自然铜、铜合金矿物及其矿床形成机理新探索   总被引：8，自引：1，他引：8  

郑大中  郑若锋 《四川地质学报》2002,22(2):72-81

描述了自然铜、铜合金矿物及其矿床形成的新机制。在岩浆及热液中，铜及铜合金可呈氢化物、羧基配合物及纳米粒子活性、迁移、富集形成自然铜矿床，或经以后的地质事件，长期、多次迁移富集，叠加形成富而大的自然铜矿床。在表生条件下，铜的硫化矿物被氧化分解，可形成亚铜的硫代硫酸盐及氯配合物，部分可形成铜的硫酸盐配合物迁移，由于硫代硫酸盐被氧化，亚铜岐化可形成高纯度的自然铜，但它易氧化形成孔雀石、蓝铜矿、赤铜矿、黑铜矿、硅孔雀石等，因此很难形成自然铜矿床。  相似文献   

Burial of redox-sensitive metals and organic matter in the equatorial Indian Ocean linked to precession     

Delphine PaillerEdouard Bard  Frauke RostekYan Zheng  Richard MortlockAlexander van Geen 《Geochimica et cosmochimica acta》2002,66(5):849-865

Authigenic metals (uranium, cadmium, and molybdenum), organic carbon (OC) and total C₃₇ alkenone (totC₃₇) concentrations were measured for the last 350 kyr in core MD900963, located in the eastern equatorial Arabian Sea. Authigenic metal concentrations on a carbonate-free basis range between 1 and 17 ppm, 0.5 and 6 ppm, and 0.5 and 4 ppm for U, Cd, and Mo, respectively. The profiles are characterized by well-defined 23 kyr cycles between oxic and mildly suboxic conditions. The redox-sensitive metal profiles also follow variations in the concentrations of OC (0.2-0.9%) and alkenones (0.2-6.7 ppm). The coupled variations in inorganic and organic constituents are attributed to a 23-kyr cycle in primary production above site MD900963, as suggested by clear correlations with independent micropaleontologic proxies (primary productivity indices based on foraminifera and coccoliths and fragmentation of foraminiferal shells). The 23-kyr cycles do appear to be primarily driven by productivity rather than changes in bottom water oxygen. Comparison with other records indicates that if this interpretation is correct, productivity variations across much of the Indian Ocean have been dominated by precessional forcing, with high productivity in phase with low summer insolation in the Northern Hemisphere. This interpretation contrasts with the traditional attribution of enhanced productivity in the Indian Ocean with periods of high summer insolation.  相似文献   

Relationships between tissue concentrations of chlorinated hydrocarbons (polychlorinated biphenyls and chlorinated pesticides) and antioxidative responses of marine mussels, Perna viridis     

C. C. C. Cheung  G. J. Zheng  P. K. S. Lam  B. J. Richardson 《Marine pollution bulletin》2002,45(1-12)

Marine mussels, Perna viridis, were transplanted from a reference site to various polluted sites around Hong Kong. After 30 d of exposure, antioxidative responses in the gills and hepatopancreas and tissue concentrations of chlorinated hydrocarbons [polychlorinated biphenyls (PCBs) and chlorinated pesticides (CPs)] were determined for individual mussels. Glutathione S transferase (GST) and glutathione (GSH) were positively correlated with tissue PCB concentrations. Only one of the enzymatic antioxidants, glutathione peroxidase (GPx), showed significant response to tissue PCB. No significant correlation was found between tissue concentrations of chlorinated hydrocarbons and other enzymatic antioxidants (superoxide dismutase (SOD), catalase (CAT), glutathione reductase (GR) and NADPH DT-diaphorase (DT-d). Oxidative stress, measured as thiobarbituric acid reactive substances, was correlated with chlorinated pesticide concentrations in tissues. This study demonstrated a correlation between GST/GSH and chlorinated hydrocarbons. The apparent lack of correlation between trace organic pollutants and some of the enzymatic antioxidants may be due to the inhibitory effects caused by these chemicals. The above results suggest that more investigations are needed before these enzymes can be used as biomarkers.  相似文献   

Chemical equilibria of thermal waters for the application of geothermometers from the Guanzhong basin, China     

Zheng Xilai  Halldor Armannsson  Li Yongle  Qiu Hanxue 《Journal of Volcanology and Geothermal Research》2002,113(1-2)

In this study, representative samples from thermal wells and springs were chemically analyzed and geothermometers were used to calculate the deep temperatures of geothermal reservoirs on the basis of water–mineral equilibrium. In some cases, however, the chemical components are not in equilibrium with the minerals in the reservoir. Therefore, log(Q/K) diagrams are used to study the chemical equilibrium for the minerals that are likely to participate. The Na–K–Mg triangular diagram is also applied to evaluate the equilibrium of water with reservoir rocks. Standard curves at the reference temperatures are prepared to reveal which type of silica geothermometer is appropriate for the specified condition. This study shows that water samples from geothermal wells W9 and W12 are in equilibrium with the selective minerals, and chalcedony may control the fluid–silica equilibrium. It is estimated that there is an exploitable low-temperature reservoir with possible temperatures of 80–90°C in the Guanzhong basin.  相似文献   

