Benthic nutrient fluxes along the Laurentian Channel: Impacts on the N budget of the St. Lawrence marine system     

Benoît Thibodeau  Moritz F. Lehmann  Jacqueline Kowarzyk  Alfonso Mucci  Yves Gélinas  Denis Gilbert  Roxane Maranger  Mohammad Alkhatib 《Estuarine, Coastal and Shelf Science》2010

Water column concentrations and benthic fluxes of dissolved inorganic nitrogen (DIN) and oxygen (DO) were measured in the Gulf of St. Lawrence and the Upper and Lower St. Lawrence Estuary (USLE and LSLE, respectively) to assess the nitrogen (N) budget in the St. Lawrence (SL) system, as well as to elucidate the impact of bottom water hypoxia on fixed-N removal in the LSLE. A severe nitrate deficit, with respect to ambient phosphate concentrations (N*∼−10 μmol L⁻¹), was observed within and in the vicinity of the hypoxic bottom water of the LSLE. Given that DO concentrations in the water column have remained above 50 μmol L⁻¹, nitrate reduction in suboxic sediments, rather than in the water column, is most likely responsible for the removal of fixed N from the SL system. Net nitrate fluxes into the sediments, derived from pore water nitrate concentration gradients, ranged from 190 μmol m⁻² d⁻¹ in the hypoxic western LSLE to 100 μmol m⁻² d⁻¹ in the Gulf. The average total benthic nitrate reduction rate for the Laurentian Channel (LC) is on the order of 690 μmol m⁻² d⁻¹, with coupled nitrification-nitrate reduction accounting for more than 70%. Using average nitrate reduction rates derived from the observed water column nitrate deficit, the annual fixed-N elimination within the three main channels of the Gulf of St. Lawrence and LSLE was estimated at 411 × 10⁶ t N, yielding an almost balanced N budget for the SL marine system.  相似文献   

Calcite and aragonite precipitation from seawater solutions of various salinities: Precipitation rates and overgrowth compositions     

Shaojun Zhong  Alfonso Mucci   《Chemical Geology》1989,78(3-4):283-299

The reaction rate and composition of calcite and aragonite overgrowths precipitated from seawater solutions of various salinities (i.e. S=5, 15, 25, 35, 44) were determined at 25°C and 10^−2.5-atm. CO₂ partial pressure using a constant disequilibrium seeded technique. The rate data were fitted to an empirical rate law of the form:

where n is the empirical reaction order; and k is the rate constant. Calcite precipitation rates in seawater solutions do not vary appreciably as a result of salinity variations over the range investigated, while those for aragonite show an increase in going from the higher (i.e. S=35, 44) to the lower (i.e. S=5, 15, 25) salinity range. This study also confirms previously published findings that above a given saturation state (i.e. Ω_c>/2.6) aragonite precipitates more rapidly than calcite at 25°C.

The incorporation of Sr²⁺ in aragonite and Mg²⁺ in calcite overgrowths are independent of the precipitation rate. The partition coefficient of Sr²⁺ in aragonite is approximately equal to unity and is unaffected by salinity variations between 5 and 44. However, the Mg²⁺ partition coefficient in calcite, increases with decreasing salinity of the parent seawater solutions, possibly as a result of variations in the sulfate content of the solutions and solids.

The experimental results were discussed in the context of a number of geological environments.  相似文献   

Approaches to analyse and model changes in impacts: reply to discussions of “How to improve attribution of changes in drought and flood impacts”*     

Heidi Kreibich  Veit Blauhut  Jeroen C. J. H. Aerts  Laurens M. Bouwer  Henny A. J. Van Lanen  Alfonso Mejia 《水文科学杂志》2020,65(3):491-494

ABSTRACT

We thank the authors, Brunella Bonaccorso and Karsten Arnbjerg-Nielsen for their constructive contributions to the discussion about the attribution of changes in drought and flood impacts. We appreciate that they support our opinion, but in particular their additional new ideas on how to better understand changes in impacts. It is great that they challenge us to think a step further on how to foster the collection of long time series of data and how to use these to model and project changes. Here, we elaborate on the possibility to collect time series of data on hazard, exposure, vulnerability and impacts and how these could be used to improve e.g. socio-hydrological models for the development of future risk scenarios.  相似文献   

The non-linear redshift-space power spectrum of galaxies     

A. F. Heavens    S. Matarrese  & L. Verde 《Monthly notices of the Royal Astronomical Society》1998,301(3):797-808

We study the power spectrum of galaxies in redshift space, with third-order perturbation theory to include corrections that are absent in linear theory. We assume a local bias for the galaxies: i.e., the galaxy density is sampled from some local function of the underlying mass distribution. We find that the effect of the non-linear bias in real space is to introduce two new features: first, there is a contribution to the power which is constant with wavenumber, whose nature we reveal as essentially a shot-noise term. In principle this contribution can mask the primordial power spectrum, and could limit the accuracy with which the latter might be measured on very large scales. Secondly, the effect of second- and third-order bias is to modify the effective bias (defined as the square root of the ratio of galaxy power spectrum to matter power spectrum). The effective bias is almost scale-independent over a wide range of scales. These general conclusions also hold in redshift space. In addition, we have investigated the distortion of the power spectrum by peculiar velocities, which may be used to constrain the density of the Universe. We look at the quadrupole-to-monopole ratio, and find that higher order terms can mimic linear theory bias, but the bias implied is neither the linear bias, nor the effective bias referred to above. We test the theory with biased N -body simulations, and find excellent agreement in both real and redshift space, providing the local biasing is applied on a scale whose fractional rms density fluctuations are < 0.5.  相似文献   

