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41.
A method of visualizing structures in closed chaotic flows out of homogenous particle distributions is presented in the example of models of a meandering jet. To this end, the system will be leaked or opened up by defining a region of the flow, so that a particle is considered to be escaped if it leaves this region. By applying this method to an ensemble of nonescaped tracers, we are able to characterize mixing processes by visualizing the converging and stretching filamentations (stable and unstable manifolds) in the flow without using additional mathematical tools. The possibility of applying the algorithm to analyze buoy data, and a comparison with the finite time manifolds are discussed.  相似文献   
42.
This paper presents the extension of the self-calibrating method to the coupled inverse modelling of groundwater flow and mass transport. The method generates equally likely solutions to the inverse problem that display the variability as observed in the field and are not affected by a linearisation of the state equations. Conditioning to the state variables is measured by an objective function including, among others, the mismatch between the simulated and measured concentrations. Conditioning is achieved by minimising the objective function by gradient-based methods. The gradient contains the partial derivatives of the objective function with respect to: log conductivities, log storativities, prescribed heads at boundaries, retardation coefficients and mass sources. The derivatives of the objective function with respect to log conductivity are the most cumbersome and need the most CPU-time to be evaluated. For this reason, to compute this derivative only advective transport is considered. The gradient is calculated by the adjoint-state method. The method is demonstrated in a controlled, synthetic study, in which the worth of concentration data is analysed. It is shown that concentration data are essential to improve transport predictions and also help to improve aquifer characterisation and flow predictions, especially in the upstream part of the aquifer, even in the case that a considerable amount of other experimental data like conductivities and heads are available. Besides, conditioning to concentration data reduces the ensemble variances of estimated transmissivity, hydraulic head and concentration.  相似文献   
43.
Separate lead isotope analyses of leachate and residue fractions are applied to a broad spectrum of rocks commonly investigated in metallogenic studies. Resulting data highlight a systematic behavior of leachate and residue fractions with respect to lead isotope compositions, which essentially depends on the mineralogical composition of the rock. Granitoid and high-grade metamorphic rocks have residue compositions virtually identical to common lead. In contrast, low-grade metasedimentary rocks may have residue compositions swamped by radiogenic lead of leach-resistant zircons. Mafic magmatic rocks have residues that are often more radiogenic than leachates, depending on the ratio of leach-refractory zircons to common lead in the residual fraction of these rocks. Separate leachate and residue analyses of source rocks provide two lead isotope end members whose mixture may represent lead with the appropriate ore fluid composition. Our leaching experiments indicate that hot acid solutions (and by inference hydrothermal fluids) preferentially leach radiogenic lead from medium- to high-grade metamorphic and granitoid rocks, whereas they preferentially leach common lead from low-grade metasedimentary and mafic magmatic rocks. The method presented in this study provides a reliable alternative to other methods (i.e., age-correction of bulk-rock compositions) for the determination of the common lead signature of felsic to intermediate magmatic rocks. This may be preferable to age-corrected bulk-rock analyses, where ages to apply for corrections of bulk-rock data are not known or where moderately to highly altered rocks must be used. Case studies of orogenic gold and MVT districts of Peru (Pataz and San Vicente, respectively) show that separate leachate and residue lead isotope analyses carried out systematically on whole rocks allow a more thorough evaluation of metal source reservoirs than does the standard method of age-corrected or uncorrected bulk-rock analyses.  相似文献   
44.
Fluorine, chlorine, bromine, iodine and sulfur were determined in seventeen geological reference materials after extraction by pyrohydrolysis. Fluorine, Cl and S (as sulfate ions) were determined in the extraction solution by ion chromatography with detection limits of around 0.2 mg l<sup>&minus;1sup>. Bromine and I were measured by ICP-MS with detection limits of 1 μg l<sup>&minus;1sup> for Br and 0.1 μg l<sup>&minus;1sup> for I. For rock samples, using normal extraction conditions (500 mg of sample and 100 ml of final solution) detection limits were 40 mg kg<sup>&minus;1sup> for F and Cl, 15 mg kg<sup>&minus;1sup> for S, 0.2 mg kg<sup>&minus;1sup> for Br and 0.02 mg kg<sup>&minus;1sup> for I. These detection limits may be improved by increasing the amount of sample and hence the concentration of the final solution. Water was also determined using an extraction technique based on H<sub>2sub>O degassing, reduction on zinc at 1000 °C and H<sub>2sub> manometry. Our results for fluorine, chlorine, sulfur and water are in good agreement with literature data. Very few reference materials have recommended values for bromine and especially for iodine. Among the analysed samples, three are new reference materials: BHVO-2, BCR-2 and AGV-2.  相似文献   
45.
Three large earthquakes (M<sub>wsub>>4.5) were triggered within 5 min, 85 km west of a M<sub>wsub> 6.5 earthquake in the South Iceland Seismic Zone (SISZ). We report on surface effects of these triggered earthquakes, which include fresh rupture, widespread rockfall, disrupted rockslides and block slides. Field data confirm that the earthquakes occurred along N-striking right-lateral strike-slip faults. Field data also support the conclusion from modeling of InSAR data that deformation from the second triggered event was more significant than for the other two. A major hydrological effect was the draining of water through an open fissure on a lake bed, lowering the lake level by greater than 4 m. Field relationships suggest that a component of aseismic slip could have been facilitated by water draining into the fault zone.  相似文献   
46.
