Geodynamics of the deep sedimentary basin of the Caspian Sea region: paragenetic correlation of seismicity and mud volcanism     

Ibrahim?Guliev  Behrouz?PanahiEmail author 《Geo-Marine Letters》2004,24(3):169-176

In this paper we analyze seismic regime and earthquake depth distribution and correlation of seismicity and mud volcanism in the Azerbaijan and the Caspian Sea region. For the present region we have calculated accurate source locations, seismic activity, earthquake repetition and released earthquake energy parameters. It is shown that the active tectonic processes in the region are concentrated within the thick sedimentary cover that we consider as a general source of contemporary stress and a main structural element responsible for the origin of regional earthquakes. The correlation of seismicity and mud volcanism is of paragenetic character.  相似文献   

Wave reflection from partially perforated-wall caisson breakwater   总被引：2，自引：0，他引：2  

Kyung-Duck Suh  Jae Kil Park  Woo Sun Park   《Ocean Engineering》2006,33(2):264-280

In 1995, Suh and Park developed a numerical model that computes the reflection of regular waves from a fully perforated-wall caisson breakwater. This paper describes how to apply this model to a partially perforated-wall caisson and irregular waves. To examine the performance of the model, existing experimental data are used for regular waves, while a laboratory experiment is conducted in this study for irregular waves. The numerical model based on a linear wave theory tends to over-predict the reflection coefficient of regular waves as the wave nonlinearity increases, but such an over-prediction is not observed in the case of irregular waves. For both regular and irregular waves, the numerical model slightly over- and under-predicts the reflection coefficients at larger and smaller values, respectively, because the model neglects the evanescent waves near the breakwater.  相似文献   

Fine resolution 3D temperature fields off Kerguelen from instrumented penguins     

Jean-Benoît Charrassin  Young-Hyang Park  Yvon Le Maho  Charles-Andr Bost 《Deep Sea Research Part I: Oceanographic Research Papers》2004,51(12):2091-2103

The use of diving animals as autonomous vectors of oceanographic instruments is rapidly increasing, because this approach yields cost-efficient new information and can be used in previously poorly sampled areas. However, methods for analyzing the collected data are still under development. In particular, difficulties may arise from the heterogeneous data distribution linked to animals’ behavior. Here we show how raw temperature data collected by penguin-borne loggers were transformed to a regular gridded dataset that provided new information on the local circulation off Kerguelen. A total of 16 king penguins (Aptenodytes patagonicus) were equipped with satellite-positioning transmitters and with temperature–time–depth recorders (TTDRs) to record dive depth and sea temperature. The penguins’ foraging trips recorded during five summers ranged from 140 to 600 km from the colony and 11,000 dives >100 m were recorded. Temperature measurements recorded during diving were used to produce detailed 3D temperature fields of the area (0–200 m). The data treatment included dive location, determination of the vertical profile for each dive, averaging and gridding of those profiles onto 0.1°×0.1° cells, and optimal interpolation in both the horizontal and vertical using an objective analysis. Horizontal fields of temperature at the surface and 100 m are presented, as well as a vertical section along the main foraging direction of the penguins. Compared to conventional temperature databases (Levitus World Ocean Atlas and historical stations available in the area), the 3D temperature fields collected from penguins are extremely finely resolved, by one order finer. Although TTDRs were less accurate than conventional instruments, such a high spatial resolution of penguin-derived data provided unprecedented detailed information on the upper level circulation pattern east of Kerguelen, as well as the iron-enrichment mechanism leading to a high primary production over the Kerguelen Plateau.  相似文献   

Species composition and spatial distribution of euphausiids of the yellow sea and relationships with environmental factors   总被引：1，自引：0，他引：1  

Won Duk Yoon  Joon Yong Yang  Donghyun Lim  Sung Hwan Cho  Gyung Soo Park 《Ocean Science Journal》2006,41(1):11-29

