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91.
92.
Xenoliths of meta-igneous origin occur as one of the two main types of ultramafic and mafic xenoliths entrained by alkaline lavas of the Kerguelen islands. These are designated type II xenoliths and are subdivided into three mineralogical groups. Subtype IIa and IIc xenoliths are interpreted as crystallisation products of basaltic melts that were emplaced near the crust-mantle boundary during the early tholeiitic–transitional magmatic activity of the Kerguelen islands. Younger magmatism became more alkaline and subtype IIb xenoliths were formed as high-pressure alkaline cumulates related to the last alkaline volcanic stage. Subsequently, the plagioclase-bearing type II rocks have been re-equilibrated under granulite facies conditions. This addition of mafic material around the crust-mantle boundary is consistent with seismic evidence for crustal thickening to 14–20 km. Calculated compressional seismic velocities (Vp) for the basic granulites are consistent with the range of observed Vp in the low-velocity region underlying the oceanic crust. Such growth in the thickness of the oceanic crust may be caused by intrusion of basalts at different levels in the lithosphere and may provide the heat responsible for granulitic metamorphism in the oceanic setting. This study suggests that basic granulites can account for the observed seismic characteristics of oceanic plateaux and can be important components of Kerguelen oceanic lithosphere where there has been large-scale magma production. Moreover we speculate that the Kerguelen islands and perhaps the surrounding plateau represent a continental nucleation process. Received: 30 September 1997 / Accepted: 17 June 1998  相似文献   
93.
Abstract Basaltic basement has been recovered by deep-sea drilling at seven sites on the linear Ninetyeast Ridge in the eastern Indian Ocean. Studies of the recovered lavas show that this ridge formed from ~ 82 to 38 Ma as a series of subaerial volcanoes that were created by the northward migration of the Indian Plate over a fixed magma source in the mantle. The Sr, Nd and Pb isotopic ratios of lavas from the Ninetyeast Ridge range widely, but they largely overlap with those of lavas from the Kerguelen Archipelago, thereby confirming previous inferences that the Kerguelen plume was an important magma source for the Ninetyeast Ridge. Particularly important are the ~ 81 Ma Ninetyeast Ridge lavas from DSDP Site 216 which has an anomalous subsidence history (Coffin 1992). These lavas are FeTi-rich tholeiitic basalts with isotopic ratios that overlap with those of highly alkalic, Upper Miocene lavas in the Kerguelen Archipelago. The isotopic characteristics of the latter which erupted in an intraplate setting have been proposed to be the purest expression of the Kerguelen plume (Weis et al. 1993a,b). Despite the overlap in isotopic ratios, there are important compositional differences between lavas erupted on the Ninetyeast Ridge and in the Kerguelen Archipelago. The Ninetyeast Ridge lavas are dominantly tholeiitic basalts with incompatible element abundance ratios, such as La/Yb and Zr/Nb, which are intermediate between those of Indian Ocean MORB (mid-ocean ridge basalt) and the transitional to alkalic basalts erupted in the Kerguelen Archipelago. These compositional differences reflect a much larger extent of melting for the Ninetyeast Ridge lavas, and the proximity of the plume to a spreading ridge axis. This tectonic setting contrasts with that of the recent alkalic lavas in the Kerguelen Archipelago which formed beneath the thick lithosphere of the Kerguelen Plateau. From ~ 82 to 38 Ma there was no simple, systematic temporal variation of Sr, Nd and Pb isotopic ratios in Ninetyeast Ridge lavas. Therefore all of the isotopic variability cannot be explained by aging of a compositionally uniform plume. Although Class et al. (1993) propose that some of the isotopic variations reflect such aging, we infer that most of the isotopic heterogeneity in lavas from the Ninetyeast Ridge and Kerguelen Archipelago can be explained by mixing of the Kerguelen plume with a depleted MORB-like mantle component. However, with this interpretation some of the youngest, 42–44 Ma, lavas from the southern Ninetyeast Ridge which have206pb/204Pb ratios exceeding those in Indian Ocean MORB and Kerguelen Archipelago lavas require a component with higher206Pb/204Pb, such as that expressed in lavas from St. Paul Island.  相似文献   
94.
A study is reported of air pollution episodes in the Broye valley, a rural area of Switzerland located to the north-east of the city of Lausanne, in which a number of industrial sources of SO2 are located. The study comprises numerical simulations of regional-scale meteorology, local plume behavior, as well as a wind tunnel investigation of the same region in order to ascertain the relative advantages and disadvantages of numerical and physical modeling. In situ data are available for certain episodes which occured during a very cold period in the winter of 1985, allowing intercomparisons to be made between nature and models. Furthermore, a significant effort undertaken by cantonal authorities has led to the setting up of a detailed emission inventory, which includes industry, individual domestic heating and traffic. Such an inventory has proved invaluable in imposing source terms in the models.  相似文献   
95.
