Sorption Characteristics of Rare Earth Element Eu^3＋ onto Silica-Water Interfaces Studied by Fluorescence Spectroscopy     

Yin Xiulan China Institute of Geo-environmental Monitoring  Beijing  China Hu Ping Faculty of Earth Sciences  China University of Geosciences  Wuhan  China  Northeastern Illinois University  Chicago  IL  USA Li Dien Division of Earth  Environmental Sciences  Los Alamos National Laboratory  Los Alamos  NM  USA 《中国地质大学学报(英文版)》2004,15(4):355-360

The sorption of Eu species onto nano-size silica-water interfaces was investigated using fluorescence spectroscopy for Ph ranges of 1-8.5 and an initial Eu concentration (Ceu) of 2×10-4 M. The sorption rate of Eu was initially low, but significantly increased at Ph>4. The sorption density of Eu species on a silica surface was ～1.58×10-7 mol/m2 when the dissolved Eu species were completely sorbed onto silica-water interfaces at Ph=～5.8. The sorbed Eu species at Ph<6 is aquo Eu3 , which is sorbed onto silica-water interfaces as an outer-sphere complex at Ph<5, but may be sorbed as an inner-sphere bidentate complex at 5相似文献   

DLG数据采集中的自动接边实现   总被引：1，自引：0，他引：1  

陈泽民  殷红霞 《现代测绘》2004,27(6):36-39

分析了实现自动接边中需要解决的基本问题，说明了DLG生产中不推荐使用曲线的理由，给出了接边程序的流程和关键算法。最后介绍了MAP系统中的自动接边功能。  相似文献   

中国大陆地区中强地震前加卸载响应比异常时间尺度的统计研究   总被引：4，自引：2，他引：4  

张晖辉  尹祥础  梁乃刚 《中国地震》2005,21(4):486-495

加卸载响应比理论是近年来提出的地震预测方法。本文进行了加卸载响应比异常时间尺度的统计研究，其中包括中国大陆地区5．0～8．1级的部分中强地震共30个震例，并得出加卸载响应比异常的时间尺度与未来地震震级之间的拟合函数。结果表明，地震前加卸载响应比异常的时间尺度与未来地震的震级具有正变关系，即震级越高，地震前加卸载响应比异常的时间尺度越长。根据加卸载响应比异常的时间尺度与震级之间的关系可以估计未来地震的发震时间，同时，可以确定加卸载响应比时空扫描过程中时问长度的大小。  相似文献   

Experimental study on reduction of U (Ⅵ) by an anaerobic bacterium, Shewanella putrefaciens: Application to sandstone-hosted interlayer oxidation-zone type uranium deposits, China     

MIN Maozhong  XU Huifang  L.L.Barton  PENG Xinjian  Yin Lin  WANG Rucheng 《中国科学D辑(英文版)》2005,48(3)

An experimental study on reduction of U (Ⅵ) by anaerobic bacteria, Shewane//a putrefaciens, is first reported here in China. The experimental conditions were: 35℃ and pH =7.0-7.4, corresponding to a physicochemical environments in which the sandstone-hosted interlayer oxidation-zone type uranium deposit formed in Northwest China's Xinjiang. Bacteria adopted in the present experiment, Shewanella putrefaciens, occur extensively in natural environment. Our study shows that nano-crystal precipitates of uraninite quickly occurred on the surface of the cells within one week. It was found that the pitchblende was characterized by a random arrangement of uraninite nanocrystals (2-4 nm) in it, significantly different from natural pitchblende in which uraninite nanocrystals are arranged in order. Finally, a possible mechanism of uranium biomineralization by microorganisms in the deposits is discussed. Our investigation may supply a technical train of thoughts for bioremediation of nuclear-contaminated water environments and for underground dissolving extraction of the sandstone-hosted uranium ores.  相似文献   

深基坑支护方案的分析与优化   总被引：3，自引：0，他引：3  

尹双  张仲先  王勇 《岩土工程技术》2005,19(3):152-154,F003

针对武汉市南湖岸边复杂的地质条件及周边环境,在某高层建筑的深基坑支护结构设计中,结合实际因地制宜地对基坑的支护方法进行了分析比较。支护效果及实测数据表明,该工程所采用的混合式支护实施方案技术安全可靠,经济合理,可为同类型基坑工程设计提供借鉴。  相似文献   

Impacts of the Wenchuan earthquake on tree mortality and biomass carbon stock     

Shuai Qiu  Ming Xu  Yunpu Zheng  Renqiang Li  Michelle Hang Gi Wong  Liyun Zhang  Lixiang Liu  Changhong Lai  Wen Zhang 《Natural Hazards》2015,77(2):1261-1274

  相似文献   

Long‐term streamflow trends in Hawai'i and implications for native stream fauna     

Hannah M. Clilverd  Yin‐Phan Tsang  Dana M. Infante  Abigail J. Lynch  Ayron M. Strauch 《水文研究》2019,33(5):699-719

