Pb isotopic constraints on the formation of the Dikulushi Cu–Pb–Zn–Ag mineralisation, Kundelungu Plateau (Democratic Republic of Congo)     

Maarten Haest  Jens Schneider  Christophe Cloquet  Kris Latruwe  Frank Vanhaecke  Philippe Muchez 《Mineralium Deposita》2010,45(4):393-410

Base metal–Ag mineralisation at Dikulushi and in other deposits on the Kundelungu Plateau (Democratic Republic of Congo) developed during two episodes. Subeconomic Cu–Pb–Zn–Fe polysulphide ores were generated during the Lufilian Orogeny (c. 520 Ma ago) in a set of E–W- and NE–SW-oriented faults. Their lead has a relatively unradiogenic and internally inhomogeneous isotopic composition (²⁰⁶Pb/²⁰⁴Pb = 18.07–18.49), most likely generated by mixing of Pb from isotopically heterogeneous clastic sources. These sulphides were remobilised and enriched after the Lufilian Orogeny, along reactivated and newly formed NE–SW-oriented faults into a chalcocite-dominated Cu–Ag mineralisation of high economic interest. The chalcocite samples contain only trace amounts of lead and show mostly radiogenic Pb isotope signatures that fall along a linear trend in the ²⁰⁷Pb/²⁰⁴Pb vs. ²⁰⁶Pb/²⁰⁴Pb diagram (²⁰⁶Pb/²⁰⁴Pb = 18.66–23.65; ²⁰⁷Pb/²⁰⁴Pb = 15.72–16.02). These anomalous characteristics reflect a two-stage evolution involving admixture of both radiogenic lead and uranium during a young fluid event possibly c. 100 Ma ago. The Pb isotope systematics of local host rocks to mineralisation also indicate some comparable young disturbance of their U–Th–Pb systems, related to the same event. They could have provided Pb with sufficiently radiogenic compositions that was added to less radiogenic Pb remobilised from precursor Cu–Pb–Zn–Fe polysulphides, whereas the U most likely originated from external sources. Local metal sources are also suggested by the ²⁰⁸Pb/²⁰⁴Pb–²⁰⁶Pb/²⁰⁴Pb systematics of combined ore and rock lead, which indicate a pronounced and diversified lithological control of the immediate host rocks on the chalcocite-dominated Cu–Ag ores. The Pb isotope systematics of polysulphide mineralisation on the Kundelungu Plateau clearly record a diachronous evolution.  相似文献   

Oxygen isotope fractionation between apatite-bound carbonate and water determined from controlled experiments with synthetic apatites precipitated at 10-37 °C     

Christophe Lécuyer  Vincent Balter  François Fourel  Romain Amiot  Olga Otero  Gérard Panczer  Rossana Martini 《Geochimica et cosmochimica acta》2010,74(7):2072-584

The oxygen isotope fractionation between the structural carbonate of inorganically precipitated hydroxyapatite (HAP) and water was determined in the range 10-37 °C. Values of 1000 ln α() are linearly correlated with inverse temperature (K) according to the following equation: 1000 ln α() = 25.19 (±0.53)·T⁻¹ − 56.47 (±1.81) (R² = 0.998). This fractionation equation has a slightly steeper slope than those already established between calcite and water ( [O’Neil et al., 1969] and [Kim and O’Neil, 1997]) even though measured fractionations are of comparable amplitude in the temperature range of these experimental studies. It is consequently observed that the oxygen isotope fractionation between apatite carbonate and phosphate increases from about 7.5‰ up to 9.1‰ with decreasing temperature from 37 °C to 10 °C. A compilation of δ¹⁸O values of both phosphate and carbonate from modern mammal teeth and bones confirms that both variables are linearly correlated, despite a significant scattering up to 3.5‰, with a slope close to 1 and an intercept corresponding to a 1000 ln α() value of 8.1‰. This apparent fractionation factor is slightly higher or close to the fractionation factor expected to be in the range 7-8‰ at the body temperature of mammals.  相似文献   

Springtime changes in snow chemistry lead to new insights into mercury methylation in the Arctic     

Catherine Larose  Aurélien Dommergue  Martine De Angelis  Bernard Averty  Nicolas Soumis  Christophe Ferrari 《Geochimica et cosmochimica acta》2010,74(22):6263-6275

Seasonal snow is an active media and an important climate factor that governs nutrient transfer in Arctic ecosystems. Since the snow stores and transforms nutrients and contaminants, it is of crucial importance to gain a better understanding of the dynamics of contaminant cycling within the snowpack and its subsequent release to catchments via meltwater. Over the course of a two-month field study in the spring of 2008, we collected snow and meltwater samples from a seasonal snowpack in Ny-Ålesund, Norway (78°56′N, 11°52′E), which were analyzed for major inorganic ions and some organic acids, as well as total, dissolved, bioavailable mercury (THg, DHg, BioHg, respectively) and monomethylmercury (MMHg) species. We observe a seasonal gradient for ion concentrations, with surface samples becoming less concentrated as the season progressed. A significant negative correlation between BioHg and MMHg was observed in the snowpack. MMHg was positively and significantly correlated to methanesulfonate concentrations. Based on these results, we propose a new model for aerobic methylation of mercury involving species in the dimethylsulfoniopropionate cycle.  相似文献   

