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1.
The transformation of Rome during the Late Antiquity and the Early Middle Ages has been investigated by archaeologists and historians. Social and political changes are the main aspects which led to a progressive modification of the urban framework; abandonment, spoliation and transformation of buildings are quite diffused as documented by the archaeological literature. The consequence of these practices is a higher vulnerability of the buildings which, from the seismological point of view, played a main role in increasing the effects of seismic shaking. A number of earthquakes have struck Rome during the period of investigation (fifth to ninth century A.D.), known from historical sources: 443, 484–508, 618, 801, 847; in some cases (443, 484–508, 801) damage has been documented. In contrast, the archaeological sources characterise collapse layers and evidence of destruction at different sites with changing and not always conclusive chronological constraints. Consequently, collapse and destruction have been alternatively attributed to the above-mentioned earthquakes. Through a geoarchaeological and stratigraphic analysis of potentially coseismic collapse units, we want (1) to describe the archaeoseismic evidence derived from recent excavations and from the available literature (e.g. Piazza Madonna di Loreto, Piazza Venezia, Palazzo Valentini Crypta Balbi, Colosseo, Basilica Hilariana, Basilica di Santa Petronilla, Santa Maria Antiqua,…); (2) to discuss the chronological problems and the uncertainty of attribution of the collapse units to known historical earthquakes; (3) to discuss the earthquake damage exaggeration due to erroneous attribution of seismic origin to the evidence of destruction derived from archaeological data. Finally, we will infer the role that earthquakes may have had on the development of the urban landscape in the fifth to ninth century A.D.  相似文献   
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Thermoluminescence (TL) dating has been used to determine the age of the meteorite impact crater at Gebel Kamil (Egyptian Sahara). Previous studies suggested that the 45 m diameter structure was produced by a fall in recent times (less than 5000 years ago) of an iron meteorite impactor into quartz‐arenites and siltstones belonging to the Lower Cretaceous Gilf Kebir Formation. The impact caused the complete fragmentation of the impactor, and the formation of a variety of impactites (e.g., partially vitrified dark and light materials) present as ejecta within the crater and in the surrounding area. After a series of tests to evaluate the TL properties of different materials including shocked intra‐crater target rocks and different types of ejecta, we selected a suite of light‐colored ejecta that showed evidence of strong thermal shock effects (e.g., partial vitrification and the presence of high‐temperature and ‐pressure silica phases). The abundance of quartz in the target rocks, including the vitrified impactites, allowed TL dating to be undertaken. The variability of radioactivity of the intracrateric target rocks and the lack of direct in situ dosimetric evaluations prevented precise dating; it was, however, possible to constrain the impact in the 2000 BC–500 AD range. If, as we believe, the radioactivity measured in the fallback deposits is a reliable estimate of the mean radioactivity of the site, the narrower range 1600–400 BC (at the 2σ confidence level) can be realistically proposed.  相似文献   
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We have recently set up a new procedure for characterising the water soluble organic compounds (WSOC) in fog water, for which information is still rather limited. Fog samples collected during the 1998–1999 fall–winter season in the Po Valley (Italy) were analysed following this procedure, which allows a quantitative determination of three main classes of organic compounds (neutral species, mono- and di-carboxylic acids, polycarboxylic acids), together accounting for ca. 85% of the total WSOC. This procedure also provides information on the main chemical characteristics of these three classes of compounds (functional groups, aliphatic vs. aromatic character, etc.). The enhanced chemical knowledge on fog/cloud chemical composition opens new scenarios as far as chemical and microphysical processes in clouds and fogs are concerned.  相似文献   
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By conducting a historical review of this large seismic event in the Mediterranean, it has been possible to identify both the epicentral area and the area in which its effects were principally felt. Ever since the nineteenth century, the seismological tradition has offered a variety of partial interpretations of the earthquake, depending on whether the main sources used were Arabic, Greek or Latin texts. Our systematic research has involved the analysis not only of Arab, Byzantine and Italian chronicle sources, but also and in particular of a large number of never previously used official and public authority documents, preserved in Venice in the State Archive, in the Marciana National Library and in the Library of the Museo Civico Correr. As a result, it has been possible to establish not only chronological parameters for the earthquake (they were previously uncertain) but also its overall effects (epicentral area in Crete, Imax XI MCS). Sources containing information in 41 affected localities and areas were identified. The earthquake also gave rise to a large tsunami, which scholars have seen as having certain interesting elements in common with that of 21 July 365, whose epicentre was also in Crete. As regards methodology, this research made it clear that knowledge of large historical earthquakes in the Mediterranean is dependent upon developing specialised research and going beyond the territorial limits of current national catalogues.  相似文献   
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The thermal dehydration process of fibroferrite, FeOH(SO4)·5H2O, a secondary iron-bearing hydrous sulfate, was investigated by in situ high-temperature synchrotron X-ray powder diffraction (HT-XRPD), in situ high-temperature Fourier transform infrared spectroscopy (HT-FTIR) and thermal analysis (TGA-DTA) combined with evolved gas mass spectrometry. The data analysis allowed the determination of the stability fields and the reaction paths for this mineral as well as characterization of its high-temperature products. Five main endothermic peaks are observed in the DTA curve collected from room T up to 800 °C. Mass spectrometry of gases evolved during thermogravimetric analysis confirms that the first four mass loss steps are due to water emission, while the fifth is due to a dehydroxylation process; the final step is due to the decomposition of the remaining sulfate ion. The temperature behavior of the different phases occurring during the heating process was analyzed, and the induced structural changes are discussed. In particular, the crystal structure of a new phase, FeOH(SO4)·4H2O, appearing at about 80 °C due to release of one interstitial H2O molecule, was solved by ab initio real-space and reciprocal-space methods. This study contributes to further understanding of the dehydration mechanism and thermal stability of secondary sulfate minerals.  相似文献   
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In the present work, crystal chemical variations between 1M and 2M 1 phlogopites coexisting in the same rock sample from kamafugite of Kasenyi (southwest Uganda, west branch of the East African Rift) were explored by electron probe microanalyses, single crystal X-ray diffraction and M?ssbauer spectroscopy. Chemical analyses revealed close similarity both within and between the two polytypic arrangements as well as high TiO2 (~4.9?wt%) and Al2O3 (~12.9?wt%), and low Cr2O3 (~0.8?wt%), F (~0.3?wt%) and BaO (~0.2?wt%) contents. Room temperature 57Fe M?ssbauer investigation proved that the studied mica is a tetraferriphlogopite with: IVFe3+?=?19(1)?%, VIFe2+?=?58(1)?%, VIFe3+?=?23(1)?%. Single crystal refinement showed that both polytypes have narrow range of variation in terms of some relevant unit cell parameters and similar values in terms of mean bond lengths, mean atomic numbers and distortion parameters. Similar substitutions were active in the structure of the 1M and 2M 1 studied phlogopites. However, in 2M 1 polytypes the oxy-type substitutions were found to occur to a greater extent. Comparison of unit layer of 1M mica (in the 2M 1 setting) with that of the 2M 1 ones showed that the 2M 1 polytypes are affected to different extent by relative shifts of the upper and lower triads of octahedral oxygens along the ±b directions. This effect did not cause any symmetry lowering in the T-O-T layer of the studied samples.  相似文献   
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