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This investigation had the purpose of evaluating the reliability of a sequential extraction procedure according to Zeien and Brümmer (1989) which is performed routinely to analyse the distribution of heavy metals to different soil phases. Reliability was tested by two hypotheses. According to the first hypothesis an error propagation increased during a morefold extraction of heavy metals from a single soil sample to such an extend that it does not allow a statistical comparison of different analyses. This assumption was confirmed in an interlaboratory study of five participants applying the sequential extraction scheme on two different soils. The heavy metal amounts extracted by the different partners were of the same magnitude, but from the results no statistical correspondence at the 95% confidence level could be observed. The second hypothesis stated that also weak extraction agents were able to release metals from the more immobile soil fractions, especially if the amount of easily soluble metals was comparatively small. To answer this question the sequential extraction was modified by carrying out selected weak extraction steps several times. As expected the intensified extraction conditions caused a decrease of the element content within the more resistant phases. However, the additional release in the first four extraction steps of Pb, Mn, Fe, and Zn was only in the range of 5 to 10%. Furthermore, it was observed that a single EDTA extraction (step four within the sequential extraction scheme) was capable to extract the same amount of metals as the first four extraction steps of the original scheme at a variation of about 15%. From these results it was concluded that the EDTA step alone already represents a reliable pool of mobilisable metals. Thus it can be maintained that such a simple single EDTA extraction can be used to assess the environmental risk from heavy metal contaminated soils or to predict the potential heavy metal release of soil remediation processes.  相似文献   
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We have examined a Hawaiian palagonitic tephra sample (PN-9) that has spectroscopic similarities to Martian bright regions using a number of analytical techniques, including Mossbauer and reflectance spectroscopy, X-ray diffraction, instrumental neutron activation analysis, electron probe microanalysis, transmission electron microscopy, and dithionite-citrate-bicarbonate extraction. Chemically, PN-9 has a Hawaiitic composition with alkali (and presumably silica) loss resulting from leaching by meteoric water during palagonitization; no Ce anomaly is present in the REE pattern. Mineralogically, our results show that nanophase ferric oxide (np-Ox) particles (either nanophase hematite (np-Hm) or a mixture of ferrihydrite and np-Hm) are responsible for the distinctive ferric doublet and visible-wavelength ferric absorption edge observed in Mossbauer and reflectivity spectra, respectively, for this and other spectrally similar palagonitic samples. The np-Ox particles appear to be imbedded in a hydrated aluminosilicate matrix material; no evidence was found for phyllosilicates. Other iron-bearing phases observed are titanomagnetite, which accounts for the magnetic nature of the sample; olivine; pyroxene; and glass. By analogy, np-Ox is likely the primary pigmenting agent of the bright soils and dust of Mars.  相似文献   
136.
The horizontal components from twenty Ocean Bottom Seismometers deployed along three profiles near the Kolbeinsey Ridge, North Atlantic, have been modelled with regard to S-waves, based on P-wave models obtained earlier. Two profiles were acquired parallel to the ridge, and the third profile extended eastwards across the continental Jan Mayen Basin. The modelling requires a thin (few 100 m) layer with very high V p/V s-ratio (3.5–9.5) at the sea-floor in the area lacking sedimentary cover. The obtained V p/V s-ratios for the remaining part of layer 2A, 2B, 3 and upper mantle, correspond to the following lithologies: pillow lavas, sheeted dykes, gabbro and peridotite, respectively. All crustal layers exhibit a decreasing trend in V p/V s-ratio away-from-the-axis, interpreted as decreasing porosity and/or crack density in that direction. A significant S-wave azimuthal anisotropy is observed within the thin uppermost layer of basalt near the ridge. The anisotropy is interpreted as being caused by fluid-filled microcracks aligned along the direction of present-day maximum compressive stress, and indicates crustal extension at the ridge itself and perpendicular-to-the-ridge compression 12 km off axis. Spreading along the Kolbeinsey Ridge has most likely been continuous since its initiation ca. 25 Ma: The data do not suggest the presence of an extinct spreading axis between the Kolbeinsey Ridge and the Aegir Ridge as has been proposed earlier. The V p/V s-ratios found in the Jan Mayen Basin are compatible with continental crust, overlain by a sedimentary section dominated by shale.  相似文献   
137.
The present paper provides an overview of glacial related seabed features and sedimentary sequences found along the formerly glaciated NW European margin and compare it with those found on contemporary glaciated margins from both the Southern and Northern Hemispheres. A brief review of the seabed physiography and strata architecture of the margins under consideration is followed by comparison of the most relevant similarities and differences. Comparison of the present-day bathymetric setting of both former and contemporary glaciated margins reveals no clear link to the effect of neither ice sheet or sediment load. Three different types of glacially eroded shelf transverse troughs have been identified, while marginal troughs seem connected to similar geological settings everywhere. Beyond the shelf edge interaction between downslope and alongslope processes has occurred resulting, amongst others, in the formation of large sedimentary mounds on the rise. More frequent large-scale mass wasting occurs on the former glaciated NW European margin than the Greenland and Antarctic margins in the latest Neogene to recent times. A two-stage evolution of the shelf prograding wedges is observed on all margins under consideration, which may reflect a general development of an ice cover from an initial phase of non- to restricted glaciation, evolving to a mature stage of expansive glaciation.  相似文献   
138.
A high-reliability, dual-mode release has been used on untethered, mid-water vehicles successfully since 1970. This device is operated by electrical signal or by hydrostatic pressure. A second release which is self-contained and includes a relocation pinger has been designed for precisely timed release at minimum cost. The release function in this device occurs after the preset time by electrical corrosion of a wire link. This release has been used to recover sedimen trap arrays.  相似文献   
139.
The results from a survey of Swedish commercial fishers on regulation compliance and attitudes to control and restrictions are reported. According to the responding fishers, 90% of all Swedish catches are reported, in spite of limited control efforts. From an economic perspective we would expect substantially lower levels of compliance. The results also show that the majority of Swedish fishers are in favour of co-management on a regional basis. However, on this and other management issues opinions divert significantly between large vessel operators and small vessel operators, which reveals conflicting interests for such and similar changes in Swedish management of fisheries.  相似文献   
140.
The local and convective accelerations of steep irregular wave events have been investigated. These properties are measured by a two-camera PIV technique. Furthermore, the experiments are compared with two different theories including a fully nonlinear and a simplified analytical model. An important result is that the convective term is of the same order of magnitude and of opposite sign as the local acceleration. The convective acceleration term can therefore not be neglected in acceleration and force estimates.  相似文献   
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