Physical behavior of the SEEDS iron-fertilized patch by sulphur hexafluoride tracer release     

Daisuke Tsumune  Jun Nishioka  Akifumi Shimamoto  Shigenobu Takeda  Atsushi Tsuda 《Progress in Oceanography》2005,64(2-4):111

The first iron (Fe) – fertilization experiment in the western North Pacific was carried out using SF₆ to trace the Fe-fertilized water mass. A solution in 10,800 liters of seawater of 350 kg of Fe and 0.48 M of SF₆ tracer was released into the mixed layer over a 8 × 10 km area. On the first underway transects through the patch after the Fe release, we observed a significant increase of dissolved Fe (ave. 2.89 nM). The fertilized patch was traced for 14 days by on-board SF₆ analysis. A Lagrangian frame of reference was maintained by the use of a drogued GPS buoy released at the center of the patch. The patch moved westward at a rate of 6.8 km d⁻¹. Mixed layer depth increased from 8.5 to 15 m during the experiment. Horizontal diffusivity was determined by the change of SF₆ concentration in the patch. The horizontal diffusivity increased during the experiment. We evaluate here the fate of Fe in a Fe-fertilized patch using the dilution rate determined from sulphur hexafluoride (SF₆) concentration. Dissolved Fe concentrations subsequently decreased rapidly to 0.15 nM on Day 13. However, the dissolved Fe half-life of 43 h was relatively longer than in previous Fe-enrichment studies, and we observed a larger increase of the centric diatom standing stock and corresponding drawdown of macro-nutrients and carbon dioxide than in the previous studies. The most important reason for the larger response was the phytoplankton species in the western North Pacific. In addition, the smaller diffusivity and shallower mixed layer were effective to sustain the higher dissolved Fe concentration compared to previous experiments. This might be one reason for the larger response of diatoms in SEEDS.  相似文献   

Surface current and vertical thermal structure on the continental slope in Tosa Bay     

Hiroshi Kuroda  Manabu Shimizu  Yuuichi Hirota  Daisuke Ambe  Hideki Akiyama 《Journal of Oceanography》2008,64(1):81-91

In order to specify a vertical thermal structure related to surface current variation on the continental slope in Tosa Bay, Japan, we analyzed monthly regular hydrographic measurements in the years 1991–2004. Subsurface temperature below 200 m on the slope was found to vary synchronously with the vertical displacement of the main thermocline around 200 m. It is shown that the vertical-averaged temperature below 200 m is significantly correlated with an along-isobath/southwestward surface current velocity on the slope. This correlation indicates that when a strong (weak) southwestward surface current is observed, temperature below 200 m decreases (increases) simultaneously, that is, isotherms below the 200 m are displaced upward (downward) together with the main thermocline. Moreover, when the strong southwestward flow is detected, across-isobath isotherms around 200 m slope upward toward the offshore direction. Furthermore, it is suggested that as the Kuroshio axis moves offshore south of the bay, the southwestward flow tends to be weakened by the combined effect of other Kuroshio parameters such as transport and stream width as well as the Kuroshio axis position. As a result, it is inferred that the correlation between the surface current and subsurface temperature can be interpreted in terms of the formation and decay of an anticlockwise circulation interacting with a cold eddy.  相似文献   

Principal fault zone width and permeability of the active Neodani fault, Nobi fault system, Southwest Japan   总被引：2，自引：0，他引：2  

A. Tsutsumi  S. Nishino  K. Mizoguchi  T. Hirose  S. Uehara  K. Sato  W. Tanikawa  T. Shimamoto 《Tectonophysics》2004,379(1-4):93-108

The internal structure and permeability of the Neodani fault, which was last activated at the time of the 1891 Nobi earthquake (M8.0), were examined through field survey and experiments. A new exposure of the fault at a road construction site reveals a highly localized feature of the past fault deformation within a narrow fault core zone. The fault of the area consists of three zone units towards the fault core: (a) protolith rocks; (b) 15 to 30 m of fault breccia, and (c) 200 mm green to black fault gouge. Within the fault breccia zone, cataclastic foliation oblique to the fault has developed in a fine-grained 2-m-wide zone adjacent to the fault. Foliation is defined by subparallel alignment of intact lozenge shaped clasts, or by elongated aggregates of fine-grained chert fragments. The mean angle of 20°, between the foliation and the fault plane suggests that the foliated breccia accommodated a shear strain of γ<5 assuming simple shear for the rotation of the cataclastic foliation. Previous trench surveys have revealed that the fault has undergone at least 70 m of fault displacement within the last 20,000 years in this locality. The observed fault geometry suggests that past fault displacements have been localized into the 200-mm-wide gouge zone. Gas permeability analysis of the gouges gives low values of the order of 10⁻²⁰ m². Water permeability as low as 10⁻²⁰ m² is therefore expected for the fault gouge zone, which is two orders of magnitude lower than the critical permeability suggested for a fault to cause thermal pressurization during a fault slip.  相似文献   

