Comparative Study of Nucleation by Different Alcoholic Solutions of Benzoin, and Benzoin Dust     

Sahana Paul  A. Hazra  U. K. De  S. Bhar  K. Goswami 《Journal of Atmospheric Chemistry》2006,53(2):155-168

Nucleation properties of different alcoholic solutions of Benzoin and Benzoin dust have been studied by varying the seeding temperature in a laboratory Cold Chamber. In the present study, three different alcoholic solutions are being used and these are due to the standard Ethyl alcohol, one higher alcohol i.e. Isopropyle alcohol and one lower alcohol i.e. Methyl alcohol. In addition, Benzil dust and droplets of Acetone and Chloroform have been used to examine if these agents have any ice nucleation ability. It has been observed that all alcoholic solutions of Benzoin have sufficient ice nucleation ability at the negative side of 0^°C, with the maximum concentration occurring at −14.4^°C. In case of Benzoin dust, the nucleation ability is better on the positive side of 0^°C than the negative side. On the other hand, Benzil dust has insignificant nucleation ability and the droplets of two other agents have no nucleation ability at all.Considering the chemical as well as crystalline structure, one can conclude that the presence of OH group in the seeding molecule plays the central role in ice nucleation/hydrate crystal formation. In fact, a number of supplementary experiments like crystal growth in an incubator, XRD analysis and NMR study are performed to identify the nature of crystals formed by Benzoin dust above 0^°C. One can conclude that these are hydrate crystals of Benzoin with water caging around Benzoin crystals.  相似文献   

Assessing soil erosion rates in cultivated areas of Navarre (Spain)     

L. M. De Santisteban  J. Casalí  J. J. Lpez 《地球表面变化过程与地形》2006,31(4):487-506

Although there is much evidence of intense soil erosion in cultivated areas of Navarre (Spain), information on it is currently scarce. Rill and ephemeral gully volumes can be used as a guide to minimum erosion rates. With the main purpose of determining the annual soil loss rates in cultivated areas of central Navarre, a detailed assessment of rainfall and of rill and gully erosion was made in 19 small catchments from October 1999 to September 2001. Seventeen of them were randomly selected, and were cultivated with winter cereals, vineyards or sunflowers. The other two catchments were selected to represent partially uncultivated lands abandoned for ten years. Channel cross‐sections were measured by using a 1‐m‐wide micro‐topographic profile meter, describing 632 cross‐sections and processing information from 31 600 pins. Erosive events happened every year in the three study areas. For cereal catchments, soil losses occurred in only one or two rainfall events each year, usually at the end of autumn and in some summers, with high erosion rates (0·20–11·50 kg m^?2 a^?1). In vineyards, soil losses occurred several times per year, and in any season. This is attributed to the small percentage of surface covered by the crop throughout the year. Again, high erosion rates were found (0·33–16·19 kg m^?2 a^?1), with ephemeral gully erosion causing more loss than rill erosion. No‐till is proposed as an effective conservation measure. From this large data set, it can be stated that rill erosion and ephemeral gully erosion are widespread in Mediterranean regions, and that much more attention should be paid to the problem. Abandoned fields showed very high erosion rates (16·19 kg m^?2 a^?1 on average), suggesting that the abandonment of marginal lands without implementing any erosion control can lead to severe erosion rates. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

A cellular model of river meandering     

Tom. J. Coulthard  Marco. J. Van De Wiel 《地球表面变化过程与地形》2006,31(1):123-132

River meandering has been successfully modelled using vector based methods, but these can not simulate multiple or braided channels. Conversely, cellular braided river models fail to replicate meandering. This paper describes a new method to simulate river meandering within a cellular model (CAESAR). A novel technique for determining bend radius of curvature on a cell by cell basis is described, that importantly allows regional information on bend curvature to be transferred to local points. This local curvature is then used to drive meandering and lateral erosion through two methods. Key difficulties are identified, including the deposition of material on point bars and cut off development, but the method illustrates how meandering can be integrated within a cellular framework. This demonstrates the potential to produce a single model that can incorporate both meandering and braiding. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