Experimentally-controlled carbon and oxygen isotope exchange between bioapatites and water under inorganic and microbially-mediated conditions     

Antoine Zazzo  Christophe Lécuyer  André Mariotti 《Geochimica et cosmochimica acta》2004,68(1):1-12

Modern bone and enamel powders have reacted at 301 K with ¹³C- and ¹⁸O-labelled waters under inorganic and microbial conditions. The aim of the study is to investigate the resistance of stable isotope compositions of bioapatite carbonate (δ¹³C, δ¹⁸Oc) and phosphate (δ¹⁸Op) to isotopic alteration during early diagenesis. Rapid and significant carbon and oxygen isotope changes were observed in the carbonate and phosphate fractions of bone apatite before any detectable change occurred in the crystallinity or organic matter content. These observations indicate that chemical alterations of bone apatite are likely to start within days of death. Enamel crystallites are much more resistant than bone crystallites, but are not exempt of alteration. Non removable carbon and oxygen isotope enrichments were measured in the carbonate phase of bone (50-90%) and enamel (40%) after the acetic acid treatment. This result indicates that a significant part of ¹³C and ¹⁸O-labelled coming from the aqueous fluid has been durably incorporated into the apatite structure, probably through isotopic exchange or secondary carbonate apatite precipitation. As a result, acetic acid pre-treatments that are currently used to remove exogenous material by selective dissolution, are not adequate to restore pristine δ¹³C and δ¹⁸Oc values of fossil apatites. Under inorganic conditions, kinetics of oxygen isotope exchange are 10 times faster in carbonate than in phosphate. On the opposite, during biologically-mediated reactions, the kinetics of oxygen isotope exchange between phosphate and water is, at least, from 2 to 15 times faster than between carbonate and water. Enamel is a more suitable material than bone for paleoenvironmental or paleoclimatical reconstructions, but interpretations of δ¹⁸Op or δ¹³C values must be restricted to specimens for which no or very limited trace of microbial activity can be detected.  相似文献   

Persistent organic pollutants (POPs) in killer whales (Orcinus orca) from the Crozet Archipelago, southern Indian Ocean     

Marie Noël  Lance Barrett-Lennard  Christophe Guinet  Neil Dangerfield  Peter S. Ross   《Marine environmental research》2009,68(4):196-202

Persistent organic pollutants (POPs), including polychlorinated biphenyls (PCBs), polychlorinated dibenzo-p-dioxins (PCDDs), and dibenzofurans (PCDFs), are ubiquitous environmental contaminants of which significant concentrations are reported in upper trophic level animals. In 1998, we collected blubber biopsy samples (n = 11) from killer whales (Orcinus orca) inhabiting the coastal waters around Possession Island, Crozet Archipelago, southern Indian Ocean, for contaminant analyses. Despite inhabiting an isolated region far removed from industrial activities, these killer whales can presently be considered among the most PCB-contaminated cetaceans in the southern hemisphere, with concentrations ranging from 4.4 to 20.5 mg/kg lipid weight (lw). PCDD levels ranged from below the detection limit (5 ng/kg) to 77.1 ng/kg lw and PCDF levels from below the detection limit (7 ng/kg) to 36.1 ng/kg lw. Over 70% of our study animals had PCB concentrations which exceeded a 1.3 mg/kg PCB threshold established for endocrine disruption and immunotoxicity in free-ranging harbour seals, suggesting that organic contaminants cannot be ruled out as an additional threat to this declining population.  相似文献   

Invigorating hydrological research through journal publications   总被引：1，自引：1，他引：0  

Nevil Quinn  Günter Blöschl  András Bárdossy  Attilio Castellarin  Martyn Clark  Christophe Cudennec 《水文科学杂志》2018,63(8):1113-1117

Editors of several journals in the field of hydrology met during the General Assembly of the European Geosciences Union—EGU in Vienna in April 2017. This event was a follow-up of similar meetings held in 2013 and 2015. These meetings enable the group of editors to review the current status of the journals and the publication process, and to share thoughts on future strategies. Journals were represented at the 2017 meeting by their editors, as shown in the list of authors. The main points on invigorating hydrological research through journal publications are communicated in this joint editorial published in the above journals.  相似文献   

Exploration tree approach to estimate historical earthquakes Mw and depth,test cases from the French past seismicity     

Paola Traversa  David Baumont  Kévin Manchuel  Emmanuelle Nayman  Christophe Durouchoux 《Bulletin of Earthquake Engineering》2018,16(6):2169-2193

