simulation: the size of the crater cavity, and the ejecta velocity and angle distributions are consistent with those obtained in laboratory experiments. The impact simulation code developed in this study is thus suggested to be useful for the analysis of the impact cratering process on granular material.  相似文献   

Gaetice depressus (Crustacea,Varunidae): Species profile and its role in organic carbon and nitrogen flow     

Wahyudi  A’an. J.  Wada  Shigeki  Aoki  Masakazu  Hama  Takeo 《Ocean Science Journal》2015,50(2):389-401

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The ultraviolet spectra of carbonaceous chondrites     

T. Inagaki  S. Yabushita  K. Wada 《Celestial Mechanics and Dynamical Astronomy》1992,54(1-3):229-231

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A quenched carbonaceous composite (QCC) grain model for the interstellar 220 NM extinction hump     

Onaka  T.  Nakada  Y.  Tanabe  T.  Sakata  A.  Wada  S. 《Astrophysics and Space Science》1986,118(1-2):411-413

The dependence of the wavelength of peak absorption of dust grains on the grain size is investigated analytically by using an oscillator model for the absorption band. The peak wavelength of a weak absorption band is much less sensitive to the grain size than that of a strong band. This is explained by the fact that the surface mode, which is excited in the strong absorption band, is not raised in the weak absorption band. A quenched carbonaceous composite (QCC) synthesized from hydrocarbon plasma is found to have a weak absorption band at 220 nm. The absorption peak wavelength of the QCC grains falls well in the range of 217±7 nm even if the grain size runs from 5 to 100 nm. This is compatible with the observed constancy of the 220 nm hump (217±5 nm). By contrast, the absorption peak of graphite grains, which have a strong band around 280 nm and have been investigated as candidates for the hump, is very sensitive to the grain size. A quite narrow range of the grain size is required to account for the observed 220 nm feature. A weak absorption model, such as the QCC grains, is suggested to be a more likely candidate for the 220 nm extinction hump than a strong absorption model, such as graphite grains.Paper presented at the IAU Third Asian-Pacific Regional Meeting, held in Kyoto, Japan, between 30 September–6 October, 1984.  相似文献   

Possible solar neutron events recorded by the ground-based neutron monitor     

Yoshimori  M.  Takahashi  K.  Wada  M.  Kusunose  M.  Kondo  I. 《Solar physics》1987,113(1-2):319-325

Solar Physics - Possible solar neutron emission associated with five SMM gamma-ray events on 7 June 1980, 21 June 1980, 6 November 1980, 26 November 1982 and 25 April 1984 was found from analysis...  相似文献   

The infrared and ultraviolet absorptions of micro-organisms and their relation to the Hoyle-Wickramashinghe hypothesis     

Shin Yabushita  Kazuhiro Wada 《Astrophysics and Space Science》1985,110(2):405-411

Absorption of yeast andE. coli in the infrared and ultraviolet regions and that of diatomaceous soil in the infrared region have been obtained. Electron microscope photographs of aggregates ofE. coli have also been obtained. These results are discussed in relation to the Hoyle-Wickramasinghe hypothesis regarding the nature of interstellar grains.Department of Nuclear Engineering  相似文献   

The ultraviolet spectra of thin evaporated films of carbonaceous chondrite     

T. Inagaki  S. Yabushita  K. Wada  E. T. Arakawa 《Astrophysics and Space Science》1993,206(1):111-117

Absorption spectra in the visible to the near ultraviolet were measured on the Belgica chondrite B-7904 in a form of thin solid film made by the vacuum evaporation. The spectra obtained exhibit a sharp peak at 226 nm and a broad bump around 280nm. These features were found arising from the meteorite component FeS (troilite). The peak at 226 nm shows a doublet structure with the band-width considerably narrower than the 217.5 nm feature in the interstellar extinction. The absorption spectra obtained previously with the pulverized chondrites suspended in a liquid were also found reproducible by the pulverized FeS.Sponsored by the Office of Health and Environmental Research, U.S. Department of Energy under contract DE-AC05-840R21400 with Martin Marietta Energy Systems, Inc.  相似文献   

Seismicity changes related to a water injection experiment in the Nojima Fault Zone   总被引：2，自引：0，他引：2  

Keiichi Tadokoro  Kin'Ya Nishigami  Masataka Ando  Naoshi Hirata  Takashi Iidaka  Yukihiro Hashida  Kunihiko Shimazaki  Shiro Ohmi  Yasuyuki Kano  Makoto Koizumi  Shigemitsu Matsuo  Hiroo Wada 《Island Arc》2001,10(3-4):235-243

Abstract A water injection experiment was carried out by the scientific drilling program named the 'Nojima Fault Zone Probe' during the two periods 9–13 February and 16–25 March 1997. The pumping pressure at the surface was approximately 4 MPa. The total amount of injected water was 258 m³. The injection was made between depths of 1480 m and 1670 m in the Disaster Prevention Research Institute, Kyoto University (DPRI) 1800 m borehole drilled into the Nojima Fault zone. A seismic observation network was deployed to monitor seismic activity related to the water injections. Seismicity suddenly increased in the region not far from the injection hole 4 or 5 days after the beginning of each water injection. These earthquakes were likely to be induced by the water injections. Most of the earthquakes had magnitudes ranging from −2 to +1. Numerous earthquakes occurred during the first injection, but only one could be reliably located and it was approximately 2 km north of the injection site. Between the two injection periods, earthquakes concentrated in the region approximately 1 km northwest of the injection site. During and after the second injection experiment, earthquakes were located approximately 1.5 km west of the injection site. Those earthquakes were located approximately 3 km or 4 km from the injection point and between 2 km and 4 km in depth. Values of intrinsic permeability of 10⁻¹⁴–10⁻¹⁵ m² were estimated from the time lapse of the induced seismic activity. The coefficient of friction in the area where the induced earthquakes occurred was estimated to be less than 0.3.  相似文献