Geochemical and hydrological controls on biannual lamination of tufa deposits     

Tatsuya Kawai  Akihiro Kano  Masako Hori 《Sedimentary Geology》2009,213(1-2):41-50

Fluvial tufa deposits in southwest Japan commonly develop biannual lamination consisting of dense summer layers and porous winter layers, and the clearness of the laminae varies among the sites. The laminae have been largely attributed to a seasonally variable inorganic precipitation rate of calcite. This rate-controlled hypothesis was examined by using quantitative data for calcite packing-density (CPD) and the precipitation rate of calcite (PWP rate) calculated from water chemistry. The results for four tufa-depositing sites in SW Japan show that a positive correlation between CPD and PWP rate becomes less certain with increasing PWP rate. In the temperature realm of SW Japan, tufas develop regular distinct seasonal change in CPD when deposited in water containing Ca values less than 65 mg/l, which results in a relatively low precipitation rate. The CPD of tufa deposits rarely exceeds 65%, owing to pore space between fine-grained calcite crystals and to porosity derived from decomposed cyanobacteria and other microorganisms. By increasing the Ca content to more than 65 mg/l, the CPD often attains an upper limit and becomes insensitive to seasonal changes in the PWP rate. Therefore, seasonal variations in CPD at sites with a higher Ca content are unclear, as seen in two examples from tropical islands in southern Japan and in one locality in a temperate climate. The flow rate and microbial density on the tufa surface are subordinate factors with respect to the CPD. Seasonal changes in these two factors often enhance the porous/dense contrast of biannual lamination in SW Japan.  相似文献   

Short-term flow fluctuations in Onagawa Bay,Japan, as revealed by long-term mooring observation     

Daisuke Takahashi  Kenji Kaneko  Yasushi Gomi  Yuki Minegishi  Michihiro Shoji  Hikaru Endo  Akihiro Kijima 《Journal of Oceanography》2017,73(1):67-86

Short-term flow fluctuations in the southern central part of Onagawa Bay were examined using long-term mooring and hydrographic data observed during the period from May 2013 to April 2014. The short-term flow fluctuations were dominant in the periodic bands of 15–27 days and shorter than 10 days. The principal and minor components of these flow fluctuations were respectively along and across the local isobaths, which are almost parallel in the north direction. The northward flow fluctuations along the local isobaths were correlated with the northeastward wind fluctuations in both periodic bands, and these correlations were more evident from fall to winter. On the basis of these results, the northward flows are regarded as wind-induced barotropic coastal jets. On other hand, the eastward flow fluctuations across the local isobaths were related to inflow and outflow via the bay mouth or the Izushima Channel. Inflow and outflow with reverse flow at lower depths formed in summer, but those with vertically uniform flow tended to form in winter. The main summertime inflow and outflow were driven by horizontal gradients in density. These permit us to regard the main summertime inflow and outflow as gravitational circulation. Also, the summertime inflow can be intermittently caused by internal waves.  相似文献   

High-West and Low-East Distribution Patterns of Chlorophyll a, Primary Productivity and Diatoms in the Subarctic North Pacific Surface Waters, Midwinter 1996   总被引：1，自引：0，他引：1  

Akihiro Shiomoto  Hiroki Asami 《Journal of Oceanography》1999,55(4):493-503

We have determined chlorophyll a (Chla) concentration, primary productivity, cell density and species composition of diatoms, and the number of microzooplankton at the surface in the subarctic North Pacific in January 1996. The wet weight of copepods obtained by vertical tows from 150 m to the surface was also measured during the cruise. Chla concentration and primary productivity tended to be higher in the region west of 180°, the western subarctic North Pacific (WSNP), than east of 180°, the eastern subarctic North Pacific (ESNP). The same results were observed for the total diatom cell densities and for the genera Thalassiosira and Denticulopsis. Significant linear relationships were observed between the Thalassiosira cell density and Chla concentration and primary productivity, indicating that Thalassiosira contributes to the high-WSNP and low-ESNP distribution patterns of Chla concentration and primary productivity. Moreover, naked ciliate abundance tended to be lower in the WSNP than in the ESNP, whereas copepod biomass showed an inverse trend. Significantly negative Spearman rank correlations were found between the Thalassiosira cell density and the number of naked ciliates and between the number of naked ciliates and the wet weight of copepods. These results indicate that copepod grazing indirectly controls Thalassiosira cell density via predation on the naked ciliates. We conclude that the high copepod biomass in the WSNP is a factor controlling the high-WSNP and low-ESNP Thalassiosira abundance and hence Chla concentration and primary productivity patterns.  相似文献   

