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1.
Gas Works Park, in Seattle, Washington, is located on the site of a coal and oil gasification plant that ceased operation in 1956. During operation, many types of wastes, including coal, tar, and oil, accumulated on-site. The park soil is currently (1986) contaminated with compounds such as polynuclear aromatic hydrocarbons, volatile organic compounds, trace metals, and cyanide. Analyses of water samples from a network of observation wells in the park indicate that these compounds are also present in the ground water.
Polynuclear aromatic hydrocarbons and volatile organic compounds were identified in ground water samples in concentrations as large as 200 mg/L. Concentrations of organic compounds were largest where ground water was in contact with a non-aqueous phase liquid in the soil. Where no non-aqueous phase liquid was present, concentrations were much smaller, even if the ground water was in contact with contaminated soils. This condition is attributed to weathering processes in which soluble, low-molecular-weight organic compounds are preferentially dissolved from the non-aqueous phase liquid into the ground water. Where no non-aqueous phase liquid is present, only stained soils containing relatively insoluble, high-molecular-weight compounds remain. Concentrations of organic contaminants in the soils may still remain large.  相似文献   

2.
Polycyclic aromatic hydrocarbons (PAHs) are types of hazardous contaminants, which their ingestion could cause severe consequences on human health. Leakages from storage tanks, underground pipelines, and evaporation ponds are the main sources of soil and groundwater contaminations at the Tehran Oil Refinery area (TOR site), located in south of Tehran, Iran. In this study, soil samples were collected from different locations at and adjacent to a polluted stream in the south of the refinery. The samples were analyzed for two hazardous PAH compounds, namely benzo[a]anthracene and acenaphthene. The clean up levels due to the accidental ingestion of contaminated soils at the site were also investigated in accordance to the U.S.EPA guidelines. Comparing the soil analysis results indicated that the benzo[a]anthracene concentrations in the samples varied from 53 to 299 mg/kg, which were higher than the clean up level of 1.17 mg/kg. Thus, soil remediation is required for this contaminant. The acenaphthene analysis results denoted that the average concentration of this contaminant was below the clean up level of 116.67 mg/kg, indicating that no treatment for this contaminant is necessary at the TOR site. Also, because the slope of the ground extends to the south of the stream, which stimulates the migration of the contaminants in this direction due to advection and dispersion mechanisms, the average of benzo[a]anthracene concentrations in south samples was higher than north samples (i.e., Cavg(S) = 160 ppm, Cavg(N) = 113 ppm). Various treatment techniques such as thermal desorption, soil vapor extraction (SVE), and solidification/stabilization (S/S) were investigated for this site. Due to moderate to high plasticity and relatively low permeability of the soil and low volatility of benzo[a]anthracene, however S/S method is recommended as a practical approach for the remediation of the soil at the site.  相似文献   

3.
Removal of natural free estrogens and estrogen conjugates in a municipal wastewater treatment plant (WWTP) was investigated and analyzed by GC‐MS, in which estrogen conjugates were first transformed to their corresponding free estrogens with an acid solvolysis procedure before their analysis. Natural free estrogens, E1‐3‐sulfate (E1‐3S), and E3‐3‐sulfate (E3‐3S) were detected with high concentrations in both the influent and effluent of the primary settling tank (PS), while no estrogen glucuronides were detected in any of the monitored wastewater samples. Regarding their removal efficiencies, all were almost completely removed, except for E1 with only a minor decrease. The estrogenic/androgenic removal of the same WWTP was also evaluated with estrogen receptor (androgen receptor) (ER (AR))‐binding assays, in which the removal efficiencies for E2 equivalents (EEQ) or testosterone equivalents (TEQ) were 68.5 and 72.2%. In addition, the chemically calculated EEQ from natural estrogens were about 20.6–39.3% that of the ER‐binding assay, in which E3 contributed the biggest proportion in both the influent and PS, while the calculated value of E1 increased from only 6.7% in the influent to as high as 20.6% in the effluent.  相似文献   