Cleavage-fissility perpendicular to bedding is a common feature in the external part of fold-and-thrust belts. Three techniques were used to determine the internal distortion in the frontal Southern Pyrenees: the analysis of strain markers such as burrows and rain drops, the measurement of fissility, and the measurement of anisotropy of magnetic susceptibility (AMS). The comparison of the three techniques showed a good fit although they differ in sensitivity to penetrative strain variations in the range of deformation values explored in the study case. On the regional scale, the values of layer parallel shortening (LPS) derived from the markers analysis are very constant and account for 16–23% of shortening. These values are two to three times larger than the shortening values calculated from the restoration of the macroscopic scale structures and indicate a good decoupling above the Cardona salt Formation. This study permitted an accurate restoration of the low-amplitude el Guix detached anticline.  相似文献   
47.
The flow of organic matter along the main navigation channel of Ria Formosa, Portugal, was assessed using determinations of suspended particulate matter (SPM), particulate organic matter (POM), and chlorophyll a (chla) concentrations in conjunction with stable isotope values of primary producers, particulate matter, and two filter feeders. SPM in the lagoon is dominated by inorganic particles comprising 80% of total weight with organic matter averaging about 20%. The algal component of the POM averaged about 5% with the remainder comprised of detritus. The δ<sup>13sup>C values of primary producers ranged from ?9.1‰ in the intertidal seagrassZostera noltii to ?30.7‰ in the red seaweedBostrychia scorpioides revealing underlying differences in the mechanisms of carbon uptake. The δ<sup>13sup>C value ofB. scorpioides, which develops entangled on the salt marsh speciesSpartina maritima, suggests that its main source of inorganic carbon is atmospheric CO<sub>2sub>. The δ<sup>13sup>C values of the high marsh macrophyteSarcocornia perennis significantly increased with distance from the ocean while δ<sup>13sup>C values ofZ. noltii decreased, probably because higher decomposition of organic matter at inner stations lowers the δ<sup>13sup>CO<sub>2sub> value in the water. The δ<sup>15sup>N values of Ulvales, seagrasses, and marsh plants significantly increased from outer stations to inner stations. This increase may be due either to recycling of nitrogen (N) within the marsh (with loss of light N<sub>2sub> or NH<sub>4sub>) or to inputs of isotopically heavy N from sewage. The δ<sup>15sup>N values of particulate matter showed an opposite trend, which indicates higher microbial degradation of organic matter at the inner lagoon. The data demonstrate that the seston in the lagoon is a mixture of detritus from lagoon primary producers with a minor contribution of microalgae. The filter feeders are most likely assimilating a mixture of phytoplankton and microphytobenthos. Digestion of lagoon seston is selective. The δ<sup>15sup>N values of both muscle and digestive gland of filter feeders showed the opposite gradient of particulate matter indicating that the depleted δ<sup>15sup>N of SPM at inner stations was not assimilated or even ingested. Stable isotopes values did not differ between the filter-feeders—the musselMytilus galloprovincialis collected on buoys and the clamTapes decussatus collected in the sediment—suggesting a considerable mixture of benthic-pelagic organic matter throughout the water column. Assessment of the changes in isotopic decomposition of detritus as it decays is required to refine our understanding of organic matter transfers in detrital food webs.  相似文献   
48.
49.
We analysed nest site selection in two shrub-steppe larks, the lesser short-toed larkCalandrella rufescensand the Thekla larkGalerida theklae. Both species nest on the ground next to a bush preferably facing north or north-east. Nestling growth and fledging weight are greater when the nest faces these directions. Both species prefer to nest next to camephytes with little foliage, and the lesser short-toed lark chooses sites with high visibility. We conclude that sunlight and nest predation are fundamental selective pressures determining nest microhabitat selection in larks in semi-arid areas.  相似文献   
50.
To determine if defoliation of a woody plant affects foraging by folivorous insects, we examined the infection rate (number of leaves damaged per total number of leaves sampled on marked stems) ofAnthyllis cytisoidesunder three experimental treatments: 10, 50 and 90% plant defoliation. Observations were made for three age classes, established by trunk base perimeter (equal to or lower than 11 cm, between 11 and 20 cm, larger than 20 cm). Plants respond positively to artificial defoliation by increasing total vegetative length of the stem and total inflorescence length. This response is most evident in young individuals.Response to herbivory was measured as overall infection rate and also as infection rate by different feeding guilds&mdash;chewing, mining, or sucking insects. We found that increased defoliation elicited increased resistance of leaves to insect attack. This was particularly evident in young plants. Different insect guilds respond in different ways. Attack by chewing insects declines with defoliation for all plant age classes; only sucking insects which feed on the oldest plants reduce feeding rate with plant defoliation. Finally, mining insects present the opposite trend in young and senescent plants.  相似文献   
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