Stable carbon isotopic ratios of CH₄-CO₂-bearing fluid inclusions in fracture-fill mineralization from the Lower Saxony Basin (Germany) - A tool for tracing gas sources and maturity   总被引：1，自引：0，他引：1  

Volker Lüders  Birgit PlessenRolando di Primio 《Marine and Petroleum Geology》2012,30(1):174-183

The stable carbon isotopic ratios (δ¹³C) of methane (CH₄) and carbon dioxide (CO₂) of gas-rich fluid inclusions hosted in fracture-fill mineralization from the southern part of the Lower Saxony Basin, Germany have been measured online using a crushing device interfaced to an isotopic ratio mass spectrometer (IRMS). The data reveal that CH₄ trapped in inclusions seems to be derived from different source rocks with different organic matter types. The δ¹³C values of CH₄ in inclusions in quartz hosted by Carboniferous rocks range between −25 and −19‰, suggesting high-maturity coals as the source of methane. Methane in fluid inclusions in minerals hosted by Mesozoic strata has more negative carbon isotope ratios (−45 to −31‰) and appears to represent primary cracking products from type II kerogens, i.e., marine shales. There is a positive correlation between increasing homogenization temperatures of aqueous fluid inclusions and less negative δ¹³C(CH₄) values of in co-genetic gas inclusions probably indicating different mtaturity of the potential source rocks at the time the fluids were released. The CO₂ isotopic composition of CH₄-CO₂-bearing inclusions shows slight negative or even positive δ¹³C values indicating an inorganic source (e.g., water-rock interaction and dissolution of detrital, marine calcite) for CO₂ in inclusions. We conclude that the δ¹³C isotopic ratios of CH₄-CO₂-bearing fluid inclusions can be used to trace migration pathways, sources of gases, and alteration processes. Furthermore, the δ¹³C values of methane can be used to estimate the maturity of the rocks from which it was sourced. Results presented here are further supported by organic geochemical analysis of surface bitumens which coexist with the gas inclusion-rich fracture-fill mineralization and confirm the isotopic interpretations with respect to fluid source, type and maturity.  相似文献   

Sources and composition of organic matter for bacterial growth in a large European river floodplain system (Danube, Austria)     

Besemer K  Luef B  Preiner S  Eichberger B  Agis M  Peduzzi P 《Organic Geochemistry》2009,40(3):321-331

Dissolved and particulate organic matter (DOM and POM) distribution, lignin phenol signatures, bulk elemental compositions, fluorescence indices and microbial plankton (algae, bacteria, viruses) in a temperate river floodplain system were monitored from January to November 2003. We aimed to elucidate the sources and compositions of allochthonous and autochthonous organic matter (OM) in the main channel and a representative backwater in relation to the hydrological regime. Additionally, bacterial secondary production was measured to evaluate the impact of organic carbon source on heterotrophic prokaryotic productivity. OM properties in the backwater tended to diverge from those in the main channel during phases without surface water connectivity; this was likely enhanced due to the exceptionally low river discharge in 2003. The terrestrial OM in this river floodplain system was largely derived from angiosperm leaves and grasses, as indicated by the lignin phenol composition. The lignin signatures exhibited significant seasonal changes, comparable to the seasonality of plankton-derived material. Microbially-derived material contributed significantly to POM and DOM, especially during periods of low discharge. High rates of bacterial secondary production (up to 135 μg C L(-1) d(-1)) followed algal blooms and suggested that autochthonous OM significantly supported heterotrophic microbial productivity.  相似文献   

Stress orientation and tectonic regime in the northwestern Valencia Trough from borehole data     

Axel Schindler  María-Jos Jurado  Birgit Müller 《Tectonophysics》1998,300(1-4):63-77

The orientation of the maximum horizontal stress S_H is obtained from the analysis of borehole breakouts, covering a depth range from 300 to 3415 m (below sea level) in twelve offshore exploration wells in the northwestern Valencia Trough. The orientation of S_H is roughly coincident with the strike of major extensional structures. From N to S it changes counterclockwise from a NE–SW orientation to a N–S orientation. Estimates of the tectonic regimes indicate that the area is characterised predominantly by normal-faulting with a strike-slip component. Both the stress orientations and the tectonic regimes are consistent with neotectonic studies in the nearby Catalan Coastal Ranges. An established method of estimating the tectonic regime by Moos and Zoback (1990) was modified by the inclusion of a nontrivial cohesion, but this changes the results insignificantly.  相似文献   

An assessment of the risk associated with urban development in the Thiaroye area (Senegal)     

Seynabou?Cissé FayeEmail author  Serigne?Faye  Stefan?Wohnlich  Cheikh?Bécaye?Gaye 《Environmental Geology》2004,45(3):312-322

