DFT study of the carbonation on mineral aerosol surface models of olivine: effect of water     

Heping Xie  Wen Jiang  Zhengmeng Hou  Ying Xue  Yufei Wang  Tao Liu  Liang Tang  Dinglu Wu 《Environmental Earth Sciences》2017,76(21):732

Mineral aerosols play a significant role in gas–solid interfacial and atmospheric chemistry. Carbonation of olivine aerosol, which takes place in a multiphase reaction processes, can be an effective means to reduce the concentration of atmospheric carbon dioxide. Due to the presence of a huge reserve of silicate minerals in nature, olivine aerosol could be an ideal potential raw material for mineral carbonation for its higher reactivity with H₂O and CO₂. However, quantitative information about the carbonation process on the surface of natural olivine aerosol is not available. In this paper, calculations on the carbonation reaction processes with and without a H₂O molecule using a periodic olivine model has been carried out via the density functional theory. The pathways and their corresponding energies and structures in the carbonation reactions have been established, and the effect of water as means to reduce the energy barriers and stabilize the carbonated structures by forming hydrogen bonds has been confirmed.  相似文献   

Identifying gravity anomalies caused by granitic intrusions in Nanling mineral district,China: a multifractal perspective          下载免费PDF全文

Qiuming Cheng  Renguang Zuo  Tianyou Liu  Yufei Xi 《Geophysical Prospecting》2015,63(1):256-270

Several power‐law relationships of geophysical potential fields have been discussed recently with renewed interests, including field value–distance () and power spectrum–wavenumber () models. The singularity mapping technique based on the density/concentration–area (C–A) power‐law model is applied to act as a high‐pass filter for extracting gravity and magnetic anomalies regardless of the background value and to detect the edges of gravity or magnetic sources with the advantage of scale invariance. This is demonstrated on a synthetic example and a case study from the Nanling mineral district, Southern China. Compared with the analytic signal amplitude and total horizontal gradient methods, the singularity mapping technique provides more distinct and less noisy boundaries of granites than traditional methods. Additionally, it is efficient for enhancing and outlining weak anomalies caused by concealed granitic intrusions, indicating that the singularity method based on multifractal analysis is a potential tool to process gravity and magnetic data.  相似文献   

陆态网络腾冲台连续重力观测质量分析     

王新胜  贾路路  韩宇飞  连尉平  李强 《大地测量与地球动力学》2015,35(1):50-52

对陆态网络腾冲台2012-07-01~2013-06-30连续重力观测资料进行处理,获得该台站观测精度及噪声水平。结果表明,腾冲台1~100s噪声水平在9×10^-8ms^-2左右,100s~100min噪声水平在0.3×10^-8ms^-2左右,白噪声水平为0.509×10^-8ms^-2,对O₁波、M₂波等主要潮波振幅因子测量精度达到SG-053超导重力仪的观测量级,其中M₂波振幅因子测量精度最高（为0.000 18）。腾冲台可为川滇地区强震和腾冲火山活动监测、震前重力变化及相关研究提供高精度、可靠的连续重力观测资料。  相似文献   

基于生态需水的石羊河北部平原生态保障技术研究     

程玉菲  王军德  李元红  金彦兆  胡想全 《冰川冻土》2014,36(3):724-731

针对石羊河流域日益严峻的生态环境问题,选择干旱区生态需水计算为切入点,以变异理论为基础,利用Mann-Kendall非参数检验的方法确定石羊河北部平原区地下水位恢复的目标年,用生态功能区划方法划分生态功能区,利用达西定律、阿维里扬诺夫公式计算了地下水恢复及生态目标条件下的生态需水量,并提出了相应的生态保障措施. 结果表明：石羊河北部平原区划分为5个生态功能亚区及16个三级区,地下水位恢复的目标年份为1977年,地下水恢复到1977年的生态需水量为 55.95×10⁸~74.10×10⁸ m³,2015年和2020年生态目标条件下的生态需水分别为1.66×10⁸ m³和1.80×10⁸ m³. 考虑到地下水恢复的缓慢性和现实性,建议优先考虑设定目标条件下的植被正常生长生态需水,其次通过继续压缩人均耕地面积和灌溉定额的方式保证地下水恢复.  相似文献   

萨拉乌苏河流域萨拉乌苏组砂丘砂沉积特征     

欧先交  李保生  靳鹤龄  董光荣  章典  吴正  温小浩  曾兰华  欧阳椿陶  杨艺  刘宇飞 《地理学报(英文版)》2008,18(2):211-224

The Salawusu Formation of Milanggouwan section in Salawusu River Valley includes 7 layers of paleo-mobile dune sands, and 4 layers of paleo-fixed and semi-fixed dune sands. Their structures have been observed and their grain size, surface textural features and several main chemical elements have been analyzed. The results showed that： 1） Some of the aeolian structural characteristics of these dune sands are similar to that of the recent dune sands. 2） They are also similar to the recent dune sands in grain size components, and parameters of Mz,σ, Sk and Kg, as well as in several main chemical components. 3） The scattergrams of Mz-σ and SiO2-Al2O3＋TOFE and the probability curves of grain size showed that these paleo-dune sands are different from paleosols and fluvio-lacustrine facies, but are consistency with recent dune sands. 4） Quartz sands have well roundness and surface textural features such as dish-shaped pits, crescent-shaped pits, pockmarked pits, upturned cleavage plates, siliceous precipitates and siliceous crevasses, indicating that they had been carried for a long time by the wind. As the 11 layers of paleo-dune sands possess the aeolian characteristics in structure, grain size, surface textural features and chemical elements, the origin of their formation should be attributed to eolation.  相似文献   

