Crystal-chemistry of clinopyroxenes from potassic and ultrapotassic rocks in central Italy: implications on their genesis   总被引：2，自引：0，他引：2  

Daniela Cellai  Sandro Conticelli  Silvio Menchetti 《Contributions to Mineralogy and Petrology》1994,116(3):301-315

The clinopyroxenes mentioned have been investigated by single crystal X-ray diffraction combined with electron microprobe analysis. The aim of this study was to characterize the crystal-chemical variations of clinopyroxenes in order to delineate the intracrystalline constraints which are characteristic of specific magmatic environments. Clinopyroxenes (cpx) crystallized from peralkaline ultrapotassic melt with kamafugitic and lamproitic affinities are characterized by high Si contents, which are insensitive to variations in silica abundance and silica saturation of the melt. The high Si occupancy in clinopyroxenes from kamafugitic magma is coupled to large M1 (i.e. Mg and Fe²⁺) and M2 (high Ca occupancy) sites, whereas in clinopyroxenes from magmas with lamproitic affinity, high Si content is combined with large M1 but small M2 sites. Clinopyroxenes from Romantype alkaline potassic and ultrapostassic rocks are characterized by an expanded tetrahedron (high ^IVA1 content) and small M1 site which is combined with small M2 polyhedron in clinopyroxenes from the potassic rocks and large M2 site in those from the ultrapotassic rocks.  相似文献   

Comparison between Pollutant Concentration in the Samples of Fog and Rime Water Collected at Mt. Milešovka     

Fišák  Jaroslav  Řezáčová  Daniela 《Studia Geophysica et Geodaetica》2001,45(3):319-324

The article aims at showing the differences in concentration of pollutants that are contained in the samples of fog and/or low cloud water in comparison with the water from rime. The results follow from the fog and rime measurements made at Mt. Mileovka (eské Stedohoí Mountains). They are compared with the results of other studies that also report the differences in fog and rime chemistry.  相似文献   

Equilibrium and disequilibrium degassing of a phonolitic melt (Vesuvius AD 79 “white pumice”) simulated by decompression experiments     

Giada Iacono Marziano  Burkhard C. Schmidt  Daniela Dolfi 《Journal of Volcanology and Geothermal Research》2007

Equilibrium and disequilibrium degassing of a volatile phase from a magma of K-phonolitic composition was investigated to assess its behavior upon ascent. Decompression experiments were conducted in Ar-pressurized externally heated pressure vessels at superliquidus temperature (1050 °C), in the pressure range 10–200 MPa using pure water as fluid phase. All experiments were equilibrated at 200 MPa and then decompressed to lower pressures with rates varying from 0.0028 to 4.8 MPa/s. Isobaric saturation experiments were performed at the same temperature and at 900–950 °C to determine the equilibrium water solubility in the pressure range 30–250 MPa. The glasses obtained from decompression experiments were analyzed for their dissolved water content, vesicularity and bubble size distribution. All decompressed samples presented a first event of bubble nucleation at the capsule–melt interface. Homogeneous bubble nucleation in the melt only occurred in fast-decompressed experiments (4.8 and 1.7 MPa/s), for ΔP ≅ 100 MPa. For these decompression rates high water over-saturations were maintained until a rapid exsolution was triggered at ΔP > 150 MPa. For slower rates (0.0028, 0.024, 0.17 MPa/s) the degassing of the melt took place by diffusive growth of the bubbles nucleating at the capsule–melt interface. This process sensibly reduced water over-saturation in the melt, preventing homogeneous nucleation to occur. For decompression rates of 0.024 and 0.17 MPa/s low water over-saturations were attained in the melt, gradually declining toward equilibrium concentrations at low pressures. A near-equilibrium degassing path was observed for a decompression rate of 0.0028 MPa/s. Experimental data combined with natural pumice textures suggest that both homogeneous and heterogeneous bubble nucleations occurred in the phonolitic magma during the AD 79 Vesuvius plinian event. Homogeneous bubble nucleation probably occurred at a depth of ∼ 3 km, in response to a fast decompression of the magma during the ascent.  相似文献   

Geodynamic implications of deep mantle upwelling in the source of Tertiary volcanics from the Veneto region (South-Eastern Alps)     

Patrizia Macera  Daniela Gasperini  Claudia Piromallo  Janne Blichert-Toft  Delphine Bosch  Aldo Del Moro  Silvana Martin 《Journal of Geodynamics》2003,36(5):563

