Effects of turbulence on the transport of individual particles as bedload in a gravel‐bed river     

Geneviève Paiement‐Paradis  Geneviève Marquis  André Roy 《地球表面变化过程与地形》2011,36(1):107-116

This study investigates the association between mean and turbulent flow variables and the movement of individual particles in a gravel‐bed river. The experimental design implemented in the Eaton‐North River (Québec, Canada) is based on the simultaneous observations at a high temporal resolution of both particle movements as bedload using an underwater video camera and of the streamwise and vertical flow velocity components using a vertical array of three electromagnetic current meters (ECMs). The frequency and distance of displacement of particles larger than 20 mm that were sliding or rolling on the bed were measured from a 10 minutes long film. Mean and turbulent flow properties obtained for periods without sediment transport are compared to those when particles were sliding and rolling. When particles are sliding, weak differences are present for the mean streamwise velocity and normal vertical stresses. Instantaneous Reynolds shear stresses are significantly lower for sliding events which was not expected but could be explained by the important dominance of Quadrant 3 events (inward interactions). When particles are rolling, only the vertical normal stresses show a weak difference from those observed in the absence of transport but they tend to occur when Quadrant 2 (ejections) dominate the flow field. For both sliding and rolling particles, vertical and/or streamwise fluid accelerations show high magnitude values when compared to periods without transport. For sliding particles, streamwise acceleration is mostly negative and combines most of the time with a positive vertical acceleration. For rolling particles, streamwise and vertical acceleration are predominantly of opposite sign. These results suggest that fluid acceleration or deceleration in the streamwise and vertical directions is affecting the pressure field around particles. In this study, fluid acceleration seems to play a more important role than Reynolds shear stress or normal stresses for bedload movements. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

Theory and experimental study for sliding isolators with variable curvature     

Lyan‐Ywan Lu  Shih‐Wei Yeh 《地震工程与结构动力学》2011,40(14):1609-1627

Because a conventional isolation system with constant isolation frequency is usually a long‐period dynamic system, its seismic response is likely to be amplified in earthquakes with strong long‐period wave components, such as near‐fault ground motions. Seismic isolators with variable mechanical properties may provide a promising solution to alleviate this problem. To this end, in this work sliding isolators with variable curvature (SIVC) were studied experimentally. An SIVC isolator is similar to a friction pendulum system (FPS) isolator, except that its sliding surface has variable curvature rather being spherical. As a result, the SIVC's isolation stiffness that is proportional to the curvature becomes a function of the isolator displacement. By appropriately designing the geometry of the sliding surface, the SIVC is able to possess favorable hysteretic behavior. In order to prove the applicability of the SIVC concept, several prototype SIVC isolators, whose sliding surfaces are defined by a sixth‐order polynomial function, were fabricated and tested in this study. A cyclic element test on the prototype SIVC isolators and a shaking table test on an SIVC isolated steel frame were all conducted. The results of both tests have verified that the prototype SIVC isolators do indeed have the hysteretic property of variable stiffness as prescribed by the derived formulas in this study. Moreover, it is also demonstrated that the proposed SIVC is able to effectively reduce the isolator drift in a near‐fault earthquake with strong long‐period components, as compared with that of an FPS system with the same friction coefficient. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Short chain ladderanes: Oxic biodegradation products of anammox lipids     

Darci Rush  Andrea Jaeschke  Ellen C. Hopmans  Stefan Schouten 《Geochimica et cosmochimica acta》2011,75(6):1662-1671