Geochemistry of the Submarine Gaseous Emissions of Panarea (Aeolian Islands, Southern Italy): Magmatic vs. Hydrothermal Origin and Implications for Volcanic Surveillance     

Giovanni Chiodini  Stefano Caliro  Giorgio Caramanna  Domenico Granieri  Carmine Minopoli  Roberto Moretti  Lavinia Perotta  Guido Ventura 《Pure and Applied Geophysics》2006,163(4):759-780

The marine sector surrounding Panarea Island (Aeolian Islands, South Italy) is affected by widespread submarine emissions of CO₂ -rich gases and thermal water discharges which have been known since the Roman Age. On November 3^rd, 2002 an anomalous degassing event affected the area, probably in response to a submarine explosion. The concentrations of minor reactive gases (CO, CH₄ and H₂) of samples collected in November and December, 2002 show drastic compositional changes when compared to previous samples collected from the same area in the 1980s. In particular the samples collected after the November 3^rd phenomenon display relative increases in H₂ and CO and a strong decrease in the CH₄ contents, while other gas species show no significant change. The interaction of the original gas with seawater explains the variable contents of CO₂, H₂S, N₂, Ar and He which characterize the different samples, but cannot explain the large variations of CO, CH₄ and H₂ which are instead compatible with changes in the redox, temperature and pressure conditions of the system. Two models, both implying an increasing input of magmatic fluids are compatible with the observed variations of minor reactive species. In the first one, the input of magmatic fluids drives the hydrothermal system towards atypical (more oxidizing) redox conditions, slowly pressurizing the system up to a critical state. In the second one, the hydrothermal system is flashed by the rising high-T volcanic fluid, suddenly released by a magmatic body at depth. The two models have different implications for volcanic surveillance and risk assessment: In the first case, the November 3^rd event may represent both the culmination of a relatively slow process which caused the overpressurization of the hydrothermal system and the beginning of a new phase of quiescence. The possible evolution of the second model is unforeseeable because it is mainly related to the thermal, baric and compositional state of the deep magmatic system that is poorly known.  相似文献   

1997年9月26日意大利中部Umbria-marche地震前的水文地质变化     

Monica Carro  Lucia Luzi  曹玲玲 《国际地震动态》2006,(7):71-85

分析了1997年9月26日意大利中部Umbria与marche交界地区的Umbria-marche地震序列引起的水文体系的变化。为了量化水文体系的变化,从地方当局和矿泉水公司收集了地下水位、泉水的流量以及河水流速等的资料,这些资料可以确定异常的影响面积,并且可以通过与从震前几年资料估算出的年平均体系的对比来量化异常的变化,试图对异常进行判定。分析结果表明,两个含水单元,即Umbria-marche山峰和Val-nerina单元,具有紧密的联系,它们都由于水文系统的改变而受到影响。地震前几个月两条河流测量站记录到了异常变化,认为是地震前兆异常。  相似文献   

Author Index     

Henk De Bruin 《Boundary-Layer Meteorology》2002,104(3):507-507

Authors Index

Author Index  相似文献   

Displaced-Beam Small Aperture Scintillometer Test. Part Ii: Cases-99 Stable Boundary-Layer Experiment   总被引：3，自引：3，他引：0  

O. K. Hartogensis  H. A. R. De Bruin  B. J. H. Van De Wiel 《Boundary-Layer Meteorology》2002,105(1):149-176

The performance of the Scintec displaced-beam small aperture scintillometer (DBSAS) in the stable boundary layer (SBL) is investigated using data gathered during the CASES-99 experiment in Kansas, U.S.A. The DBSAS is superior to the eddy-covariance method in determining vertical fluxes of sensible heat and momentumclose to the ground and/or over short (< 1 min) averaging intervals. Both aspects are of importance in the shallow and non-stationary SBL.The friction velocity, u_*, the temperature scale, _*, and from these the sensible heat flux, H, were calculated from the indirectly determined dissipation rate, , and the structure parameter of temperature, C_T ², by the DBSAS, which was operated over a path length of 112 m. All these variables are compared with eddy-covariance data for 10-minute time averages. Previously reported systematic errors in the DBSAS, overestimation of u_* for low u_* values and underestimation of u_* for high u_* values, have in part been dealt with by adjusting the beam displacement distance from 2.7 mm to 2.6 mm in the calculations. The latter adjustment is presented as a working hypothesis, not a general solution.  相似文献   