Water quality data from 56 wells, aquifer characteristics, soil types and land use in the city suburb of Dakar were compared to assess the effects of land use on the Thiaroye groundwater quality. The study area encompassed an unsewered densely populated zone, agricultural land, low density villages, and undeveloped land located in the sand dunes. A method similar to GIS technologies was applied to evaluate the degree of vulnerability of the different parts of the aquifer in relation to urban development, land use and aquifer characteristics. The aquifer parameters (hydraulic conductivity, groundwater level depth, recharge, soil type) were re-evaluated qualitatively into three class rankings (high, moderate and low), depending on the likelihood for contaminants reaching the water table, then combined using the two matrix Boolean logic based approaches to identify the nine classes of vulnerability assessed in the aquifer domain. An attempt was made to explain the distribution of nitrate concentration with the assessed vulnerability. In the area assessed, in the densely populated zone running from Pikine, to Thiaroye and Yeumbeul, very high nitrate concentrations correspond with the highest vulnerability index (H1). Nitrate contamination in this area is a consequence of point-source seepage from individual septic systems improperly built in this area. In the eastern part of the aquifer, high nitrate concentrations at Deni B. Ndao, Mbawane and Golam localities coincide with a moderate vulnerability assessment. The major source of nitrate in these areas is induced by agricultural activities.  相似文献   

On the variability of 18 Degree Water formation as observed from moored instruments at 55°W     

Birgit Klein  Nelson Hogg 《Deep Sea Research Part I: Oceanographic Research Papers》1996,43(11-12)

The analysis of hydrographic time series from moored sensors from the eastern end of the Sargasso Sea has shown that in the late 1980s the Subtropical Mode Water was dominated by high temperatures. The 18 Degree Water observed during this period was warmer and saltier than the definition given by Worthington, with an increase in values over the observation period. Although severe winter conditions in 1988 led to the formation of colder types of 18 Degree Water at the eastern part of the Sargasso Sea, they were not incorporated in the subtropical gyre. Simultaneous current meter measurements indicated eastward flow within the “southern recirculation gyre” during spring that might have been responsible for the fact that these cold Mode Water types have not been entrained into the gyre. The meteorological forcing fields show considerable interannual variability that is, in part, mimicked by changes in the 18 Degree Water properties. Due to the strong influence of the advection field on the 18 Degree Water properties, the relationship between the surface forcing and 18 Degree Water properties remains qualitative. The continuing influence of further mild winters after 1989, however, is manifested in rising temperatures within the Mode Water range.  相似文献   

Nesseltalgraben,a new reference section of the last glacial period in southern Germany     

Christoph Mayr  Birgit Brandlmeier  Volker Diersche  Philipp Stojakowits  Uwe Kirscher  Renate Matzke-Karasz  Valerian Bachtadse  Michael Eigler  Ulrich Haas  Bernhard Lempe  Paula J. Reimer  Christoph Spötl 《Journal of Paleolimnology》2017,57(2):213-219

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Viruses, bacteria and suspended particles in a backwater and main channel site of the Danube (Austria)     

Peter Peduzzi  Birgit Luef 《Aquatic Sciences - Research Across Boundaries》2008,70(2):186-194

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Storm surge and tidal interaction in the Tjeldsund channel, northern Norway   总被引：1，自引：1，他引：0  

Birgit Kjoss Lynge  Karina Hjelmervik  Bjørn Gjevik 《Ocean Dynamics》2013,63(7):723-739

The aim of this study is to investigate tide–surge interaction in narrow channels with complex and relatively shallow topography. A high-resolution depth-integrated tidal and storm surge model has been implemented for the Tjeldsund channel which is an important sailing lane in northern Norway. A horizontal grid resolution down to 50 m is applied in order to represent the complex bottom topography and the formation of jets and small-scale eddies. Two typically storm surge events in December 2004 have been examined in detail. The tide–surge interaction is found to influence the generation of higher harmonics and the formation of eddies in the current field. In some cases, the magnitude of storm surge currents may reach the same magnitude as the tidal currents enhancing the formation of jets and eddies.  相似文献   

Effects of detrital carbonate on stable oxygen and carbon isotope data from varved sediments of the interglacial Piànico palaeolake (Southern Alps,Italy)     

Clara Mangili  Achim Brauer  Birgit Plessen  Peter Dulski  Andrea Moscariello  Rudolf Naumann 《第四纪科学杂志》2010,25(2):135-145

