离子色谱法检测土壤样品水溶态中的七种阴离子   总被引：3，自引：0，他引：3  

李庆霞  刘亚轩  陈卫明  肖细炼  张勤 《物探与化探》2012,36(3):418-421

采用离子色谱法测定土壤样品水溶态中的F^-、Cl^-、NO2^-、SO4^2-、Br^-、NO3^-、PO4^3-。通过优化提取条件,得出最优条件下7种阴离子的加标回收率为94.4%～102.5%,精密度为3.1%～4.6%。对实际样品进行测试,结果表明,该方法适用于土壤样品水溶态中7种阴离子的定性、定量分析。  相似文献   

稀土元素对鲁西铜石、铜井、龙宝山杂岩体的同源性制约   总被引：2，自引：0，他引：2  

肖淳  于海涛  刘传朋  许玉森  郭闯 《西北地质》2012,(3):26-31

20世纪80年代,在山东省平邑县发现归来庄大型金矿床,实现了鲁西黄金找矿的重大突破。此后,鲁西相继发现卓家庄、磨坊沟和龙宝山金矿。近年,又在沂南金矿的深部发现新的矿体,鲁西良好的金矿成矿前景引起了地质学界的广泛关注。目前,鲁西发现的金矿床主要分布在铜石、铜井和龙宝山等燕山期杂岩体的附近。这些岩体在成因上有什么关系值得研究。通过对上述岩体稀土元素的地球化学分析,每种岩体不同期次侵入的岩浆岩的稀土元素分布形式和3种岩体综合稀土元素分布形式均呈向右陡倾的弧形线,且配分曲线形态基本相似,都没有明显的Ce、Eu异常,指示了岩体之间存在同源性,均来自深部同一岩浆房。该认识对于指导鲁西黄金找矿具有一定的意义。  相似文献   

Mineralogy and Mineral Chemistry of the Cretaceous Duolong Gold‐Rich Porphyry Copper Deposit in the Bangongco Arc,Northern Tibet     

Jinxiang LI  Guangming LI  Kezhang QIN  Bo XIAO  Lei CHEN  Junxing ZHAO 《Resource Geology》2012,62(1):19-41

The Early Cretaceous Duolong gold‐rich porphyry copper deposit is a newly discovered deposit with proven 5.38 Mt Cu resources of 0.72% Cu and 41 t gold of 0.23 g t^?1 in northern Tibet. Granodiorite porphyry and quartz diorite porphyrite are the main ore‐bearing porphyries. A wide range of hydrothermal alteration associated with these porphyries is divided into potassic, argillic and propylitic zones from the ore‐bearing porphyry center outward and upward. In the hydrothermal alteration zones, secondary albite (91.5–99.7% Ab) occurs along the rim of plagioclase phenocryst and fissures. Secondary K‐feldspar (75.1–96.9% Or) replaces plagioclase phenocryst and matrix or occurs in veinlets. Biotite occurs mainly as matrix and veinlet in addition to phenocryst in the potassic zone. The biotite are Mg‐rich and formed under a highly oxidized condition at temperatures ranging from 400°C to 430°C. All the biotites are absent in F, and have high Cl content (0.19–0.26%), with log (X_Cl/X_OH) values of ?2.74 to ?2.88 and IV (Cl) values of ?3.48 to ?3.35, suggesting a significant role of chloride complexes (CuCl₂^‐ and AuCl₂^‐) in transporting and precipitating copper and gold. Chlorites are present in all alteration zones and correspond mainly to pycnochlorite. They have similar Fe/(Fe+Mg), Mn/(Mn+Mg) ratios, and a formation temperature range of 280–360°C. However, the formation temperature of chlorite in the quartz‐gypsum‐carbonate‐chlorite vein is between 190°C and 220°C, indicating that it may have resulted from a later stage of hydrothermal activity. Fe³⁺/Fe²⁺ ratios of chlorites have negative correlation with Al^IV, suggesting oxygen fugacity of fluids increases with decreasing temperature. Apatite mineral inclusions in the biotite phenocrysts show high SO₃ content (0.44–0.82%) and high Cl content (1–1.37%), indicating the host magma had a high oxidation state and was enriched in S and Cl. The highest Cl content of apatite in the propylitic zone may have resulted from pressure decrease, and the lowest Cl content of apatite in the argillic zone may have been caused by a low Cl content in the fluids. The low concentration of SO₃ content in the hydrothermal apatite compared to the magmatic one may have resulted from the decrease of oxygen fugacity and S content in the hydrothermal fluid, which are caused by the abundant precipitation of magnetite.  相似文献   

