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1.
Almeev Renat; Holtz Francois; Koepke Jurgen; Haase Karsten; Devey Colin 《Journal of Petrology》2008,49(1):25-45
Phase equilibria simulations were performed on naturally quenchedbasaltic glasses to determine crystallization conditions priorto eruption of magmas at the Mid-Atlantic Ridge (MAR) east ofAscension Island (7–11°S). The results indicate thatmid-ocean ridge basalt (MORB) magmas beneath different segmentsof the MAR have crystallized over a wide range of pressures(100–900 MPa). However, each segment seems to have a specificcrystallization history. Nearly isobaric crystallization conditions(100–300 MPa) were obtained for the geochemically enrichedMORB magmas of the central segments, whereas normal (N)-MORBmagmas of the bounding segments are characterized by polybariccrystallization conditions (200–900 MPa). In addition,our results demonstrate close to anhydrous crystallization conditionsof N-MORBs, whereas geochemically enriched MORBs were successfullymodeled in the presence of 0·4–1 wt% H2O in theparental melts. These estimates are in agreement with direct(Fourier transform IR) measurements of H2O abundances in basalticglasses and melt inclusions for selected samples. Water contentsdetermined in the parental melts are in the range 0·04–0·09and 0·30–0·55 wt% H2O for depleted and enrichedMORBs, respectively. Our results are in general agreement (within±200 MPa) with previous approaches used to evaluate pressureestimates in MORB. However, the determination of pre-eruptiveconditions of MORBs, including temperature and water contentin addition to pressure, requires the improvement of magma crystallizationmodels to simulate liquid lines of descent in the presence ofsmall amounts of water. KEY WORDS: MORB; Mid-Atlantic Ridge; depth of crystallization; water abundances; phase equilibria calculations; cotectic crystallization; pressure estimates; polybaric fractionation 相似文献
2.
Fleurice Parat François Holtz Miloš René Renat Almeev 《Contributions to Mineralogy and Petrology》2010,159(3):331-347
The equilibrium phase relations of a mafic durbachite (53 wt.% SiO2) from the Třebíč pluton, representative of the Variscan ultrapotassic magmatism of the Bohemian Massif (338–335 Ma), have
been determined as a function of temperature (900–1,100°C), pressure (100–200 MPa), and H2O activity (1.1–6.1 wt.% H2O in the melt). Two oxygen fugacity ranges were investigated: close to the Ni–NiO (NNO) buffer and 2.6 log unit above NNO
buffer (∆NNO + 2.6). At 1,100°C, olivine is the liquidus phase and co-crystallized with phlogopite and augite at 1,000°C for
the whole range of investigated pressure and water content in the melt. At 900°C, the mineral assemblage consists of augite
and phlogopite, whereas olivine is not stable. The stability field of both alkali feldspar and plagioclase is restricted to
low pressure (100 MPa) at nearly water-saturated conditions (<3–4 wt.% H2O) and T < 900°C. A comparison between experimental products and natural minerals indicates that mafic durbachites have a near-liquidus
assemblage of olivine, augite, Ti-rich phlogopite, apatite and zircon, followed by alkali feldspar and plagioclase, similar
to the mineral assemblage of minette magma. Natural amphibole, diopside and orthopyroxene were not reproduced experimentally
and probably result from sub-solidus reactions, whereas biotite re-equilibrated at low temperature. The crystallization sequence
olivine followed by phlogopite and augite reproduces the sequence inferred in many mica-lamprophyre rocks. The similar fractionation
trends observed for durbachites and minettes indicate that mafic durbachites are probably the plutonic equivalents of minettes
and that K- and Mg-rich magmas in the Bohemian Massif may have been generated from partial melting of a phlogopite–clinopyroxene-bearing
metasomatized peridotite. Experimental melt compositions also suggest that felsic durbachites can be generated by simple fractionation
of a more mafic parent and mixing with mantle-derived components at mid crustal pressures. 相似文献
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4.
