The content of selenium and its chemical form in sea water   总被引：1，自引：0，他引：1  

Yukio Sugimura  Yoshimi Suzuki  Yasuo Miyake 《Journal of Oceanography》1976,32(5):235-241

By using the new fluorometric method of determination of the total selenium ( Se), Se (IV) and Se (VI), the content of selenium in sea weter was determined in the western North Pacific. Results showed that the content of Se in surface water ranged from 0.06 to 0.12g l^–1, while in deeper layers, the content increased to 0.20g l^–1. It was found that Se (IV) showed rather uniform distribution with depth, while Se (VI) increased with depth to about three times that in the surface. The ratio of Se (IV) to the Se ranged from 0.5 to 0.8 in the surface and 0.4 to 0.6 in the deep. The coexistence of the hexa- and tetravalent ions of selenium was confirmed both in surface and deep layers. Some results of observations on the content of selenium in the coastal areas of Japan were also reported.  相似文献   

Responses of phytoplankton and heterotrophic bacteria in the northwest subarctic Pacific to in situ iron fertilization as estimated by HPLC pigment analysis and flow cytometry   总被引：3，自引：0，他引：3  

Koji Suzuki  Akira Hinuma  Hiroaki Saito  Hiroshi Kiyosawa  Hongbin Liu  Toshiro Saino  Atsushi Tsuda 《Progress in Oceanography》2005,64(2-4):167

To verify the hypothesis that the growth of phytoplankton in the Western Subarctic Gyre (WSG), which is located in the northwest subarctic Pacific, is suppressed by low iron (Fe) availability, an in situ Fe fertilization experiment was carried out in the summer of 2001. Changes over time in the abundance and community structure of phytoplankton were examined inside and outside an Fe patch using phytoplankton pigment markers analyzed by high-performance liquid chromatography (HPLC) and flow cytometry (FCM). In addition, the abundance of heterotrophic bacteria was also investigated by FCM. The chlorophyll a concentration was initially ca. 0.9 μg l⁻¹ in the surface mixed layer where diatoms and chlorophyll b-containing green algae (prasinophytes and chlorophytes) were predominant in the chlorophyll biomass. After the iron enrichment, the chlorophyll a concentration increased up to 9.1 μg l⁻¹ in the upper 10 m inside the Fe patch on Day 13. At the same time, the concentration of fucoxanthin (a diatom marker) increased 45-fold in the Fe patch, and diatoms accounted for a maximum 69% of the chlorophyll biomass. This result was consistent with a microscopic observation showing that the diatom Chaetoceros debilis had bloomed inside the Fe patch. However, chlorophyllide a concentrations also increased in the Fe patch with time, and reached a maximum of 2.2 μg l⁻¹ at 5 m depth on Day 13, suggesting that a marked abundance of senescent algal cells existed at the end of the experiment. The concentration of peridinin (a dinoflagellate marker) also reached a maximum 24-fold, and dinoflagellates had contributed significantly (>15%) to the chlorophyll biomass inside the Fe patch by the end of the experiment. Concentrations of 19′-hexanoyloxyfucoxanthin (a prymnesiophyte marker), 19′-butanoyloxyfucoxanthin (a pelagophyte marker), and alloxanthin (a cryptophyte marker) were only incremented a few-fold increment inside the Fe patch. On the contrary, chlorophyll b concentration reduced to almost half of the initial level in the upper 10 m water column inside the Fe patch at the end of the experiment. A decrease with time in the abundance of eukaryotic ultraphytoplankton (<ca. 5 μm in size), in which chlorophyll b-containing green algae were possibly included was also observed by FCM. Overall, our results indicate that Fe supply can dramatically alter the abundance and community structure of phytoplankton in the WSG. On the other hand, cell density of heterotrophic bacteria inside the Fe patch was maximum at only ca. 1.5-fold higher than that outside the Fe patch. This indicates that heterotrophic bacteria abundance was little respondent to the Fe enrichment.  相似文献   

A new fluorometric method of analysis of selenium in sea water     

Yukio Sugimura  Yoshimi Suzuki 《Journal of Oceanography》1977,33(1):23-29

A new method of determination of selenium and separation of Se(IV) and Se(VI) in sea water is described. The selenium is determined by fluorometric method using Se-DAN complex in cyclohexane media. Prior to the fluorometric determination, Se(IV) is separated from sea water by means of Se(IV)-DDTC complex which is adsorbed on the macroreticular resin. As to the separation of the total selenium from sea water sample, the reduction and coprecipitation method is used. Se(VI) is determined with the same method as used for the total selenium after the separation of Se(IV). The average recoveries are 92.5±1.3% for Se(IV) and 97.4±0.9% for Se. The standard deviation of analytical results is below 10%.  相似文献   

