A new procedure for separating and measuring radiogenic isotopes (U, Th, Pa, Ra, Sr, Nd, Hf) in ice cores     

Sarah M. Aciego  Bernard Bourdon  Maarten Lupker  Joerg Rickli 《Chemical Geology》2009,266(3-4):203-213

A new method for the radiogenic isotope (U–Th–Pa–Ra, Sr, Nd, Hf) analysis of the soluble and insoluble components found within ice cores is presented. Melting experiments with rock standards in the presence of EDTA indicate that carbonates, as well as silicates, can be buffered sufficiently to preclude dissolution. The use of EDTA allows adsorbing species, such as Th and Hf, to remain in solution during melting thus fully separating the dust (insoluble) and sea salt (soluble) components of the ice after filtration. A new elemental separation scheme for low sample masses, less than 5 mg solid material, utilizes 4 primary ion exchange columns and two “clean-up” columns to fully isolate U, Th, Pa, Ra, Sr, Nd, and Hf while maintaining high yields. Elution schemes measured for USGS rock standards and a Chinese loess are presented to provide a comparison for variable matrix compositions. Mass spectrometer techniques were modified to measure small aliquots of the standards, equivalent to the amounts found in ice core samples, 10 ng and less. A MC-ICPMS was employed for the measurement of U, Th, Pa, Ra, and Hf; results of the experiments show that with ion yields up to 1%, rock standards have errors for ²³⁴U/²³⁸U of 1%, ²³⁰Th/²³²Th of 1.5%, [²²⁸Ra] of 9%, and ¹⁷⁶Hf/¹⁷⁷Hf of 100 ppm. MC-TIMS measurements of Sr and Nd show similar errors for small sample sizes: ⁸⁷Sr/⁸⁶Sr of 50 ppm and ¹⁴³Nd/¹⁴⁴Nd of 80 ppm. This new analytical method increases the number of possible tracers measured from a single sample, reducing separation times and sample consumption, as well as providing the addition of a radiometric clock, U-series, to the traditional suite of isotopic tracers, Sr, Nd, and Hf.  相似文献   

GETEMME—a mission to explore the Martian satellites and the fundamentals of solar system physics     

Jürgen Oberst  Valéry Lainey  Christophe Le Poncin-Lafitte  Veronique Dehant  Pascal Rosenblatt  Stephan Ulamec  Jens Biele  J?rn Spurmann  Ralph Kahle  Volker Klein  Ulrich Schreiber  Anja Schlicht  Nicolas Rambaux  Philippe Laurent  Beno?t Noyelles  Bernard Foulon  Alexander Zakharov  Leonid Gurvits  Denis Uchaev  Scott Murchie  Cheryl Reed  Slava G. Turyshev  Jesus Gil  Mariella Graziano  Konrad Willner  Kai Wickhusen  Andreas Pasewaldt  Marita W?hlisch  Harald Hoffmann 《Experimental Astronomy》2012,34(2):243-271

GETEMME (Gravity, Einstein??s Theory, and Exploration of the Martian Moons?? Environment), a mission which is being proposed in ESA??s Cosmic Vision program, shall be launched for Mars on a Soyuz Fregat in 2020. The spacecraft will initially rendezvous with Phobos and Deimos in order to carry out a comprehensive mapping and characterization of the two satellites and to deploy passive Laser retro-reflectors on their surfaces. In the second stage of the mission, the spacecraft will be transferred into a lower 1500-km Mars orbit, to carry out routine Laser range measurements to the reflectors on Phobos and Deimos. Also, asynchronous two-way Laser ranging measurements between the spacecraft and stations of the ILRS (International Laser Ranging Service) on Earth are foreseen. An onboard accelerometer will ensure a high accuracy for the spacecraft orbit determination. The inversion of all range and accelerometer data will allow us to determine or improve dramatically on a host of dynamic parameters of the Martian satellite system. From the complex motion and rotation of Phobos and Deimos we will obtain clues on internal structures and the origins of the satellites. Also, crucial data on the time-varying gravity field of Mars related to climate variation and internal structure will be obtained. Ranging measurements will also be essential to improve on several parameters in fundamental physics, such as the Post-Newtonian parameter ?? as well as time-rate changes of the gravitational constant and the Lense-Thirring effect. Measurements by GETEMME will firmly embed Mars and its satellites into the Solar System reference frame.  相似文献   

Constraints on the flux of meteoritic and cometary water on the Moon from volatile element (N–Ar) analyses of single lunar soil grains,Luna 24 core     