PP-P differential traveltime measurement with crustal correction     

Masayuki Obayashi  Daisuke Suetsugu  Yoshio Fukao 《Geophysical Journal International》2004,157(3):1152-1162

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Stability and P–V–T equation of state of KAlSi3O8-hollandite determined by in situ X-ray observations and implications for dynamics of subducted continental crust material     

Norimasa Nishiyama  Robert Paul Rapp  Tetsuo Irifune  Takeshi Sanehira  Daisuke Yamazaki  Ken-ichi Funakoshi 《Physics and Chemistry of Minerals》2005,32(8-9):627-637

In situ X-ray diffraction measurements of KAlSi₃O₈-hollandite (K-hollandite) were performed at pressures of 15–27 GPa and temperatures of 300–1,800 K using a Kawai-type apparatus. Unit-cell volumes obtained at various pressure and temperature conditions in a series of measurements were fitted to the high-temperature Birch-Murnaghan equation of state and a complete set of thermoelastic parameters was obtained with an assumed K′_300,0=4. The determined parameters are V _300,0=237.6(2) Å³, K _300,0=183(3) GPa, (?K _T,0/?T) _P =?0.033(2) GPa K^?1, a ₀=3.32(5)×10^?5 K^?1, and b ₀=1.09(1)×10^?8 K^?2, where a ₀ and b ₀ are coefficients describing the zero-pressure thermal expansion: α _T,0 = a ₀ + b ₀ T. We observed broadening and splitting of diffraction peaks of K-hollandite at pressures of 20–23 GPa and temperatures of 300–1,000 K. We attribute this to the phase transitions from hollandite to hollandite II that is an unquenchable high-pressure phase recently found. We determined the phase boundary to be P (GPa)=16.6 + 0.007 T (K). Using the equation of state parameters of K-hollandite determined in the present study, we calculated a density profile of a hypothetical continental crust (HCC), which consists only of K-hollandite, majorite garnet, and stishovite with 1:1:1 ratio in volume. Density of HCC is higher than the surrounding mantle by about 0.2 g cm^?3 in the mantle transition zone while this relation is reversed below 660-km depth and HCC becomes less dense than the surrounding mantle by about 0.15 g cm^?3 in the uppermost lower mantle. Thus the 660-km seismic discontinuity can be a barrier to prevent the transportation of subducted continental crust materials to the lower mantle and the subducted continental crust may reside at the bottom of the mantle transition zone.  相似文献   

Phase boundary between ilmenite and perovskite structures in MnGeO3 determined by in situ X-ray diffraction measurements     

Daisuke Yamazaki  Eiji Ito  Yoshinori Tange  Takashi Yoshino  Shuangmeng Zhai  Hiroshi Fukui  Anton Shatskiy  Tomoo Katsura  Ken-ichi Funakoshi 《Physics and Chemistry of Minerals》2007,34(4):269-273

In situ X-ray observations of the phase transition from ilmenite to perovskite structure in MnGeO₃ were carried out in a Kawai-type high-pressure apparatus interfaced with synchrotron radiation. The phase boundary between the ilmenite and perovskite structures in the temperature range of 700–1,400°C was determined to be P (GPa) = 16.5(±0.6) − 0.0034(±0.0006)T (°C) based on Anderson’s gold pressure scale. The Clapeyron slope, dP/dT, determined in this study is consistent with that for the transition boundary between the ilmenite and the perovskite structure in MgSiO₃.  相似文献   

Experimental study of a low-alkali tholeiite at 1–5 kbar: optimal condition for the crystallization of high-An plagioclase in hydrous arc tholeiite     

Daisuke?Takagi  Hiroaki?SatoEmail author  Mitsuhiro?Nakagawa 《Contributions to Mineralogy and Petrology》2005,149(5):527-540

We conducted melting experiments on a low-alkali tholeiite (SiO₂ ~52 wt%, MgO ~6.5 wt%, CaO/Na₂O~4.4, Al₂O₃/SiO₂ ~0.33) under both H₂O-undersaturated and H₂O-saturated conditions to investigate the effect of H₂O on the Ca–Na partitioning between plagioclase and melt. Experiments were performed in the temperature and pressure ranges of 1,000–1,300°C and 1–5 kbar, respectively, with varying H₂O contents of 0–12wt%. Redox condition was 0–2 log unit above NNO (nickel–nickel oxide) buffer. Temperature-bulk H₂O diagrams for the low-alkali tholeiite are constructed at 1, 2, and 5 kbar, and compositions of near-liquidus plagioclase and coexisting melt are determined. To exclude the effect of melt composition (CaO/Na₂O and Al₂O₃/SiO₂ ratios) on plagioclase composition and to reveal the effect of H₂O on An (=100×Ca/(Ca+Na)) content and (=(Ca/Na)_pl/(Ca/Na)_melt), we focused on the composition of near-liquidus plagioclases which crystallized from melts with nearly constant CaO/Na₂O and Al₂O₃/SiO₂ ratios. Our experimental results show that, at each experimental pressure, An content of the near-liquidus plagioclase and the K_D^Ca-Na almost linearly increases as H₂O content in melt increases. Each of the An content and the variations in a low-alkali tholeiitic system (CaO/Na₂O~4.0–4.5, Al₂O₃/SiO₂ ~0.27–0.33) can be described by one equation using temperature, pressure, and melt H₂O content as parameters. An content and of liquidus plagioclase increases with increasing melt H₂O and with decreasing pressure, elucidating that nearly H₂O-saturated conditions of 2–3 kbar is optimal for the crystallization of the most An-rich plagioclase (>An₈₈). We suggest this pressure condition of 2–3 kbar, corresponding to depth of 7–11 km, plays an important role for the origin of An-rich plagioclase in H₂O-rich low-alkali tholeiite. At pressures more than ca. 4 kbar, crystallization of liquidus Ca-rich clinopyroxene decreases the CaO/Na₂O ratio of liquid, thus prohibiting the crystallization of high-An plagioclase from hydrous tholeiite.  相似文献   

