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81.
Masaki Akaogi Akira TanakaEiji Ito 《Physics of the Earth and Planetary Interiors》2002,132(4):303-324
Phase relations in the system Mg4Si4O12-Mg3Al2Si3O12 were examined at pressures of 19-27 GPa and relatively low temperatures of 800-1000 °C using a multianvil apparatus to clarify phase transitions of pyroxene-garnet assemblages in the mantle. Both of glass and crystalline starting materials were used for the experiments. At 1000 °C, garnet solid solution (s.s.) transforms to aluminous ilmenite s.s. at 20-26 GPa which is stable in the whole compositional range in the system. In Mg4Si4O12-rich composition, ilmenite s.s. transforms to a single-phase aluminous perovskite s.s., while Mg3Al2Si3O12-rich ilmenite s.s. dissociates into perovskite s.s. and corundum s.s. These newly determined phase relations at 1000 °C supersede preliminary phase relations determined at about 900 °C in the previous study. The phase relations at 1000 °C are quite different from those reported previously at 1600 °C where garnet s.s. transforms directly to perovskite s.s. and ilmenite is stable only very close to Mg4Si4O12. The stability field of Mg3Al2Si3O12 ilmenite was determined at 800-1000 °C and 25-27 GPa by reversed phase boundaries. In ilmenite s.s., the a-axis slightly increases but the c-axis and molar volume decrease substantially with increasing Al2O3 content. Enthalpies of ilmenite s.s. were measured by differential drop-solution calorimetry method using a high-temperature calorimeter. The excess enthalpy of mixing of ilmenite s.s. was almost zero within the errors. The measured enthalpies of garnet-ilmenite and ilmenite-perovskite transitions at 298 K were 105.2±10.4 and 168.6±8.2 kJ/mol, respectively, for Mg4Si4O12, and 150.2±15.9 and 98.7±27.3 kJ/mol, respectively, for Mg3Al2Si3O12. Thermodynamic calculations using these data give rise to phase relations in the system Mg4Si4O12-Mg3Al2Si3O12 at 1000 and 1600 °C that are generally consistent with those determined experimentally, and confirm that the single-phase field of ilmenite expands from Mg4Si4O12 to Mg3Al2Si3O12 with decreasing temperature. The earlier mentioned phase relations in the simplified system as well as those in the Mg2SiO4-Fe2SiO4 system are applied to estimate mineral proportions in pyrolite as a function of depth along two different geotherms: one is a horizontally-averaged temperature distribution in a normal mantle, and the other being 600 °C lower than the former as a possible representative geotherm in subducting slabs. Based on the previously described estimated mineral proportions versus depth along the two geotherms, density and compressional and shear wave velocities are calculated as functions of depth, using available mineral physics data. Along a normal mantle geotherm, jumps of density and velocities at about 660 km corresponding to the post-spinel transition are followed by steep gradients due to the garnet-perovskite transition between 660 and 710 km. In contrast, along a low-temperature geotherm, the first steep gradients of density and velocities are due to the garnet-ilmenite transition between 610 and 690 km. This is followed by abrupt jumps at about 690 km for the post-spinel transition, and steep gradients between 700 and 740 km that correspond to the ilmenite-perovskite transition. In the latter profile along the low-temperature geotherm, density and velocity increases for garnet-ilmenite and ilmenite-perovskite transitions are similar in magnitude to those for the post-spinel transition. The likely presence of ilmenite in cooler regions of subducting slabs is suggested by the fact that the calculated velocity profiles along the low-temperature geotherm are compatible with recent seismic observations indicating three discontinuities or steep velocity gradients at around 600-750 km depth in the regions of subducting slabs. 相似文献
82.
83.
84.