Anammox, the microbial anaerobic oxidation of ammonium by nitrite to produce dinitrogen gas, has been recognized as a key process in both the marine and freshwater nitrogen cycles, and found to be a major sink for fixed inorganic nitrogen in the oceans. Ladderane lipids are unique anammox bacterial membrane lipids that have been used as biomarkers for anammox bacteria in recent and past environmental settings. However, the fate of ladderane lipids during diagenesis is as of yet unknown. In this study, we performed oxic degradation experiments (at 20-100 °C) with anammox bacterial biomass to simulate early diagenetic processes occurring in the water column and at the sediment-water interface. Abundances of C₁₈ and C₂₀ ladderane lipids decreased with increasing temperatures, testifying to their labile nature. The most abundant products formed were ladderane lipids with a shorter alkyl side chain (C₁₄ and C₁₆ ladderane fatty acids), which was unambiguously established using two-dimensional NMR techniques on an isolated C₁₄-[3]-ladderane fatty acid. The most pronounced production of these short-chain lipids was at 40 °C, suggesting that degradation of ladderane lipids was microbially mediated, likely through a β-oxidation pathway. An HPLC-MS/MS method was developed for the detection of these ladderane alteration products in environmental samples and positively tested on various sediments. This showed that the ladderanes formed during degradation experiments also naturally occur in the marine environment. Thus, short-chain ladderane lipids may complement the original longer-chain ladderane lipids as suitable biomarkers for the detection of anammox processes in past depositional environments.  相似文献   

Viability of pyrite pulled metabolism in the ‘iron-sulfur world’ theory: Quantum chemical assessment     

Andrea Michalkova  Dmytro Kosenkov  Leonid Gorb  Jerzy Leszczynski 《Geochimica et cosmochimica acta》2011,75(7):1933-1941

The viability of pyrite-pulled metabolism in the ‘iron-sulfur world’ theory was assessed using a simple model of iron-nickel sulfide (Fe-Ni-S) surface and data obtained from quantum chemical calculations. We have investigated how the individual reactions in the carbon fixation cycle (carboxylic acids formation) on an Fe-Ni-S surface could have operated to produce carboxylic acids from carbon oxide and water. The proposed model cycle reveals how the individual reactions might have functioned and provides the thermodynamics of each step of the proposed pathway. The feasibility of individual reactions, as well the whole cycle was considered. The reaction of acetic acid production from CH₃SH and CO on an Fe-Ni sulfide surface was revealed to be endergonic with a few partial steps having positive Gibbs free energy. On the other hand, the pyrite formation was found to be slightly exergonic. The significance of the catalytic activity of transition metal sulfides in generation of acetic acid was shown. The Gibbs free energy values indicate that the acetic acid synthesis is unfavorable to proceed on the studied Fe-Ni-S model under simulated conditions. The importance of these results in terms of a primordial chemistry on iron-nickel sulfide surfaces is discussed.  相似文献   

Bounding difference: Intersectionality and the material production of gender, caste, class and environment in Nepal   总被引：1，自引：0，他引：1  

Andrea J. Nightingale 《Geoforum》2011,42(2):153-162

Current theorising in human geography draws attention to the relational emergence of space and society, challenging ideas of difference that rely on fixed identities and emphasising the importance of the everyday in the production of social inequalities. Similarly, feminist political ecology has emphasised the role of ‘nature’ or ‘environment’ in the production of subjectivities such that ideas of gender and nature arise in relation to each other. In this paper I build from these insights to explore the ways in which the embodied performance of gender, caste and other aspects of social difference collapse the distinction between the material and the symbolic. Symbolic ideas of difference are produced and expressed through embodied interactions that are firmly material. Through this kind of conceptualisation, I hope to push forward debates in geography on nature and feminist political ecology on how to understand the intersectional emergence of subjectivities, difference and socio-natures. Importantly, it is the symbolic meanings of particular spaces, practices and bodies that are (re)produced through everyday activities including forest harvesting, agricultural work, food preparation and consumption, all of which have consequences for both ecological processes and social difference. Through the performance of everyday tasks, not only are ideas of gender, caste and social difference brought into view, but the embodied nature of difference that extends beyond the body and into the spaces of everyday life is evident. I use ethnographic evidence from rural Nepal to explore the ways in which boundaries between bodies, spaces, ecologies and symbolic meanings of difference are produced and maintained relationally through practices of work and ritual.  相似文献   

