Uranium-rich accessory minerals in the peraluminous and perphosphorous Belvís de Monroy pluton (Iberian Variscan belt)     

Cecilia?Pérez-SobaEmail author  Carlos?Villaseca  David?Orejana  Teresa?Jeffries 《Contributions to Mineralogy and Petrology》2014,167(5):1008

The strongly peraluminous, perphosphorous (<0.85 wt% P₂O₅) and low-Ca granites from the Belvís de Monroy pluton contain the most U-rich monazite-(Ce) and xenotime known in igneous rocks. Along with these accessory minerals, P-rich zircon occurs, reaching uncommon compositions particularly in the more fractionated units of this zoned pluton. Monazite displays a wide compositional variation of UO₂ (<23.13 wt%) and ThO₂ (<19.58 wt%), positively correlated with Ca, Si, P, Y and REE. Xenotime shows a high UO₂ content (2.37–13.34 wt%) with parallel increases of LREE, Ca and Si. Zircon contains comparatively much lower UO₂ (<1.53 wt%) but high P₂O₅ (<14.91 wt%), Al₂O₃ (<6.96 wt%), FeO (<2.93 wt%) and CaO (<2.24 wt%) contents. The main mechanism of incorporating large U and Th amounts in studied monazite and U in xenotime is the cheralite-type [(Th,U)⁴⁺ + Ca²⁺ = 2(Y,REE)³⁺] substitution. Zircon requires several coupled mechanisms to charge balance the P substitution, resulting in non-stoichiometric compositions with low analytical totals. Compositional variations in the studied accessory phases indicate that the substitution mechanisms during crystal growth depend on the availability of non-formula elements. The strong P-rich character of the studied granites increases monazite crystallization, triggering a progressive impoverishment in Th and LREE in the residual melts, and consequently increasing extraordinarily the U content in monazite and xenotime. This is in marked contrast to other peraluminous (I-type or P-poor S-type) granite series. The P-rich and low-Ca peraluminous melt inhibits uraninite crystallization, so contributing to the U availability for monazite and xenotime.  相似文献   

Fluid Inclusion and Stable Isotope Studies at Don Sixto,a Precious Metal Low Sulfidation Deposit in Mendoza Province,Argentina     

Ana Cecilia Mugas Lobos  María Florencia Márquez‐Zavalía 《Resource Geology》2013,63(4):350-359

The Don Sixto mining area in Mendoza province, central‐western Argentina, contains an epithermal low sulfidation Au–Ag deposit. It is a small deposit (～4 km²), with a gold resource of 36 t. In Don Sixto, ore minerals are disseminated in the hydrothermal quartz veins and hydrothermally altered volcanic‐pyroclastic rock units of Permian–Triassic age. On the basis of the texture, ore mineral paragenesis and cross cutting relationship of gangue minerals, seven stages of mineralization were recognized and described. The first six stages are characterized by quartz veins with minor amounts of base metal minerals and the last stage is represented by fluorite veins with minimal quantities of base metal minerals; the precious metal mineralization is mainly related to the fourth stage. The hydrothermal veins exhibit mainly massive, crustiform and comb infilling textures; the presence of bladed quartz replacement textures and quartz veins with adularia crystals are indicative of boiling processes in the system. Fluid inclusion and complementary stable isotope studies were performed in quartz, fluorite, and pyrite samples from the vein systems. The microthermometric data were obtained from primary, biphasic (liquid‐vapor) fluid inclusion assemblages in quartz and fluorite. The maximum values for salinity and homogenization temperature (T_h) came from the stage IV where quartz with petrographic evidence of boiling has average values of 4.96 wt% NaCl_equiv. and 286.9°C respectively. The lower values are related to the last stage of mineralization, where the fluid inclusions in fluorite have average salinities of 1.05 wt% NaCl_equiv. and average homogenization temperatures of 173.1°C. The oxygen and sulfur isotopic fractionation was analyzed in quartz and pyrite. The calculated isotopic fractionation for oxygen in the hydrothermal fluid is in the range of δ¹⁸O_H2O = ?6.92 up to ?3.08‰, which indicates dominance of a meteoric source for the water, while sulfur reaches δ³⁴S_H2S = 1.09‰, which could be reflecting a possible magmatic, or even a mixed source.  相似文献   