Major and trace element and Sr–Nd–Hf–Pb isotopic data for the most primitive Tertiary lavas from the Veneto region (South-Eastern Alps, Italy) show the typical features of HIMU hotspot volcanism, variably diluted by a depleted asthenospheric mantle component (⁸⁷Sr/⁸⁶Sr_i=0.70306–0.70378; _Ndi=+3.9 to +6.8; _Hfi=+6.4 to +8.1, ²⁰⁶Pb/²⁰⁴Pb_i=18.786–19.574). P-wave seismic tomography of the mantle below the Veneto region shows the presence of low-velocity anomalies at depth, which is consistent with possible upwellings of plume material. Between the depths of 100–250 km the velocity anomalies are approximately 2–2.5% slower than average, implying a temperature excess of about 220–280 K, in agreement with estimates for other mantle plumes in the world. In this context, the Veneto volcanics may represent the shallow expression of a mantle upflow. The presence of a HIMU-DM component in a collision environment has significant geodynamic implications. Slab detachment and ensuing rise of deep mantle material into the lithospheric gap is proposed to be a viable mechanism of hotspot magmatism in a subduction zone setting.  相似文献   

Magnetic data analysis at low latitudes using magnitude transforms   总被引：2，自引：0，他引：2  

Daniela Gerovska  Petar Stavrev 《Geophysical Prospecting》2006,54(1):89-98

Magnitude transforms include magnitude magnetic anomalies (MMA), their gradients and Laplacians. They can be calculated from the total magnetic anomalies or other component anomalies. Magnitude magnetic anomalies have a space distribution different from that of the component anomalies. Their values are non‐negative and their respective patterns are similar to the positive gravity anomalies. Magnitude transforms are an effective tool for magnetic data analysis due to their simplified pattern and direct correlation with the space location of the source. They have advantages over the traditionally used reduction‐to‐the‐pole (RTP) transform, especially at low magnetic latitudes. The calculation of magnitudes of the anomalous field requires the total field data to be transformed into the component anomalies, while the reduction‐to‐the‐pole transform also includes a rotation of the magnetization vector, the orientation of which is usually assumed. For equal latitudes, the transfer functions of component‐component transforms in the frequency domain show better stability than the component‐component‐rotation transfer function. This is illustrated by a comparison of analytical expressions, and synthetic models of magnetic fields. The Dixon seamount case shows the possibilities for an improved data analysis and more confident source recognition at low latitudes using magnetic transforms.  相似文献   

A radar-based verification of precipitation forecast for local convective storms     

Daniela Rezacova  Zbynek Sokol  Petr Pesice 《Atmospheric Research》2007,83(2-4):211-224

Local flash flood storms with a rapid hydrological response are a real challenge for quantitative precipitation forecasting (QPF). It is relevant to assess space domains, to which the QPF approaches are applicable. In this paper an attempt is made to evaluate the forecasting capability of a high-resolution numerical weather prediction (NWP) model by means of area-related QPF verification. The results presented concern two local convective events, which occurred in the Czech Republic (CR) on 13 and 15 July 2002 and caused local flash floods. We used the LM COSMO model (Lokall Model of the COSMO consortium) adapted to the horizontal resolution of 2.8 km over a model domain covering the CR. The 18 h forecast of convective precipitation was verified by using radar rainfall totals adjusted to the measured rain gauge data. The grid point-related root mean square error (RMSE) value was calculated over a square around the grid point under the assumption that rainfall values were randomly distributed within the square. The forecast accuracy was characterized by the mean RMSE over the whole verification domain. We attempt to show a dependence of both the RMSE field and the mean RMSE on the square size. The importance of a suitable merger between the radar and rain gauge datasets is demonstrated by a comparison between the verification results obtained with and without the gauge adjustment. The application of verification procedure demonstrates uncertainties in the precipitation forecasts. The model was integrated with initial conditions shifted by 0.5° distances. The four verifications, corresponding to the shifts in the four directions, show differences in the resulting QPF, which depend on the size of verification area and on the direction of the shift.  相似文献   

Do We Really Need Mantle Components to Define Mantle Composition?   总被引：2，自引：0，他引：2  

Armienti  Pietro; Gasperini  Daniela 《Journal of Petrology》2007,48(4):693-709

We discuss the concept of components in the Earth's mantle startingfrom a petrological and geochemical approach, but adopting anew method of projection of geochemical and isotopic data. Thisallows the compositional variability of magmatic associationsto be evaluated in multi-dimensional space, thus simultaneouslyaccounting for a large number of compositional variables. Wedemonstrate that ocean island basalts (OIB) and mid-ocean ridgebasalts (MORB) are derived from a marble-cake mantle, in whichdifferent degrees of partial melting of recycled lithosphere,which are heterogeneous in age and composition, contribute tothe magma genesis. This view is supported by the variabilityin the geochemical and isotopic signatures of OIB that are observedon the scale of a single ocean island as well as on that ofan ocean, mostly varying between two extreme compositions, thatare not strictly related to the commonly accepted mantle components(DMM, EMI, EMII, HIMU). Rather they are a distinctive featureof the mantle source sampled at each ocean island and are stronglydependent on the Pb isotope system. We recommend a change inperspective in studies of MORB–OIB geochemistry from onebased on physically distinct mantle components to a model basedon the existence of a marble-cake-like upper mantle. Althoughresembling the statistical upper mantle, this model impliesthat geochemical homogenization can be attained only withinthe limits of local mantle composition, so that a world-wideuniform depleted reservoir cannot be sampled by simply extendingthe volume of the region undergoing partial melting. KEY WORDS: geochemistry; isotope; mantle; OIB  相似文献   