Contamination with detrital matter is a well‐known bias in δ¹⁸O records from lake carbonates but quantitative information of this effect is yet lacking. Therefore, we developed a new methodological approach combining isotope analyses with microfacies, X‐ray diffraction and micro‐X‐ray fluorescence data and applied this in a case study for the Piànico interglacial lake record in order to provide a quantitative estimate of the effect of detrital carbonate on stable δ¹⁸O and δ¹³C data. The Piànico record contains a long series of distinct and well‐preserved calcite varves and is correlated to Marine Isotope Stage 11. Intercalated in the varve sequence are detrital layers triggered by surface erosion events. These detrital layers are mainly composed of dolomite, thus reflecting the mineralogical signature of the catchment. Microfacies analyses of a 9350 varve year interval allows the identification of detrital layers down to sub‐millimetre scale and a precise selection of three different types of samples for isotope analyses: (1) pure endogenic calcite varves (five varves per sample) without detrital contamination; (2) individual detrital layers; and (3) ‘mixed’ samples including five calcite varves and up to four thin detrital layers. Detrital samples show the isotopic signature of the catchment dolomite and are up to 5.7‰ enriched in δ¹⁸O values with respect to endogenic calcite samples. In mixed samples, the degree of isotopic enrichment is directly related to the amount of detrital contamination; δ¹⁸O of bulk carbonates is significantly biased when the detrital component amounts to more than 5% of the sample. It is also shown that samples containing detrital material have an influence on the calculation of the covariance between δ¹³C and δ¹⁸O. Covariance is high (r = 0.76) when the correlation coefficient is calculated on the base of all samples, but absent (r = ?0.43) when samples containing detrital dolomite are excluded. It has been demonstrated that microfacies analysis is a quick tool to avoid or reduce detrital contamination in bulk carbonate samples during sample selection. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

Transient Eastern Mediterranean deep waters in response to the massive dense-water output of the Aegean Sea in the 1990s   总被引：3，自引：0，他引：3  

Wolfgang Roether  Birgit Klein  Beniamino Bruno Manca  Alexander Theocharis  Sotiris Kioroglou 《Progress in Oceanography》2007,74(4):540-571

We present a detailed account of the changing hydrography and the large-scale circulation of the deep waters of the Eastern Mediterranean (EMed) that resulted from the unique, high-volume influx of dense waters from the Aegean Sea during the 1990s, and of the changes within the Aegean that initiated the event, the so-called ‘Eastern Mediterranean Transient’ (EMT). The analysis uses repeated hydrographic and transient tracer surveys of the EMed in 1987, 1991, 1995, 1999, and 2001/2002, hydrographic time series in the southern Aegean and southern Adriatic Seas, and further scattered data. Aegean outflow averaged nearly 3 × 10⁶ m³ s⁻¹ between mid-1992 and late 1994, and was largest during 1993, when south and west of Crete Aegean-influenced deep waters extended upwards to 400 m depth. EMT-related Aegean outflow prior to 1992, confined to the region around Crete and to 1800 m depth-wise, amounted to about 3% of the total outflow. Outflow after 1994 up to 2001/2002, derived from the increasing inventory of the tracer CFC-12, contributed 20% to the total, of 2.8 × 10¹⁴ m³. Densities in the southern Aegean Sea deep waters rose by 0.2 kg/m³ between 1987 and 1993, and decreased more slowly thereafter. The Aegean waters delivered via the principal exit pathway in Kasos Strait, east of Crete, propagated westward along the Cretan slope, such that in 1995 the highest densities were observed in the Hellenic Trench west of Crete. Aegean-influenced waters also crossed the East Mediterranean Ridge south of Crete and from there expanded eastward into the southeastern Levantine Sea. Transfer into the Ionian mostly followed the Hellenic Trench, largely up to the trench’s northern end at about 37°N. From there the waters spread further west while mixing with the resident waters. Additional transfer occurred through the Herodotus Trough in the south. Levantine waters after 1994 consistently showed temperature–salinity (T–S) inversions in roughly 1000–1700 m depth, with amplitudes decreasing in time. The T–S distributions in the Ionian Sea were more diverse, one cause being added Aegean outflow of relatively lower density through the Antikithira Strait west of Crete. Spreading of the Aegean-influenced waters was quite swift, such that by early 1995 the entire EMed was affected. and strong mixing is indicated by near-linear T–S relationships observed in various places. Referenced to 2000 and 3000 dbar, the highest Aegean-generated densities observed during the event equaled those generated by Adriatic Sea outflow in the northern Ionian Sea prior to the EMT. A precarious balance between the two dense-water source areas is thus indicated. A feedback is proposed which helped triggering the change from a dominating Adriatic source to the Aegean source, but at the same time supported the previous long-year dominance of the Adriatic. The EMed deep waters will remain transient for decades to come.  相似文献