Daisuke Yamazaki Eiji Ito Yoshinori Tange Takashi Yoshino Shuangmeng Zhai Hiroshi Fukui Anton Shatskiy Tomoo Katsura Ken-ichi Funakoshi 《Physics and Chemistry of Minerals》2007,34(4):269-273
In situ X-ray observations of the phase transition from ilmenite to perovskite structure in MnGeO3 were carried out in a Kawai-type high-pressure apparatus interfaced with synchrotron radiation. The phase boundary between
the ilmenite and perovskite structures in the temperature range of 700–1,400°C was determined to be P (GPa) = 16.5(±0.6) − 0.0034(±0.0006)T (°C) based on Anderson’s gold pressure scale. The Clapeyron slope, dP/dT, determined in this study is consistent with that for the transition boundary between the ilmenite and the perovskite structure
in MgSiO3. 相似文献
85.
K. Fujimoto A. Ueda T. Ohtani M. Takahashi H. Ito H. Tanaka Anne-Marie Boullier 《Tectonophysics》2007,443(3-4):174
The active fault drilling at Nojima Hirabayashi after the 1995 Hyogoken-nanbu (Kobe) earthquake (MJMA = 7.2) provides us with a unique opportunity to investigate subsurface fault structure and the in-situ properties of fault and fluid. The borehole intersected the fault gouge of the Nojima fault at a depth interval of 623 m to 625 m. The lithology is mostly Cretaceous granodiorite with some porphyry dikes.The fault core is highly permeable due to fracturing. The borehole water was sampled in 1996 and 2000 from the depth interval between 630 and 650 m, just below the fault core. The chemical and isotopic compositions were analyzed. Carbon and oxygen isotope ratios of carbonates from the fault core were analyzed to estimate the origin of fluid.The following conclusions were obtained. (1) The ionic and isotopic compositions of borehole water did not change from 1996 to 2000. They are mostly derived from local ground water as mentioned by Sato and Takahashi [Sato, T., Takahashi, M., 2000. Chemical and isotopic compositions of groundwater obtained from the Hirabayashi well. Geological Survey of Japan Interim Report No. EQ/00/1, 187–192.]. (2) Geochemical speciation revealed that the borehole water was derived from a relatively deep reservoir, which may be situated at a depth of 3 to 4 km where the temperature is about 80–90 °C. (3) The shallower part of the Nojima fault (shallower than the reservoir depth) has not been healed from the hydrological viewpoints 5 years after the event, in contrast to the rapid healing detected by S wave splitting [Tadokoro, K., Ando, M., 2002. Evidence for rapid fault healing derived from temporal changes in S wave splitting, Geophys. Res. Lett., 29, 10.1029/2001GL013644.]. (4) Precipitation of calcite from the present borehole water since drilling supports the idea of precipitation of some calcite in coseismic hydraulic fractures in the fault core [Boullier, A-M., Fujimoto, K., Ohtani, T., Roman-Ross, G., Lewin, E., Ito, H., Pezard, P., Ildefonse, B., 2004. Textural evidence for recent co-seismic circulation of fluids in the Nojima fault zone, Awaji Island, Japan., Tectonophysics, 378, 165–181.]. (5) Carbon and oxygen isotope ratios of calcite indicated that the meteoric water flux had been localized at the fault core. (6) A difference in the carbon isotope ratio between the footwall and the hanging wall suggests that the fault has been acted as a hydrologic barrier, although the permeability along the fault is still high. 相似文献
86.
Summary. Middle Precambrian and Cretaceous kimberlites were collected from three sites (Premier, Montrose and National) and two sites (Wesselton and Koffyfontein) in South Africa respectively. The natural remanent magnetization of these rocks remains stable to both alternating field and thermal demagnetization. The virtual geomagnetic pole-positions derived from the directions of stable remanence of the Precambrian rocks can be correlated with palaeomagnetic poles obtained from other Middle-Late Precambrian rocks in Africa. The Cretaceous poles for the Wesselton and the Koffyfontein rocks coincide with other Cretaceous poles. 相似文献
87.
Michio Hashizume Kiyoshi Ito Toshikatsu Yoshii 《Geophysical Journal International》1981,66(1):157-168
Summary. Two record sections have been prepared for a series of explosions near Lake Biwa, south-western Honshu, Japan. The record sections cover both the array stations and the network of microearthquake stations that are distributed throughout the area. This enabled us to detect for the first time in the Japanese islands the phase reflected at the Mohorovicić discontinuity. Until now the weakness and obscurity of the phase has made it difficult to detect. We were able to overcome this problem by processing the seismograms to enhance the phase. Our work leads us to propose that the surface of the Mohorović discontinuity may be divided into pieces by a number of deep faults, while a thin layer of ultrabasic rock in the lower crust may account for the weakness of the signal. 相似文献
88.