4.
Polyhydroxyalkanoates (PHAs), environmental friendly polyesters, can be produced by a wide range of microorganisms in nutrient‐limiting conditions. In the present study a new bacterial strain, able to produce high quantities of poly‐3‐hydroxybutyrate (PHB), is isolated from contaminated soil. The isolate is characterized and identified as Bacillus cereus Y23, based on morphological, physiological characteristics, and 16S ribosomal RNA gene sequences. PHB production is evaluated using different carbon and nitrogen sources and nutritional and culture conditions are optimized. The highest PHB production of 5.12 g L?1 was obtained in growth medium containing fructose and ammonium sulfate at a C/N ratio of 30, 0.3% yeast extract, 4.5 g L?1 phosphate solution, pH 7, inoculum size of 0.3%, and agitation rate of 150 rpm after 48 h of incubation at 32 °C. The PHB production decrement can be attributed to the intracellular utilization of the polymer during the stationary phase of the cellular growth and to the sporulation process. The presence of the main functional groups of PHB polymer is verified by Fourier‐transform infrared analysis. At optimum conditions, B. cereus Y23 turned out to be a good candidate for industrial production of PHB since it accumulates up to 67.9% of its dry weight.  相似文献   

5.
The effect of nutrient and surfactant addition on the biodegradation of phenanthrene was studied in a batch scale soil–slurry system using isolated Mycoplana sp. MVMB2strain. The study was conducted using an artificially phenanthrene spiked and as well as contaminated soil from petrochemical industrial site. Maximum phenanthrene degradation and subsequent high microbial growth were observed at optimum pH (pH 6) and C/N/P ratio (100:20:3). To investigate maximum substrate degradation potential of Mycoplana sp. MVMB2, very high concentrations of phenanthrene (50–200 mg/kg soil) were used. The organism was capable of degrading >60% for a concentration below 20 mg/kg soil and >40% for concentrations up to 200 mg/kg within 8 days. Further the influence of five different surfactants namely Span 80, Tween 20, Triton X‐100, cetyl trimethyl ammonium bromide, and sodium dodecyl sulfate were tested at their critical micelle concentration (CMC) levels for phenanthrene degradation in the soil. The addition of surfactant enhanced the biodegradation and a maximum of 84.49% was obtained for Triton X‐100. Complete phenanthrene degradation by Mycoplana sp. MVMB2 was observed at 3 CMC concentration of Triton X‐100. The optimized parameters obtained were used for the degradation of phenanthrene present in the contaminated soil and 98.6% biodegradation was obtained. Thus, the results obtained in the study suggested that biodegradation of phenanthrene by Mycoplana sp. MVMB2 appeared to be feasible to remediate phenanthrene rich contaminated sites.  相似文献   

6.
Study of the Biological Degradation of Polycyclic Aromatic Hydrocarbons in a Laboratory-scale Plant A one-stage laboratory-scale wastewater treatment plant composed of a bubble column reactor with sedimentor and sludge recycle is fed with an oil/water emulsion from a contaminated site. The oil phase is highly contaminated with polycyclic aromatic hydrocarbons (PAH). The samples are taken regularly at defined points of the treatment plant (influent, reactor, return sludge, effluent). The analysis of PAH is performed by HPLC. We can show that all analysed PAH including the poorly degradable carcinogenic substances such as benzo[a]pyrene are biologically transformed. Additional measurements of the toxic and mutagenic potential of the wastewater show that in the laboratory-scale plant full removal of the carcinogenic potential is not achieved. This is due to the fact that during the biological transformation of higher condensated PAH mutagenic dead-end metabolites are produced.  相似文献   

7.
A cloud point extraction procedure is presented for the preconcentration and simultaneous determination of Ag+ and Pd2+ in various samples. After complexation with 2‐((2‐((1H‐benzo[d]imidazole‐2‐yl)methoxy)phenoxy)methyl)‐1H‐benzo[d]imidazol (BIMPI), which was used as a new chelating agent, analyte ions were quantitatively extracted to a phase rich in Triton X‐114 following centrifugation, and determination was carried out by flame atomic absorption spectrometry (FAAS). Under the optimum experimental conditions (i. e., pH = 7.0, 15.0·10–5 mol/L BIMPI and 0.036% (w/v) Triton X‐114), calibration graphs were linear in the range of 28.0–430.0 μg/L and 57.0–720.0 μg/L with detection limits of 10.0 and 25.0 μg/L for Ag+ and Pd2+, respectively. The enrichment factors were 35.0 and 28.0 for Ag+ and Pd2+, respectively. The method has been successfully applied to evaluate these metals in some real samples, including waste water, soil and hydrogenation catalyst samples.  相似文献   

