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61.
Chemical structure of Jurassic vitrinites isolated from the coals in basins in NW China have been checked using solid state 13C NMR and flash pyrolysis-GC/MS. Study shows some Jurassic collodetrinites are rich in aliphatic products in pyrolysates, consisting with the high amount of methylene carbon in 13C NMR spectra. In contrast, pyrolysates of Jurassic collotelinites are rich in phenols and alkylbenzenes. Also one Pennsylvanian and one Permian vitrinite selected from the Ordos basin, NW China have been checked for comparison. The proportion of aliphatics is low in pyrolysates, and aliphatic carbon peak in 13C NMR spectrum of Permian vitrinite is mostly composed of gas-prone carbons compared with collodetrinites in those Jurassic basins. But both pyrolysis and 13C NMR data shows the Pennsylvanian vitrinite is not only gas-prone but also oil-prone. Relatively high proportion of long chain aliphatic structure of some Jurassic vitrinite in Junggar, Turpan-Hami basins may be due to the contribution of liptodetrinites, which may be included during the formation of vitrinites. And it seems that suberinite is the most possible precursor of long chain aliphatics in the structure of Jurassic collodetrinite. 相似文献
62.
华南寒武系年代地层系统的修订及相关问题 总被引:10,自引:3,他引:7
将早先提出的华南寒武系4统9阶的年代地层系统,修订成4统10阶,除王村阶的底界略高于全球鼓山阶(Drumian Stage)的底界外,其余界线都与目前的全球4统10阶的年代地层界线一致。新系统采纳了在我国华南建立的全球芙蓉统、排碧阶和古丈阶,在原桃源阶的上部另建"牛车河阶"。原王村阶和桃源阶的时限因这一修订有所缩减。全球鼓山阶的底界与台江阶上部的Ptychagnostus atavus带底界可以精确对比。滇东统包含晋宁阶和梅树村阶(狭义)两个年代地层单位,晋宁阶的底界采用全球寒武系的底界,梅树村阶的底界采用罗惠麟等1994年正式修订后的定义,即位于梅树村剖面的"B"点。梅树村阶的原始定义仅指梅树村剖面的磷块岩层(即现今的中谊村段),它的底界高于现在的以Tricophycus pedum首现定义的全球寒武系底界。 相似文献
63.
江西省德兴铜矿矿区重金属元素的环境效应 总被引:6,自引:0,他引:6
本文系统研究了德兴铜矿排石场和尾砂库的环境问题,以环境介质(水土植物)中重金属元素含量为研究对象,论述矿区重金属的环境效应。研究结果表明祝家村低品位矿石堆浸场淋滤产生的酸性废水是造成大坞河流域重金属污染的主要来源。大坞河上游水体中Cu元素含量高达14506μg/L,是国家Ⅲ级水标准的14倍之多,Zn元素含量高达2938μg/L,是国家Ⅲ级水标准的2.9倍,同时pH值在3~4范围内;到中下游水体中Cu元素含量减小到几千到几百μg/L,水质有所改善。大坞河沿岸上游和中游土壤重金属含量受河水影响,随着与河岸距离的增加而减小。同时水稻中Pb元素含量是国家粮食标准的2倍。推测4#尾砂库尾砂表层氧化带深度大于80cm;而1#尾砂库库内尾砂中氧化带估计在0~25cm处。推测两个尾砂库产酸能力小于酸中和能力,故坝底水中pH值在7左右,对周围水体影响较小。与4#尾砂库距离近的石墩头村稻田表层土壤中Cu、Mo元素含量较高,远离尾砂库土壤中重金属含量降低。同时4#尾砂库周围土壤中Cd、Pb、Cu元素的吸附态、碳酸盐态比例在20%左右,因而在酸性环境下较容易被植物吸收。1#尾砂库矿建村种植的小白菜中Pb元素含量超过国家蔬菜标准的4倍,Cu、Pb、Zn元素含量严重超过背景值。 相似文献
64.