Mn-carbonates are documented in the late-glacial varved sediments from Big Watab Lake, Minnesota, USA. The Mn-carbonate is authigenic and forms rims around contemporaneous epilimnetic calcite. Although such carbonates are found in minor amounts throughout the entire late-glacial sequence, significant quantities of Mn-carbonate are associated mainly with laminated intervals.Because of the suspected difference in isotopic fractionation between different carbonate minerals, the stable-isotopic compositions of bulk carbonate samples are used as a proxy for relative amounts of the Mn-carbonate in the sediment. High 18O and low 13C values are associated with abundant Mn-carbonates. Low 18O and high 13C values are associated with only minor concentrations of Mn-carbonates.The oxygen-18 record is correlated with fluctuations in the vegetation assemblage based on pollen spectra using a multiple regression model with backward elimination. The proposed link between the sedimentary archive and local vegetation is the mediation of advective mixing in the lake by forest composition. In this model, periods of forest closure resulted in a well-stratified water column that was anoxic at the sediment/water interface, permitting the formation of authigenic Mn-carbonates. Openings of Artemisia in the forest allowed wind shear to mix oxygen to depth, causing bioturbation of the laminations and preventing the formation of Mn-carbonate. 相似文献
89.
Akihiko Ito 《Climate Dynamics》2005,24(5):435-448
A terrestrial ecosystem model (Sim-CYCLE) was driven by multiple climate projections to investigate uncertainties in predicting the interactions between global environmental change and the terrestrial carbon cycle. Sim-CYCLE has a spatial resolution of 0.5°, and mechanistically evaluates photosynthetic and respiratory CO2 exchange. Six scenarios for atmospheric-CO2 concentrations in the twenty-first century, proposed by the Intergovernmental Panel on Climate Change, were considered. For each scenario, climate projections by a coupled atmosphere–ocean general circulation model (AOGCM) were used to assess the uncertainty due to socio-economic predictions. Under a single CO2 scenario, climate projections with seven AOGCMs were used to investigate the uncertainty stemming from uncertainty in the climate simulations. Increases in global photosynthesis and carbon storage differed considerably among scenarios, ranging from 23 to 37% and from 24 to 81 Pg C, respectively. Among the AOGCM projections, increases ranged from 26 to 33% and from 48 to 289 Pg C, respectively. There were regional heterogeneities in both climatic change and carbon budget response, and different carbon-cycle components often responded differently to a given environmental change. Photosynthetic CO2 fixation was more sensitive to atmospheric CO2, whereas soil carbon storage was more sensitive to temperature. Consequently, uncertainties in the CO2 scenarios and climatic projections may create additional uncertainties in projecting atmospheric-CO2
concentrations and climates through the interactive feedbacks between the atmosphere and the terrestrial ecosystem. 相似文献
90.
S. Ono E. Ito T. Katsura A. Yoneda M. J. Walter S. Urakawa W. Utsumi K. Funakoshi 《Physics and Chemistry of Minerals》2000,27(9):618-622
In situ synchrotron X-ray experiments in the system SnO2 were made at pressures of 4–29 GPa and temperatures of 300–1400 K using sintered diamond anvils in a 6–8 type high-pressure
apparatus. Orthorhombic phase (α-PbO2 structure) underwent a transition to a cubic phase (Pa3ˉ structure) at 18 GPa. This transition was observed at significantly lower pressures in DAC experiments. We obtained the
isothermal bulk modulus of cubic phase K
0 = 252(28) GPa and its pressure derivative K
′=3.5(2.2). The thermal expansion coefficient of cubic phase at 25 GPa up to 1300 K was determined from interpolation of the
P-V-T data obtained, and is 1.7(±0.7) × 10−5 K−1 at 25 GPa.
Received: 7 December 1999 / Accepted: 27 April 2000 相似文献