The Impact of Vegetation Cover on Sahelian Drought Persistence     

Koen De Ridder 《Boundary-Layer Meteorology》1998,88(2):307-321

The sensitivity of the potential for convective precipitation to land surface characteristics in the West African Sudano-Sahelian zone is studied. Simulations are performed with a one-dimensional version of a mesoscale atmospheric model coupled to a detailed land surface model to investigate the influence of the land surface on rain infiltration, surface evapotranspiration, and their impact on the convective available potential energy. The simulations show that the presence of a densely vegetated surface acts as a catalyst in the hydrological cycle, creating a positive feedback and enhancing precipitation recycling. It is argued that this is due to the relation between the characteristic drying-out time of the soil and the return frequency of the rain-triggering African easterly waves.  相似文献   

意大利埃特纳火山的三维速度结构与地震活动性   总被引：2，自引：2，他引：0  

Luca  G 《CT理论与应用研究》1998,7(1):43-51

本文的研究工作,得到了埃特纳火山下面的一组新的三维速度模型。作者们用１９８０年以来地方性地震在永久和临时地震台网在４个或更多台记录到的１２４９次地震的Ｐ和Ｓ波,被选来作走时反演。选择了几种判别标志与参数化办法以显示其类似的基本特征。表明在火山的东南象限在浅层,有Ｐ波的高速分怖,它同布格重力高异常有密切关系。在该区存在低的Ｖｐ／Ｖｓ比值;沿着中央火山管道,分布有高速Ｐ波和高的Ｖｐ／Ｖｓ比值;建议该处存在有稠密的侵入的岩浆体,延伸到２０千米左右的深度,该区附近有低速的Ｐ波速度。对震源的重新定位也显示出向外倾斜的易碎区,与中央火山管道延伸出一段Ｐ波高速异常区,位于中央火山口的附近。沿着中央火山口附近,有Ｐ波的低速区,它同次生的火山锥的分布有关,与部份熔融的深部岩浆库有联系。  相似文献   

Relative optical mass functions for air, water vapour, ozone and nitrogen dioxide in atmospheric models presenting different latitudinal and seasonal conditions     

C. Tomasi  V. Vitake  L. V. De Santis 《Meteorology and Atmospheric Physics》1998,65(1-2):11-30

Summary A study of the dependence features of the relative optical mass functions for air, water vapour, ozone and nitrogen dioxide on the apparent solar zenith angle was performed by calculating these optical parameters by means of the well-known computer code LOWTRAN 7 at several values of and for nine atmospheric models characterized by different latitudes and seasons. Moreover, other investigations were performed on the dependence features of (i) the relative optical air mass on the thermal characteristics of the low troposphere, (ii) the relative optical water vapour mass on the vertical distribution characteristics of absolute humidity in the troposphere, and (iii) the relative optical mass function for ozone and nitrogen dioxide on the shape characteristics of the vertical profiles of the two gaseous concentrations and the concentration peak altitudes. The results are compared with the values given by the two simple formulas proposed by Kasten (1966) for air and water vapour and the formulas defined by Young (1969) and Staehelin et al. (1995) for ozone and nitrogen dioxide. From this comparison, a wide set of correction factors were obtained which can be conveniently used in the analysis of multispectral sun-radiometric measurements for calculating, with a very high precision, the values of the four optical mass functions at all the angles in the 0° to 87° range, corresponding to the various latitudinal and seasonal conditions described by the nine atmospheric models.With 9 Figures  相似文献