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51.
Isotopic ratios and abundances of all REE in two Oklo ore samples have been measured. We have succeeded in developing a new method to estimate the neutron fluence, the conversion factor of uranium and the average neutron energy (or temperature) based on Gd and U isotopic ratios. This new calculation is found to be useful in evaluating those parameters for the natural nuclear reactors at Oklo. Comparison is made between the neutron fluence values evaluated by our new method employing Gd isotopes and a previous one [11] employing Sm and Nd isotopes. The relative agreement becomes better with the increase of fluence. A relationship between the abundances of fissiongenic nuclides of La, Ce, Nd, Sm, and Gd and their mass numbers is also presented.  相似文献   
52.
Partial melting experiments on plagioclase (An60) and diopside have been carried out using pairs of large crystals to investigate textures and kinetics of melting. The experiments were done at one atmosphere pressure as a function of temperature (1,190–1,307° C) and time (1.5–192 h). Melting took place mainly at the plagioclase-diopside contact planes. Reaction zones composed of fine mixtures of calcic plagioclase and melt were developed from the surface of the plagioclase crystal inward. There exists a critical temperature, below which only a few % melting can occur over the duration of the experiments. This sluggish melting is caused by slow NaSi-CaAl diffusion in plagioclase, because the plagioclase crystal must change its composition to produce albite-rich cotectic melts. Diffusion in the solid also affects the chemical composition of the melts. During initial melting, potassium is preferentially extracted from plagioclase because K-Na diffusion in plagioclase is faster than that of NaSi-CaAl. This also causes a shift in the cotectic compositions. Above the critical temperature, on the other hand, melting is promoted by a metastable reaction in which the plagioclase composition does not change, and which produces melts with compositional gradients along the original An60-diopside tie line. The critical temperature is determined by the intersection of the cotectic and the An60-diopside tie line. Interdiffusion coefficients of plagioclase-diopside components in the melt are estimated from melting rates above the critical temperature by using a simplified steady-state diffusion model (e.g., 10–8 cm2/sec at 1,300° C).Many examples of reaction zones due to partial melting have been described as spongy or fingerprint-like textures in xenoliths. Metastable melting above the critical temperature is considered to take place in natural melting where there is a high degree of melting. However, we cannot exclude the possibility of disequilibrium created by sluggish melting controlled by diffusion in the minerals. If melting occurs close to the solidus, this process can be important even for partial melting in the upper mantle.  相似文献   
53.
The textures and kinetics of reaction between plagioclase and melts have been investigated experimentally, and origin of dusty plagioclase in andesites has been discussed. In the experiments plagioclase of different compositions (An96, An61, An54, An23, and An22) surrounded by glasses of six different compositions in the system diopside-albite-anorthite was heated at temperatures ranging from 1,200 to 1,410° C for 30 min to 88 h. Textures were closely related to temperature and chemical compositions. A crystal became smaller and rounded above the plagioclase liquidus temperature of the starting melt (glass) and remained its original euhedral shape below the liquidus. Whatever the temperature, the crystal-melt interface became rough and often more complicated (sieve-like texture composed of plagioclase-melt mixture in the scale of a few m was developed from the surface of the crystal inward; formation of mantled plagioclase) if the crystal is less calcic than the plagioclase in equilibrium with the surrounding melt, and the interface remained smooth if the crystal is more calcic than the equilibrium plagioclase. From these results the following two types of dissolution have been recognized; (1) a crystal simply dissolves in the melt which is undersaturated with respect to the phase (simple dissolution), and a crystal is partially dissolved to form mantled plagioclase by reaction between sodic plagioclase and calcic melt (partial dissolution). The amount of a crystal dissolved and reacted increased proportional to the square root of time. This suggests that these processes are controlled by diffusion, probably in the crystal.Mantled plagioclase produced in the experiments were very similar both texturally and chemically to some of the so-called resorbed plagioclase in igneous rocks. Chemical compositions and textures of plagioclase phenocrysts in island-arc andesites of magma mixing origin have been examined. Cores of clear and dusty plagioclase were clacic (about An90) and sodic (about An50), respectively. This result indicates that dusty plagioclases were formed by the partial melting due to reaction between sodic plagioclase already precipitated in a dacitic magma and a melt of intermediate composition in a mixed magma during the magma mixing.  相似文献   
54.