Methane with Abnormally High δ13C and δD Values from the Coastal Hot Springs in Lake Baikal     

Kalmychkov  G. V.  Hachikubo  A.  Pokrovsky  B. G.  Minami  H.  Yamashita  S.  Khlystov  O. M. 《Lithology and Mineral Resources》2020,55(6):439-444

Lithology and Mineral Resources - We studied the composition and isotopic characteristics (δ13C and δD) of hydrocarbon gases from the Kotelnikovsky, Zmeiny, and Goryachnisky hot springs...  相似文献   

Isotopic composition of dissolved inorganic carbon in subsurface sediments of gas hydrate-bearing mud volcanoes, Lake Baikal: implications for methane and carbonate origin   总被引：1，自引：1，他引：0  

Alexey A. Krylov  Oleg M. Khlystov  Akihiro Hachikubo  Hirotsugu Minami  Yutaka Nunokawa  Hitoshi Shoji  Tamara I. Zemskaya  Lieven Naudts  Tatyana V. Pogodaeva  Masato Kida  Gennady V. Kalmychkov  Jeffrey Poort 《Geo-Marine Letters》2010,30(3-4):427-437

We report on the isotopic composition of dissolved inorganic carbon (DIC) in pore-water samples recovered by gravity coring from near-bottom sediments at gas hydrate-bearing mud volcanoes/gas flares (Malenky, Peschanka, Peschanka 2, Goloustnoe, and Irkutsk) in the Southern Basin of Lake Baikal. The δ¹³C values of DIC become heavier with increasing subbottom depth, and vary between ?9.5 and +21.4‰ PDB. Enrichment of DIC in ¹³C indicates active methane generation in anaerobic environments near the lake bottom. These data confirm our previous assumption that crystallization of carbonates (siderites) in subsurface sediments is a result of methane generation. Types of methanogenesis (microbial methyl-type fermentation versus CO₂-reduction) were revealed by determining the offset of δ¹³C between dissolved CH₄ and CO₂, and also by using δ¹³C and δD values of dissolved methane present in the pore waters. Results show that both mechanisms are most likely responsible for methane generation at the investigated locations.  相似文献   

P–V–T equation of state of Mn3Al2Si3O12 spessartine garnet     

Steeve Gréaux  Akihiro Yamada 《Physics and Chemistry of Minerals》2014,41(2):141-149

The thermoelastic parameters of synthetic Mn₃Al₂Si₃O₁₂ spessartine garnet were examined in situ at high pressure up to 13 GPa and high temperature up to 1,100 K, by synchrotron radiation energy dispersive X-ray diffraction within a DIA-type multi-anvil press apparatus. The analysis of room temperature data yielded K ₀ = 172 ± 4 GPa and K ₀ ^′  = 5.0 ± 0.9 when V _0,300 is fixed to 1,564.96 Å³. Fitting of P–V–T data by means of the high-temperature third-order Birch–Murnaghan EoS gives the thermoelastic parameters: K ₀ = 171 ± 4 GPa, K ₀ ^′  = 5.3 ± 0.8, (?K _0,T /?T) _P  = ?0.049 ± 0.007 GPa K^?1, a ₀ = 1.59 ± 0.33 × 10^?5 K^?1 and b ₀ = 2.91 ± 0.69 × 10^?8 K^?2 (e.g., α _0,300 = 2.46 ± 0.54 × 10^?5 K^?1). Comparison with thermoelastic properties of other garnet end-members indicated that the compression mechanism of spessartine might be the same as almandine and pyrope but differs from that of grossular. On the other hand, at high temperature, spessartine softens substantially faster than pyrope and grossular. Such softening, which is also reported for almandine, emphasize the importance of the cation in the dodecahedral site on the thermoelastic properties of aluminosilicate garnet.  相似文献   

