Accurate Determination of Sr Isotopic Compositions in Clinopyroxene and Silicate Glasses by LA‐MC‐ICP‐MS          下载免费PDF全文

Xirun Tong  Yongsheng Liu  Zhaochu Hu  Haihong Chen  Lian Zhou  Qinghai Hu  Rong Xu  Lixu Deng  Chunfei Chen  Lu Yang  Shan Gao 《Geostandards and Geoanalytical Research》2016,40(1):85-99

The low‐Sr content (generally < 100 μg g^?1) in clinopyroxene from peridotite makes accurate Sr isotopic determination by LA‐MC‐ICP‐MS a challenge. The effects of adding N₂ to the sample gas and using a guard electrode (GE) on instrumental sensitivity for Sr isotopic determination by LA‐MC‐ICP‐MS were investigated. Results revealed no significant sensitivity enhancement of Sr by adding N₂ to the ICP. Although using a GE led to a two‐fold sensitivity enhancement, it significantly increased the yield of polyatomic ion interferences of Ca‐related ions and TiAr⁺ on Sr isotopes. Applying the method established in this work, ⁸⁷Sr/⁸⁶Sr ratios (Rb/Sr < 0.14) of natural clinopyroxene from mantle and silicate glasses were accurately measured with similar measurement repeatability (0.0009–0.00006, 2SE) to previous studies but using a smaller spot size of 120 μm and low‐to‐moderate Sr content (30–518 μg g^?1). The measurement reproducibility was 0.0004 (2s, n = 33) for a sample with 100 μg g^?1 Sr. Destruction of the crystal structure by sample fusion showed no effect on Sr isotopic determination. Synthesised glasses with major element compositions similar to natural clinopyroxene have the potential to be adopted as reference materials for Sr isotopic determination by LA‐MC‐ICP‐MS.  相似文献   

A Practical Method for Accurate Measurement of Trace Level Fluorine in Mg‐ and Fe‐Bearing Minerals and Glasses Using Electron Probe Microanalysis          下载免费PDF全文

Chao Zhang  Jürgen Koepke  Lian‐Xun Wang  Paul E. Wolff  Sören Wilke  André Stechern  Renat Almeev  Francois Holtz 《Geostandards and Geoanalytical Research》2016,40(3):351-363

Fluorine plays an important role in magmatic and hydrothermal processes, but due to its low abundance in geological samples determining F is difficult by electron probe microanalysis. By using a W‐Si multi‐layered pseudocrystal as the diffraction crystal instead of thallium acid phthalate (TAP), count rates were considerably higher, which however introduced spectral interferences between FKα and FeLα and MgKβ lines when normal integral mode is applied. In this study, we developed a protocol using a W‐Si multi‐layered pseudocrystal for measuring accurately trace level F in both minerals and glasses. First, we used differential mode with an optimised PHA (pulse height analysis) setting in signal processing, instead of normal integral mode, which completely eliminated the second‐order MgKβ line. Second, the overlap of the first‐order FeLα on FKα peak, which cannot be filtered by modifying the PHA setting, was calibrated quantitatively using F‐free minerals and silicate glasses. Applying this two‐step method, F was determined in a number of reference glasses, as well as in glasses synthesised from powders of the rock reference materials AC‐E, GS‐N and DR‐N. Our data are consistent within error with F concentrations determined by other methods, demonstrating the reliability of this method.  相似文献   

Variation of molybdenum isotopes in molybdenite from porphyry and vein Mo deposits in the Gangdese metallogenic belt,Tibetan plateau and its implications   总被引：1，自引：0，他引：1  

Yong Wang  Lian Zhou  Shan Gao  Jian-Wei Li  Zhi-Fang Hu  Lu Yang  Zhao-Chu Hu 《Mineralium Deposita》2016,51(2):201-210

  相似文献   

Interannual variability of summer rainfall over the northern part of China and the related circulation features     