Magnetic properties and cation ordering of nanopowders of the synthetic analogue of kuramite, Cu3SnS4     

Francesco Di Benedetto  Daniele Borrini  Andrea Caneschi  Gabriele Fornaciai  Massimo Innocenti  Alessandro Lavacchi  Carlo Andrea Massa  Giordano Montegrossi  Werner Oberhauser  Luca A. Pardi  Maurizio Romanelli 《Physics and Chemistry of Minerals》2011,38(6):483-490

An extensive characterisation of the magnetic properties of synthetic powders of kuramite, with formal composition Cu₃SnS₄, was performed. Powders were investigated through superconducting quantum interference device (SQUID) magnetometry, electron paramagnetic resonance (EPR) spectroscopy, X-ray powder diffraction (XRPD), scanning and transmission electron microscopies (SEM and TEM) and microanalysis. SEM and TEM reveal the presence of nanodimensioned particles. XRPD clearly shows that Cu₃SnS₄ crystallised in a cubic sphalerite-type structural model, in spite of the stannite-type tetragonal structure described for the natural phase. This difference arises from a full random distribution of cations. Synthetic kuramite nanopowders exhibit a marked paramagnetism, originated by the presence of Cu(II), definitely assessed by EPR measurements. Moreover, the overall magnetic behaviour of the sample cannot be simply ascribed to diluted paramagnetism, and this suggests the presence of strong superexchange interactions among Cu(II) ions even at room temperature. The main consequences of these results are the definitive assessment of the chemical formula Cu(I)₂Cu(II)SnS₄ and of a random distribution of Cu(II), Cu(I) and Sn(IV) ions within the available tetrahedral sites.  相似文献   

Behavior of Gd-DTPA in simulated bank filtration     

Peter Möller  Andrea KnappePeter Dulski  Asaf Pekdeger 《Applied Geochemistry》2011,26(1):140-149

The behavior of Gd-DTPA during bank filtration was simulated in a 30 m column filled with Pleistocene sand and flushed by surface water from a lakeside in Berlin, Germany. The surface water is about a 1:1 mixture of river water and effluents from a sewage treatment plant. Throughout 34 days this water was continuously spiked with Gd-DTPA at a level of 60 μg/L. The broad plateau of the Gd-DTPA pulse declined by 15.4% within 34 days by transmetallation. Nine percentage of the total decline is caused by Y and rare earth elements; the remaining part is attributed to Cu²⁺ which is the most influential metal in surface water. All other metals also contributing to transmetallation are combined with Cu to Cu equivalents because only the rate constant of transmetallation of Cu²⁺ is known. The analytical results of the column effluents prove the pseudo-first-order kinetics of transmetallation based on reversible sorption of metals by pools in the column sediment and disprove biodegradation at noticeable levels. The mass ratio of water to tracer is <10¹⁰.  相似文献   

Geochronology of the Xihuashan Tungsten Deposit in Southeastern China: Constraints from Re–Os and U–Pb Dating     

Fang‐Yue WANG  Cong‐Ying LI  Ming‐Xing LING  Hong ZHANG  Ya‐Li SUN  Weidong SUN 《Resource Geology》2011,61(4):414-423

Xihuashan tungsten deposit is one of the earliest explored tungsten deposits in southeastern China. It is a vein type deposit genetically associated with the Xihuashan granite pluton. Here we report new dating and zircon geochemistry results. Re–Os isotopic dating for molybdenite intergrowth with wolframite in the oldest generation of the Xihuashan pluton yielded an isochron age of 157.0 ± 2.5 Ma (2σ). Zircon U–Pb laser ablation inductively coupled plasma mass spectrometry (LA‐ICP‐MS) dating shows that the pluton crystallized at 155.7 ± 2.2 Ma (2σ). This age is similar to the molybdenite Re–Os age for the ore deposit within error. This, together with published data, suggests that the major W(Mo)‐Sn mineralization occurred between 160–150 Ma in southeastern China. These deposits constitute a major part of the magmatic‐metallogenic belt of eastern Nanlin. The lower Re content in molybdenite of the Xihuashan tungsten deposit shows crustal origin for the ore‐forming material. The limited direct contributions from the subducting slab for the tungsten mineralization in the Nanling region suggest a change of the style of the paleo‐Pacific plate beneath southeastern China.  相似文献   

