Oil-generation kinetics for organic facies with Type-II and -IIS kerogen in the Menilite Shales of the Polish Carpathians     

M.D. Lewan  M.J. Kotarba  D. Wi?c?aw 《Geochimica et cosmochimica acta》2006,70(13):3351-3368

The Menilite Shales (Oligocene) of the Polish Carpathians are the source of low-sulfur oils in the thrust belt and some high-sulfur oils in the Carpathian Foredeep. These oil occurrences indicate that the high-sulfur oils in the Foredeep were generated and expelled before major thrusting and the low-sulfur oils in the thrust belt were generated and expelled during or after major thrusting. Two distinct organic facies have been observed in the Menilite Shales. One organic facies has a high clastic sediment input and contains Type-II kerogen. The other organic facies has a lower clastic sediment input and contains Type-IIS kerogen. Representative samples of both organic facies were used to determine kinetic parameters for immiscible oil generation by isothermal hydrous pyrolysis and S₂ generation by non-isothermal open-system pyrolysis. The derived kinetic parameters showed that timing of S₂ generation was not as different between the Type-IIS and -II kerogen based on open-system pyrolysis as compared with immiscible oil generation based on hydrous pyrolysis. Applying these kinetic parameters to a burial history in the Skole unit showed that some expelled oil would have been generated from the organic facies with Type-IIS kerogen before major thrusting with the hydrous-pyrolysis kinetic parameters but not with the open-system pyrolysis kinetic parameters. The inability of open-system pyrolysis to determine earlier petroleum generation from Type-IIS kerogen is attributed to the large polar-rich bitumen component in S₂ generation, rapid loss of sulfur free-radical initiators in the open system, and diminished radical selectivity and rate constant differences at higher temperatures. Hydrous-pyrolysis kinetic parameters are determined in the presence of water at lower temperatures in a closed system, which allows differentiation of bitumen and oil generation, interaction of free-radical initiators, greater radical selectivity, and more distinguishable rate constants as would occur during natural maturation. Kinetic parameters derived from hydrous pyrolysis show good correlations with one another (compensation effect) and kerogen organic-sulfur contents. These correlations allow for indirect determination of hydrous-pyrolysis kinetic parameters on the basis of the organic-sulfur mole fraction of an immature Type-II or -IIS kerogen.  相似文献   

T -distributed Random Fields: A Parametric Model for Heavy-tailedWell-log Data1     

Jo R?islien  Henning Omre 《Mathematical Geology》2006,38(7):821-849

Histograms of observations from spatial phenomena are often found to be more heavy-tailed than Gaussian distributions, which makes the Gaussian random field model unsuited. A T-distributed random field model with heavy-tailed marginal probability density functions is defined. The model is a generalization of the familiar Student-T distribution, and it may be given a Bayesian interpretation. The increased variability appears cross-realizations, contrary to in-realizations, since all realizations are Gaussian-like with varying variance between realizations. The T-distributed random field model is analytically tractable and the conditional model is developed, which provides algorithms for conditional simulation and prediction, so-called T-kriging. The model compares favourably with most previously defined random field models. The Gaussian random field model appears as a special, limiting case of the T-distributed random field model. The model is particularly useful whenever multiple, sparsely sampled realizations of the random field are available, and is clearly favourable to the Gaussian model in this case. The properties of the T-distributed random field model is demonstrated on well log observations from the Gullfaks field in the North Sea. The predictions correspond to traditional kriging predictions, while the associated prediction variances are more representative, as they are layer specific and include uncertainty caused by using variance estimates.  相似文献   

Late Early Miocene lake deposits near Mauensee, central Switzerland: Fish fauna (otoliths, teeth), accompanying biota and palaeoecology     

Jürg Jost  Daniel K?lin  Tanja Schulz-Mirbach  Bettina Reichenbacher 《Eclogae Geologicae Helvetiae》2006,99(3):309-326

  相似文献   

REE/trace element characteristics of sandstone-type uranium deposits in the Ordos Basin     

凌明星  杨晓勇  孙卫  苗建宇  刘池阳 《中国地球化学学报》2006,25(4):355-365

1 Introduction The Ordos Basin is the second largest sedimentary basin in China. During the last 10 years, a great progress has been achieved in the aspects of tectonic evolution, dynamics process, inner and outer geological processes during Mesozoic-Cen…  相似文献   

深层地震勘探激发井深探讨     

HUANG Ling YANG Guang-da HAN Li-guo .Geophysical Exploration Company of Jilin Petroleum Group Co.  Ltd  Songyuan  China .Jilin Petroleum Group Company  Songyuan    China .College of GeoExploration Science  Technology  Jilin University  Changchun  China 《吉林大学学报(地球科学版)》2006,(Z2)

