EXCESS POSSIBILITIES? ETHICS,POPULISM AND COMMUNITY ECONOMY     

Filomeno V. Aguilar Jr. 《Singapore journal of tropical geography》2005,26(1):27-31

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Karst database development in Minnesota: design and data assembly   总被引：1，自引：0，他引：1  

Y. Gao  E. C. Alexander Jr  R. G. Tipping 《Environmental Geology》2005,47(8):1072-1082

The Karst Feature Database (KFD) of Minnesota is a relational GIS-based Database Management System (DBMS). Previous karst feature datasets used inconsistent attributes to describe karst features in different areas of Minnesota. Existing metadata were modified and standardized to represent a comprehensive metadata for all the karst features in Minnesota. Microsoft Access 2000 and ArcView 3.2 were used to develop this working database. Existing county and sub-county karst feature datasets have been assembled into the KFD, which is capable of visualizing and analyzing the entire data set. By November 17 2002, 11,682 karst features were stored in the KFD of Minnesota. Data tables are stored in a Microsoft Access 2000 DBMS and linked to corresponding ArcView applications. The current KFD of Minnesota has been moved from a Windows NT server to a Windows 2000 Citrix server accessible to researchers and planners through networked interfaces.  相似文献   

Tetrahedral Plots of the Phase Relations for Basalts     

Sven Maal?e  Richard N. Abbott Jr. 《Mathematical Geology》2005,37(8):869-893

The phase relations of quaternary systems are generally represented by projections onto ternary compositional planes. Such projections often obscure relationships that would only be evident in a three-dimensional tetrahedral plot. The tetrahedral plot requires that compositions of the minerals and melts be transformed into Cartesian coordinates. It is shown here how this transformation is carried out. The application is demonstrated by tetrahedral plots of experimental melt compositions of partially molten lherzolite. Furthermore, the plot can be used to evaluate whether or not a particular basaltic composition represents a primary melt. The methods are applicable to any four-component system.  相似文献   

The effects of solution chemistry on the sticking efficiencies of viable Enterococcus faecalis: An atomic force microscopy and modeling study     

Tracy L. Cail  Michael F. Hochella Jr. 《Geochimica et cosmochimica acta》2005,69(12):2959-2969

Atomic force microscopy (AFM) and Derjaguin-Landau-Verwey-Overbeek (DLVO) theory in combination with the interaction force boundary layer (IFBL) model have been used to empirically and theoretically calculate sticking efficiencies (α) of Enterococcus faecalis cells against a silica glass surface. Sticking efficiencies were calculated in solutions of varying pH and ionic strength and related to maximum distances of transport through a hypothetical soil block using colloid filtration theory.AFM measurements show that the repulsive and attractive forces between E. faecalis cells and a glass surface are a function of ionic strength but are less sensitive to changes in solution pH. Zeta (ζ)-potential measurements of the cells and glass surfaces correlate with these trends. Calculated DLVO energy profiles predict much greater sensitivity to changing solution chemistry. Sticking efficiencies derived from AFM measurements range from 9.6 × 10⁻¹⁷ to 1 in solutions of low ionic strength (IS) and from 2.6 × 10⁻³³ to 1 at higher IS. Corresponding α values determined from DLVO theory are essentially zero in all tested solutions.Sticking efficiencies calculated in this study are smaller than values determined from column and field studies in similar systems; however, α derived from AFM data and the IFBL model more closely represent field data than do values calculated from DLVO energy values. A comparison with different methods of calculating α suggests that reversible adhesion may be significant in column-scale transport studies.  相似文献   

Uranyl adsorption onto montmorillonite: Evaluation of binding sites and carbonate complexation   总被引：2，自引：0，他引：2  

Jeffrey G. Catalano  Gordon E. Brown Jr. 《Geochimica et cosmochimica acta》2005,69(12):2995-3005