8.
Transport and losses of nitrate from sloped soils are closely linked to nitrogen fertilizer management. Previous studies have always focused on different types of fertilizer applications and rarely analysed various initial nitrate distributions as a result of nitrogen fertilizer applications. Under certain conditions, both subsurface lateral saturated flow and vertical leaching dominate nitrate losses. Soil tank experiments and HYDRUS‐2D modelling were used to better understand the subsurface nitrate transport and losses through lateral saturated flow and vertical leaching under various initial nitrate distributions. Low (L: 180 mg L?1), normal (N: 350 mg L?1), and high (H: 500 mg L?1) nitrate concentrations were used in five different distributions (NNNN, NLLN, LHHL, LNLN, and HNHN) along the slope of the tank. The first two treatments (NNNN and NLLN) were analysed both experimentally and numerically. Experiments were conducted under 12 rainfall events at intervals of 3 days. The HYDRUS‐2D model was calibrated and validated against the experimental data and demonstrated good model performance. The other three treatments (LHHL, LNLN, and HNHN) were investigated using the calibrated model. Nitrate concentrations in purple sloped soils declined exponentially with time under intermittent rainfalls, predominantly in the upper soil layers. Non‐uniform initial nitrate distributions contributed to larger differences between four locations along the slope in deeper soil layers. The non‐uniform nitrate distribution either enhanced or reduced decreases in nitrate concentrations in areas with higher or lower initial nitrate concentrations, respectively. Higher nitrate concentrations at the slope foot and along the slope were reduced mainly by lateral flow and vertical leaching, respectively. Increasing nitrogen application rates increased subsurface nitrate losses. Mean subsurface lateral nitrate fluxes were twice as large as mean vertical leaching nitrate fluxes. However, due to longer leaching durations, total nitrate losses due to vertical leaching were comparable with those due to lateral flow, which indicated comparable environmental risks to surface waters and groundwater.  相似文献   

9.
Natural estrogens from humans increasingly attract attention because of their strong endocrine disrupting potency. The discharge of sewage water is considered as the most important source of these endocrine disrupting chemicals (EDCs) in the environment. Therefore, a GC‐MS method was developed for the simultaneous analysis of six natural free estrogens and their sulfate conjugates in municipal wastewater, in which natural free estrogens and sulfate conjugates were successfully separated from an Oasis HLB solid phase extraction (SPE) cartridge with two different eluents, and the sulfate conjugates were then transformed to their corresponding free estrogens by acid solvolysis. Before the analysis with GC‐MS, samples were derivatized by N,O‐bis (trimethylsilyl) trifluoroacetamide (BSTFA) plus 1% trimethylchlorosilane (TMCS) at 80°C for 40 min. Satisfactory recoveries ranging from 64 to 112.3% were obtained by spiking ultra‐purified water, raw, and treated municipal wastewater with the six estrogens at 50, 100, and 50 ng/L, respectively. The method was successfully applied to wastewater samples from one WWTP, which suggested that E1 was the dominant natural estrogens in effluent and E3‐3S was one of the conjugates possibly occurring in the effluent.  相似文献   

10.
Exchange of groundwater and lake water with typically quite different chemical composition is an important driver for biogeochemical processes at the groundwater‐lake interface, which can affect the water quality of lakes. This is of particular relevance in mine lakes where anoxic and slightly acidic groundwater mixes with oxic and acidic lake water (pH < 3). To identify links between groundwater‐lake exchange rates and acid neutralization processes in the sediments, exchange rates were quantified and related to pore‐water pH, sulfate and iron concentrations as well as sulfate reduction rates within the sediment. Seepage rates measured with seepage meters (?2.5 to 5.8 L m‐2 d‐1) were in reasonable agreement with rates inverted from modeled chloride profiles (?1.8 to 8.1 L m‐2 d‐1). Large‐scale exchange patterns were defined by the (hydro)geologic setting but superimposed by smaller scale variations caused by variability in sediment texture. Sites characterized by groundwater upwelling (flow into the lake) and sites where flow alternated between upwelling and downwelling were identified. Observed chloride profiles at the alternating sites reflected the transient flow regime. Seepage direction, as well as seepage rate, were found to influence pH, sulfate and iron profiles and the associated sulfate reduction rates. Under alternating conditions proton‐consuming processes, for example, sulfate reduction, were slowed. In the uppermost layer of the sediment (max. 5 cm), sulfate reduction rates were significantly higher at upwelling (>330 nmol g‐1 d‐1) compared to alternating sites (<220 nmol g‐1 d‐1). Although differences in sulfate reduction rates could not be explained solely by different flux rates, they were clearly related to the prevailing groundwater‐lake exchange patterns and the associated pH conditions. Our findings strongly suggest that groundwater‐lake exchange has significant effects on the biogeochemical processes that are coupled to sulfate reduction such as acidity retention and precipitation of iron sulfides. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