Fluid Inclusions and Hydrogen,Oxygen, Sulfur Isotopes of Nuri Cu‐W‐Mo Deposit in the Southern Gangdese,Tibet     

Lei CHEN  Kezhang QIN  Jinxiang LI  Bo XIAO  Guangming LI  Junxing ZHAO  Xin FAN 《Resource Geology》2012,62(1):42-62

The Nuri Cu‐W‐Mo deposit is located in the southern subzone of the Cenozoic Gangdese Cu‐Mo metallogenic belt. The intrusive rocks exposed in the Nuri ore district consist of quartz diorite, granodiorite, monzogranite, granite porphyry, quartz diorite porphyrite and granodiorite porphyry, all of which intrude in the Cretaceous strata of the Bima Group. Owing to the intense metasomatism and hydrothermal alteration, carbonate rocks of the Bima Group form stratiform skarn and hornfels. The mineralization at the Nuri deposit is dominated by skarn, quartz vein and porphyry type. Ore minerals are chalcopyrite, pyrite, molybdenite, scheelite, bornite and tetrahedrite, etc. The oxidized orebodies contain malachite and covellite on the surface. The mineralization of the Nuri deposit is divided into skarn stage, retrograde stage, oxide stage, quartz‐polymetallic sulfide stage and quartz‐carbonate stage. Detailed petrographic observation on the fluid inclusions in garnet, scheelite and quartz from the different stages shows that there are four types of primary fluid inclusions: two‐phase aqueous inclusions, daughter mineral‐bearing multiphase inclusions, CO₂‐rich inclusions and single‐phase inclusions. The homogenization temperature of the fluid inclusions are 280°C–386°C (skarn stage), 200°C–340°C (oxide stage), 140°C–375°C (quartz‐polymetallic sulfide stage) and 160°C–280°C (quartz‐carbonate stage), showing a temperature decreasing trend from the skarn stage to the quartz‐carbonate stage. The salinity of the corresponding stages are 2.9%–49.7 wt% (NaCl) equiv., 2.1%–7.2 wt% (NaCl) equiv._, 2.6%–55.8 wt% (NaCl) equiv. and 1.2%–15.3 wt% (NaCl) equiv., respectively. The analyses of CO₂‐rich inclusions suggest that the ore‐forming pressures are 22.1 M Pa–50.4 M Pa, corresponding to the depth of 0.9 km–2.2 km. The Laser Raman spectrum of the inclusions shows the fluid compositions are dominated in H₂O, with some CO₂ and very little CH₄, N₂, etc. δD values of garnet are between ?114.4‰ and ?108.7‰ and δ¹⁸O_H2O between 5.9‰ and 6.7‰; δD of scheelite range from ?103.2‰ to ?101.29‰ and δ¹⁸O_H2O values between 2.17‰ and 4.09‰; δD of quartz between ?110.2‰ and ?92.5‰ and δ¹⁸O_H2O between ?3.5‰ and 4.3‰. The results indicate that the fluid came from a deep magmatic hydrothermal system, and the proportion of meteoric water increased during the migration of original fluid. The δ³⁴S values of sulfides, concentrated in a rage between ?0.32‰ to 2.5‰, show that the sulfur has a homogeneous source with characteristics of magmatic sulfur. The characters of fluid inclusions, combined with hydrogen‐oxygen and sulfur isotopes data, show that the ore‐forming fluids of the Nuri deposit formed by a relatively high temperature, high salinity fluid originated from magma, which mixed with low temperature, low salinity meteoric water during the evolution. The fluid flow through wall carbonate rocks resulted in the formation of layered skarn and generated CO₂ or other gases. During the reaction, the ore‐forming fluid boiled and produced fractures when the pressure exceeded the overburden pressure. Themeteoric water mixed with the ore‐forming fluid along the fractures. The boiling changed the pressure and temperature, oxygen fugacity, physical and chemical conditions of the whole mineralization system. The escape of CO₂ from the fluid by boiling resulted in scheelite precipitation. The fluid mixing and boiling reduced the solubility of metal sulfides and led the precipitation of chalcopyrite, molybdenite, pyrite and other sulfide.  相似文献   