For the assessment of shallow landslides triggered by rainfall, the physically based model coupling the infinite slope stability
analysis with the hydrological modeling in nearly saturated soil has commonly been used due to its simplicity. However, in
that model the rainfall infiltration in unsaturated soil could not be reliably simulated because a linear diffusion-type Richards’
equation rather than the complete Richards’ equation was used. In addition, the effect of matric suction on the shear strength
of soil was not actually considered. Therefore, except the shallow landslide in saturated soil due to groundwater table rise,
the shallow landslide induced by the loss in unsaturated shear strength due to the dissipation of matric suction could not
be reliably assessed. In this study, a physically based model capable of assessing shallow landslides in variably saturated
soils is developed by adopting the complete Richards’ equation with the effect of slope angle in the rainfall infiltration
modeling and using the extended Mohr–Coulomb failure criterion to describe the unsaturated shear strength in the soil failure
modeling. The influence of rainfall intensity and duration on shallow landslide is investigated using the developed model.
The result shows that the rainfall intensity and duration seem to have similar influence on shallow landslides respectively
triggered by the increase of positive pore water pressure in saturated soil and induced by the dissipation of matric suction
in unsaturated soil. The rainfall duration threshold decreases with the increase in rainfall intensity, but remains constant
for large rainfall intensity. 相似文献
65.
66.
Yuan-Bao Wu Shan Gao Hong-Fei Zhang Sai-Hong Yang Wen-Fang Jiao Yong-Sheng Liu Hong-Lin Yuan 《Contributions to Mineralogy and Petrology》2008,155(1):123-133
The Hong’an area (western Dabie Mountains) is the westernmost terrane in the Qinling-Dabie-Sulu orogen that preserves UHP
eclogites. The ages of the UHP metamorphism have not been well constrained, and thus hinder our understanding of the tectonic
evolution of this area. LA-ICPMS U–Pb age, trace element and Hf isotope compositions of zircons of a granitic gneiss and an
eclogite from the Xinxian UHP unit in the Hong’an area were analyzed to constrain the age of the UHP metamorphism. Most zircons
are unzoned or show sector zoning. They have low trace element concentrations, without significant negative Eu anomalies.
These metamorphic zircons can be further subdivided into two groups according to their U–Pb ages, and trace element and Lu–Hf
isotope compositions. One group with an average age of 239 ± 2 Ma show relatively high and variable HREE contents (527 ≥ LuN ≥ 14) and 176Lu/177Hf ratios (0.00008–0.000931), indicating their growth prior to a great deal of garnet growth in the late stage of continental
subduction. The other group yields an average age of 227 ± 2 Ma, and shows consistent low HREE contents and 176Lu/177Hf ratios, suggesting their growth with concurrent garnet crystallization and/or recrystallization. These two groups of age
are taken as recording the time of prograde HP to UHP and retrograde UHP–HP stages, respectively. A few cores have high Th/U
ratios, high trace element contents, and a clear negative Eu anomaly. These features support a magmatic origin of these zircon
cores. The upper intercept ages of 771 ± 86 and 752 ± 70 Ma for the granitic gneiss and eclogite, respectively, indicate that
their protoliths probably formed as a bimodal suite in rifting zones in the northern margin of the Yangtze Block. Young Hf
model ages (T
DM1) of magmatic cores indicate juvenile (mantle-derived) materials were involved in their protolith formation.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
67.
We have determined the metallographic cooling rates for 13 IVA irons using the most recent and most accurate metallographic cooling rate model. Group IVA irons have cooling rates that vary from 6600 °C/Myr at the low-Ni end of the group to 100 °C/Myr at the high-Ni end of the group. This large cooling rate range is totally incompatible with cooling in a mantled core which should have a uniform cooling rate. Thermal and fractional crystallization models have been used to describe the cooling and solidification of the IVA asteroid. The thermal model indicates that a metallic body of 150 ± 50 km in radius with less than 1 km of silicate on the outside of the body has a range of cooling rates that match the metallographic cooling rates in IVA irons in the temperature range 700-400 °C where the Widmanstätten pattern formed. The fractional crystallization model for Ni with initial S contents between 3 and 9 wt% is consistent with the measured variation of cooling rate with bulk Ni and the thermal model. New models for impacts in the early solar system and the evolution of the primordial asteroid belt allow us to propose that the IVA irons crystallized and cooled in a metallic body that was derived from a differentiated protoplanet during a grazing impact. Other large magmatic iron groups, IIAB, IIIAB, and IVB, also show significant cooling rate ranges and are very likely to share a similar history. 相似文献
68.