Electron Probe Microanalysis of Bromine in Minerals and Glasses with Correction for Spectral Interference from Aluminium,and Comparison with Microbeam Synchrotron X‐Ray Fluorescence Spectrometry 
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下载免费PDF全文 Chao Zhang Jinru Lin Yuanming Pan Renfei Feng Renat R. Almeev Francois Holtz 《Geostandards and Geoanalytical Research》2017,41(3):449-457
The strong spectral interference between Br‐ and Al‐induced X‐ray lines hampers the utilisation of electron probe microanalysis (EPMA) for measuring Br mass fractions in Al‐bearing minerals and glasses. Through measuring Br‐free Al‐bearing materials, we established an EPMA method to quantify the overlap from AlKα on BrLβ, which can be expressed as a linear function of the Al2O3 content. The count rate of the BrLβ peak signal was enhanced by high beam currents and long measurement times. Application of this EPMA method to Al‐ and Br‐bearing materials, such as sodalite and scapolite, and to five experimental glasses yielded Br mass fractions (in the range of 250–4000 μg g?1) that are consistent with those measured by microbeam synchrotron X‐ray fluorescence (μ‐SXRF) spectrometry. The EPMA method has an estimated detection limit of ~ 100–300 μg g?1. We propose that this method is useful for measuring Br mass fractions (hundreds to thousands of μg g?1) in Al‐bearing minerals and glasses, including those produced in Br‐doped experiments. In addition, the natural marialitic scapolite (ON70) from Mpwapwa (Tanzania) containing homogeneously distributed high mass fractions of Br (2058 ± 56 μg g?1) and Cl (1.98 ± 0.03% m/m) is an ideal reference material for future in situ analyses. 相似文献
5.
Le Duc Luong Shakirov Renat B. Hoang Nguyen Shinjo Ryuichi Obzhirov Anatoly Syrbu Nadezhda Shakirova Maria 《Water Resources》2019,46(5):807-816
Water Resources - This paper presents review of dissolved Rare Earth Elements (REE) and methane anomalies distribution in the East China Sea water column. In general, the REE concentrations of the... 相似文献
6.
Mud volcanoes and gas vents in the Okhotsk Sea area 总被引：5，自引：0，他引：5
Shakirov Renat Obzhirov Anatoly Suess Erwin Salyuk Anatoly Biebow Nicole 《Geo-Marine Letters》2004,24(3):140-149
Gas emissions from mud volcanoes on Sakhalin Island and water-column gas flares arising from cold seeps in the Okhotsk Sea appear to be related. They are likely activated by tectonic movements along the transform plate boundary separating the Okhotsk Sea Plate from the Eurasian and Amur plates. Gas vents (flares) and methane anomalies occur in the waters offshore Sakhalin Island, along with NE-SW-trending mounds and fluid escape structures on the seafloor. The intersection of the NE-striking transverse faults on land with the Central Sakhalin and Hokkaido-Sakhalin shear zones apparently determines the sites of mud volcanoes, a pattern that continues offshore where the intersection with the East Sakhalin and West Derugin shear zones determines the sites of the submarine gas vents. 相似文献
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8.
Torsten Bolte Francois Holtz Renat Almeev Barbara Nash 《Contributions to Mineralogy and Petrology》2015,169(2):15
The magma storage conditions of the 6.62 Ma Blacktail Creek Tuff eruption, belonging to the Heise volcanic field (6.62–4.45 Ma old) of the Yellowstone hotspot system, have been investigated by combining thermobarometric and experimental approaches. The results from different geothermometers (e.g., Fe–Ti oxides, feldspar pairs, apatite and zircon solubility, and Ti in quartz) indicate a pre-eruptive temperature in the range 825–875 °C. The temperature estimated using two-pyroxene pairs varies in a range of 810–950 °C, but the pyroxenes are probably not in equilibrium with each other, and the analytical results of melt inclusion in pyroxenes indicate a complex history for clinopyroxene, which hosts two compositionally different inclusion types. One natural Blacktail Creek Tuff rock sample has been used to determine experimentally the equilibrium phase assemblages in the pressure range 100–500 MPa and a water activity range 0.1–1.0. The experiments have been performed at fluid-present conditions, with a fluid phase composed of H2O and CO2, as well as at fluid-absent conditions. The stability of the quartzo-feldspathic phases is similar in both types of experiments, but the presence of mafic minerals such as biotite and clinopyroxene is strongly dependent on the experimental approach. Possible explanations are given for this discrepancy which may have strong impacts on the choice of appropriate experimental approaches for the determination of magma storage conditions. The comparison of the composition of natural phases and of experimentally synthesized phases confirms magma storage temperatures of 845–875 °C. Melt water contents of 1.5–2.5 wt% H2O are required to reproduce the natural Blacktail Creek Tuff mineral assemblage at these temperatures. Using the Ti-in-quartz barometer and the Qz–Ab–Or proportions of natural matrix glasses, coexisting with quartz, plagioclase and sanidine, the depth of magma storage is estimated to be in a pressure range between 130 and 250 MPa. 相似文献
9.