We investigated species composition and spatial distribution of the euphausiid community in the Yellow Sea and identified the relationship with environmental factors (temperature, salinity, chlorophyll a, nitrate, phosphate, and silicate) using bimonthly data from June, 1997 to April, 1998. The environment varied during the sampling period. In warm seasons, thermocline was well developed rendering lower temperature and higher salinity and nutrient concentrations in the bottom layer. During cold seasons the water column was well mixed and no such vertical stratification was noted. Horizontal distribution of temperature, however, differed slightly between near-coast and offshore areas because of the shallow depth of the Yellow Sea, and between southern and northern areas because of the intrusion of water masses such as Yellow Sea Warm Current and Changjiang River Diluted Water. Four euphausiid species were identified:Euphausia pacifica, E. sanzoi, Pseudeuphausia sp. andStylocheron affine. E. sanzoi andS. affine were collected, just one juvenile each, from the southern area in June and December, respectively.Pseudeuphausia sp. were collected in the eastern area all the year round except June.E. pacifica occurred at the whole study area and were the predominant species, representing at least 97.6% of the euphausiid abundance. Further, the distribution pattern of the species was varied in regards to developmental stages (adult, furcilia, calyptopis, egg). From spring to fall,E. pacifica adults were abundant in the central area where the Yellow Sea Bottom Cold Water prevailed. Furcilia and calyptopis extended their distribution into nearly all the study area during the same period. From late fall to winter, adults were found at the near-coastal area with similar pattern for furcilia and calyptopis. The distribution pattern ofE. pacifica was consistent regarding temperature, salinity, and three nutrients during the sampling period, whereas chlorophyll a showed a different pattern according to the developmental stages. The nutrients should indirectly affect via chlorophyll a and phytoplankton concentration. With respect to these results, we presented a scenario about how the environmental factors along with the water current affect the distribution ofE. pacifica in the Yellow Sea.  相似文献   

Organic carbon transport in the Columbia River     

Clifford N. Dahm  Stanley V. Gregory  P. Kilho Park 《Estuarine, Coastal and Shelf Science》1981,13(6):645-658

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Tephrostratigraphy and paleo-environmental implications of Late Quaternary sediments and interstitial water in the western Ulleung Basin, East/Japan Sea     

M. H. Park  J. H. Kim  I. S. Kim  B. J. Ryu  K. M. Yu 《Geo-Marine Letters》2005,25(1):54-62

Two piston cores, collected from the western Ulleung Basin of the East/Japan Sea, were used to investigate the Late Quaternary tephrostratigraphy, lithology, and mineralogy of the sediments, as well as the elemental composition of both sediments and interstitial water, and their paleo-environmental implications. The cores show two lapilli tephra layers and one rhyolitic ash layer at the boundaries between sedimentary lithofacies units I, II, and III. These layers can be correlated with the well-known Ulleung-Oki (ca. 9.3 ka; boundary of units I/II), Ulleung-Yamato (ca. 25–33 ka), and Aira-Tanzawa (ca. 25.1 ka; boundary of units II/III) layers, respectively. These data suggest that the cores cover the period from the middle stage of marine isotope stage (MIS) 3 to the Holocene. In each core, a so-called dark laminated mud (DLM) layer in unit II commonly has high contents of Si and Al, suggesting that the DLM layer generally contains significant amounts of fine-grained silicates and/or aluminosilicates. In addition, these DLM layers are enriched in Fe relative to Mn, iron being predominantly bound in framboidal pyrite. The size distribution of pyrite in the DLM layers suggests that these have formed under anoxic (euxinic) conditions at times of reduced water circulation in the basin during sea-level lowstand (euxinic environment). The C/N ratios [5–12] suggest that sedimentary organic matter in the cores is predominantly of marine origin. Total organic carbon (TOC) contents increased shortly before Termination I. This could have been caused by an increased flux of marine organic matter in association with sea-level rise. The C and S values of units II and III (Late Pleistocene sediments; C: <2.0%; S: 0.5–2.1%) suggest a more euxinic environment than that of unit I (Holocene sediments; C: 1.0–3.5%; S: <1.0%). Concentrations of SO₄^2– in the interstitial water decrease with increasing burial depth, whereas CH₄ concentrations show the reverse trend. Therefore, it seems that sulfate reduction, probably related to microbial activity, predominates in the upper core sections (<5 m), shifting to methanogenesis in the lower core sections.  相似文献   