The altitude effect on the isotopic composition of precipitation and its application to paleoelevation reconstruction using authigenic or pedogenic minerals have been intensively studied. However, there are still no studies on variations in biomarker δD along altitude transects to investigate its potential as a paleoelevation indicator, although it has been observed that δD of higher plant lipid may record changes in precipitation δD (δDp). Here, we present δD values of higher plant-derived C27, C29, and C31n-alkanes from surface soil along the eastern slope of Mount Gongga, China with great changes in physical variables and vegetation over a range from 1000 to 4000 m above sea level. The weighted-mean δD values of these n-alkanes (δDwax) show significant linear correlations with predicted δDp values (R2 = 0.76) with an apparent isotopic enrichment (εwax-p) of −137 ± 9‰, indicating that soil δDwax values track overall δDp variation along the entire altitudinal transect. Leaf δDwax is also highly correlated with mountain altitude by a significant quadratic relationship (R2 = 0.80). Evapotranspiration is found declining with altitude, potentially lowering δDwax values at higher elevations. However, this evapotranspiration effect is believed to be largely compensated by the opposing effect of vegetation changes, resulting in less varied εwax-p values over the slope transect. This study therefore confirms the potential of using leaf δDwax to infer paleoelevations, and more generally, to infer the δD of precipitation. 相似文献
69.
Identification of sources and causes of leakage on a zoned earth dam in northern Taiwan: Hydrological and isotopic evidence 总被引:3,自引:0,他引:3
Seepage through an earth dam body must be regulated as a well–planned process, if it is not properly managed, the abnormal seepage may cause dam failure. This study employed stable isotopic and statistical methods to identify the source and cause of an abnormal leakage on the zoned earth dam of the Xin–Shan reservoir located in northern Taiwan. Water samples from the dam area over a 2-a period were collected and analyzed for their stable O and H isotope compositions. In addition, a 4-a period of hydrological data, including rainfall, reservoir level, well level, seepage of filter drainage and leakage, were statistically analyzed with a stepwise multiple regression approach. Both the stable isotopic and hydrological results indicate that the abnormal leakage on the dam shell comes from the filter drainage in the dam. The reason for abnormal leakage is due to unexpected and significant precipitation–sourced water flowing into the dam’s body. The dam filter fails to drain out the incoming water sufficiently, thus generating the abnormal seepage. In addition, the defect in the dam filter may also cause the drainage filter to drain off reservoir seepage inadequately. Therefore, it is suggested that checking the filter function and preventing excessive precipitation–sourced water from flowing into the dam are the two top priorities for the follow-up remedial strategy of the dam. 相似文献
70.
The concentrations of twenty four chemical elements in the surface layer of natural desert soils and the cultivated farmland soils were measured at a desert-oasis ecotone in the middle of Heihe river basin, north-west China. Background values were estimated for (a) major elements (Si 335.3 g kg− 1, Al 49.4 g kg− 1, Fe 19.1 g kg− 1, Ca 29.4 g kg− 1, Mg 8.9 g kg− 1, K 20.1 g kg− 1, Na 17.5 g kg− 1 and P 0.338 g kg− 1), (b) heavy metals and non-metals (Cr 55.8 mg kg− 1, Mn 404.8 mg kg− 1, Ni 17.7 mg kg− 1, Cu 5.1 mg kg− 1, Zn 33.7 mg kg− 1, Pb 15.5 mg kg− 1 and As 5.2 mg kg− 1) and (c) other trace elements (Ti 2.0 mg kg− 1, V 55.3 mg kg− 1, Co 5.7 mg kg− 1, Rb 82.4 mg kg− 1, Sr 232.9 mg kg− 1, Y 14.7 mg kg− 1, Zr 194.9 mg kg− 1, Nb 7.8 mg kg− 1 and Ba 720.6 mg kg− 1). After natural desert soil was cultivated for agricultural use, significant changes in element concentrations occurred under tillage, irrigation and fertilisation management. Compared to natural soil, the for the levels of Si, K, Na, Sr, Zr and Ba decreased, and no changes were observed for Rb, while the values of the other 17 elements increase in agricultural soil from 1.2 to 3.5 times. However, their absolute concentrations are still low, suggesting that the arable soil in this region remains comparatively a clean soil. The increased silt, clay and organic carbon content, under long-term irrigation, enriched the fine-grained materials, and application of fertilisers and manure contributed to the accumulation of most elements in arable soil. The accumulation of elements in agricultural soil increased with increasing cultivation years and extent of soil development. 相似文献