Removal of Volatile Organic Compounds in Vertical Flow Filters: Predictions from Reactive Transport Modeling     

Cecilia De Biase  Uli Maier  Oliver Baeder‐Bederski  Peter Bayer  Sascha E. Oswald  Martin Thullner 《Ground Water Monitoring & Remediation》2012,32(2):106-121

Vertical flow filters are containers filled with porous medium that are recharged from top and drained at the bottom, and are operated at partly saturated conditions. They have recently been suggested as treatment technology for groundwater containing volatile organic compounds (VOCs). Numerical reactive transport simulations were performed to investigate the relevance of different filter operation modes on biodegradation and/or volatilization of the contaminants and to evaluate the potential limitation of such remediation mean due to volatile emissions. On the basis of the data from a pilot‐scale vertical flow filter intermittently fed with domestic waste water, model predictions on the system’s performance for the treatment of contaminated groundwater were derived. These simulations considered the transport and aerobic degradation of ammonium and two VOCs, benzene and methyl tertiary butyl ether (MTBE). In addition, the advective‐diffusive gas‐phase transport of volatile compounds as well as oxygen was simulated. Model predictions addressed the influence of depth and frequency of the intermittent groundwater injection, degradation rate kinetics, and the composition of the filter material. Simulation results show that for unfavorable operation conditions significant VOC emissions have to be considered and that operation modes limiting VOC emissions may limit aerobic biodegradation. However, a suitable combination of injection depth and composition of the filter material does facilitate high biodegradation rates while only little VOC emissions take place. Using such optimized operation modes would allow using vertical flow filter systems as remediation technology suitable for groundwater contaminated with volatile compounds.  相似文献   

Benthic foraminifera as bio-indicators of trace element pollution in the heavily contaminated Santa Gilla lagoon (Cagliari, Italy)     

Fabrizio Frontalini  Carla Buosi  Rodolfo Coccioni  Carla Bucci 《Marine pollution bulletin》2009,58(6):858-877

In order to assess the response of benthic foraminifera to trace element pollution, a study of benthic foraminiferal assemblages was carried out into sediment samples collected from the Santa Gilla lagoon (Sardinia, Italy). The lagoon has been contaminated by industrial waste, mainly trace elements, as well as by agricultural and domestic effluent. The analysis of surficial sediment shows enrichment in trace elements, including Cr, Cu, Hg, Ni, Pb and Zn. Biotic and abiotic data, analyzed with multivariate techniques of statistical analysis, reveal a distinct separation of both the highly polluted and less polluted sampling sites. The innermost part of the lagoon, comprising the industrial complex at Macchiareddu, is exposed to a high load of trace elements which are probably enhanced by their accumulation in the finer sediment fraction. This area reveals lower diversity and higher percentages of abnormalities when compared to the outermost part of the lagoon.  相似文献   

Seasonal dynamics of zooplankton in Lake Huetzalin, Xochimilco (Mexico City, Mexico)     

Cecilia Enríquez García  S. Nandini  S.S.S. Sarma 《Limnologica》2009,39(4):283-291

We quantified the seasonal changes in the zooplankton abundances collected from the Huetzalin Lake (Mexico City, Mexico) for two years (February 2003–January 2004 and then March 2005–February 2006). Selected physicochemical variables (Secchi depth, temperature, pH, conductivity, dissolved oxygen, phosphorus, nitrogen, carbon and chlorophyll a concentration) were also measured at the time of zooplankton collection. The data on zooplankton abundances and the physicochemical variables were subjected to multiple correlation analysis and we also derived Shannon–Wiener species diversity index. Secchi depth ranged from 9 to 65 cm. Generally the lake was alkaline (pH 7–12). The conductivity ranged from 500–1000 mS cm⁻¹, while the mean water temperature was 20.5 °C. Dissolved oxygen levels were generally >3 mg L⁻¹ and were higher in the winter than warmer months. Nitrates (90–95 μg L⁻¹) and phosphates (.2–.5 mg L⁻¹) indicated that the water was eutrophic. Chlorophyll a levels ranged from 143 to 696 μg L⁻¹ during the study period. The zooplankton community was dominated by rotifers (46 species), followed by cladocerans (9 species) and there were only two copepod species. The dominant rotifer species were Brachionus angularis, Brachionus calyciflorus, Brachionus havanaensis, Brachionus quadridentatus, Lecane bulla and Polyarthra vulgaris. Rare rotifer species in Lake Huetzalin were Lecane ohioensis, Dicranophorus forcipatus, Lecane pyriformis, Lindia torulosa, Pleurotrocha petromyzon and Brachionus durgae. Highest densities (occasional peaks of 400 ind L⁻¹) of B. quadridentatus occurred between April and December, while B. havanaensis reached peak densities, during June to October. B. calyciflorus reached densities higher than 1240 ind L⁻¹ during May–September. Cladoceran and copepod densities in Lake Huetzalin were much lower than that of the rotifers. This study confirmed the earlier findings that Xochimilco system of canals is dominated by rotifers and the crustacean zooplankton have much lower abundances possibly due to predation from fish.  相似文献   