Highly Oxidized Magma and Fluid Evolution of Miocene Qulong Giant Porphyry Cu‐Mo Deposit,Southern Tibet,China     

Bo XIAO  Kezhang QIN  Guangming LI  Jinxiang LI  Daixiang XIA  Lei CHEN  Junxing ZHAO 《Resource Geology》2012,62(1):4-18

The Miocene Qulong porphyry Cu‐Mo deposit, which is located at the Gangdese orogenic belt of Southern Tibet, is the largest porphyry‐type deposit in China, with confirmed Cu ～10 Mt and Mo ～0.5 Mt. It is spatially and temporally associated with multiphase granitic intrusions, which is accompanied by large‐scale hydrothermal alteration and mineralization zones, including abundant hydrothermal anhydrite. In addition to hydrothermal anhydrite, magmatic anhydrite is present as inclusions in plagioclase, interstitial minerals between plagioclase and quartz, and phenocrysts in unaltered granodiorite porphyry, usually in association with clusters of sulfur‐rich apatite in the Qulong deposit. These observations indicate that the Qulong magma‐hydrothermal system was highly oxidized and sulfur‐rich. Three main types of fluid inclusions are observed in the quartz phenocrysts and veins in the porphyry: (i) liquid‐rich; (ii) polyphase high‐salinity; and (iii) vapor‐rich inclusions. Homogenization temperatures and salinities of all type inclusions decrease from the quartz phenocrysts in the porphyry to hydrothermal veins (A, B, D veins). Microthermometric study suggests copper‐bearing sulfides precipitated at about 320–400°C in A and B veins. Fluid boiling is assumed for the early stage of mineralization, and these fluids may have been trapped at about 35–60 Mpa at 460–510°C and 28–42 Mpa at 400–450°C, corresponding to trapping depths of 1.4–2.4 km and 1.1–1.7 km, respectively.  相似文献   

西昆仑康西瓦断裂西段斜长片麻岩LA-ICP-MS锆石U-Pb定年及其构造意义   总被引：3，自引：2，他引：1  

康磊  校培喜  高晓峰  董增产  过磊  奚仁刚 《地质通报》2012,31(8):1244-1250

在康西瓦断裂西段发育着一套含石榴子石二云斜长片麻岩。根据锆石的阴极发光图像和Th、U、REE等特征,锆石可分为岩浆成因和变质热液成因2类。利用LA-ICP-MS法进行锆石U-Pb定年,测得含石榴子石斜长片麻岩的源岩形成年龄为254.5Ma±4.2Ma(MSWD=0.16),变质年龄为242.7Ma±2.3Ma(MSWD=0.11)。结合区域地质资料,含石榴子石二云斜长片麻岩的变质作用与古特提斯碰撞造山有关,表明西昆仑造山带在中三叠世早期(243Ma)仍处于古特提斯碰撞造山期。  相似文献   