11.
The remediation of mangrove sediment contaminated with mixed polycyclic aromatic hydrocarbons (PAHs) having 3-, 4- and 5-rings by natural attenuation, bioaugmentation, phytoremediation and its combination was compared by greenhouse microcosm studies. At Days 90 and 154, the decreases of PAHs in contaminated mangrove sediment by phytoremediation, planted with one-year old Aegiceras corniculatum, and bioaugmentation, the inoculation of PAH-degrading bacterial strains isolated from mangrove sediment, either SCSH (Mycobacterium parafortuitum) or SAFY (Sphingobium yanoikuyae), were not better than that by natural attenuation (the non-vegetated and un-inoculated microcosms). The populations of SCSH and SAFY in sediment could not be maintained even with repeated inoculation, suggesting that the two isolates were not able to compete with the indigenous microbes and had little enhancement effect. Although some PAHs were accumulated in roots, root uptake only accounted for <15% of the spiked PAHs and the effect of plants on remediation were also insignificant. At the end of the 154-day experiment, the mass balance calculation revealed that the overall losses of PAHs by phytoremediation were comparable to that by bioaugmentation but were lower than that by natural attenuation, especially for the high molecular weight PAHs. Under natural attenuation, around 90% fluorene, 80% phenanthrene, 70% fluoranthene, 68% pyrene and 32% benzo[a]pyrene in contaminated sediment were removed. These results demonstrated that the mangrove sediment itself had sufficient indigenous microorganisms capable of naturally remedying PAH contamination.  相似文献   

12.
Patterns of change in the structure of bacterial communities monitored by ribosomal intergenic spacer analysis (RISA) in oil contaminated sediments inhabited or not by the marine polychaete Nereis diversicolor were studied during 45 days under laboratory conditions. Results supported by principal component analysis showed a marked response of the bacterial communities to the oil contamination and to the presence of N. diversicolor. Phylogenetic affiliation of specific RISA bands showed that, in the contaminated sediments, the presence of the marine polychaetes favoured the development of bacteria which may play an active role in natural bioremediation processes of oil polluted environments.  相似文献   

13.
Previous experimental studies of capillary barriers have identified highly hysteretic soil moisture retention characteristics in the materials used. In this study, numerical modelling is used to analyse the role of soil moisture hysteresis in capillary barrier functioning. Comparisons between published experimental results and model simulations indicate that soil moisture hysteresis was a necessary inclusion in the modelling approach to adequately reproduce pore water pressure distributions and the timing of breakthrough occurrences. Under hypothetical intermittent infiltration and evaporation conditions, the predicted volumetric water content in the moisture retention layer was significantly different for hysteretic and non‐hysteretic models. The hysteresis effect was found to be dependent on the nature of infiltration–evaporation cycling, although the predicted volume of flow through the hysteretic barrier was lower than that of the non‐hysteretic case, regardless of the nature of the cyclic upper boundary conditions. For practical engineering designs, where the water leakage through the barrier is the primary concern, the inclusion of soil moisture hysteresis in numerical modelling is needed. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

14.
Electrokinetic (EK) process was performed to restore sulfate‐originated saline soil and to evaluate the effect of treatment duration. Sulfate and potassium were the major ionic salts in the saline soil used in this study. A constant voltage gradient of 1 V/cm was applied for 8, 12, and 16 days. After EK treatment, anions and cations were transported toward anode and cathode, respectively, by electromigration. Chloride was completely removed, and 85.6% of nitrate was removed after 8 days of treatment. The increase of treatment period from 8 to 12 days had a negligible effect on the enhancement in the rate of sulfate removal; however, over 70% was removed after16 days. At the end of experiment, the electrical conductivity (EC) of the soil, an indicator of soil salinity, decreased to 1.93 dS/m from an initial value of 5.3 dS/m, and the distribution of sulfate was similar to that of EC. The operation time of 16 days was sufficient to restore the sulfate‐originated saline soil using the EK process.  相似文献   