Growth and deformation mechanisms of talc along a natural fault: a micro/nanostructural investigation     

Cecilia Viti  Cristiano Collettini 《Contributions to Mineralogy and Petrology》2009,158(4):529-542

This paper documents the occurrence of large amounts of talc within a continental normal fault. The talc-in reaction is deformation-enhanced and occurs by the interaction between dolostones and silica-rich hydrothermal fluids. In the high-strain, foliated fault core, talc forms an interconnected network of oriented (001) lamellae, 200–300 nm thick, locally associated with minor tremolite fibres, up to 300 nm in diameter. The talc structure is affected by several strain-induced defects, among which (001) interlayer delamination that produces talc “sublamellae” down to 10–30 nm thick. Micro/nanostructural observations definitely point to a predominant deformation mechanism of (001) frictional sliding, further enhanced by pervasive delamination that gives rise to an almost infinite number of possible sliding surfaces. These effects have fundamental implications in fault mechanics, resulting in significant fault weakening.  相似文献   

First historical evidence of a significant Mt. Etna eruption in 1224     

Emanuela Guidoboni  Cecilia Ciuccarelli 《Journal of Volcanology and Geothermal Research》2008

The 1224 Mt. Etna eruption is a significant event both in terms of the mass of erupted materials and because it involved the lower eastern slope of the volcano, reaching down to the sea. Nevertheless, it is unknown to current historical catalogues. According to the historical sources, only two other lava flows actually reached as far as the sea: in 396 BC, just north of the present-day inhabited area of Acireale, according to the geological data alone, and in 1669, when the lava covered the south-eastern flank of Mt. Etna and damaged Catania. We present and discuss the two medieval sources that attest to the eruption of 1224 and make available the original texts. Furthermore, through the close analysis of the historical and topographic context of the Etna area, taking account of the roads and ports in the early 13th century, we have tried to single out the possible area of the lava's outlet into the sea in 1224 on historical grounds. A repeat of an eruption similar to that of 1224 would have a serious impact today as the coast is densely populated.  相似文献   

Occurrence,shape and movement of daily rainfall in the Huai Basin,China     

Cecilia Svensson 《水文研究》1999,13(8):1197-1215

The upper reaches of the Huai River in Central China are located in the East Asian monsoon region. Strong seasonality, as well as large interannual variability of rainfall, causes floods and an uneven supply of water. In order to conserve the water and mitigate the floods, dams and flood protection structures are constructed. Their design requires information about the rainfall. Daily observations from 1957 to 1986 from 78 rain gauges were used to study shape, orientation, movement and geographical and seasonal occurrence of storms in the 79 000 km² study area. The rainfall characteristics were described using graphical plots, cross‐ and autocorrelation. Storms larger than 50 mm/day were found to occur from February to November, whereas storms exceeding 350 mm/day were confined to the main rainfall season from late June to mid‐August. The southern part of the study area experienced a break in the rainfall season in late July, corresponding to the seasonal northward shift of the rain belt. A weekly periodicity of 7–8 days for rainfall was found during June–July, but not during August–September. During the whole period June–September, the spatial pattern of daily rainfall revealed an elongated shape, more pronounced during June–July than August–September. The rainfall area was orientated approximately from WSW to ENE during the whole period, and showed an anticlockwise rotation of about 16° per day during June–July. The cross‐correlation analysis revealed that the rainfall area moved about 100 km/day eastward. These results and an investigation of meteorological maps indicate that the spatial correlation pattern of daily rainfall is produced by cold fronts on the Mei‐Yu front. Suggestions are made as to how to use the results for the construction of design rainfalls in the study area. Copyright © 1999 John Wiley & Sons, Ltd.  相似文献   