Periodic Intrusion of Cold Water from the Pacific Ocean into the Bottom Layer of the Bungo Channel in Japan     

Atsushi Kaneda  Hidetaka Takeoka  Eiji Nagaura  Yoshitsugu Koizumi 《Journal of Oceanography》2002,58(4):547-556

A cold-water intrusion, called a “bottom intrusion”, occurs in the lower layer of the Bungo Channel in Japan. It is an intrusion from the shelf slope region of the Pacific Ocean margin in the south of the channel. In order to reveal the fundamental characteristics of the bottom intrusion, we conducted long-term observations of water temperature at the surface and bottom layers of the channel and 15-day current observations at the bottom of the shelf-break region. The long-term water temperature data indicated that the bottom intrusion occurs repeatedly between early summer and late autumn, and its reiteration between early and mid-summer causes a local minimum of water temperature in the lower layer in mid-summer. Moreover, the data revealed that most of the bottom intrusions occurred in neap tidal periods. The current meter recorded a bottom intrusion with a speed of approximately 15 cm⋅s⁻¹. The current meter also revealed that the intruded cold water slowly retreated back to the shelf slope region after the intrusion. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Jellyfish patch formation investigated by aerial photography and drifter experiment     

Shinya Magome  Tomohiro Yamashita  Takeshi Kohama  Atsushi Kaneda  Yuichi Hayami  Satoru Takahashi  Hidetaka Takeoka 《Journal of Oceanography》2007,63(5):761-773

Jellyfish patch formation is investigated by conducting a drifter experiment combined with aerial photography of a sustained patch of the moon jellyfish in Hokezu Bay, Japan. Jellyfish patches are aggregations of individuals that are caused by a combination of swimming (active influence) and advection by currents (passive influence). The drifter experiment involved the injection of 49 drifters around a distinct surface patch of jellyfish within an area of approximately 300 m × 300 m. The drifters’ motion, caused only by the passive influence, was recorded in a series of 38 aerial photographs taken over approximately 1 h. The ambient uniform current field larger than the patch scale was estimated from the movement of the centroid position of drifters, while the distribution of horizontal divergence and relative vorticity around the patch was estimated from the time-derivative in areas of triangles formed by the drifters. The centroid positions of both drifters and patches moved stably toward the bay head at different speeds. The difference vector between the patch and drifter centroids was directed to the sun, and was opposite to the ambient current. The distributions of vorticity and divergence around patches exhibited inhomogeneity within the patch scale, and the drifters in this nonuniform current field aggregated near the convergence area within 1 h. The results suggest that horizontal patch formation is predominantly influenced by passive factors at the surface of Hokezu Bay. Furthermore, the upward swimming against downwelling may make sustained patch in surface layer.  相似文献   

Relationship between atmospheric fluxes and concentrations of terrigenous materials in the surface air over the Japan Sea     

Suzuki  Toshitaka 《Journal of Oceanography》1994,50(2):173-178

Relationship between atmospheric deposition fluxes and concentrations of Si and²¹⁰Po in the surface air were examined through daily basis simultaneous observation at the coast of the Japan Sea. Both the Si and²¹⁰Po, the atmospheric fluxes were highly variable from day to day. According to correlation analysis, there was no significant correlation between flux and atmospheric concentration of these terrigenous materials in the surface air. On the other hand, flux of Si and²¹⁰Po significantly correlated to precipitation rate. These results indicate that the atmospheric flux of terrigenous material is not constantly proportional to atmospheric concentration in the surface air. This may be due to the deposition flux represents an integrated value throughout the air column of in-and below-cloud, while the air concentration represents only the environment of earth's surface.  相似文献   

Community Structure and Dynamics of Phytoplankton in the Western Subarctic Pacific Ocean: A Synthesis   总被引：1，自引：1，他引：1  

Hongbin Liu  Koji Suzuki  Hiroaki Saito 《Journal of Oceanography》2004,60(1):119-137