The fate and transport of uranium in contaminated soils and sediments may be affected by adsorption onto the surface of minerals such as montmorillonite. Extended X-ray absorption fine structure (EXAFS) spectroscopy has been used to investigate the adsorption of uranyl (UO₂²⁺) onto Wyoming montmorillonite. At low pH (∼4) and low ionic strength (10⁻³ M), uranyl has an EXAFS spectrum indistinguishable from the aqueous uranyl cation, indicating binding via cation exchange. At near-neutral pH (∼7) and high ionic strength (1 M), the equatorial oxygen shell of uranyl is split, indicating inner-sphere binding to edge sites. Linear-combination fitting of the spectra of samples reacted under conditions where both types of binding are possible reveals that cation exchange at low ionic strengths on SWy-2 may be more important than predicted by past surface complexation models of U(VI) adsorption on related montmorillonites. Analysis of the binding site on the edges of montmorillonite suggests that U(VI) sorbs preferentially to [Fe(O,OH)₆] octahedral sites over [Al(O,OH)₆] sites. When bound to edge sites, U(VI) occurs as uranyl-carbonato ternary surface complexes in systems equilibrated with atmospheric CO₂. Polymeric surface complexes were not observed under any of the conditions studied. Current surface complexation models of uranyl sorption on clay minerals may need to be reevaluated to account for the possible increased importance of cation exchange reactions at low ionic strengths, the presence of reactive octahedral iron surface sites, and the formation of uranyl-carbonato ternary surface complexes. Considering the adsorption mechanisms observed in this study, future studies of U(VI) transport in the environment should consider how uranium retardation will be affected by changes in key solution parameters, such as pH, ionic strength, exchangeable cation composition, and the presence or absence of CO₂.  相似文献   

Acidic deposition impacts mediated by sulfur cycling in a coastal plain forest ecosystem     

Mark D. Morgan  Ralph E. Good  Henry G. Spratt Jr. Dr. 《GeoJournal》1988,17(2):183-187

Deposition in the New Jersey Pinelands was very acidic (pH=4.17) and contained high levels of SO₂ ⁻² based on bulk deposition measurementsfrom July 1984–July 1986. Streamwater over the same interval in undisturbed watersheds was less acidic (pH =4.52) and had proportionately less SO₄ ⁻². A preliminary alkalinity budget for undisturbed watersheds suggested that SO₄ ⁻² retention within Pinelands watersheds accounted for a large portion of the total alkalinity generated and thereby lessened the impact of acidic deposition on surface waters. The only process capable of explaining the retention of SO₄ ⁻² was microbial sulfate reduction in the extensive wetlands surrounding Pinelands streams which occurred at high rates.  相似文献   

Soft rock pillars     

J. F. Abel Jr. 《Geotechnical and Geological Engineering》1988,6(3):215-248

Summary Soft rock pillars can be designed by several methods available in the mining literature. All of these methods include the effect of shape, or geometry, on the average strength of specimens and pillars. All of the pillar design methods include some measurement of the strength of specimens of the pillar rock. The most common rock specimen strength property measured is the unconfined compressive strength. However, the average strength of triaxially confined rock specimens is much greater than the unconfined specimen strength, which can be more important to pillar strength. The estimation of the strength of a pillar is complicated by the decrease in rock specimen strength with increase in specimen size.Editor's note: In common with North American engineering practise, the paper uses English units throughout, where feasible conversions are included in the text. Where not, the following factors may be used: 1 inch=25.4 mm; 1 ft=0.3048 m; 1 lbf/in.^–2=6.895 kn/m^–2; 1Tonf.=8.896 kN.  相似文献   

A strontium,neodymium and oxygen isotope study of hydrothermal metamorphism and crustal anatexis in the Trois Seigneurs Massif,Pyrenees, France     

M. J. Bickle  S. M. Wickham  H. J. Chapman  H. P. Taylor Jr. 《Contributions to Mineralogy and Petrology》1988,100(4):399-417