Polyphase thrusting and dyke emplacement in the central Southern Alps (Northern Italy)     

Paolo D’Adda  Andrea Zanchi  Maria Bergomi  Fabrizio Berra  Marco G. Malusà  Annalisa Tunesi  Stefano Zanchetta 《International Journal of Earth Sciences》2011,100(5):1095-1113

The Triassic succession of the central Southern Alps (Italy) is stacked into several units bounded by south-verging low-angle thrust faults, which are related to two successive steps of crustal shortening. The thrust surfaces are cut by high-angle extensional and strike-slip faults, which controlled the emplacement of hypabissal magmatic intrusions that post-date thrusts motions. Intrusion ages based on SHRIMP U–Pb zircon dating span between 42 ± 1 and 39 ± 1 Ma, suggesting close time relationships with the earliest Adamello intrusion stages and, more in general, with the widespread calc-alkaline magmatism described in the Southern Alps. Fission-track ages of magmatic apatites are indistinguishable from U–Pb crystallization ages of zircons, suggesting that the intrusion occurred in country rocks already exhumed above the partial annealing zone of apatite (depth < 2–4 km). These data indicate that the central Southern Alps were already structured and largely exhumed in the Middle Eocene. Although we describe minor faults affecting magmatic bodies and local reactivations of older structures, no major internal deformations have occurred in the area after the Bartonian. Neogene deformations were instead concentrated farther south, along the frontal part of the belt.  相似文献   

Hypogeal geological survey in the “Grotta del Re Tiberio” natural cave (Apennines, Italy): a valid tool for reconstructing the structural setting     

Alice Ghiselli  Marzio Merazzi  Andrea Strini  Roberto Margutti  Michele Mercuriali 《Central European Journal of Geosciences》2011,3(2):155-168

As karst systems are natural windows to the underground, speleology, combined with geological surveys, can be useful tools for helping understand the geological evolution of karst areas. In order to enhance the reconstruction of the structural setting in a gypsum karst area (Vena del Gesso, Romagna Apennines), a detailed analysis has been carried out on hypogeal data. Structural features (faults, fractures, tectonic foliations, bedding) have been mapped in the ”Grotta del Re Tiberio” cave, in the nearby gypsum quarry tunnels and open pit benches. Five fracture systems and six fault systems have been identified. The fault systems have been further analyzed through stereographic projections and geometric-kinematic evaluations in order to reconstruct the relative chronology of these structures. This analysis led to the detection of two deformation phases. The results permitted linking of the hypogeal data with the surface data both at a local and regional scale. At the local scale, fracture data collected in the underground have been compared with previous authors’ surface data coming from the quarry area. The two data sets show a very good correspondence, as every underground fracture system matches with one of the surface fracture system. Moreover, in the cave, a larger number of fractures belonging to each system could be mapped. At the regional scale, the two deformation phases detected can be integrated in the structural setting of the study area, thereby enhancing the tectonic interpretation of the area (e.g., structures belonging to a new deformation phase, not reported before, have been identified underground). The structural detailed hypogeal survey has, thus, provided very useful data, both by integrating the existing information and revealing new data not detected at the surface. In particular, some small structures (e.g., displacement markers and short fractures) are better preserved in the hypogeal environment than on the surface where the outcropping gypsum is more exposed to dissolution and recrystallization. The hypogeal geological survey, therefore, can be considered a powerful tool for integrating the surface and log data in order to enhance the reconstruction of the deformational history and to get a three-dimensional model of the bedrock in karst areas.  相似文献