Evelyn Füri  Bernard Marty  Sergey S. Assonov 《Icarus》2012,218(1):220-229

We report new nitrogen and argon isotope and abundance results for single breccia clasts and agglutinates from four different sections of the Luna 24 drill core in order to re-evaluate the provenance of N trapped in lunar regolith, and to place limits on the flux of planetary material to the Moon’s surface. Single Luna 24 grains with ⁴⁰Ar/³⁶Ar ratios <1 show δ¹⁵N values between ?54.5‰ and +123.3‰ relative to terrestrial atmosphere. Thus, low-antiquity lunar soils record both positive and negative δ¹⁵N signatures, and the secular increase of the δ¹⁵N value previously postulated by Kerridge (Kerridge, J.F. [1975]. Science 188(4184), 162–164. doi:10.1126/science.188.4184.162) is no longer apparent when the Luna and Apollo data are combined. Instead, the N isotope signatures, corrected for cosmogenic ¹⁵N, are consistent with binary mixing between isotopically light solar wind (SW) N and a planetary N component with a δ¹⁵N value of +100‰ to +160‰. The lower δ¹⁵N values of Luna 24 grains compared to Apollo samples reflect a higher relative proportion of solar N, resulting from the higher SW fluence in the region of Mare Crisium compared to the central near side of the Moon. Carbonaceous chondrite-like micro-impactors match well the required isotope characteristics of the non-solar N component trapped in low-antiquity lunar regolith. In contrast, a possible cometary contribution to the non-solar N flux is constrained to be ?3–13%. Based on the mixing ratio of SW to planetary N obtained for recently exposed lunar soils, we estimate the flux of micro-impactors to be (2.2–5.7) × 10³ tons yr^?1 at the surface of the Moon. Our estimate for Luna 24 agrees well with that for young Apollo regolith, indicating that the supply of planetary material does not depend on lunar location. Thus, the continuous influx of water-bearing cosmic dust may have represented an important source of water for the lunar surface over the past ～1 Ga, provided that water removal rates (i.e., by meteorite impacts, photodissociation, and sputtering) do not exceed accumulation rates.  相似文献   

Snow cover monitoring in the Northern Patagonia Icefield using MODIS satellite images (2000–2006)     

Paulina Lopez  Pascal Sirguey  Yves Arnaud  Bernard Pouyaud  Pierre Chevallier 《Global and Planetary Change》2008,61(3-4):103-116

The snow cover of the Northern Patagonia Icefield (NPI) was monitored after applying the Normalized Difference Snow Index (NDSI) and the Red/NIR band ratio to 134 Moderate Resolution Imaging Spectroradiometer (MODIS) images captured between 2000 and 2006. The final results show that the snow cover extent of the NPI fluctuates a lot in winter, in addition to its seasonal behaviour. The minimum snow cover extent of the period (3600 km²) was observed in March 2000 and the maximum (11,623 km²) in August 2001. We found that temperature accounts for approximately 76% of the variation of the snow cover extent over the entire icefield. We also show two different regimes of winter snow cover fluctuations corresponding to the eastern and the western sides of the icefield. The seasonality of the snow cover on the western side was determined by temperature rather than precipitation, while on the east side the seasonality of the snow cover was influenced by the seasonal behaviour of both temperature and precipitation. This difference can be explained by the two distinct climates: coastal and continental. The fluctuations in the winter snow cover extent were more pronounced and less controlled by temperature on the western side than on the eastern side of the icefield. Snow cover extent was correlated with temperature R² = 0.75 and R² = 0.74 for the western and eastern sides, respectively. Since limited meteorological data are available in this region, our investigation confirmed that the change in snow cover is an interesting climatic indicator over the NPI providing important insights in mass balance comprehension. Since snow and ice were distinguished snow cover fluctuations can be associated to fluctuations in the snow accumulation area of the NPI. In addition, days with minimum snow covers of summer season can be associated to the period in which Equilibrium Line Altitude (ELA) is the highest.  相似文献   

S₂O, polysulfuroxide and sulfur polymer on Io's surface?     

Donia Baklouti  Bernard Schmitt  Olivier Brissaud 《Icarus》2008,194(2):647-659

To settle the question of disulfur monoxide and sulfur monoxide deposition and occurrence on Io's surface, we performed series of laboratory experiments reproducing the condensation of S₂O at low temperature. Its polymerization has been monitored by recording infrared spectra under conditions of temperature, pressure, mixing with SO₂ and UV-visible radiation simulating that of Io's surface. Our experiments show that S₂O condensates are not chemically stable under ionian conditions. We also demonstrate that SO and S₂O outgassed by Io's volcanoes and condensing on Io's surface should lead to yellow polysulfuroxide deposits or to white deposits of S₂O diluted in sulfur dioxide frost (i.e., S₂O/SO₂ < 0.1%). Thus S₂O condensation cannot be responsible for the red volcanic deposits on Io. Comparison of the laboratory infrared spectra of S₂O and polysulfuroxide with NIMS/Galileo infrared spectra of Io's surface leads us to discuss the possible identification of polysulfuroxide. We also recorded the visible transmission spectra of sulfur samples resulting from polysulfuroxide decomposition. These samples consist in a mixture of sulfur polymer and orthorhombic sulfur. Using the optical constants extracted from these measurements, we show that a linear combination of the reflectance spectra of our samples, the reflectance spectrum of orthorhombic S₈ sulfur and SO₂ reflectance spectrum, leads to a very good matching of Io's visible spectrum between 330 and 520 nm. We conclude then that Io's surface is probably mainly composed of sulfur dioxide and a mixture of sulfur S₈ and sulfur polymer. Some polysulfuroxide could also co-exist with these dominant components, but is probably restricted to some volcanic areas.  相似文献   