深层地震勘探野外资料采集的关键是在保证原始资料一定信噪比的基础上,同时兼顾分辨率,激发井深是决定资料品质的重要因素之一。通过对虚反射滤波作用分析,提出了充分利用虚反射能量设计最佳激发井深,增强下传地震波能量的采集方法。理论分析和试验资料表明,在高速层下4～7m的最佳激发岩性深度是深层勘探的理想井深。  相似文献   

基于GIS的供电台区经营综合评价     

王玲  边馥苓 《测绘信息与工程》2005,30(6):32-33

探讨了运用GIS技术对供电台区经营综合评价的实现方法,选取了业务属性和空间属性两个方面评价因子,介绍了从系统软硬件、评价实现过程及显示结果等方面评价过程的具体技术实现。  相似文献   

云南中甸五村-移山晚三叠世沉积及盆地特征   总被引：6，自引：0，他引：6  

尹光侯  刘星  邓志祥  肖玲 《云南地质》2005,24(1):58-66

五村-移山地区晚三叠世地层发育齐全，并在中咱地块边缘至甘孜-理塘结合带之间构成一个较为完整的沉积盆地。中甸、格咱和弥里淌三条平行控制性断裂将盆地由西向东依次横向分割成中咱微大陆五村台地边缘三角洲、哈工弧后断陷盆地、属都火山复理石盆地和尼汝弧前斜坡(盆地)。在上述4种构造-相区中沉积了各具特色的沉积物，具有不同基本层序结构、不同生物组合及沉积相特征。显示盆地经历下降-抬升-下降-抬升两个周期性演化过程。  相似文献   

韧性剪切变形对岩石地球化学行为的制约——以北阿尔金巴什考供韧性剪切带为例   总被引：6，自引：0，他引：6  

戚学祥李海兵  吴才来陈松永 《地质通报》2005,24(3):252-257

韧性剪切变形对岩石地球化学行为的制约一直是地质学家们探讨的课题。本文以构成北阿尔金红柳沟——拉配泉俯冲碰撞杂岩带与北阿尔金地块边界的巴什考供斜向逆冲型韧性剪切带为例，通过对韧性剪切带内花岗岩变形前后不同变形强度构造岩的地球化学组成进行对比，确定等比线斜率，探讨韧性变形对岩石体积和成分变异的影响。计算结果表明，在糜棱岩化过程中，糜棱岩化花岗岩体积亏损21％，花岗质糜棱岩体积亏损31％。质量平衡计算结果和等比线图表明，韧；陛剪切作用导致SiO2，流失量最大，A12O3、K2O及Ba、Rb、Sr等都有不同程度的丢失，显示出较强的活动性，MnO、P2O5、Sc位于等比线上或附近，表现出相对的稳定性。岩石中活动组分的变异是流体渗滤作用引起的，不活动组分的变异是体．积亏损造成的。  相似文献   

鄂尔多斯盆地的三维可视化及其应用     

邹永玲  韩玲  杜子涛  丁辉 《现代测绘》2005,28(4):35-36

地形三维可视化作为测绘行业的一项新技术正处于蓬勃发展阶段。本文以鄂尔多斯盆地为例，着重介绍了基于ARCGIS9．0的三维可视化建库、实现过程，并指出其在矿产勘探中的具体应用。  相似文献   

大气污染物SO_x输送方程的尺度分析   总被引：5，自引：1，他引：5  

程新金  黄美元  安峻岭  王自发  徐华英  周玲  肖辉 《气象学报》2002,60(4):468-476

文中用量纲分析方法分析了控制大气污染物输送方程的动力学特性。提出了 6种反映大气污染物输送过程中各种动力、物理和化学过程相对重要性的动力学参数。并以硫氧化物为例进行了各参数量级大小分析 ,尤其对 3种起汇作用 (去除机理 )的机理 (化学转化、干沉降和湿清除 )在不同尺度大气污染过程中的作用进行了详细分析。结果表明 :在一般情况下 ,SO2 的气相化学作用小于干沉降和湿清除的作用 ;干沉降作用很依赖于模式最底层厚度的选取 ;在有降雨时湿清除作用一般较大。文中还对大气污染物SOx 输送方程各项特征量的量级作了分析对比 ,得出了控制不同尺度大气污染物输送过程的零级近似方程和一级近似方程 ,并指出了这些方程的基本特征  相似文献