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The characterization of trace elements in terms of their apportionment among dissolved, macromolecular, nano- and micro-particulate phases in the water column of the Great Salt Lake carries implications for the potential entry of toxins into the food web of the lake. Samples from the anoxic deep and oxic shallow brine layers of the lake were fractionated using asymmetric flow field-flow fractionation (AF4). The associated trace elements were measured via online collision cell inductively-coupled plasma mass spectrometry (CC-ICP-MS). Results showed that of the total (dissolved + particulate) trace element mass, the percent associated with particulates varied from negligible (e.g. Sb), to greater than 50% (e.g. Al, Fe, Pb). Elements such as Cu, Zn, Mn, Co, Au, Hg, and U were associated with nanoparticles, as well as being present as dissolved species. Particulate-associated trace elements were predominantly associated with particulates larger than 450 nm in size. Among the smaller nanoparticulates (<450 nm), some trace elements (Ni, Zn, Au and Pb) showed higher percent mass (associated with nanoparticles) in the 0.9–7.5 nm size range relative to the 10–250 nm size range. The apparent nanoparticle size distributions were similar between the two brine layers; whereas, important differences in elemental associations to nanoparticles were discerned between the two layers. Elements such as Zn, Cu, Pb and Mo showed increasing signal intensities from oxic shallow to anoxic deep brine, suggesting the formation of sulfide nanoparticles, although this may also reflect association with dissolved organic matter. Aluminum and Fe showed greatly increased concentration with depth and equivalent size distributions that differed from those of Zn, Cu, Pb and Mo. Other elements (e.g. Mn, Ni, and Co) showed no significant change in signal intensity with depth. Arsenic was associated with <2 nm nanoparticles, and showed no increase in concentration with depth, possibly indicating dissolved arsenite. Mercury was associated with <2 nm nanoparticles, and showed greatly increased concentration with depth, possibly indicating association with dissolved organic matter.  相似文献   
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The deterioration of environmental conditions is the major contributory factor to poor health and quality of life that hinders sustainable development in any region.Coal mining is one of the major industries that contribute to the economy of a country but it also impacts the environment.The chemical parameters of the coal,overburden,soil and sediments along with the coal mine drainage(CMD)were investigated in order to understand the overall environmental impact from high sulphur coal mining at northeastern coalfield(India).It was found that the total sulphur content of the coal is noticeably high compared to the overburden(OB)and soil.The volatile matter of the coal is sufficiently high against the high ash content of the soil and overburden.The water samples have a High Electrical Conductivity(EC)and high Total Dissolve Solid(TDS).Lower values of pH,indicate the dissolution of minerals present in the coal as well as other minerals in the mine rejects/overburden.The chemical and nano-mineralogical composition of coal,soil and overburden samples was studied using a High Resolution-Transmission Electron Microscopy(HR-TEM),Energy Dispersive Spectroscopy(EDS),Selected-Area Diffraction(SAED),Field Emission-Scanning Electron Microscopy(FE-SEM)/EDS,X-ray diffraction(XRD),Fourier Transform Infrared Spectroscopy(FTIR),Raman and Ion-Chromatographic analysis,and Mossbauer spectroscopy.From different geochemical analysis it has been found that the mine water sample from Ledo colliery has the lowest pH value of 3.30,Tirap colliery samples have the highest electrical conductivity value of5.40 ms cm~(-1)Both Ledo and Tirap coals have total sulphur contents within the range 3-3.50%.The coal mine water from Tirap colliery(TW-15 B)has high values of Mg~(2+)(450 ppm),and Br~-(227.17 ppm).XRD analysis revealed the presence of minerals including quartz and hematite in the coals.Mineral analysis of coal mine overburden(OB)indicates the presence both of pyrite and marcasite which was also confirmed in XRD and Mossbauer spectral analysis.The presented data of the minerals and ultra/nano-particles present shows their ability to control the mobility of hazardous elements,suggesting possible use in environmental management technology,including restoration of the delicate Indian coal mine areas.  相似文献   
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Five mafic dike swarms between 30° and 33°45′S were studied for their geochemical signature and kinematics of magma flow directions by means of AMS data. In the Coastal Range of central Chile (33°−33°45′S), Middle Jurassic dike swarms (Concón and Cartagena dike swarms, CMDS and CrMDS, respectively) and an Early Cretaceous dike swarm (El Tabo Dike Swarm, ETDS) display the presence of dikes of geochemically enriched (high-Ti) and depleted (low-Ti) basaltic composition. These dikes show geochemical patterns that are different from the composition of mafic enclaves of the Middle Jurassic Papudo-Quintero Complex, and this suggests that the dikes were injected from reservoirs not related to the plutonic complex. The mantle source appears to be a depleted mantle for Jurassic dikes and a heterogeneous-enriched lithospheric mantle for Cretaceous dikes. In the ETDS, vertical and gently plunging magma flow vectors were estimated for enriched and depleted dikes, respectively, which suggest, together with variations in dike thickness, that reservoirs were located at different depths for each dike family. In the Elqui Dike Swarm (EDS) and Limarí Mafic Dike Swarm (LMDS), geochemical patterns are similar to those of the mafic enclaves of the Middle Jurassic plutons. In the LMDS, east to west magma flow vectors are coherent with injection from neighbouring pluton located to the east. In the EDS, some dikes show geochemical and magma flow patterns supporting the same hypothesis. Accordingly, dikes do not necessarily come from deep reservoir; they may propagate in the upper crust from coeval shallow pluton chamber. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   
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We present 83 new galaxy radial velocities in the field of 18 APM clusters with redshifts between 0.06 and 0.13. The clusters have Abell identifications and the galaxies were selected within 0.75  h −1 Mpc in projection from their centres. We derive new cluster velocity dispersions for 13 clusters using our data and published radial velocities.
We analyse correlations between cluster velocity dispersions and cluster richness counts as defined in Abell and APM catalogues. The correlations show a statistically significant trend although with a large scatter, suggesting that richness is a poor estimator of cluster mass irrespectively of cluster selection criteria and richness definition. We find systematically lower velocity dispersions in the sample of Abell clusters that do not fulfil APM cluster selection criteria, suggesting artificially higher Abell richness counts owing to contamination by projection effects in this subsample.  相似文献   
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High waves at ocean occur during a complex space–time evolution of wave groups. In this paper the nonlinear structure of three-dimensional sea wave groups at intermediate water depth is investigated. To this purpose, the Boccotti's Quasi-Determinism theory is firstly applied to describe the linear wave groups when a given exceptionally high crest occurs. Then, the second-order correction to the linear solution is derived for the general condition of three-dimensional wave groups, at a finite water depth. Several numerical applications, finally, have been carried out in order to show how both the spectral bandwidth and the directional spreading modify the nonlinear high waves at different water depth.  相似文献   
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This paper presents a numerical formulation of a three dimensional embedded beam element for the modeling of piles, which incorporates an explicit interaction surface between soil and pile. The formulation is herein implemented for lateral loading of piles but is able to represent soil–pile interaction phenomena in a general manner for different types of loading conditions or ground movements. The model assumes perfect adherence between beam and soil along the interaction surface. The paper presents a comparison of the results obtained by means of the present formulation and by means of a previously formulated embedded pile element without interaction surface, as well as reference semi‐analytical solutions and a fully 3D finite element (FE) model. It is seen that the proposed embedded element provides a better convergence behavior than a previously formulated embedded element and is able to reproduce key features of a full 3D FE model. Copyright © 2015 John Wiley & Sons, Ltd.  相似文献   
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