GPS observations of the ionospheric F2-layer behavior during the 20th November 2003 geomagnetic storm over South Korea   总被引：4，自引：1，他引：3  

Shuanggen Jin  O. F. Luo  P. Park 《Journal of Geodesy》2008,82(12):883-892

The ionospheric F2-layer peak density (NmF2) and its height (hmF2) are of great influence on the shape of the ionospheric electron density profile Ne (h) and may be indicative of other physical processes within the ionosphere, especially those due to geomagnetic storms. Such parameters are often estimated using models such as the semiempirical international reference ionosphere (IRI) models or are measured using moderately priced to expensive instrumentation, such as ionosondes or incoherent scatter radars. Global positioning system (GPS) observations have become a powerful tool for mapping high-resolution ionospheric structures, which can be used to study the ionospheric response to geomagnetic storms. In this paper, we describe how 3-D ionospheric electron density profiles were produced from data of the dense permanent Korean GPS network using the tomography reconstruction technique. These profiles are verified by independent ionosonde data. The responses of GPS-derived parameters at the ionospheric F2-layer to the 20th November 2003 geomagnetic storm over South Korea are investigated. A fairly large increase in the electron density at the F2-layer peak (the NmF2) (positive storm) has been observed during this storm, which is accompanied by a significant uplift in the height of the F2 layer peak (the hmF2). This is confirmed by independent ionosonde observations. We suggest that the F2-layer peak height uplift and NmF2 increase are mainly associated with a strong eastward electric field, and are not associated with the increase of the O/N₂ ratio obtained from the GUVI instruments aboard the TIMED satellite. It is also inferred that the increase in NmF2 is not caused by the changes in neutral composition, but is related to other nonchemical effects, such as dynamical changes of vertical ion motions induced by winds and E × B drifts, tides and waves in the mesosphere/lower thermosphere region, which can be dynamically coupled upward to generate ionospheric perturbations and oscillations.  相似文献   

Oil-generation kinetics for organic facies with Type-II and -IIS kerogen in the Menilite Shales of the Polish Carpathians     

M.D. Lewan  M.J. Kotarba  D. Wi?c?aw 《Geochimica et cosmochimica acta》2006,70(13):3351-3368

The Menilite Shales (Oligocene) of the Polish Carpathians are the source of low-sulfur oils in the thrust belt and some high-sulfur oils in the Carpathian Foredeep. These oil occurrences indicate that the high-sulfur oils in the Foredeep were generated and expelled before major thrusting and the low-sulfur oils in the thrust belt were generated and expelled during or after major thrusting. Two distinct organic facies have been observed in the Menilite Shales. One organic facies has a high clastic sediment input and contains Type-II kerogen. The other organic facies has a lower clastic sediment input and contains Type-IIS kerogen. Representative samples of both organic facies were used to determine kinetic parameters for immiscible oil generation by isothermal hydrous pyrolysis and S₂ generation by non-isothermal open-system pyrolysis. The derived kinetic parameters showed that timing of S₂ generation was not as different between the Type-IIS and -II kerogen based on open-system pyrolysis as compared with immiscible oil generation based on hydrous pyrolysis. Applying these kinetic parameters to a burial history in the Skole unit showed that some expelled oil would have been generated from the organic facies with Type-IIS kerogen before major thrusting with the hydrous-pyrolysis kinetic parameters but not with the open-system pyrolysis kinetic parameters. The inability of open-system pyrolysis to determine earlier petroleum generation from Type-IIS kerogen is attributed to the large polar-rich bitumen component in S₂ generation, rapid loss of sulfur free-radical initiators in the open system, and diminished radical selectivity and rate constant differences at higher temperatures. Hydrous-pyrolysis kinetic parameters are determined in the presence of water at lower temperatures in a closed system, which allows differentiation of bitumen and oil generation, interaction of free-radical initiators, greater radical selectivity, and more distinguishable rate constants as would occur during natural maturation. Kinetic parameters derived from hydrous pyrolysis show good correlations with one another (compensation effect) and kerogen organic-sulfur contents. These correlations allow for indirect determination of hydrous-pyrolysis kinetic parameters on the basis of the organic-sulfur mole fraction of an immature Type-II or -IIS kerogen.  相似文献   

