Estimation of fault-zone conductance by calibration of a regional groundwater flow model: Desert Hot Springs,California   总被引：1，自引：2，他引：1  

Alex Mayer  Wesley May  Chad Lukkarila  Jimmy Diehl 《Hydrogeology Journal》2007,15(6):1093-1106

The hydraulic conductance of a large fault zone has been estimated by calibrating a regional groundwater flow model. Drops in groundwater elevations of over 80 m have been observed along a 15-km length of the Mission Creek fault, California, USA. The large drops in elevation are attributed to the reduced hydraulic conductivity of the fault materials. A conceptual and numerical model of the two hydrologic subbasins in Desert Hot Springs, separated by the Mission Creek fault, was developed. The model was used to estimate the hydraulic conductance along the fault. The parameter estimation involved calibrating the model with observed groundwater elevations from over 40 locations over a 60-year period. The fault hydraulic conductances were estimated assuming a linear trend in the fault length, yielding variations in the fault hydraulic conductance of about an order of magnitude along the fault length (2?×?10^?11–4?×?10^?10 1/s). When an average fault thickness of 35 m is assumed, the fault hydraulic conductivity values are estimated to be from three to five orders of magnitude lower than the surrounding materials. A sensitivity analysis indicated that assumptions made in the conceptual model do not significantly affect estimated fault hydraulic conductances.  相似文献   

Zirconium isotope evidence for incomplete admixing of r-process components in the solar nebula     

Maria Schönbächler  Der-Chuen Lee  Alex N. Halliday  Bodo Hattendorf 《Earth and Planetary Science Letters》2003,216(4):467-481

Isotopic anomalies in Mo and Zr have recently been reported for bulk chondrites and iron meteorites and have been interpreted in terms of a primordial nucleosynthetic heterogeneity in the solar nebula. We report precise Zr isotopic measurements of carbonaceous, ordinary and enstatite chondrites, eucrites, mesosiderites and lunar rocks. All bulk rock samples yield isotopic compositions that are identical to the terrestrial standard within the analytical uncertainty. No anomalies in ⁹²Zr are found in any samples including high Nb/Zr eucrites and high and low Nb/Zr calcium-aluminum-rich inclusions (CAIs). These data are consistent with the most recent estimates of <10⁻⁴ for the initial ⁹²Nb/⁹³Nb of the solar system. There exists a trace of isotopic heterogeneity in the form of a small excess of r-process ⁹⁶Zr in some refractory CAIs and some metal-rich phases of Renazzo. A more striking enrichment in ⁹⁶Zr is found in acetic acid leachates of the Allende CV carbonaceous chondrite. These data indicate that the r- and s-process Zr components found in presolar grains were well mixed on a large scale prior to planetary accretion. However, some CAIs formed before mixing was complete, such that they were able to sample a population of r-process-enriched material. The maximum amount of additional r-process component that was added to the otherwise well-mixed Zr in the molecular cloud or disk corresponds to ∼0.01%.  相似文献   

Isotopic exchange of carbon-bound hydrogen over geologic timescales     

Alex L. Sessions  Sean P. Sylva  John M. Hayes 《Geochimica et cosmochimica acta》2004,68(7):1545-1559

The increasing popularity of compound-specific hydrogen isotope (D/H) analyses for investigating sedimentary organic matter raises numerous questions about the exchange of carbon-bound hydrogen over geologic timescales. Important questions include the rates of isotopic exchange, methods for diagnosing exchange in ancient samples, and the isotopic consequences of that exchange. This article provides a review of relevant literature data along with new data from several pilot studies to investigate such issues. Published experimental estimates of exchange rates between organic hydrogen and water indicate that at warm temperatures (50-100°C) exchange likely occurs on timescales of 10⁴ to 10⁸ yr. Incubation experiments using organic compounds and D-enriched water, combined with compound-specific D/H analyses, provide a new and highly sensitive method for measuring exchange at low temperatures. Comparison of δD values for isoprenoid and n-alkyl carbon skeletons in sedimentary organic matter provides no evidence for exchange in young (<1 Ma), cool sediments, but strong evidence for exchange in ancient (>350 Ma) rocks. Specific rates of exchange are probably influenced by the nature and abundance of organic matter, pore-water chemistry, the presence of catalytic mineral surfaces, and perhaps even enzymatic activity.Estimates of equilibrium fractionation factors between organic H and water indicate that typical lipids will be depleted in D relative to water by ∼75 to 140‰ at equilibrium (30°C). Thus large differences in δD between organic molecules and water cannot be unambiguously interpreted as evidence against hydrogen exchange. A better approach may be to use changes in stereochemistry as a proxy for hydrogen exchange. For example, estimated rates of H exchange in pristane are similar to predicted rates for stereochemical inversion in steranes and hopanes. The isotopic consequences of this exchange remain in question. Incubations of cholestene with D₂O indicate that the number of D atoms incorporated during structural rearrangements can be far less than the number of C-H bonds that are broken. Sample calculations indicate that, for steranes in immature sediments, the D/H ratio imparted by biosynthesis may be largely preserved in spite of significant structural changes.  相似文献   