15.
The aim of this research was to assess the impact caused by a long‐term pollution by fluoride and heavy metals in two soils (PS1 and PS2) near an aluminium smelter in Slovakia, on soil microbial biomass C (MBC), basal respiration, metabolic quotient (qCO2) water‐soluble organic C (WSOC) and enzymes activities involved in the C, N and P biogeochemical cycles. An unpolluted soil was used as control (C0). Results obtained for soil fluoride content reflected a gradient of fluoride exposure in topsoils of contaminated sites. Decreases in microbial and enzymatic activities and in MBC to organic C ratio were found in PS2 site, which is closer to the smelter and exhibited the highest fluoride content. PS1‐soil showed an extreme alkaline pH caused by leaching of waste effluents from the smelter dumping site, higher contents of Zn, Cu, Pb and Cd, significantly larger MBC, qCO2 and catalase and urease activities, and much larger basal respiration and dehydrogenase activity than PS2 and C0‐soil. Phosphatase, β‐glucosidase and BAA‐protease were negatively correlated with WSOC, basal respiration and dehydrogenase activity, and showed some degree of inhibition in polluted sites. These results may indicate different responses of microbial communities to ecosystem disturbances, caused by the drastic changes in soil's physicochemical properties as result of the long‐term emissions of fly ash with high levels of contaminants that are still affecting soil microbial and enzymatic activities.  相似文献   

16.
The impact of tar aggregates deriving from the Haven oil spill that occurred in 1991 on the soft-bottom macrobenthos off Arenzano (Ligurian Sea, NW Mediterranean; Italy) was investigated in this study. Core samples were collected to evaluate the composition, abundance and stratification of macrobenthos in three contaminated and three control sites. The distribution of tar aggregates (often settled by hydroids, bryozoans and serpulids) in the impacted area did not show distinct patterns related to sediment depth. The macrobenthos was numerically dominated by polychaetes, followed by crustaceans (amphipods, isopods and tanaids) and sipunculids, whereas bivalve molluscs were less represented. Ophiuroids and nemerteans were only occasionally found. Stratification was the main factor explaining the distribution of benthic invertebrates, highest abundances being observed in the upper 5 cm of sediment, while densities of individuals declined sharply in deeper sediment layers. No significant differences were observed in the abundance of both the whole benthic assemblage and of the main benthic taxonomic groups between contaminated and control sites. The higher abundance of sipunculids at the contaminated sites, instead, was attributed to the availability of empty tubes of polychaetes in which they take refuge. The polychaetes/amphipods ratios did not show strong differences between impacted and control sites. Multivariate analysis (MDS) showed a wide scattering among deep bottom samples and a comparatively high similarity among intermediate and superficial layers, regardless of the contamination level. In conclusion, the results reported here suggest that tar aggregates do not determine appreciable detrimental effects on the soft-bottom macrobenthos, which appeared to have recovered towards natural pristine conditions.  相似文献   

17.
A whole-core injection method was used to determine depth-related rates of microbial mineralization of (14)C-phenanthrene added to both contaminated and clean marine sediments of Puget Sound, WA. For 26-day incubations under micro-aerobic conditions, conversions of (14)C-phenanthrene to (14)CO(2) in heavily PAH-contaminated sediments from two sites in Eagle Harbor were much higher (up to 30%) than those in clean sediments from nearby Blakely Harbor (<3%). The averaged (14)C-phenanthrene degradation rates in the surface sediment horizons (0-3 cm) were more rapid (2-3 times) than in the deeper sediment horizons examined (>6 cm), especially in the most PAH polluted EH9 site. Differences in mineralization were associated with properties of the sediments as a function of sediment depth, including grain-size distribution, PAH concentration, total organic matter and total bacterial abundance. When strictly anaerobic incubations (in N(2)/H(2)/CO(2) atmosphere) were used, the phenanthrene biodegradation rates at all sediment depths were two times slower than under micro-aerobic conditions, with methanogenesis observed after 24 days. The main rate-limiting factor for phenanthrene degradation under anaerobic conditions appeared to be the availability of suitable electron acceptors. Addition of calcium sulfate enhanced the first order rate coefficient (k(1) increased from 0.003 to 0.006 day(-1)), whereas addition of soluble nitrate, even at very low concentration (<0.5 mM), inhibited mineralization. Long-term storage of heavily polluted Eagle Harbor sediment as intact cores under micro-aerobic conditions also appeared to enhance anaerobic biodegradation rates (k(1) up to 0.11 day(-1)).  相似文献   