The estimation of the seismological parameters of historical earthquakes is a key step when performing seismic hazard assessment in moderate seismicity regions as France. We propose an original method to assess magnitude and depth of historical earthquakes using intensity data points. A flowchart based on an exploration tree (ET) approach allows to apply a consistent methodology to all the different configurations of the earthquake macroseismic field and to explore the inherent uncertainties. The method is applied to French test case historical earthquakes, using the SisFrance (BRGM, IRSN, EDF) macroseismic database and the intensity prediction equations (IPEs) calibrated in the companion paper (Baumont et al. Bull Earthq Eng, 2017). A weighted least square scheme allowing for the joint inversion of magnitude and depth is applied to earthquakes that exhibit a decay of intensity with distance. Two cases are distinguished: (1) a “Complete ET” is applied to earthquakes located within the metropolitan territory, while (2) a “Simplified ET” is applied to both, offshore and cross border events, lacking information at short distances but disposing of reliable data at large ones. Finally, a priori-depth-based magnitude computation is applied to ancient or poorly documented events, only described by single/sporadic intensity data or few macroseismic testimonies. Specific processing of “felt” testimonies allows exploiting this complementary information for poorly described earthquakes. Uncertainties associated to magnitude and depth estimates result from both, full propagation of uncertainties related to the original macroseismic information and the epistemic uncertainty related to the IPEs selection procedure.  相似文献   

Effects of porosity and composition on seismic wave velocities and elastic moduli of lower cretaceous rocks,central Lebanon     

Mohamed K. Salah  Mohammad Alqudah  Ahmad K. Abd El-Aal  Christophe Barnes 《Acta Geophysica》2018,66(5):867-894

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Soil erosion assessment using RUSLE model in the Congo Nile Ridge region of Rwanda     

Enan M. Nyesheja  Attia M. El-Tantawi  Fidele Karamage  Christophe Mupenzi  Jean Baptiste Nsengiyumva 《自然地理学》2019,40(4):339-360

This research assessed the soil erosion threat in the Congo Nile Ridge Region of Rwanda. The study forecasted erosion by applying the Revised Universal Soil Erosion (RUSLE) with five factors (rainfall, soil, topography, cover management, and support practices) and spatial data. About 85.5% of the area under investigation was predisposed to erosion with unsustainable average soil loss rates of > 1 t/ha/yr. The outcomes of the research highlighted that the average rate of estimated soil loss in the region prone to erosion was > 63.62 t/ha/yr, resulting in an overall annual predicted soil loss of approximately 44 × 10⁶ t in 2016. All of the districts studied have steep slope gradients (30.4%–36.1%) and high annual rainfall totals (1199–1484 mm/yr), except Rubavu district. More than 88.8% of croplands had unsustainable average soil loss rates of > 1 t/ha/yr. The analysis indicated that both terracing and strip cropping have the potential to reduce rates of soil loss in the farmland, by 64.4% and 10.4%, respectively. The results of this study will serve as a baseline for soil erosion mitigation and land-use planning in the study area and Rwanda at large.  相似文献   

Scientific detector workshop 2022 on-sky performance verification of near-infrared e−APD technology for wavefront sensing and demonstration of e−APD pixel performance to improve the sensitivity of large science focal planes     

Gert Finger  Frank Eisenhauer  Reinhard Genzel  Christopher Mandla  Ian Baker  Domingo Alvarez  Antonio Amorim  Wolfgang Brandner  Christophe Dupuy  Casey Deen  Derek Ives  Leander Mehrgan  Manfred Meyer  Karin Perraut  Guy Perrin  Jörg Stegmeier  Christian Straubmeier  Harald J. Weller  Vincent Isgar 《Astronomische Nachrichten》2023,344(8-9):e20230069

Near-infrared adaptive optics as well as fringe tracking for coherent beam combination in optical interferometry require the development of high-speed sensors. Because of the high speed, a large analog bandwidth is required. The short exposure times result in small signal levels which require noiseless detection. Both requirements cannot be met by state-of-the-art conventional CMOS technology of near-infrared arrays as has been attempted previously. A total of five near-infrared SAPHIRA 320 × 256 pixel HgCdTe e⁻APD arrays have been deployed in the wavefront sensors and in the fringe tracker of the VLTI instrument GRAVITY. The current limiting magnitude for coherent exposures with GRAVITY is m_k = 19, which is made possible with ADP technology. New avalanche photo-diode array (APD) developments since GRAVITY include the extension of the spectral sensitivity to the wavelength range from 0.8 to 2.5 μm. After GRAVITY a larger format array with 512 × 512 pixels has been developed for both AO applications at the ELT and for long integration times. Since dark currents of <10⁻³ e⁻/s have been demonstrated with 1Kx1K e⁻APD arrays and 2Kx2K e⁻APD arrays have already been developed, the possibilities and adaptations of e⁻APD technology to provide noiseless large-format science-grade arrays for long integration times are also discussed.  相似文献