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The microbial transformation of typical tar oil compounds such as acridine, benzo(b)thiophene, dibenzofuran, indane, and indene under different redox conditions was investigated in microcosm studies. Under aerobic conditions the inherent contamination in polluted soil as well as the added N‐, S‐, O‐ heterocyclic and homocyclic compounds were transformed predominantly apart from thiophene. 1‐Indanone was detected by RP‐HPLC‐DAD and GC‐MS as an intermediate metabolite from indane and indene. Under nitrate and sulfate reducing conditions indane, benzo(b)thiophene, and dibenzofuran were transformed in assays with the polluted soil samples from well B 65 and B 66 within 426 days, whereas they were persistent in assays with the highly polluted soil B 67. All heterocyclic and homocyclic compounds added to the non‐contaminated soil from well B 85 were not degraded under nitrate and sulfate reducing conditions, too. The results indicate that for the decision, wether natural attenuation can be implemented in the remediation of contaminated site, in addition to BTEX and PAHs especially the fate of further tar oil compounds in anoxic aquifers has to be considered.  相似文献   
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Rasid  Harun  Haider  Wolfgang 《Natural Hazards》2003,28(1):101-129
A maximum difference conjoint (MDC) model was part of a questionnaire toassess floodplain residents' preferences for the outcomes of water level managementinside an enclosed embankment system on the left bank of the Dhaleswari River, calledthe Compartmentalization Pilot Project (CPP)-Tangail. The outcomes were described as(a) varied flood depths in the rice field, (b) incidence of flooding on the courtyard andinside homes, (c) changes in floodplain and culture fisheries, and (d) varied conditionsof drainage congestion. Following a standard survey, the respondents from inside andoutside a completed section of the compartment (Cluster 1b) were shown profiles of these flood management outcomes and were asked to indicate for each profile the one most preferred and the one least preferred item. The results of the study indicated that the respondents had a clear preference for preventing flooding of their homes and courtyards and for an ideal water depth of 2 ft in the aman rice fields. At the same time, they also showed a strong concern about malfunctioning of sluices and to a lesser extent about the changes in the fish habitat. The successful application of the MDC as an approach to model tradeoffs among rural residents of Bangladesh shows that a relatively complex quantitative survey method, incorporating choice cards as pictograms, can be applied successfully even in a developing country.  相似文献   
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The Kärlich–Seeufer archaeological site in Germany's central Rhineland was excavated between 1980 and 1992. The site provides evidence for hominid activity during a Middle Pleistocene interglaciation known up to now only from the Kärlich clay pit and therefore defined as the Kärlich Interglaciation, which is considered to be post-Cromer IV and pre-Holstein (sensu stricto) in age. The site is characterized by Acheulean artifacts, a fauna dominated byElephas (Palaeoloxodon) antiquus,and a unique and outstanding preservation of wooden and other palaeobotanical remains. Assuming all finds are associated, the site previously was interpreted as an elephant hunting camp with a wooden structure, together with wood and bone implements preservedin situ.Recent analysis of the same features has shown that the site can also be interpreted as a reworked archaeological sample. Hominid occupation occurred in the vicinity of a small lake with prevailing meso-oligotrophic conditions. Expanding boreal forests and fen vegetation characterized the landscape.  相似文献   
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We provide a reconstruction of atmospheric CO2 from deep-sea sediments, for the past 625000 years (Milankovitch chron). Our database consists of a Milankovitch template of sea-level variation in combination with a unique data set for the deep-sea record for Ontong Java plateau in the western equatorial Pacific. We redate the Vostok ice-core data of Barnola et al. (1987). To make the reconstructions we employ multiple regression between deep-sea data, on one hand, and ice-core CO2 data in Antarctica, on the other. The patterns of correlation suggest that the main factors controlling atmospheric CO2 can be described as a combination of sea-level state and sea-level change. For best results squared values of state and change are used. The square-of-sea-level rule agrees with the concept that shelf processes are important modulators of atmospheric CO2 (e.g., budgets of shelf organic carbon and shelf carbonate, nitrate reduction). The square-of-change rule implies that, on short timescales, any major disturbance of the system results in a temporary rise in atmospheric CO2.  相似文献   
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On the basis of different sets of aerial photos the dynamics of the reed bed areas of Lake Constance were investigated in relation to the dynamics of the water levels. The objectives of the study were to quantify the changes of reed areas due to different flood events in the last decades and their recovery in the time periods between these events. The results should given information of the relevance of water level variations on reed bed dynamics and the regeneration times of reed beds after extreme disturbance events.Following the extreme flood at Lake Constance in 1999 the reed belts of Lake Constance lost approximately 30 ha (24%) of the lakeside reed beds. The loss is comparable to the situation in the late 1960s, when approximately 40 ha died back due to the extreme flood in 1965 and the high spring water levels in the subsequent years. In the time period between the extreme floods of 1965 and 1999, the reed areas expanded to nearly 85% of the area before 1965. The expansion rates increased with increasing distance to the flood event of 1965. Especially in periods with series of years of low spring water level the expansion rates were high.The damage degrees of the reed areas in the years 2000 and 2002 showed a clear relation to the elevation (i.e. average water level) of the stands. The damage degree increased with decreasing elevation. Furthermore the regeneration process of severely damaged stands was related to the elevation level of the stands. Whereas stands at high elevation regenerate fast, those at low elevation died off completely in the years after the extreme flood. This supports the hypothesis that the water level flutuations play a major role in the reed dynamics of Lake Constance.As a consequence of the climate change an increase in the frequency of high spring water levels is expected. Thus, it seems unlikely that reed stands will ever expand again to the same area as before 1965.  相似文献   
37.