布和朝鲁  李妍  林大伟  廉毅 《Acta Meteorologica Sinica》2016,30(5):615-630

In this study, interannual variability of summer rainfall over the northern part of China (NPC) and associated circulation patterns were investigated by using long-term (1961–2013) observational and reanalysis data. Two important NPC rainfall modes were identified by empirical orthogonal function analysis: the first is characterized by an almost uniformly distributed rainfall anomaly over most parts of the NPC, while the second shows rainfall variability in Northeast China (NEC) and its out-of-phase relationship with that in North China (NC) and the northern part of Northwest China. The results also suggest that the NPC summer rainfall anomalies are also closely associated with those in some other parts of China.It is revealed that the circumglobal teleconnection pattern associated with the anomalous Indian summer monsoon (ISM) and the Polar/Eurasia (PEA) pattern work in concert to constitute the typical circulation pattern of the first rainfall mode. The cooperative engagement of the anomalous ISM circulation and the PEA pattern is fundamental in transporting water vapor to the NPC. The study emphasizes that the PEA pattern is essential for the water vapor transport to the NPC through the anomalous midlatitude westerly.In the second NPC rainfall mode, the typical circulation pattern is characterized by the anomalous surface Okhotsk high and the attendant lower tropospheric circulation anomaly over NEC. The circulation anomaly over NEC leads to a redistribution of water vapor fluxes over the NPC and constitutes an out-of-phase relationship between the rainfall anomalies over NEC and NC.  相似文献   

Integrity monitoring-based ratio test for GNSS integer ambiguity validation     

Li  Liang  Li  Zishen  Yuan  Hong  Wang  Liang  Hou  Yanqing 《GPS Solutions》2016,20(3):573-585

GPS Solutions - The combination of multiple global navigation satellite systems (GNSSs) is able to improve the accuracy and reliability, which is beneficial for navigation in safety–critical...  相似文献   

利用芳烃参数研究煤系烃源岩中重排藿烷成因   总被引：4，自引：1，他引：3  

李红磊  张敏  姜连  程熊 《沉积学报》2016,34(1):191-199

研究发现鄂尔多斯盆地部分地区上古生界煤系烃源岩存在较高丰度的17α(H)-重排藿烷和早洗脱重排藿烷,在对重排藿烷分布、组成特征及生标组成特征研究的基础上,应用芳烃参数对高丰度重排藿烷的成因进行了探讨。饱和烃生物标志物组成特征显示,高重排藿烷与陆源高等植物生源关系密切,主要在弱氧化沉积环境下演化形成。具有高-异常高丰度17α(H)-重排藿烷和早洗脱重排藿烷(C₃₀*/C₃₀H>0.2、C₃₀E/C₃₀H>0.1)的烃源岩二环+三环芳烃相对含量一般大于50%,四环、五环芳烃含量相对较低,普遍低于35%,未见芳香甾萜类,研究认为其生源主要为陆生高等植物;甲基菲指数MPI₁、MPI₂和甲基菲比值F1研究结果显示,Pr/Ph>1的弱氧化环境烃源岩17α(H)-重排藿烷和早洗脱重排藿烷在进入成熟阶段后开始大量形成,并随成熟度升高而增大;Pr/Ph<1还原环境下的烃源岩重排藿烷丰度相对较低,但在进入成熟阶段后仍有随成熟度升高而增大的趋势;三芴系列化合物参数表明,沉积环境的弱氧化性质对17α(H)-重排藿烷和早洗脱重排藿烷的形成有较大的影响,沼泽相沉积环境最有利于重排藿烷的形成。  相似文献   

泰莱盆地土壤有机质含量及pH值对微量元素有效性的影响分析          下载免费PDF全文

冷旭勇  张宗元  刘丰武  刘连 《山东国土资源》2015,31(4)

土壤微量元素有效性,对农作物的生长及农产品的品质特征有重要的影响作用。该文首先阐述了泰莱盆地土壤微量元素有效性情况,分析探讨了土壤有机质含量及pH值对泰莱盆地土壤微量养分的有效性影响。结果表明：有效铜、硼和锌的含量有随着土壤中有机质含量增加而增大的趋势;有效硼的含量有随着土壤pH值升高而增大的趋势,有效铁、锰和钼的含量随着pH值的升高逐渐降低。  相似文献   