Paleolimnological significance of spinose and non-spinose morphs of Pyrgophorus hibbardi (Leonard and Franzen, 1944)     

Barry B. Miller  Michael J.S. Tevesz  Daniela C. Smith 《Journal of Paleolimnology》1998,20(1):99-102

The basal portion of the Ogallala Formation (=Laverne Formation) (Lower Pliocene) Beaver County, Oklahoma, contains an interesting assemblage of non-marine fossil molluscs that include both spinose and non-spinose forms of the aquatic gastropod species Pyrgophorus hibbardi. The origin and paleolimnological significance of the spinose morph has been a source of much conjecture that has influenced environmental reconstructions of this assemblage. In one hypothesis the spinose forms of P. hibbardi are assumed to be associated with brackish water conditions by analogy with some populations of a related hydrobiid Potamopyrgus jenkinsi. To test the hypothesis that the spinose forms lived under different water conditions than the non-spinose morphs, we analyzed 10 specimens each of the two varieties for stable oxygen and carbon isotope ratios in the shell aragonite.The mean isotope ratios for the smooth and spinose morphs show no significant difference (oxygen: t = 0.28, df = 18, P (T t) 0.78 n.s.; carbon: t = 0.96, df = 18, P (T t) 0.35 n.s). We conclude that the lack of a statistically significant difference between the means of the oxygen and carbon isotope values for the smooth and spinose morphs suggests that the two forms lived in waters having similar isotope signatures. The considerable range in oxygen isotope values recorded by both morphs of P. hibbardi, including values as high as 5–6, suggest that both morphs were associated with waters which were periodically evaporatively enriched in ¹⁸O.  相似文献   

Relict sand dredging for beach nourishment in the central Tyrrhenian Sea (Italy): effects on benthic assemblages     

Barbara La Porta  Monica Targusi  Loretta Lattanzi  Paola La Valle  Daniela Paganelli  & Luisa Nicoletti 《Marine Ecology》2009,30(S1):97-104

The aim of this study is to analyse the effects in space and time of relict sand-dredging activities on macrobenthic assemblages, in an area situated offshore Montalto di Castro (central Tyrrhenian Sea, Italy), and to analyse the recolonisation processes of macrobenthos in the dredged areas. The area in question is characterised by relict sand deposits (Holocenic paleo-beaches), used for beach nourishment along the Latium coast. The effects of sand extraction on benthic assemblages were investigated before, during and after three dredging operations. The sites analysed are located within the dredged areas (inside stations) and in neighbouring, not dredged, areas (outside stations). The results showed that the impact of sand extraction was confined to the dredged stations and to the areas in proximity to the dredged areas. During dredging activities, the structure of benthic assemblages within the impacted stations was characterised by low species richness and diversity. Both the direct removal of sediment and the re-suspension and consequent deposition of fine sediment affected benthic assemblages of the impacted stations. A few months after the dredgings, a recolonisation process was still observed at all the impacted stations. A gradual recolonisation process was observed at those stations affected by only one dredging, whereas a different recolonisation was observed at those stations affected by two dredgings over time. This study suggests that differences of re-colonisation processes of benthic assemblages are related to the intensity of dredging operations in terms of dredging frequency.  相似文献   

Use of immunofluorescence technique in cultured fibroblasts from Mediterranean cetaceans as new "in vitro" tool to investigate effects of environmental contaminants     

Marsili L  Casini S  Bucalossi D  Porcelloni S  Maltese S  Fossi MC 《Marine environmental research》2008,66(1):151-153

The aim of the present study was to propose the immunofluorescence technique in cultured fibroblasts from Mediterranean cetaceans as a new "in vitro" tool to explore the susceptibility of these marine mammals to different xenobiotic compounds. The cell lines were cultured from integument biopsies of free-ranging and stranded cetaceans (dead within 12h). Using the indirect immunofluorescence assay, we detected endogenous proteins induced by different contaminants. Here we present the method used for qualitative and quantitative evaluation of cytochromes P450 (CYP1A1 and CYP2B) induced by some POPs (DDTs and PCBs) and emerging contaminants (PBDEs) in fibroblast cell cultures of striped dolphin (Stenella coeruleoalba) and bottlenose dolphin (Tursiops truncatus). Immunofluorescence was quantified with a specially designed Olympus macro, DetectIntZ. A major result was the possibility of using this "in vitro" assay to quantify induction of endogenous proteins.  相似文献