At T > 100°C development of thermodynamic models suffers from missing experimental data, particularly for solubilities of sulfate minerals in mixed solutions. Solubilities in Na+-K+-Ca2+-Cl-SO42−/H2O subsystems were investigated at 150, 200°C and at selected compositions at 100°C. The apparatus used to examine solid-liquid phase equilibria under hydrothermal conditions has been described.In the system NaCl-CaSO4-H2O the missing anhydrite (CaSO4) solubilities at high NaCl concentrations up to halite saturation have been determined. In the system Na2SO4-CaSO4-H2O the observed glauberite (Na2SO4 · CaSO4) solubility is higher than that predicted by the high temperature model of Greenberg and Møller (1989), especially at 200°C. At high salt concentrations, solubilities of both anhydrite and glauberite increase with increasing temperature. Stability fields of the minerals syngenite (K2SO4 · CaSO4 · H2O) and goergeyite (K2SO4 · 5 CaSO4 · H2O) were determined, and a new phase was found at 200°C in the K2SO4-CaSO4-H2O system. Chemical and single crystal structure analysis give the formula K2SO4 · CaSO4. The structure is isostructural with palmierite (K2SO4 · PbSO4). The glaserite (“3 K2SO4 · Na2SO4”) appears as solid solution in the system Na2SO4-K2SO4-H2O. Its solubility and stoichiometry was determined as a function of solution composition.  相似文献   
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Traditionally, the surveillance component of the air traffic management system has been based on radar, which consists of two separate systems: primary radar and secondary radar, which both enable the measurement of the aircraft range and bearing to the radar station. Primary radar is based on signals emitted by a ground station simply being reflected off an object and detected by a ground-based receiver. Secondary radar also emits signals, but relies upon a transponder onboard the aircraft to emit a signal itself, modulated among others by a four-digit aircraft identity (Mode A), aircraft altitude (Mode C) and/or 24-bit unique address (Mode S). Typical accuracies of secondary radar are of the order of 0.03 NM in range and 0.07° in azimuth. However, no position integrity report is provided. Air traffic density is expected to significantly increase in the future. In order to maintain or enhance air travel efficiency, while maintaining safety, more accurate surveillance systems, with the required integrity, will be required. Automatic dependent surveillance–broadcast (ADS-B) is a new aviation surveillance system, envisioned to overcome the limitations of radar and to enhance surveillance performance and thereby increase airspace capacity. However, its high dependence on external systems such as onboard navigation and communication systems also increases the number of potential points of failure. It is important to understand and mitigate these failure modes before the system can reliably be implemented. The present study emerged as an exploratory research as part of a safety assessment framework development for the ADS-B system. It reviews the ADS-B failure modes, data collection and analysis of ADS-B and its corresponding onboard GPS data. The study identifies a set of failures common to certain aircraft models, with consistent error patterns. A key failure mode was found to be associated with the navigation data from the onboard GPS. We discuss the identified failure modes and investigate the nature and causes of these failures. The findings highlight some of the deficiencies of the current ADS-B system, which will need to be addressed before the ADS-B system can reliably be implemented.  相似文献   
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