Estimating sand concentrations using ADCP-based acoustic inversion in a large fluvial system characterized by bi-modal suspended-sediment distributions     

Ricardo N. Szupiany  Cecilia Lopez Weibel  Massimo Guerrero  Francisco Latosinski  Molly Wood  Lucas Dominguez Ruben  Kevin Oberg 《地球表面变化过程与地形》2019,44(6):1295-1308

Quantifying sediment flux within rivers is a challenge for many disciplines due, mainly, to difficulties inherent to traditional sediment sampling methods. These methods are operationally complex, high cost, and high risk. Additionally, the resulting data provide a low spatial and temporal resolution estimate of the total sediment flux, which has impeded advances in the understanding of the hydro-geomorphic characteristics of rivers. Acoustic technologies have been recognized as a leading tool for increasing the resolution of sediment data by relating their echo intensity level measurements to suspended sediment. Further effort is required to robustly test and develop these techniques across a wide range of conditions found in natural river systems. This article aims to evaluate the application of acoustic inversion techniques using commercially available, down-looking acoustic Doppler current profilers (ADCPs) in quantifying suspended sediment in a large sand bed river with varying bi-modal particle size distributions, wash load and suspended-sand ratios, and water stages. To achieve this objective, suspended sediment was physically sampled along the Paraná River, Argentina, under various hydro-sedimentological regimes. Two ADCPs emitting different sound frequencies were used to simultaneously profile echo intensity level within the water column. Using the sonar equation, calibrations were determined between suspended-sand concentrations and acoustic backscatter to solve the inverse problem. The study also analyzed the roles played by each term of the sonar equation, such as ADCP frequency, power supply, instrument constants, and particle size distributions typically found in sand bed rivers, on sediment attenuation and backscatter. Calibrations were successfully developed between corrected backscatter and suspended-sand concentrations for all sites and ADCP frequencies, resulting in mean suspended-sand concentration estimates within about 40% of the mean sampled concentrations. Noise values, calculated using the sonar equation and sediment sample characteristics, were fairly constant across evaluations, suggesting that they could be applied to other sand bed rivers. © 2018 John Wiley & Sons, Ltd.  相似文献   

Patterns and Levels of Organochlorines (DDTs, PCBs, non-ortho PCBs and PCDD/Fs) in Male Harbour Porpoises (Phocoena phocoena) from the Baltic Sea, the Kattegat-Skagerrak Seas and the West Coast of Norway     

Per Berggren  Rasha Ishaq  Yngve ZebÜhr  Carina Nf  Cecilia Bandh  Dag Broman 《Marine pollution bulletin》1999,38(12):238-1084

Patterns and levels of chlorinated aromatic contaminants (DDTs, PCBs, non-ortho PCBs and PCDD/Fs) in blubber tissue were compared among six sample groups of male harbour porpoises (Phocoena phocoena) from the Baltic Sea, the Kattegat-Skagerrak Seas and the west coast of Norway. A principal component and classification analysis showed that mature harbour porpoises from the Baltic had significantly different contaminant patterns than animals from the Kattegat-Skagerrak and Norway. ANOVAs showed that mature porpoises from the Baltic had higher levels of ΣPCB and several individual PCBs and PCDD/Fs than the Kattegat-Skagerrak and the Norwegian samples and higher ΣDDT than the Norwegian. A comparison between immature porpoises showed that Baltic animals had higher levels of ΣPCDD/F than the corresponding sample from the Kattegat-Skagerrak. The levels of ΣDDT, ΣPCB and Σnon-ortho PCB were significantly higher in animals collected during 1978–81 compared to animals collected in 1988–90 indicating a temporal decline of these organochlorines in the Kattegat-Skagerrak Seas. The contaminant levels recorded in the Baltic Sea are a serious cause for concern and could have management implications for the already threatened harbour porpoises in this area.  相似文献