18.
The non‐aqueous phase liquid simulator was used to model and interpret the occurrence of a thin benzene‐contaminated soil layer 9.0 m below the groundwater table in an abandoned gas plant site. The simulator was first evaluated in column tests under similar conditions to the contaminated site. Saturation–capillary pressure (S–P) relationships were extended from the laboratory scale of the column tests to the field scale of the subsurface at the abandoned site. Dynamic boundary conditions were established in order to prevent the model from generating excessive vertical velocities. The modelled benzene layer formation process agreed well with the in situ observations. With falling and then rising of the water table, benzene release from the surface migrated downward and then upward and distributed itself below and above the water table. Biochemical degradation of benzene made the distribution discontinuous in the subsurface. These two factors resulted in the thin benzene‐contaminated layer below the groundwater table. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

19.
Following the basic incubation study, a greenhouse experiment was conducted to elucidate the efficiency of vetiver grass (Vetiveria zizanioides L.), with or without chelating agents, in remediating lead (Pb)‐contaminated soils from actual residential sites where Pb‐based paints were used. Because the primary factor affecting Pb phytoavailability in soils is soil pH, we used two soil types widely varying in pH that have total Pb concentrations above 1500 mg kg?1 soil. Lead‐contaminated, low pH, acidic soils were collected from residential sites in Baltimore, MD and high pH, alkaline soils were collected from residential sites in San Antonio, TX. Based on the soil characterization results, two most appropriate soils (one from each city, having similar Pb levels but variable soil physico‐chemical properties) were selected for this study. Ethylenediaminetetraacetic acid (EDTA) and [S,S′]ethylenediaminedisuccinate (EDDS) were applied at 5, 10, and 15 mmol kg?1 soil. Lead uptake and translocation in vetiver was determined on day 10 after chelants addition. Plant and soil analysis show that EDTA treated soils have maximum Pb uptake and lower total soil Pb levels. Prediction models developed for exchangeable Pb show a strong correlation for total Pb accumulated in vetiver grass. Results of the sequential chemical extraction of the soils at both initial and final time‐points, indicates a significant mobilization of Pb by the two chelants from carbonate‐bound fraction to exchangeable pool. Information on physico‐chemical properties of contaminated residential soils help in predicting Pb phytoextraction and thus further help in calibrating a successful chelant‐assisted phytoremediation model.  相似文献   

20.
Sulfate reducing conditions are widely observed in groundwater plumes associated with petroleum hydrocarbon releases. This leads to sulfate depletion in groundwater which can limit biodegradation of hydrocarbons (usually benzene, toluene, ethylbenzene, xylenes [BTEX] compounds) and can therefore result in extended timeframes to achieve groundwater cleanup objectives by monitored natural attenuation. Under these conditions, sulfate addition to the subsurface can potentially enhance BTEX biodegradation and facilitate enhanced natural attenuation. However, a delivery approach that enables effective contact with the hydrocarbons and is able to sustain elevated and uniform sulfate concentrations in groundwater remains a key challenge. In this case study, sulfate addition to a groundwater plume containing predominantly benzene by land application of agricultural gypsum and Epsom salt is described. Over 4 years of groundwater monitoring data from key wells subjected to pilot‐scale and site‐wide land application events are presented. These are compared to data from pilot testing employing liquid Epsom salt injections as an alternate sulfate delivery approach. Sulfate land application, sulfate retention within the vadose zone, and periodic infiltration following ongoing precipitation events resulted in elevated sulfate concentrations (>150 mg/L) in groundwater that were sustained over 12 months between application events and stimulated benzene biodegradation as indicated by declines in dissolved benzene concentration, and compound‐specific isotope analysis data for carbon in benzene. Long‐term groundwater benzene concentration reductions were achieved in spite of periodic rebounds resulting from water table fluctuations across the smear zone. Land application of gypsum is a potentially cost‐effective sulfate delivery approach at sites with open, unpaved surfaces, relatively permeable geology, and shallow hydrocarbon impacts. However, more research is needed to understand the fate and persistence of sulfate and to improve the likelihood of success and effectiveness of this delivery approach.  相似文献   

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