The present study systematically investigates shock-induced alteration of organic simulants of planetary bodies (OSPBs) as a function of peak shock pressure and temperature by impact experiments. Our results show that the composition and structure of OSPBs are unchanged upon impacts at peak pressures ≤~5 GPa and temperatures ≤~350 °C. On the other hand, these are dramatically changed upon impacts at >7–8 GPa and > ~400 °C, through loss of hydrogen-related bonds and concurrent carbonization, regardless of the initial compositions of OSPBs. Compared with previous results on static heating of organic matter, we suggest that shock-induced alteration cannot be distinguished from static heating only by Raman and infrared spectroscopy. Our experimental results would provide a proxy indicator for assessing degree of shock-induced alteration of organic matter contained in carbonaceous chondrites. We suggest that a remote-sensing signature of the 3.3–3.6 μm absorption due to hydrogen-related bonds on the surface of small bodies would be a promising indicator for the presence of less-thermally-altered (i.e., <350 °C) organic matter there, which will be a target for landing to collect primordial samples in sample-return spacecraft missions, such as Hayabusa2 and OSIRIS-REx. 相似文献
We discuss several models of the evolution of the trench-trench-trench triple junction off central Honshu during the past 1 m.y. on the basis of plate kinematics, morphology, gravity and seismic reflection profile data available for the area. The study area is characterized by large basins, 7–8 km deep on the inner lower trench slope on the Philippine Sea side and the deep (9 km) Izu-Bonin Trench to the east. Between the basins and the trench, there are 6–7 km-deep basement highs. The triple junction is unstable due to the movement of the Philippine Sea plate at a velocity of 3 cm/yr in WNW direction with respect to Eurasia (Northeast Japan), subparallel to the strike of the Sagami Trough. Generally we can expect the boundary area between the Philippine Sea and Pacific plates to be extended because the Pacific plate is unlikely to follow the retreating Philippine Sea plate due to the obstruction of the southeastern corner of Eurasia. The above peculiar morphology of the junction area could have resulted from this lack of stability. However, there are several possible ways to explain the above morphology.
Our gravity model across the trench-basement high-basin area shows that the basement highs are made of low-density materials (1.8–2 g/cm3). Thus we reject the mantle diapir model which proposes that the basement highs have been formed by diapiric injection of serpentinites between the retreating Philippine Sea plate and the Pacific plate.
The stretched basin model proposes that the basins have been formed by stretching of the Philippine Sea plate wedge. We estimated the extension to be about 10 km at the largest basin. We reconstructed the morphology at 1 Ma by moving the Philippine Sea plate 20 km farther to the east after closing the basins, and thus obtained 8 km depth of the 1 Ma trench, which is similar to that of the present Japan Trench to the north. Although this stretched basin model can explain the formation of the basins and the deep trench, other models are equally possible. For instance, the eduction model explains the origin of the basin by the eduction of the Philippine Sea basement from beneath the basement high, while the accretion model explains the basement highs by the accretion of the Izu-Bonin trench wedge sediments. In both of these models we can reconstruct the 1 Ma trench depth as about 8 km, similar to that of the stretched basin model.
The deformation of the basement of the basins constitutes the best criterion to differentiate between these models. The multi-channel seismic reflection profiles show that the basement of the largest basin is cut by normal faults, in particular at its eastern edge. This suggests that the stretched basin model is most likely. However, the upper part of the sediments shows that the basement high to the east has been recently uplifted. This uplift is probably due to the recent (0.5 Ma) start of accretion of the trench wedge sediments beneath this basement high. 相似文献
Abstract The significance of timing and formation of mélange in accretionary prisms, particularly concerning basaltic and related rocks and pelagic sediments, is exemplified in the Sawadani area of the Jurassic Chichibu accretionary complex in Shikoku, southwest Japan. Major and trace element geochemistry of the basaltic and related rocks indicates that all are of a hot-spot origin which produced a seamount. Most of the rocks have a trend of differentiation from an alkalic parental magma. The time relationship between the blocks and matrices of the mélange deduced from radiolarian fossil evidence and macro- to microscopic characteristics of contacts between different lithologies indicates two stages of mixing of materials in the seafloor. The first mixing occurred on the flank of the seamount in the pelagic environments in the Late Permian, and the second occurred on the trench floor or in the accretionary prism after the Early Jurassic. These two stages show respectively the geological phenomena of a seamount within the Izanagi-Kula plate and its incorporation into the Asian continental margin. 相似文献
During the 1982 and 1983 Balloon Intercomparison Campaigns, the vertical profile of stratospheric NO2 was measured remotely by nine instruments and that of NO by two. Total overhead columns were measured by two more instruments. Between 30 and 35km, where measurements overlapped, agreement between NO profiles was within ±30%, which is better than the accuracies claimed by the experimenters. Between 35 and 40km there was similarly good agreement between NO2 profiles, but below 30km, differences of greater than a factor three were found. In the second Campaign, NO2 values from most instruments agreed within their quoted errors, except that the Oxford radiometer gave much lower values; but the first Campaign and the column measurements show a more uniform spread of results.These differences below 30km could not be resolved, but new laboratory measurements are planned which should do so. 相似文献