Organic carbon isotope ratios of recent sediments from coastal lagoons of the Gulf of Mexico,Mexico     

Alfonso V. Botello  Enrique F. Mandelli  Steve Macko  Patrick L. Parker 《Geochimica et cosmochimica acta》1980,44(3):557-559

The stable carbon isotope composition sedimentary organic carbon was determined in the sediments of seven coastal lagoons of the Gulf of Mexico, Mexico. For most of the lagoons the δ¹³C values for sediments ranged from ?20.1 to ?23.9%. Anomalously low values, ?26.8 to 29.3%. were determined in sediments of two of the studied lagoons, probably due to the presence of organic carbon from anthropogenic sources, naturally absent in these environments. The δ¹³C values determined in the tissues of oysters collected at the same time in the different lagoons were very similar to those recorded in the sediments.  相似文献   

Climate‐driven cyclicity in an Early Cretaceous synrift lacustrine series (Aguilón sub‐basin,NE Spain)     

Ana R. Soria  Arsenio Muñoz  Carlos L. Liesa  Aránzazu Luzón  Alfonso Meléndez  M. Nieves Meléndez 《地学学报》2012,24(5):407-416

  相似文献   

Interannual variability patterns of the world’s total column water content: Amazon River basin     

Isabella Bordi  Roberto De Bonis  Klaus Fraedrich  Alfonso Sutera 《Theoretical and Applied Climatology》2015,122(3-4):441-455

  相似文献   

Meteorites at Meridiani Planum provide evidence for significant amounts of surface and near‐surface water on early Mars     

Alberto G. FAIRÉN  James M. DOHM  Victor R. BAKER  Shane D. THOMPSON  William C. MAHANEY  Kenneth E. HERKENHOFF  J. Alexis P. RODRÍGUEZ  Alfonso F. DAVILA  Dirk SCHULZE‐MAKUCH  M. Ramy EL MAARRY  Esther R. UCEDA  Ricardo AMILS  Hirdy MIYAMOTO  Kyeong J. KIM  Robert C. ANDERSON  Christopher P. McKAY 《Meteoritics & planetary science》2011,46(12):1832-1841

Abstract– Six large iron meteorites have been discovered in the Meridiani Planum region of Mars by the Mars Exploration Rover Opportunity in a nearly 25 km‐long traverse. Herein, we review and synthesize the available data to propose that the discovery and characteristics of the six meteorites could be explained as the result of their impact into a soft and wet surface, sometime during the Noachian or the Hesperian, subsequently to be exposed at the Martian surface through differential erosion. As recorded by its sediments and chemical deposits, Meridiani has been interpreted to have undergone a watery past, including a shallow sea, a playa, an environment of fluctuating ground water, and/or an icy landscape. Meteorites could have been encased upon impact and/or subsequently buried, and kept underground for a long time, shielded from the atmosphere. The meteorites apparently underwent significant chemical weathering due to aqueous alteration, as indicated by cavernous features that suggest differential acidic corrosion removing less resistant material and softer inclusions. During the Amazonian, the almost complete disappearance of surface water and desiccation of the landscape, followed by induration of the sediments and subsequent differential erosion and degradation of Meridiani sediments, including at least 10–80 m of deflation in the last 3–3.5 Gy, would have exposed the buried meteorites. We conclude that the iron meteorites support the hypothesis that Mars once had a denser atmosphere and considerable amounts of water and/or water ice at and/or near the surface.  相似文献   

In Memoriam: John W. Morse (1946–2009) Texas A&;M University     

Fred T. Mackenzie  Alfonso Mucci  George W. Luther III 《Aquatic Geochemistry》2010,16(2):219-221

  相似文献   

Field characterization and data integration to define the hydraulic heterogeneity of a shallow granular aquifer at a sub-watershed scale     

Daniel Paradis  Laurie Tremblay  René Lefebvre  Erwan Gloaguen  Alfonso Rivera  Michel Parent  Jean-Marc Ballard  Yves Michaud  Patrick Brunet 《Environmental Earth Sciences》2014,72(5):1325-1348

Providing a sound basis for aquifer management or remediation requires that hydrogeological investigations carried out to understand groundwater flow and contaminant transport be based on representative data that capture the heterogeneous spatial distribution of aquifer hydraulic properties. This paper describes a general workflow allowing the characterization of the heterogeneity of the hydraulic properties of granular aquifers at an intermediate scale of a few km². The workflow involves characterization and data integration steps that were applied on a 12-km² study area encompassing a decommissioned landfill emitting a leachate plume and its main surface water receptors. The sediments composing the aquifer were deposited in a littoral–sublittoral environment and show evidence of small-scale transitional heterogeneities. Cone penetrometer tests (CPT) combined with soil moisture and electrical resistivity (SMR) measurements were thus used to identify and characterize spatial heterogeneities in hydraulic properties over the study area. Site-specific statistical relationships were needed to infer hydrofacies units and to estimate hydraulic properties from high-resolution CPT/SMR soundings distributed all over the study area. A learning machine approach was used due to the complex statistical relationships between colocated hydraulic and CPT/SMR data covering the full range of aquifer materials. Application of this workflow allowed the identification of hydrofacies units and the estimation of horizontal hydraulic conductivity, vertical hydraulic conductivity and porosity over the study area. The paper describes and discusses data acquisition and integration methodologies that can be adapted to different field situations, while making the aquifer characterization process more time-efficient and less labor-intensive.  相似文献