Citation for presentation of the 2002 Clair C. Patterson Award to Henry Elderfield     

Alex N Halliday 《Geochimica et cosmochimica acta》2003,67(13):2309

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The structure and the phyllosilicates (chemistry, crystallinity and texture) of Talas Ala-Tau (Tien Shan, Kyrgyz Republic): comparison with more recent subduction complexes     

Isabel Abad  Gabriel Gutirrez-Alonso  Fernando Nieto  Igor Gertner  Alex Becker  Ana Cabero 《Tectonophysics》2003,365(1-4):103

Geological mapping and structural analysis of the Talas Ala Tau (Tien Shan, Kyrgyz Republic) have revealed a complex structure composed of folds with axial-plane cleavage and thrust faults verging towards the NE. The main structures of the range correspond to minor Tertiary and Carboniferous–Permian deformation superimposed on the main deformation event that took place during the Baikalian orogeny. The pervasive axial-plane cleavage diminishes in penetrativity from the hinterland to the foreland in both the Uzunakhmat and Karagoin sheets. The main thrusts developed phyllonitic shear-related rocks on the hangingwall immediately above the thrust planes. A crystal-chemical study of the phyllosilicates growth during the Baikalian deformation event along a cross-section revealed changes in the crystallinity, composition and lattice parameters of them. The phyllosilicates present in the Talas Ala Tau rocks were crystallized in very low-grade metamorphic conditions, that is below 300 °C, as indicated by their Kübler Index (KI), which decreases from SW towards the NE. Detailed TEM study of the phyllosilicates reveals a clear textural difference at the lattice level between samples with higher or lower KI parameters. There is also a clear difference in crystal-chemical parameters (KI and b) and composition between the phyllosilicates growth in relation to the axial-plane cleavage and the ones belonging to the thrust-related phyllonites. The first ones are more affected by the ferrimuscovitic vector than the phyllosilicates of phyllonites, closer to the theoretical phengitic component. Huge ranges of values of phengitic content of micas at sample level are interpreted as the result of a decompression path from at least 8 kbar. We propose a subduction geodynamic environment for the regional deformation and the origin of the phyllosilicates, as they are similar to those obtained in more recent accretionary complexes.  相似文献   

Precise Determination of Cadmium, Indium and Tellurium Using Multiple Collector ICP-MS   总被引：1，自引：1，他引：0  

Wen Yi  Alex N. Halliday  Der-Chuen Lee  Mark Rehkämper 《Geostandards and Geoanalytical Research》1998,22(2):173-179

New sample preparation and ion-exchange separation methods as well as instrumental measurement protocols were established for the determination of trace-level Cd, In, and Te concentrations in geological materials by isotope-dilution mass spectrometry. High precision isotope ratio measurements were performed with a multiple collector inductively coupled plasma-mass spectrometer (MC-ICP-MS). The mass biases incurred for In and Te were corrected by adding and monitoring Pd and Sb standard solutions, respectively. Mass fractionation of Cd was corrected by using the mass fractionation factor calculated from the measurement of a standard solution. The measurement precision was better than 1 % for Cd, In and Te. Detection limits were < 1 ng g^-1 for Cd, < 0.02 ng g^-1 for In and Te. Using these new analytical techniques, the concentrations of Cd, In and Te were determined in six international geological reference materials. Concentrations could be reproduced within 3% for Cd, 4% for In and 10% for Te. Sample heterogeneity and volatility problems might have been the reason for the relatively large differences between Te replicates. Our results displayed excellent reproducibility compared with those of other techniques and agree well with data from previously published recommended values.  相似文献   

Plume dynamics beneath the African plate inferred from the geochemistry of the Tertiary basalts of southern Ethiopia     