Geological and archaeological chronology of a late Holocene coastal enclosure: The Sanguinet lake (SW France)     

Jean‐Pierre Tastet  Ren Lalanne  Bernard Maurin  Bernard Dubos 《Geoarchaeology》2008,23(1):131-149

Sanguinet lake is separated from the Atlantic Ocean by a wide Holocene coastal dunes system in SW France. The present day lake level is 21 m above mean sea level (msl). It formed when aeolian sand closed the mouth of the small La Gourgue river which gradually became a lagoon and then a lake. Dated sub‐lacustrine archaeological remains (human settlements, canoes, and wooden architectural structures), as well as paleoenvironmental evidence (drowned tree stumps and lagoonal deposits exposed on the beach) are used to interpret the formation and chronology of lake level rise during the past 4000 years. Around 2000–1650 B.C., the river flowed into a lagoon or an estuary which connected with the ocean west of the present Sanguinet Lake. Its level was affected by the tide, which ranged between 2 m below and 3 m above msl. The accumulation of aeolian sand before 1500–1000 B.C. began to close the connection with the sea. At this time, the elevation of the surface of the lake water was approximately 5 m above msl, but it still remained connected to the ocean. Around 1000 B.C., the lake level rose quickly by 1 to 2 m during a period of renewed mobility of the coastal aeolian sand, and continued to rise slowly until about 100 A.D. when there was a gradual closure of the lake outlet. This rise forced people who were living on the lake shore and along the rivers to move to higher land along the valley. The nearby Gallo‐Roman site of Losa was settled at the end of the 1st century B.C.; then the final blocking of the outlet occurred because of spit growth as a result of north‐south littoral drift accompanied by the deposit of aeolian sand. This led to the lake level rising rapidly. Consequently, Losa was abandoned in the 3rd century A.D. and ruins of its temple (at 17 m above msl) were submerged in the 6th century. Further oscillations of the lake level probably correspond to water table fluctuations before it became stable at around 1000 A.D. The highest lake level (23.35 m) was reached during the 18th century as a consequence of modern dune formation, and thus was artificially reduced to 21 m in 1840 by construction of an overflow channel. © 2008 Wiley Periodicals, Inc.  相似文献   

Post‐orogenic sediment drape in the Northern Pyrenees explained using a box model     

Thomas Bernard  Hugh D. Sinclair  Mark Naylor  Frdric Christophoul  Mary Ford 《Basin Research》2021,33(1):118-137

The transition to a post‐orogenic state in mountain ranges has been identified by a change from active subsidence to isostatic rebound of the foreland basin. However, the nature of the interplay between isostatic rebound and sediment supply, and their impact on the topographic evolution of a range and foreland basin during this transition, has not been fully investigated. Here, we use a box model to explore the syn‐ to post‐orogenic evolution of foreland basin/thrust wedge systems. Using a set of parameter values that approximate the northern Pyrenees and the neighbouring Aquitaine foreland basin, we evaluate the controls on sediment drape over the frontal parts of the retro‐wedge following cessation of crustal thickening. Conglomerates preserved at approximately 600‐m elevation, which is ~ 300 m above the present mountain front in the northern Pyrenees are ca. 12 Ma, approximately 10 Myrs younger than the last evidence of crustal thickening in the wedge. Using the model, this post‐orogenic sediment drape is explained by the combination of a sustained, high sediment influx from the range into the basin relative to the efflux out of the basin, combined with cessation of the generation of accommodation space through basin subsidence. Post‐orogenic sediment drape is considered a generic process that is likely to be responsible for elevated low‐gradient surfaces and preserved remnants of continental sedimentation draping the outer margins of the northern Pyrenean thrust wedge.  相似文献   

Personal news     

A. Bernard 《Mineralium Deposita》1970,5(4):398

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Project cyclops study: Conclusions and recommendations     

Bernard M. Oliver 《Icarus》1973,19(3):425-428

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The Mynydd Cricor inlier     

Bernard Smith 《Proceedings of the Geologists' Association. Geologists' Association》1935,46(2):187-192

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