The phytoplankton community in the western subarctic Pacific (WSP) is composed mostly of pico- and nanophytoplankton. Chlorophyll a (Chl a) in the <2 μm size fraction accounted for more than half of the total Chl a in all seasons, with higher contributions of up to 75% of the total Chl a in summer and fall. The exception is the western boundary along the Kamchatka Peninsula and Kuril Islands and the Oyashio region where diatoms make up the majority of total Chl a during the spring bloom. Among the picophytoplankton, picoeukaryotes and Synechococcus are approximately equally abundant, but the former is more important in term of carbon biomass. Despite the lack of a clear seasonal variation in Chl a concentration, primary productivity showed a large seasonal variation, and was lowest in winter and highest in spring. Seasonal succession in the phytoplankton community is also evident with the abundance of diatoms peaking in May, followed by picoeukaryotes and Synechococcus in summer. The growth of phytoplankton (especially >10 μm cell size) in the western subarctic Pacific is often limited by iron bioavailability, and microzooplankton grazing keeps the standing stock of pico- and nano-phytoplankton low. Compared to the other HNLC regions (the eastern equatorial Pacific, the Southern Ocean, and the eastern subarctic Pacific), iron limitation in the Western Subarctic Gyre (WSG) may be less severe probably due to higher iron concentrations. The Oyashio region has similar physical condition, macronutrient supply and phytoplankton species compositions to the WSG, but much higher phytoplankton biomass and primary productivity. The difference between the Oyashio region and the WSG is also believed to be the results of difference in iron bioavailability in both regions. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Spatial Patterns in Nutrient and In Vivo Fluorescence Distributions in the Marginal Ice Zone and the Seasonally Open Oceanic Zone in the Indian Sector of the Antarctic Ocean, in Austral Summer     

Tsuneo Odate  Toru Hirawake  Atsushi Tanimura  Mitsuo Fukuchi 《Journal of Oceanography》2000,56(2):185-196

Surface temperature, salinity, concentrations of silicate (Si) and nitrate + nitrite (N), and in vivo fluorescence (Fluor) were investigated in the marginal ice zone (MIZ) and the seasonally open oceanic zone (SOOZ) (32–40°E, 64–69°S) from February 23 to 28 1992. In the MIZ the mean Si and N were 67.8 ± 2.2 M and 32.5 ± 1.7 M, respectively. There was a trend that low N values coincided with high Fluor values. Observation conducted at one point (64°S, 38°E) revealed a diel variation pattern in Fluor. Applying this pattern of deviation from noon value, all Fluor data were normalized to value at local noon. In the MIZ a significant negative correlation was observed between the normalized Fluor and N but not Si. On the other hand, Si decreased continuously from south to north in the SOOZ and was negatively correlated with the normalized Fluor. Difference in Si concentration was about 30 M between the sea around 64°S and the MIZ, while the difference in N concentration was estimated as less than 10 M. If diatoms take up silicate and nitrogen at an approximate ratio of 1:1, additional nitrogenous nutrients other than nitrate and nitrite (e.g. ammonia, urea etc.) would be required. In this case, an f-ratio of lower than 33% is obtained. It is suggested that in the MIZ abundance of phytoplankton community dominated by non-diatom increases utilizing nitrate while in the SOOZ abundance of phytoplankton community dominated by diatoms increases consuming Si and regenerated nitrogen.  相似文献   

A theory of semigeostrophic gravity waves and its application to the intrusion of a density current along a coast     

Atsushi Kubokawa  Kimio Hanawa 《Journal of Oceanography》1984,40(4):247-259

Semigeostrophic gravity waves associated with a coastal boundary current, which has finite and uniform potential vorticity and is bounded away from the coastline by a density front on the ocean surface, are investigated. It is shown that the semigeostrophic coastal current has two waves which are named here the Semigeostrophic Coastal Wave (SCW) and the Semigeostrophic Frontal Wave (SFW). The SCW becomes an elementary Kelvin wave at some limit while the SFW is caused by the existence of the surface density front. The SCW appears mainly as variations in the upper layer depth at the coast and as alongshore velocity at the density front. On the other hand, the SFW appears mainly as variations in the width of the current. When the weak nonlinearity and ageostrophic effect are included, these semigeostrophic gravity waves satisfy the Kortweg- de Vries equation, which suggests that the local changes in the width and/or velocity of the semigeostrophic coastal current propagate as wave-like disturbances.  相似文献   

Hydrography and budget of dissolved total nitrogen and dissolved oxygen in the stratified season in Mikawa Bay,Japan     

Teruaki Suzuki  Yasuo Matsukawa 《Journal of Oceanography》1987,43(1):37-48

Distributions of salinity, dissolved total nitrogen (DTN) and dissolved oxygen (DO) were observed once a month throughout a year in Mikawa Bay, one of the most eutrophic bays in Japan. Supply of freshwater, DTN and DO from the land and precipitation was estimated. Hydrography, circulation and transformation of DTN and DO during the stratified period were investigated simultaneously by a two-layered box model analysis dividing the bay into five boxes. The two-layered circulation was confirmed. In the upper layer of the river mouth regions, a high production of particulate organic nitrogen (PON) due to the strong upwelling together with the river inflow was found. On the other hand, in the lower layer of the bay mouth region, a high deposition of PON due to weak upwelling and sometimes downwelling and a high decomposition of PON due to the inflow of DO abundant water were also found. The reason why the eutrophication is more severe in the eastern part than in the north-western part of the bay is discussed.  相似文献