R. George  N. Rogers 《Contributions to Mineralogy and Petrology》2002,144(3):286-304

Southern Ethiopian flood basalts erupted in two episodes: the pre-rift Amaro and Gamo transitional tholeiites (45-35 million years) followed by the syn-extensional Getra-Kele alkali basalts (19-11 million years). These two volcanic episodes are distinct in both trace element and isotope ratios (Zr/Nb ratios in Amaro/Gamo lavas fall between 7 and 14, and 3-4.7 in the Getra-Kele lavas whereas ²⁰⁶Pb/²⁰⁴Pb ratios fall between 18-19 and 18.9-20, respectively). The distinctive chemistries of the two eruptive phases record the tapping of two distinct source regions: a mantle plume source for the Amaro/Gamo phase and an enriched continental mantle lithosphere source for the Getra-Kele phase. Isotope and trace element variations within the Amaro/Gamo lavas reflect polybaric fractional crystallisation initiated at high pressures accompanied by limited crustal contamination. We show that clinopyroxene removal at high (0.5 GPa) crustal pressures provides an explanation for the common occurrence of transitional tholeiites in Ethiopia relative to other, typically tholeiitic flood basalt provinces. The mantle plume signature inferred from the most primitive Amaro basalts is isotopically distinct from that contributing to melt generation in central Ethiopian and Afar. This, combined with Early Tertiary plate reconstructions and similarities with Kenyan basalts farther south, lends credence to derivation of these melts from the Kenyan plume rather than the Afar mantle plume. The break in magmatism between 35 and 19 Ma is consistent with the northward movement away from the Kenya plume predicted from plate tectonic reconstructions. In this model the Getra-Kele magmatism is a response to heating of carbonatitically metasomatised lithosphere by the Afar mantle plume beneath southern Ethiopia at this time.  相似文献   

The Clarno Formation of central Oregon,U.S.A. — Volcanism on a thin continental margin     

John J.W. Rogers  Joyce M. Novitsky-Evans 《Earth and Planetary Science Letters》1977,34(1):56-66

The Clarno Formation (mostly Eocene) of central Oregon, U.S.A., was formed as North America moved westward over subducting Pacific Ocean crust. The Clarno is a volcanic and volcanogenic assemblage whose flow rocks show: a calc-alkaline pattern on a Harker diagram, K₂O-SiO₂ diagram, alkali-SiO₂ diagram, and AFM diagram; and a pattern transitional between calc-alkaline and tholeiitic on a SiO₂-FeO^*/MgO diagram. Its basalts are chemically similar to those of intra-oceanic island arcs (e.g., K₂O of 0.30%), but subaerial deposition of the entire formation plus differentiation to rocks of high SiO₂ and alkali contents indicate that the Clarno was formed on a continental margin. Comparison of the Clarno with other Pacific-margin volcanic suites indicates that the Clarno was formed on thin (20–30 km) continental crust overlying a subduction zone of about 120 km depth.  相似文献   

A crustal suture and lineament in North Africa — reply     

Richard M. Nagy  Mohamed A. Ghuma  John J.W. Rogers 《Tectonophysics》1977,40(3-4):380-382

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Workshop on Indices and Indicators for Climate Extremes, Asheville, NC, USA, 3–6 June 1997 Breakout Group C: Temperature Indices for Climate Extremes     

C.K. Folland  C. Miller  D. Bader  M. Crowe  P. Jones  N. Plummer  M. Richman  D.E. Parker  J. Rogers  P. Scholefield 《Climatic change》1999,42(1):31-43

The "temperature" breakout group at the 1997 Asheville Workshop on Indicators and Indices for Climate Extremes reviewed and developed the rationale for a choice of temperature indices for monitoring changes in climate extremes, and the supporting data required. A set of basic and supplementary key indices was drawn up. The key indices are meant to be easy to interpret, be relevant to the practical concerns of policy makers and others in the public sector and provide potential inputs into the Third Assessment Review of the Intergovernmental Panel on Climate Change that is expected to report in 2001. The indices are expressed in various ways to facilitate spatial and temporal trend detection and impact analysis. There is flexibility in the number and the form of the indices identified and the choice for any particular application is subject to further analysis and prioritization. The success of this endeavor will depend on original work being done to further develop the indices and on the cooperation of organizations globally to provide the data necessary for the development and the implementation of the indices. This paper summarizes the group's recommendations.  相似文献