Climate change has fundamentally altered the water cycle in tropical islands, which is a critical driver of freshwater ecosystems. To examine how changes in streamflow regime have impacted habitat quality for native migratory aquatic species, we present a 50‐year (1967–2016) analysis of hydrologic records in 23 unregulated streams across the five largest Hawaiian Islands. For each stream, flow was separated into direct run‐off and baseflow and high‐ and low‐flow statistics (i.e., Q10 and Q90) with ecologically important hydrologic indices (e.g., frequency of flooding and low flow duration) derived. Using Mann–Kendall tests with a running trend analysis, we determined the persistence of streamflow trends through time. We analysed native stream fauna from ~400 sites, sampled from 1992 to 2007, to assess species richness among islands and streams. Declines in streamflow metrics indicated a general drying across the islands. In particular, significant declines in low flow conditions (baseflows), were experienced in 57% of streams, compared with a significant decline in storm flow conditions for 22% of streams. The running trend analysis indicated that many of the significant downward trends were not persistent through time but were only significant if recent decades (1987–2016) were included, with an average decline in baseflow and run‐off of 10.90% and 8.28% per decade, respectively. Streams that supported higher native species diversity were associated with moderate discharge and baseflow index, short duration of low flows, and negligible downward trends in flow. A significant decline in dry season flows (May–October) has led to an increase in the number of no‐flow days in drier areas, indicating that more streams may become intermittent, which has important implications for mauka to makai (mountain to ocean) hydrological connectivity and management of Hawai'i's native migratory freshwater fauna.  相似文献   

Enhancement of backtracking search algorithm for identifying soil parameters     

Yin-Fu Jin  Zhen-Yu Yin 《国际地质力学数值与分析法杂志》2020,44(9):1239-1261

In this paper, an enhanced backtracking search algorithm (so-called MBSA-LS) for parameter identification is proposed with two modifications: (a) modifying the mutation of original backtracking search algorithm (BSA) considering the contribution of current best individual for accelerating convergence speed and (b) novelly incorporating an efficient differential evolution (DE) as local search for improving the quality of population. The proposed MBSA-LS is first validated with better performance than the original BSA and some other typical state-of-the-art optimization algorithms on a benchmark of soil parameter identification in terms of effectiveness, efficiency, and robustness. Then, the efficiency of the MBSA-LS is further illustrated by two representative cases: identifying soil parameters from both laboratory tests and field measurements. All comparisons demonstrate that the proposed MBSA-LS algorithm can give accurate results in a short time. Finally, to conveniently solve the problems of parameter identification, a practical tool ErosOpt for parameter identification is developed by integrating the proposed MBSA-LS and some other efficient algorithms for readers to conduct the parameter identification using optimisation algorithms.  相似文献   

Groundwater recharge in an arid grassland as indicated by soil chloride profile and multiple tracers          下载免费PDF全文

Tianming Huang  Zhonghe Pang  Jilai Liu  Lihe Yin  W. Mike Edmunds 《水文研究》2017,31(5):1047-1057

Previous studies have shown that shallow groundwater in arid regions is often not in equilibrium with near‐surface boundary conditions due to human activities and climate change. This is especially the case where the unsaturated zone is thick and recharge rate is limited. Under this nonequilibrium condition, the unsaturated zone solute profile plays an important role in estimating recent diffuse recharge in arid environments. This paper combines evaluation of the thick unsaturated zone with the saturated zone to investigate the groundwater recharge of a grassland in the arid western Ordos Basin, NW China, using the soil chloride profiles and multiple tracers (²H, ¹⁸O, ¹³C, ¹⁴C, and water chemistry) of groundwater. Whereas conventional water balance and Darcy flux measurements usually involve large errors in recharge estimations for arid areas, chloride mass balance has been widely and generally successfully used. The results show that the present diffuse recharge beneath the grassland is 0.11–0.32 mm/year, based on the chloride mass balance of seven soil profiles. The chloride accumulation age is approximately 2,500 years at a depth of 13 m in the unsaturated zone. The average Cl content in soil moisture in the upper 13 m of the unsaturated zone ranges from 2,842 to 7,856 mg/L, whereas the shallow groundwater Cl content ranges from 95 to 351 mg/L. The corrected ¹⁴C age of shallow groundwater ranges from 4,327 to 29,708 years. Stable isotopes show that the shallow groundwater is unrelated to modern precipitation. The shallow groundwater was recharged during the cold and wet phases of the Late Pleistocene and Holocene humid phase based on palaeoclimate, and consequently, the groundwater resources are nonrenewable. Due to the limited recharge rate and thick unsaturated zone, the present shallow groundwater has not been in hydraulic equilibrium with near‐surface boundary conditions in the past 2,500 years.  相似文献   

基于FME的国家基本比例尺图幅坐标系转换研究     

李帅  王丹  赵丽娜 《测绘与空间地理信息》2016,(4):207-208,211

我国测绘成果长期存在坐标系统不统一的现状,使得不同坐标系测绘成果的使用存在一定的局限性,无法充分地利用测绘成果。本文以1∶10 000比例尺成果数据从西安80系到国家2000系转换为例,详细地介绍了基于FME软件零编程实现坐标系转换的方法。  相似文献