Study on the kinetics of iron oxide leaching by oxalic acid   总被引：2，自引：0，他引：2  

Suong Oh Lee  Tam Tran  Yi Yong Park  Seong Jun Kim  Myong Jun Kim   《International Journal of Mineral Processing》2006,80(2-4):144-152

The presence of iron oxides in clay or silica raw materials is detrimental to the manufacturing of high quality ceramics. Although iron has been traditionally removed by physical mineral processing, acid washing has been tested as it is more effective, especially for extremely low iron (of less than 0.1% w/w). However, inorganic acids such as sulphuric or hydrochloric acids easily contaminate the clay products with SO₄²⁻ and Cl⁻, and therefore should be avoided as much as possible. On the other hand, if oxalic acid is used, any acid left behind will be destroyed during the firing of the ceramic products. The characteristics of dissolution of iron oxides were therefore investigated in this study.The dissolution of iron oxides in oxalic acid was found to be very slow at temperatures within the range 25–60 °C, but its rate increases rapidly above 90 °C. The dissolution rate also increases with increasing oxalate concentration at the constant pH values set within the optimum range of pH2.5–3.0. At this optimum pH, the dissolution of fine pure hematite (Fe₂O₃) (105–140 μm) follows a diffusion-controlled shrinking core model. The rate expression expressed as 1 − (2 / 3)x − (1 − x)^2 / 3 where x is a fraction of iron dissolution was found to be proportional to [oxalate]^1.5.The addition of magnetite to the leach liquor at 10% w/w hematite was found to enhance the dissolution rate dramatically. Such addition of magnetite allows coarser hematite in the range 0.5–1.4 mm to be leached at a reasonable rate.  相似文献   

Hydrometallurgical processing and recovery of molybdenum trioxide from spent catalyst   总被引：5，自引：0，他引：5  

Kyung Ho Park  B. Ramachandra Reddy  D. Mohapatra  Chul-Woo Nam 《International Journal of Mineral Processing》2006,80(2-4):261-265

Hydrometallurgical processing of spent hydrodesulphurisation (HDS) catalyst for the recovery of molybdenum using sodium carbonate and hydrogen peroxide mixtures was investigated. The results indicated that the recovery of molybdenum was largely dependent on the concentrations of Na₂CO₃ and H₂O₂ in the reaction medium, which controls the acidity of the leach liquor and carry over of impurities such as Al, Ni, P, Si and V. Leaching process was exothermic and leaching efficiency of molybdenum decreased with increasing solid to liquid ratio. Large scale leaching of spent catalyst, under optimum conditions: 20% pulp density, 85 g/L Na₂CO₃, 10 vol.% H₂O₂ and 1 h reaction, resulted a leaching efficiency of 84% Mo. The obtained leach liquor contained (g/L): Mo — 22.0, Ni — 0.015 and Al — 0.82, P — 1.1, Si — 0.094 and minor quantities of V — 8 mg/L, As and Co — < 1 mg/L. Recovery of Mo from leach solution as MoO₃ of 97.30% purity was achieved by ammonium molybdate precipitation method.  相似文献