Phytotoxicity assessment of γ-Fe2O3 nanoparticles on root elongation and growth of rice plant     

Darioush Alidoust  Akihiro Isoda 《Environmental Earth Sciences》2014,71(12):5173-5182

This study was conducted to determine the phytotoxicity of 6 nm γ-Fe₂O₃ nanoparticles (IONPs) in terms of root elongation and the physiological performance of rice plants. Rice seeds (Oryza sativa L. var. Koshihikari) exposed to IONPs at 500, 1,000 and 2,000 mg/L, had a significantly higher root elongation than the control and its bulk counterparts (IOBKs), indicating that the effect can be nanospecific. In a 14-week greenhouse pot experiment, the CO₂ assimilation rate in IOBK and IONP-treated pots (500 and 1,000 mg/pot) decreased over time, with the decline (maximum 42.5 %) being less pronounced for IONPs, indicating that the effect cannot be inferred from the toxicity of nanoscale size iron oxide. Excessive adsorption of IONPs onto soil colloids with subsequent low water extractable iron was responsible for the unremarkable phytotoxic nature of IONPs in the rice plants. Amendment of IONPs coated with 20 mmol citric acid (IONPs-Cit) significantly diminished the CO₂ assimilation rate and the decrease was similar to its bulk counterpart (IOBKs-Cit). However, maximum shoot growth inhibition (37 %) was associated with the application of IOBKs-Cit. It was concluded that massive accumulations of Fe plaque on the root surfaces of IOBKs-Cit treatments due to a decline in the pH of rhizoplane soils compared to the IONPs-Cit treatments were responsible for the remarkable shoot growth reduction. This study provided evidence of the phytotoxicity of γ-Fe₂O₃ nanoparticles, demonstrating the lower toxicity of nanosized iron oxide compared to a microsized preparation under reductive conditions.  相似文献   

A measurement of H₀ from Ryle Telescope, ASCA and ROSAT observations of Abell 773     

Richard Saunders  Rüdiger Kneissl  Keith Grainge  William F. Grainger  Michael E. Jones  Alessia Maggi  Rhiju Das  †  Alastair C. Edge  Anthony N. Lasenby  G. G. Pooley  Shigeru J. Miyoshi  Taisuke Tsuruta  Koujun Yamashita  Yuzuru Tawara  Akihiro Furuzawa  Akihiro Harada  Izamu Hatsukade 《Monthly notices of the Royal Astronomical Society》2003,341(3):937-940

  相似文献   

Upper Eocene travertine-lacustrine carbonate in the Jianchuan basin,southeastern Tibetan Plateau: Reappraisal of its origin and implication for the monsoon climate     

Aki Sakuma  Akihiro Kano  Yoshihiro Kakizaki  Ryuji Tada  Honbo Zheng 《Island Arc》2021,30(1):e12416