Modelling of meteorological conditions at an urban scale for the PUMA winter campaign     

X.-M Cai  Y Zheng  G.R McGregor 《Physics and Chemistry of the Earth》2002,27(35):1479-1485

For the winter 2000 campaign of the Pollution of Urban Midlands Atmosphere project, observation and numerical modelling of meteorological conditions over the West Midlands conurbation, UK, was undertaken. Modelling was performed using the regional atmospheric meteorological system (RAMS). This paper presents a comparison of modelled and observed wind and temperature for 25 and 26 January 2000. The RAMS model uses two nested grids with a mesh size of 2 km for the inner grid which is embedded in the outer grid with a mesh size of 8 km. Statistical evaluation of the model results against the observational data of wind speed, direction and temperature at 10 m was conducted. In general, the modelling results are in a reasonable agreement with observation. The statistical evaluation suggests that model performance is poorer for the inner grid than the outer grid as the model uncertainties (mainly mean bias) transfer from the outer to inner one. The low indices of agreement of temperature and wind are mainly associated with the systematic root-mean-square-difference values. For temperature, the systematic bias may also be affected by representation of cloud amount by the model. For wind, the model tends to have a poor performance for calm conditions, as under a stable anti-cyclonic situation local wind patterns associated with topography may develop, although the topography of the region is relatively flat. The results for the inner grid reveal some subtle spatial patterns at a scale smaller than 10 km near hills and valleys with differences in elevation of a few hundred metres.  相似文献   

多种驱动力作用下东亚大陆形变及应力场演化   总被引：7，自引：0，他引：7  

李祖宁  傅容珊  郑勇  董树谦 《地震学报》2002,24(1):17-26

将印度板块持续地向北推进、下伏地幔小尺度对流对增厚大陆岩石层的搬离作用以及剥蚀作用视为形成现今东亚大陆形变和应力场格局的主驱动力。在一梯形区域内，利用数值模拟的方法，研究了东亚大陆在不同的边界条件、不同的剥蚀率系数及不同的岩石力学参数条件下的形变及应力场格局。与现代空间大地测量技术 CGPS)以及利用地震观测得到的结果进行了对比。结果表明，本文模型预测的结果与上述的观测结果有较好的吻合，其西部地区比东部吻合得更好。说明控制东亚大陆西部形变和应力场基本格局的主驱动力，来源于印度板块对欧亚板块的碰撞、挤压，而对东部地区还应当考虑其与太平洋板块和菲律宾板块的相互作用。与此同时，下伏地幔小尺度对流对增厚大陆岩石层的搬离作用以及风化剥蚀对应力场的演化过程也不可忽视。   相似文献   

Basalt platforms in Inner Mongolia and Hebei Province, northeastern China: New K–Ar ages, geochemistries, and revision of palaeomagnetic results     

Zhong Zheng  Hidefumi Tanaka  Yoshiyuki Tatsumi  Masaru Kono 《Geophysical Journal International》2002,151(2):654-662

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“面向区域”的GIS控件的设计与使用   总被引：4，自引：0，他引：4  

陈正江 《地理研究》2003,22(2):227-236

本文提出了一个“面向区域”GIS控件的概念———即以特定的地理区域为对象,将基础地理信息连同有关的GIS功能操作融合为一个可重用的程序模块,以Microsoft的COM(即“组件对象模型”)技术为基础,组织为“GIS化”的ActiveX控件。这种GIS控件,将面向对象技术中的“对象”扩展到了整个特定的地理区域空间,其核心思想是不仅封装了GIS的数据模型,必要的功能操作,而且封装了所有的基础地理信息。由于省去了对空间数据的处理,因而这种GIS控件可被广大非GIS专业的信息系统开发者灵活、简便地用于各种管理信息系统、办公自动化系统和决策支持系统的GIS功能扩充,也可用于构建一般的地理信息系统,因而有利于GIS技术应用的普及。文章最后给出了有关陕西省的应用实例  相似文献   

电法勘探在汤岗子地热田中的应用   总被引：1，自引：0，他引：1  

崔瑞华  谷社  李争  李清华 《地质找矿论丛》2003,18(Z1):196-199

文章从不同岩石的电性差异及地热区视电阻率与温度的关系出发,通过综合电法在汤岗子地热田又找到了新的地热资源,说明综合电法对勘查地热是行之有效的.  相似文献   

求解变分不等式的Newton迭代的半局部收敛性分析     

王征宇  沈祖和 《华东地质学院学报》2003,26(2):159-162

分析了求解变分不等式Newton方法的半局部收敛性，建立了类似于Kantorovich定理的收敛性结果。该结果不仅为判断Newton方法的收敛性提供了可计算的充分条件，也给出了Newton方法的收敛域以及问题解的存在区域。同时，文章也得到了Newton方法的若干收敛性质，包含收敛阶以及可计算的误差估计式等。  相似文献