Through 2004 and 2005, δ34S of sinking material from Otsuchi Bay was measured at the center and rocky shore of the bay. At the center of the bay δ34S was high (18∼21‰) in the material collected from April to November. However, δ34S was low (9∼14‰) in the material collected from December to March. The increase in δ34S in April was attributed to an increase in phytoplankton biomass because marine phytoplanktonic δ34S is high. When δ34S of sinking material was low, input of riverine material or bottom sediment resuspension were considered as the probable
causes, because their δ34S is low. Marine sulfur was always high (more than 70%) at both stations. The difference between the δ34S of sinking material collected from the different sampling stations indicates that marine macroalgae contribute to sinking
material near the shore when phytoplankton is scarce. In conclusion, the relative influence of different material sources
to sinking materials could be successfully estimated using δ34S. 相似文献
A method for the analysis of selenium in marine aquatic products by HG-AFS has been investigated. The method is based on the reduction of inorganic selenium to volatile SeH2 which is bubbled out by carrier gas of pure argon, and then swept to Ar-H2 flame quarts atomizer to measure its fluorescence intensity. The hydride generation, transportation, atomization and some instrumental parameters were studied by a kind of orthogonal design. The optimum conditions selected are as follows: reactive acidity, 20% HC1; the amount of NaBH4, 4.9mL; gas flow of argon, 600mLmin^-1; atomizing temperature, 200 ℃ ; negative high voltage, - 300V; light current, 100 mA; integral time, 7s. The detection limit of the presented method is 0.072μgL^-1 for selenium. The calibration curve shows a satisfactory line inthe concentration range from 0.000 to 1.000μgL^-1 Se. The recovery is 95.8%-102.2%. 相似文献
Nine submersible dives were made in three trenches off central Japan, between 2990 and 5900 m of water depth. Our observations confirm the interpretation that Daiichi-Kashima Seamount is a Cretaceous guyot formed on the Pacific plate that has traveled into the Japan Trench. We also confirmed the previous interpretation of a large normal fault that splits the seamount in two halves, the lower one being now subducting beneath the Japan margin. Compressional deformation was identified within the lower part of the inner slope in front of the seamount. The pattern of deformation that affects Quaternary sediments is in agreement with the present kinematics of the convergence between the Pacific plate and Japan. Deep-water (5700 m) clam colonies are associated with advection of fluids, driven by the subduction-related overpressures. In the northern slope of the Boso Canyon, along the Sagami Trough system (Philippine Sea plate-Japan boundary), the deformation affecting a thick upper Miocene to lower Pliocene sequence indicates two directions of shortening: a N175°E direction which is consistent with the present relative motion along the Sagami Trough (N285–N300°E) and a N30°E direction which could be related to a more northerly direction of convergence that occured during the early Quaternary and earlier. 相似文献
High-temperature and high-pressure recovery experiments were made on experimentally deformed olivines at temperatures of 1613–1788 K and pressures of 0.1 MPa to 2.0 GPa. In the high-pressure experiments, a piston cylinder apparatus was used with BN and NaCl powder as the pressure medium, and the hydrostatic condition of the pressure was checked by test runs with low dislocation density samples. No dislocation multiplication was observed. The kinetics of the dislocation annihilation process were examined by different initial dislocation density runs and shown to be of second order, i.e. where ρ is the dislocation density, k0 is a constant, are the activation energy and volume respectively, and P, R and T are pressure, gas constant and temperature, respectively. Activation energy and volume were estimated from the temperature and pressure dependence of the dislocation annihilation rate as and , respectively.The diffusion constants relevant to the dislocation annihilation process were estimated from a theoretical relation k=αD where is the diffusion constant and α is a non-dimensional constant of ca. 300. The results agree well with the self-diffusion constant of oxygen in olivine. This suggests that the dislocation annihilation is rate-controlled by the (oxygen) diffusion-controlled dislocation climb.The mechanisms of creep in olivine and dry dunite are examined by using the experimental data of static recovery. It is suggested that the creep of dry dunite is rate-controlled by recovery at cell walls or at grain boundaries which is rate-controlled by oxygen diffusion. Creep activation volume is estimated to be 16±3 cm3 mol?1. 相似文献
Night airglow of oxygen 130.4 and 135.6 nm emissions was measured by a spectrophotometer aborad an S520 sounding rocket, launched at 19:50 JST (10:50 UT) on 14 February, 1982 from Kagoshima, Japan. The altitude variation of the emissions was obtained from 110 to 266 km at zenith angles of 35.5°±4°. The emission intensity around 260 km was about 160R and is roughly compatible with model calculations taking account of O++e– radiative recombination as well as O+–O– mutual neutralization. Some excess of about 50R, compared to the model calculation, was observed around 200 km. Possible explanations of the excess are: (i) remnant oxygen ions during the transition period from day to night and (ii) diffuse radiation from the background sky. Model calculations taking account of remnant oxygen ions were also performed by adding an excess electron density to the original density profile. However, it was found that an unreasonably large electron density is required around 200 km (5×105 cm–3) to produce the observed intensity. It is also probable that some contribution from the background sky is present in the observed intensity. 相似文献