Sedimentary characteristics of paleo-aeolian dune sands of Salawusu Formation in the Salawusu River Valley     

OU Xianjiao  LI Baosheng  JIN Heling  DONG Guangrong  David Dian ZHANG  WU Zheng  WEN Xiaohao  ZENG Lanhua  OUYANG Chuntao  YANG Yi  LIU Yufei 《地理学报》2008,18(2):211-224

The Salawusu Formation of Milanggouwan section in Salawusu River Valley in-cludes 7 layers of paleo-mobile dune sands, and 4 layers of paleo-fixed and semi-fixed dune sands. Their structures have been observed and their grain size, surface textural features and several main chemical elements have been analyzed. The results showed that: 1) Some of the aeolian structural characteristics of these dune sands are similar to that of the recent dune sands. 2) They are also similar to the recent dune sands in grain size components, and parameters of Mz, σ, Sk and Kg, as well as in several main chemical components. 3) The scattergrams of Mz-σ and SiO2–Al2O3+TOFE and the probability curves of grain size showed that these paleo-dune sands are different from paleosols and fluvio-lacustrine facies, but are consistency with recent dune sands. 4) Quartz sands have well roundness and surface textural features such as dish-shaped pits, crescent-shaped pits, pockmarked pits, upturned cleavage plates, siliceous precipitates and siliceous crevasses, indicating that they had been carried for a long time by the wind. As the 11 layers of paleo-dune sands possess the aeolian characteristics in structure, grain size, surface textural features and chemical elements, the origin of their formation should be attributed to eolation.  相似文献   

郯庐断裂带及两侧地区强震异常特征分析     

李建勇  李杰  张锐  李瑜  韩宇飞  王坦 《中国地震研究》2015,29(4):498-513

对郯庐断裂带及两侧的山东、辽宁、河北、江苏、江西等地区1966～2005年发生的24次中强以上地震的前兆观测异常,从异常持续时间、空间分布、时空相关性、异常形态、幅度特征、异常种类和可靠性等方面进行了系统的统计和分析,结果表明：①7级和6级地震中期异常最多,短期异常其次,临震异常最少。5级地震短期异常最多,其次是临震异常,中期异常最少;②异常具有阶段性特征,部分中期和短期地震前兆异常在发展过程中出现了短期或临震异常;③异常发展具有准同步性,越临近发震,异常转折项目越多;④异常主要出现在震中距100km范围内,在空间上具有相对集中性,且震中距越小,异常台项比越高;⑤异常空间分布与构造走向比较一致,显示出与构造较好的相关性;⑥异常持续时间与震中距之间没有显著的相关性;⑦震级越大,同一观测手段的异常幅度相对越大;⑧流体学科异常最多,其次是形变、电磁;⑨不同学科的异常均表现为中、短期异常为主,少数短临异常;⑩流体、形变和电磁学科较可靠异常数量均约为可靠异常的1倍。  相似文献   

页岩气地震识别与预测技术   总被引：2，自引：0，他引：2  

林建东  任森林  薛明喜  孙宇菲 《中国煤炭地质》2012,(8):56-60

依据页岩气的地质特点及当前地震勘查技术的水平,指出地震在识别和追踪页岩储层空间分布（包括埋深、厚度以及构造形态）方面具有明显的优势;综合利用测井及地质资料,对页岩储层有机质丰度、含气性等参数进行解释及优选敏感的地球物理参数,进而建立储层特征与地震响应的关系,以此反演预测页岩气储层有利区;运用相干与曲率等属性分析技术、宽方位甚至全方位地震各向异性分析技术、叠前反演技术、横波分裂技术等,可解决储层裂缝和岩石力学特征问题,直接为钻井和压裂工程技术服务;与压裂技术配套发展的微地震监测技术,可实时提供压裂过程中产生的裂缝位置、方位、大小以及复杂程度,并对储层改造方案的有效性作出准确评价。  相似文献   

适用于全国气象自动站正点相对湿度资料的质量控制方法   总被引：6，自引：5，他引：1  

赵煜飞  任芝花  张强 《气象科学》2011,31(6):687-693

在国家气象信息中心制作的全国自动站正点相对湿度资料数据集基础上,结合地面月报文件中相对湿度资料,通过深入分析错误数据的存在方式,最终研制形成全国自动站(包括国家级自动站和区域自动站)正点相对湿度资料质量控制方案.利用该方案,对2006-2009年实时上传的全国自动站正点相对湿度资料进行了质量评估,数据的可用率、可疑率、错误率分别为:96.68％、0.30％、3.02％.并指出当经过质量控制后,数据被判为可疑数据时,可考虑结合人工分析辅助判断.  相似文献   

gPhone重力仪网络数据采集系统中Web服务功能的设计与实现     

韩宇飞  刘子维  张锐  邹锐  江颖  李建勇  张晓彤 《大地测量与地球动力学》2016,36(5):460

针对gPhone重力仪网络数据采集系统,开发了一套嵌入式Web服务系统。基于uClinux平台和轻量级BOA Web服务器,利用C语言编写通用网关接口(CGI)程序,实现了远程数据下载及仪器监控等功能。  相似文献