Petrology and geochemistry of LaPaz Icefield 02205: A new unique low-Ti mare-basalt meteorite     

Mahesh Anand  Lawrence A. Taylor  Clive R. Neal  Shiho Tanikawa 《Geochimica et cosmochimica acta》2006,70(1):246-264

LaPaz Icefield 02205 (LAP 02205) is a new low-Ti mare-basalt meteorite that was discovered in the LaPaz Ice Field in Antarctica. This is the first crystalline lunar basalt in the US Antarctic collection and the only 5th unbrecciated mare-basalt meteorite to be discovered to date. The rock has a typical basaltic texture with tabular and elongated pyroxene and plagioclase crystals, and minor olivine grains commonly rimmed by pyroxenes. Core- to rim-zoning in terms of Fe and Mg is present in almost all pyroxene grains. Accessory minerals include ilmenite, chromite, ulvöspinel, troilite, and FeNi metal. This rock is highly enriched in late-stage mesostasis. Free silica is also abundant. In terms of texture and mineralogy, LAP 02205 displays features of low-Ti mare basalts, with similarities to some low-Ti Apollo 12 and Apollo 15 basalts. Whole-rock major- and trace-element compositions confirm the highly fractionated nature of this basalt. The whole-rock REE contents of the meteorite are the highest among all known low-Ti mare basalts. The platinum group element (PGE) contents in LAP are also enriched suggesting the possibility of endogenously enriched source regions or the PGEs generally behaved as incompatible elements during crystal fractionation under low fO₂ conditions. Trace-element contents of mineral grains in LAP 02205 display wide variations, suggesting extensive non-equilibrium crystallization. The REE concentrations in the earliest-formed minerals provide constraints on the composition of the parental liquid, which is similar to the measured whole-rock composition. Crystallization modeling of the LAP 02205 bulk composition yields a reasonable fit between predicted and observed mineral phases and compositions, except for the high-Mg olivine cores, which are observed in the rock but not predicted by the modeling. An isochron age of 2929 ± 150 Ma for phosphate minerals makes this rock one of the youngest lunar basalts known to date. The young age and specific geochemical characteristics of LAP distinguish it from those of most other low-Ti mare basalts. However, the low-Ti mare basalt meteorite, NWA 032, has a similar young age, and the two meteorites also appear to be closely related from some geochemical perspectives and might have originated from similar source regions on the Moon.  相似文献   

Proximal–distal fall deposit correlation of VEI-5 tephra (Towada-Chuseri) from Towada volcano,northeast Japan     

Daisuke Ishimura  Reona Hiramine 《第四纪科学杂志》2020,35(1-2):334-348

A tephra layer offers an isochronous surface in sediments, thus serving as a key bed and/or an age marker. Recent high-resolution sediment research (e.g. varved sediments) has revealed optically invisible tephra fingerprints and provided high-precision tephra ages. However, a tephra-based correlation cannot succeed without detailed knowledge of the tephra characteristics in a proximal area to correlate with tephra in high-resolution sediments in remote areas. Here we documented the detailed characteristics of Towada-Chuseri (To-Cu) tephra, which is associated with the Middle Holocene volcanic explosivity index 5 eruption of Towada volcano, northeast Japan. We used To-Cu tephra samples to achieve the proximal–distal correlation of three members: Chuseri pumice (Cu), Kanegasawa pumice (Kn) and Utarube ash (Ut). These distal occurrences correlate with proximal To-Cu tephra based on volcanic glass morphology and refractive index, as well as on major element composition of volcanic glass shards. Refractive indices allow the preliminary correlation of each member, and major element composition helps in distinguishing Ut from the other members. Glass morphology provides additional support. These correlations reveal that To-Cu, especially Cu, covered central to northeast Japan while confirming that To-Cu is the representative tephra in the Middle Holocene of the Tohoku region.  相似文献   

Decadal variability of Subtropical Mode Water subduction and its impact on biogeochemistry     

Eitarou Oka  Bo Qiu  Yusuke Takatani  Kazutaka Enyo  Daisuke Sasano  Naohiro Kosugi  Masao Ishii  Toshiya Nakano  Toshio Suga 《Journal of Oceanography》2015,71(4):389-400

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