The Asian monsoon is one of the largest climatic systems in the world, but age of its onset has been estimated differently ranging from the late Eocene to the Quaternary. We investigated the sedimentology and stable isotopic compositions of the upper Eocene Jiuziyan Formation, a terrestrial limestone unit in the Jianchuan basin, Yunnan Province in China. This limestone formation is restricted in several localities in the central part of the basin. Previously, this has been characterized as palustrine carbonate and the transition to the sublacustrine deposit of the overlying Shuanghe Formation was interpreted as the appearance of wetter climate during the late Eocene. Our observations of macro- and microfacies revealed sedimentary fabrics indicating rapid CaCO₃ precipitation, such as dendritic calcite and calcified reed stems, which are unlikely to develop in a simple lacustrine setting. High carbonate content (mostly >90 %) and restricted distribution of the Jiuziyan limestone indicate a depositional setting spatially limited and isolated from clastic influx. These findings, together with clearly higher δ¹³C values (−0.7 ‰ to +6.9 ‰) and lower δ¹⁸O values (−14.6 ‰ to −10.5 ‰) than those of the Shuanghe Formation, indicate that the limestone was mainly travertine, carbonate formed from endogenic spring water. The elevated δ¹³C resulted from a large amount of CO₂ degassing from spring water with high pCO₂. In addition, the occurrence of centimeter-scale lamination coupled with cyclic changes in δ¹³C and δ¹⁸O is almost identical with the modern annually-laminated travertine reported from Baishuitai in northern Yunnan Province, implying comparable amplitude of seasonal temperature and precipitation changes to the record of the modern travertine at Baishuitai. Our results do not contradict the previous interpretation of late Eocene wetting and additionally suggest the existence of the late Eocene monsoon climate in the Jianchuan basin.  相似文献   

Sequentially sampled gas hydrate water,coupled with pore water and bottom water isotopic and ionic signatures at the Kukuy mud volcano,Lake Baikal: ambiguous deep-rooted source of hydrate-forming water     

Hirotsugu Minami  Akihiro Hachikubo  Hirotoshi Sakagami  Satoshi Yamashita  Yusuke Soramoto  Tsuyoshi Kotake  Nobuo Takahashi  Hitoshi Shoji  Tatyana Pogodaeva  Oleg Khlystov  Andrey Khabuev  Lieven Naudts  Marc De Batist 《Geo-Marine Letters》2014,34(2-3):241-251

The isotopic and ionic composition of pure gas hydrate (GH) water was examined for GHs recovered in three gravity cores (165–193 cm length) from the Kukuy K-9 mud volcano (MV) in Lake Baikal. A massive GH sample from core St6GC4 (143–165 cm core depth interval) was dissociated progressively over 6 h in a closed glass chamber, and 11 sequentially collected fractions of dissociated GH water analyzed. Their hydrogen and oxygen isotopic compositions, and the concentrations of Cl^– and HCO₃ ^– remained essentially constant over time, except that the fraction collected during the first 50 minutes deviated partly from this pattern. Fraction #1 had a substantially higher Cl^– concentration, similar to that of pore water sampled immediately above (135–142 cm core depth) the main GH-bearing interval in that core. Like the subsequent fractions, however, the HCO₃ ^– concentration was markedly lower than that of pore water. For the GH water fractions #2 to #11, an essentially constant HCO₃ ^–/Cl^– ratio of 305 differed markedly from downcore pore water HCO₃ ^–/Cl^– ratios of 63–99. Evidently, contamination of the extracted GH water by ambient pore water probably adhered to the massive GH sample was satisfactorily restricted to the initial phase of GH dissociation. The hydrogen and oxygen isotopic composition of hydrate-forming water was estimated using the measured isotopic composition of extracted GH water combined with known isotopic fractionation factors between GH and GH-forming water. Estimated δD of ?126 to ?133‰ and δ¹⁸O of ?15.7 to ?16.7‰ differed partly from the corresponding signatures of ambient pore water (δD of ?123‰, δ¹⁸O of ?15.6‰) and of lake bottom water (δD of ?121‰, δ¹⁸O of ?15.8‰) at the St6GC4 coring site, suggesting that the GH was not formed from those waters. Observations of breccias in that core point to a possible deep-rooted water source, consistent with published thermal measurements for the neighboring Kukuy K-2 MV. By contrast, the pore waters of core St6GC4 and also of the neighboring cores GC2 and GC3 from the Kukuy K-9 MV show neither isotopic nor ionic evidence of such a source (e.g., elevated sulfate concentration). These findings constrain GH formation to earlier times, but a deep-rooted source of hydrate-forming water remains ambiguous. A possible long-term dampening of key deep-water source signatures deserves further attention, notably in terms of diffusion and/or advection, as well as anaerobic oxidation of methane.  相似文献