Experimental study into the petrogenesis of crystal-rich basaltic to andesitic magmas at Arenal volcano 总被引：1，自引：1，他引：0
F. Parat M. J. Streck F. Holtz R. Almeev 《Contributions to Mineralogy and Petrology》2014,168(2):1-18
Arenal volcano is nearly unique among arc volcanoes with its 42 year long (1968–2010) continuous, small-scale activity erupting compositionally monotonous basaltic andesites that also dominate the entire, ~7000 year long, eruptive history. Only mineral zoning records reveal that basaltic andesites are the result of complex, open-system processes deriving minerals from a variety of crystallization environments and including the episodic injections of basalt. The condition of the mafic input as well as the generation of crystal-rich basaltic andesites of the recent, 1968–2010, and earlier eruptions were addressed by an experimental study at 200 MPa, 900–1,050 °C, oxidizing and fluid-saturated conditions with various fluid compositions [H2O/(H2O + CO2) = 0.3–1]. Phase equilibria were determined using a phenocryst-poor (~3 vol%) Arenal-like basalt (50.5?wt% SiO2) from a nearby scoria cone containing olivine (Fo92), plagioclase (An86), clinopyroxene (Mg# = 82) and magnetite (Xulvö = 0.13). Experimental melts generally reproduce observed compositional trends among Arenal samples. Small differences between experimental melts and natural rocks can be explained by open-system processes. At low pressure (200 MPa), the mineral assemblage as well as the mineral compositions of the natural basalt were reproduced at 1,000 °C and high water activity. The residual melt at these conditions is basaltic andesitic (55 wt% SiO2) with 5 wt% H2O. The evolution to more evolved magmas observed at Arenal occurred under fluid-saturated conditions but variable fluid compositions. At 1,000 °C and 200 MPa, a decrease of water content by approximately 1 wt% induces significant changes of the mineral assemblage from olivine + clinopyroxene + plagioclase (5 wt% H2O in the melt) to clinopyroxene + plagioclase + orthopyroxene (4 wt% H2O in the melt). Both assemblages are observed in crystal-rich basalt (15 vol%) and basaltic andesites. Experimental data indicate that the lack of orthopyroxene and the presence of amphibole, also observed in basaltic andesitic tephra units, is due to crystallization at nearly water-saturated conditions and temperatures lower than 950 °C. The enigmatic two compositional groups previously known as low- and high-Al2O3 samples at Arenal volcano may be explained by low- and high-pressure crystallization, respectively. Using high-Al as signal of deeper crystallization, first magmas of the 1968–2010 eruption evolved deep in the crust and ascent was relatively fast leaving little time for significant compositional overprint by shallower level crystallization. 相似文献
10.
Eric Lichtfouse Karyne Rogers Cécile Payet Jean-Christophe Renat 《Geochemical transactions》2002,3(1):48
δ
13C values of crop and forest soils were measured 8 years after disposal of paper sewage sludge. The carbon transfer from paper
sludge downward to the first humic layer is evidenced by a 13C-enrichnient of up to + 5.6‰ due to the input of 13C-enriched sludge carbonates. 13C/12C composition is thus a novel, sensitive parameter to follow the downward transfer of paper sludge carbon. 相似文献