重力仪一次项系数对重力场动态变化的影响研究   总被引：1，自引：0，他引：1  

梁伟锋  刘芳  祝意青  徐云马  郭树松  赵云峰  刘练 《大地测量与地球动力学》2015,35(5):882-886

利用2011~2013喜马拉雅项目在南北地震带北段获得的10余个绝对重力值作为基准,运用甘肃、宁夏和河西3个重力网的数据对各重力仪一次项系数进行重新解算,获得重力场动态变化。结果显示:1)2011-05~2013-06的重力场反映出,青藏高原深部物质向北东运移过程中出现自西南向东北、由负向正的大空间尺度趋势性显著重力变化;2)LCR-G型及Burris型金属弹簧重力仪的一次项较稳定,基本不变,而CG-5型石英弹簧重力仪的一次项逐年减小,应每年利用绝对基准进行实测标定;3)利用绝对基准进行实测一次项标定后,重力场总的变化趋势与利用长基线标定的一次项计算结果基本一致,只是量级有所减小。  相似文献   

中国大陆斑岩铜矿资源潜力定量评价   总被引：1，自引：0，他引：1  

严光生  邱瑞照  连长云  曹黎  陈秀法  毛景文  肖克炎  李锦轶  肖庆辉  周肃  王明燕  刘大文  元春华  韩九曦  王靓靓  陈正  陈玉明  谢桂青  丁建华 《地学前缘》2007,14(5):27-41

应用美国"三部式"资源评价方法原理,对中国大陆斑岩铜矿成矿地质背景、时空分布规律、矿床模型等方面研究,圈出46个远景区;以中国1999年金属储量数据库和区划矿产地数据为基础,建立了铜矿数据库共984个,分不同类型进行品位吨位的研究,以此为基础构造出数字找矿模型和开发出矿产资源定量评价模型程序,并计算了每个远景区的概率资源量,为评估中国斑岩铜矿资源潜力提供了参照。  相似文献   

95 Ma是华南晚中生代岩浆演化转折点吗？——来自浙闽典型花岗岩体的证据     

高秦  丁嘉林  张延青  周鹏  曾志杰  厉子龙 《地质论评》2022,68(5):1760-1771

中国东南沿海地区出露的大面积中生代岩浆岩与矿化作用与区域构造域转换密切相关,在100~90 Ma左右浙闽地区壳幔作用强烈,前人大多数的研究工作是针对单个岩体或几个复式岩体展开的相应研究工作,缺少对浙闽沿海中生代花岗岩类的跨区域研究,特别是具体时间节点的对比和剖析。本研究选取浙闽地区100~90 Ma形成的典型花岗岩体为研究对象,通过对其进行地球化学数据分析和整理,并与前人在华南地区的研究数据相结合,认为100~90 Ma的浙闽花岗岩不同于日本和安第斯型的典型岛弧酸性岩。浙闽花岗岩可能起源于古太平洋板块俯冲引起基性岩浆上涌,少量基性岩浆与花岗质岩浆以不同比例混合形成了这一时期东南沿海中生代花岗岩类的母岩浆。地壳组成的差异造成浙闽一带形成的母岩浆的不同,而花岗质岩体则是在这种不同母岩浆基础上高度演化的结果。利用Rhyolite—MELTS方法计算浙闽地区在100~90 Ma的岩浆过程,以福建长泰岩体为例,在含水量为6%,压力为300 MPa 的条件下进行模拟,计算结果显示98 Ma岩体的分离结晶程度约37%,而从95 Ma开始,岩浆演化开始趋向于无明显规律。浙闽中生代花岗岩体显示以斜长石、钾长石、黑云母的分离结晶为主导的结晶过程,不同岩体的分离结晶程度有所不同。特别是在95 Ma时,浙闽一带的岩体同时出现了斜长石的分离结晶作用,随后又进入由钾长石和黑云母的分离结晶控制的阶段,结合Sr、Ba的变化特征和Nd同位素等变化,认为95 Ma左右存在地幔物质的介入,从而导致浙闽地区在晚中生代岩浆演化上出现了转变,而且95 Ma很可能是浙闽晚中生代花岗岩形成的转折期,岩浆温度的计算结果也证实了这一点。  相似文献