Nd, Sr, and O isotope analyses have been made on metamorphic and igneous rocks and minerals from a 310–340 Ma Hercynian-age metamorphic terrane in the Pyrenees, France. Lower Paleozoic shales and phyllites have ⁸⁷Sr/⁸⁶Sr values of 0.707–0.717 at 310 Ma, but model values at 310 Ma of 0.709–0.736 (based on assumed depositional age of 450 Ma and an initial ⁸⁷Sr/⁸⁶Sr=0.707). On a regional scale, ⁸⁷Sr/⁸⁶Sr was homogenized to about 0.713 to 0.717 in the higher-grade pelitic schists during metamorphism. Much of this ⁸⁷Sr/⁸⁶Sr exchange occurred at very low grades (below the biotite isograd), but significant changes also accompanied the δ ¹⁸O lowering of the phyllites (+13 to +16) during their transformation to andalusite- and sillimanite-grade schists (δ ¹⁸O=+11 to +12); all of these effects are attributed to pervasive interactions with hydrothermal fluids (Wickham and Taylor 1985). The data also show that a syn-metamorphic plutonic complex, dominated by a biotite granite body, was derived by mixing of a relatively mafic magmatic end-member (⁸⁷Sr/⁸⁶Sr～ 0.7025–0.7050 and δ ¹⁸O～ +7.5 to +8.0) with two metasedimentary sources, both having ⁸⁷Sr/⁸⁶Sr～0.715 and δ ¹⁸O～ +10.0 to +12.0, but with one being more homogeneous than the other. The more homogeneous component and the (mantle-derived?) magmatic end-member dominate at low structural levels within the complex. The less homogeneous end-member that dominates at high levels is clearly derived from the local Paleozoic pelitic schists. A Rb-Sr age of 330±20 Ma was obtained on hornblende from a deep level within the complex, which fixes this age for the regional metamorphism, as well. Although a post-metamorphic granodiorite magma body at Trois Seigneurs also displays heterogeneities in δ ¹⁸O and ⁸⁷Sr/⁸⁶Sr (and thus does not give a clear-cut Rb-Sr isochron), the data are consistent with an emplacement age between 260 and 310 Ma, similar to ages of other late granodiorites in the Pyrenees. ¹⁴³Nd/ ¹⁴⁴Nd is very uniform within the Hercynian crust, both at Trois Seigneurs (? _Nd=?3 to ?7) and elsewhere in the Pyrenees; almost all igneous lithologies have depleted-mantle, mid-Proterozoic model ages, consistent with efficient recycling of crustal material following original crustal accretion in this area at about 1600 Ma or earlier. Rb-Sr mineral ages exhibit a complex cooling history reflecting late Hercynian and Mesozoic thermal events. Our results show that profound homogenization of the ⁸⁷Sr/⁸⁶Sr and ¹⁸O/¹⁶O ratios of large volumes of the crust can occur during regional metamorphism and crustal anatexis, particularly in regions undergoing extensional tectonics. Such processes can significantly modify the isotopic compositions of the protoliths of granitic magmas; this may explain why many peraluminous Hercynian granitoids of Western Europe have anomalously low (⁸⁷Sr/⁸⁶Sr) initial values compared to their probable sedimentary parent rocks.  相似文献   

Estimating the crush zone size under a cutting tool in coal     

R. K. Zipf Jr.  Z. T. Bieniawski 《Geotechnical and Geological Engineering》1988,6(4):279-295

Summary As part of an effort to understand the mechanics of fine fragment formation in coal, which is important in studies of respirable dust due to mining, fracture toughness measurements and the strain energy density (SED) theory were applied to calculate the crush zone size under a cutting tool in coal. This zone is the major source of fine fragments in the 1 to 10 µm size range. The model used in these calculations is a boundary element program containing a failure criterion based on the SED theory. The boundary element program calculates linear elastic stresses at numerous points in the coal material ahead of a cutting bit. These stresses are then input to a subroutine called critical flaw length and orientation (CFLO) which uses the SED theory to determine the CFLO for a small crack at the boundary element stress computation point. The extent of crushing is based on earlier postulates about the role of inherent flaws in a fragmentation process. To form 1 to 10 µm fragments requires firstly a local stress strong enough to activate flaws with a characteristic length less than 1 to 10 µm and secondly, a flaw density sufficient to provide an average spacing between flaws also on the order of 1 to 10 µm. The locus of active 10 µm flaws represents the maximum possible extent of fine fragmentation in the 10 µm or less size range assuming that a sufficient inherent flaw density exists. The approach offers a first order approximation to the extent of crushing under a tool tip. The size and shape of the crush zone volume is affected by the attack angle and geometry of the tool.  相似文献   

The macungie Sinkhole,Lehigh valley Pennsylvania: Cause and repair   总被引：1，自引：0，他引：1  

Percy H. Dougherty  Michael Perlow Jr. 《Environmental Geology》1988,12(2):89-98

A dramatic sinkhole collapse measuring some 100 feet in diameter by 41 feet deep occurred suddenly in the Borough of Macungie on June 23, 1986. The sinkhole collapse resulted in a major disruption of traffic, utility services, as well as a major health and safety hazard. Continual growth of the sinkhole could have resulted in almost certain damage or loss to more than 17 residences adjacent to the sinkhole collapse. Stabilization and repair costs totaled some $450,000 and required almost three months to restore utility services, roadway, and parking areas.  相似文献