The sulfide and sulfate contents and their δ34S values were determined in Quaternary volcanic rocks from the Japanese Islands Arc. The total sulfur contents are much lower (less than 40 ppm) and the δ34S values are higher (+4.4 ± 2.1) than those of ocean-floor basalts (800 ± 100 ppm and +0.8 ± 0.5, respectively; Moore and Fabbi, 1971; Sakaiet al., 1982). Lateral variations of both sulfur content and δ34S values were observed in the four volcanic belts in Japan. In the Northeast Japan belt, the sulfur content (30 ± 10 ppm) of the rocks in the inner zone (the Japan Sea side) is 3 to 5 times that in the outer zone (the Pacific side), although the δ34S values of the two zones are almost the same (+4.3 ± 1.0). The δ34S values for the two belts in West Japan are on the average 2%. higher than those of East Japan.This study suggests that the primary magmas that formed the island arc volcanic rocks are initially depleted in sulfur (<120 ppm) and enriched in 34S (δ34S: +5 ~ +7) compared to ocean-floor tholeiitic basalts which formed at mantle under oceanic region. This indicates that the upper-mantle is heterogeneous in sulfur content and isotope composition.  相似文献   
55.
对有代表性的中国东部新生代玄武岩的Sr、Nd和Ce同位素组成进行了系统的研究,结合系统的微量元素研究结果,进一步阐明其地幔源区同位素组成的不均一性;利用Ce、Nd同位素地球化学给出的信息,探讨富集Ⅰ型(EMⅠ)地幔端元的成因。  相似文献   
56.
This paper discusses the situation of sea navigation in south East Asia focusing on the Strait of Malacca. The strait links the Indian and Pacific oceans, which is considered one of the busiest in several narrow channels around the world. The paper highlights the significance of the strait to global maritime trade, volume of traffic, and rising environmental and social consequences in the strait. A feasibility study of constructing a new shipping canal in the South Thai Kra Isthmus as an alternative option of Malacca route had been studied since 19th century. The paper explores suitable sites for a potential shipping canal in the Kra Isthmus using physiographic spatial data i.e., elevation, sea charts, geology, soils and river systems. Each spatial data was considered as a separate decision variable for site evaluation. Separate evaluation criterions were prepared for each variable based on shipping canal requirements. Overlaying the maps in GIS environment, the variables were carefully evaluated, and five geographic sites for the canal were derived. The length of the shipping canal over sea and land was computed for each site. Site B located in south of Ranong and Chumphon provinces, was the shortest one, whereas site C in Surat Thani, Pangnna and Krabi provinces was the longest. However, each site consisted of benefits and constraints.  相似文献   
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Abstract   The lithology of shallow-water carbonates collected from 19 sites on 16 seamounts in six areas of the northwestern Pacific Ocean using the Deep-sea Boring Machine System are described. The areas include the Amami Plateau, Daito Ridge, Oki-Daito Ridge, Urdaneta Plateau, Kyushu-Palau Ridge and Ogasawara Plateau. Chronological constraint is provided by calcareous nannofossil biostratigraphy, planktonic foraminiferal biostratigraphy, larger foraminiferal biostratigraphy and strontium (Sr) isotope stratigraphy. Large amounts of shallow-water carbonates accumulated on the seamounts during the Oligocene, a relatively cool period, whereas limited carbonate deposits formed during the Early Miocene, a relatively warm period. This might indicate that deposition of shallow-water carbonates on seamounts in the northwestern Pacific Ocean was not necessarily controlled by climatic conditions, but was related to volcanism and tectonics that served as foundations for reef/carbonate-platform formation. Remarkable differences in biotic composition exist between Cretaceous and Cenozoic shallow-water carbonates. Late Cretaceous shallow-water carbonates are distinguished by the occurrence of rudists, solenoporacean algae and microencrusters. Middle Eocene to Early Oligocene shallow-water carbonates are dominated by Halimeda or nummulitid and discocyclinid larger foraminifers. Scleractinian corals became common from the Oligocene onward. Nongeniculate coralline algae and larger foraminifers were common to abundant throughout the Eocene to the Pleistocene. The replacement of major carbonate producers in the shallow-water carbonate factory during post-Cretaceous time is in accordance with previous studies and is considered to reflect a shift in seawater chemistry.  相似文献   
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