湘南宜章地区辉绿岩、花岗斑岩、安山岩的形成时代和成因——锆石U-Pb年龄和Hf同位素组成   总被引：2，自引：1，他引：1  

刘勇  李廷栋  肖庆辉  耿树方  王涛  陈必河 《地质通报》2012,31(9):1363-1378

湘南宜章县长城岭地区广泛出露以辉绿岩、花岗斑岩为主的燕山早期岩体,而宜章平和地区主要分布安山岩体,其年龄和成因有待进一步研究。分别用SHRIMP和LA-ICP-MS法测试了它们的年龄和Hf同位素组成,长城岭辉绿岩的SHRIMP锆石U-Pb年龄为153.7Ma±3.1Ma、227.0Ma±4.2Ma;长城岭花岗斑岩的LA-ICP-MS锆石U-Pb测年结果为153Ma±14Ma和231.58Ma±0.67Ma;平和安山岩的SHRIMP锆石U-Pb测年结果为159Ma±14Ma和229.3Ma±7.6Ma,LA-ICP-MS锆石U-Pb测年结果为161Ma±1Ma,显示为燕山早期岩浆侵位和印支期基性岩浆底侵。锆石Lu-Hf同位素原位分析结果表明,εHf(t)值在正值和负值范围内变化,指示岩浆为壳幔混合来源。结合长城岭花岗岩体中继承锆石的年龄信息,认为花岗质岩石可能来源于中元古代基底的重熔。岩体岩浆很可能是由元古宙火成岩石部分熔融形成的,并伴有年轻或新生幔源物质的加入,岩浆上升侵位的过程中发生了混合作用。  相似文献   

基于InSAR技术的江苏水闸垂直位移监测方法可行性探讨     

杨星  肖怀前  侯苗  缪融融  翁松干  张泽雄 《大地测量与地球动力学》2021,41(9):895-898

利用Sentinel-1雷达卫星影像,探讨InSAR技术作为水闸垂直位移变形监测辅助手段的可行性。结果表明,InSAR技术与水准测量相比,两种方法得到的水闸垂直位移变化趋势基本一致;InSAR测量结果具有可信性,后续可进一步推广应用。  相似文献   

山东省金刚石深部找矿成果及技术进展          下载免费PDF全文

肖丙建  王伟德  冯爱平  褚志远  王玉峰  赵红娟  朱成河  吕青 《山东国土资源》2021,37(11)

自原国土资源部等四部委发布《找矿突破战略行动纲要（2011—2020年)》,山东加强了对蒙阴金刚石原生矿深部及外围的勘查,深部及外围找矿工作取得丰硕成果,并在金刚石找矿方法和综合研究方面取得改进和新认识。本文总结了10年来山东省第七地质矿产勘查院金刚石找矿成果,蒙阴常马庄和西峪金刚石原生矿深部钻探控制至1000m,新增金刚石矿物量550万ct,改进了金刚石原生矿重砂矿物组合和粒级,完善了金刚石找矿方法和选矿方法,对金刚石成矿理论取得新认识,并在深部新发现含金刚石的金伯利岩管,在蒙阴金刚石原生矿外围发现了含金刚石的煌斑岩,查明了费县朱田大井头岩管为含金刚石的钾镁煌斑岩岩管。编制了《矿产地质勘查规范金刚石》,填补了我国没有《金刚石矿勘查规范》的空白,对我国今后的金刚石矿勘查具有重要的指导作用。  相似文献   

空间U统计量法在遥感蚀变信息提取中的应用研究   总被引：2，自引：0，他引：2  

胡波  朱谷昌  张远飞  肖燃 《国土资源遥感》2011,(3):71-76

鉴于传统蚀变异常信息提取方法的局限性,试图在二维光谱特征空间(即散点图)中研究遥感蚀变信息的提取方法.在二维散点图中,两个波段灰度值的联合分布体现了各向异性的特点,聚类常呈类似椭圆形分布.对散点图中点的频数使用空间U统计量法逐个获得地物聚类的椭圆参数,将每个椭圆内的点映射到遥感图像上,经过目视解译,最终获得蚀变异常信息...  相似文献