Ellenbergerite occurs as purple millimetre-size grains associated with talc, kyanite, clinochlore, rutile, and zircon in composite inclusions within decimetre-large pyrope crystals (90–98 mole percent end-member) in the quartzite layer of the Dora Maira massif, Western Alps, from which coesite has been recently reported (Chopin 1984). It is hexagonal, a=12.255(8), c=4.932(4) Å, Z=1, space group P63. Mohs hardness 6.5; Dmes 3.15, Dcal 3.10; no cleavage. Uniaxial negative and vividly pleochroic, colourless, colourless to deep lilac with colour zoning. The intensely coloured variety has 1.6789(5), 1.670(1); microprobe analysis yields SiO2 39.1, P2O5 0.45, Al2O3 25.1, TiO2 4.0, MgO 22.2, FeO 0.20, sum 99.05 wt.% including H2O 8.0 (coulometrically). The formula calculated on a O28(OH)10 basis (implying 7.5 wt.% H2O) is Mg6.71 Fe0.03 Ti0.61 Al6.00 Si7.92 P0.08 O28(OH)10 The colour zoning is due to nearly complete TiZr substitution. In addition ellenbergerite may contain more than 8 wt.% P2O5 with strictly correlated changes of Si, Mg, Al and Ti+Zr contents, over 80% of which represent the SiAlPMg substitution.The structure has been determined from 1049 observed independent reflections and refined to R=0.034, Rw=0.031, including six of ten protons. It consists of single chains of face-sharing octahedra with one third vacancies extending along the six-fold screw axes, and of pairs of fully occupied face-sharing octahedra linked by edge-sharing to form octahedral double chains parallel to the twofold screw axes, all interconnected by SiO4 tetrahedra. It may be compared with the dumortierite polymorph with space group P63mc derived hypothetically by Moore and Araki (1978). The structural formula is (Mg,Ti,Zr,)2 Mg6(Al,Mg)6 (Si,P)2 Si6 O28(OH)10 Face-sharing octahedra are an unusual feature in silicates which results in a dense structure and reflects, considering the common bulk composition, the uncommon high-pressure formation conditions (about 25–30 kbar, 700–800° C). Ti4+-Fe2+ charge transfer between face-sharing octahedra on the six-fold screw axes most likely accounts for the absorption scheme.  相似文献   
96.
An experimental study of the system Zr-Fe-Ti-O in equilibrium with metallic iron has been conducted at atmospheric pressure and in the temperature range 950–1300° C, with the purpose of modelling sub-solidus relations between Zr-bearing Fe-Ti oxide phases in lunar rocks. The phase relations are governed by the coexistence of the Fe-Ti oxides with ZrO2 at temperatures below 1247° C, but with the new cubic ZFT phase at higher temperatures. ZFT, approximately Zr Fe Ti O5, is probably related to the so-called stabilized cubic zirconia and could represent a synthetic equivalent of some lunar Zr-Fe-Ti rich oxide minerals.The zirconium contents in all Fe-, Ti and Fe-Ti-oxide phases increase with increasing temperature. At each temperature, Zr is incorporated preferentially in the Ti-oxide (up to 11 wt% ZrO2), followed by ferropseudobrookite (up to 6 wt% ZrO2), ilmenite (max. 4 wt%) and wüstite (max. 2.5 wt%). Ulvöspinel coexisting with ilmenite (+Fe0+ ZrO2 and/or ZFT) always contains less than 1.2 wt% ZrO2, whereas the same mineral in assemblage with wüstite-ZrO2-Fe0 displays even higher ZrO2 contents than ilmenite (above 4 wt%). Considering that the values determined here in the synthetic parageneses represent saturation concentrations at high temperatures in a simple model system, the ZrO2 concentrations in the corresponding lunar minerals should generally be significantly lower. This is realized, except for the so-called Cr-Zr-Ca armalcolites which display ZrO2 contents in the range 3.5–7 wt% and are thus probably related rather to Zr-rich oxide minerals than to armalcolite itself.  相似文献   
97.
The Tenryu Canyon deep-sea fan biological community is characterized by both reduced and oxidized sediments in the immediate vicinity of the pore water vents. The upper sediments in contact with the clams are reduced, the organic matter is enriched in sulfur, and inorganic sulfides (Fe, Cu, Zn) are forming. Towards the outer fringes of the communities the sediment is oxidized and metals generally associated with ferro-manganese oxides are concentrated. Several metals, Cd, Pb, Mo show distributions which are strongly influenced by the metabolism of the clam colony. Comparison of water and sediment geochemistry leads to the conclusion that there should be a downward flux of oxygenated seawater on the boundaries of the colony and an upward flux of chemically more reduced deep pore water at the location of the colony. Trace metals anomalies as well asδ15N anomalies of organic matter may be useful to prospect for extinct venting areas in ancient subduction zones.  相似文献   
98.
99.
We introduce a surface approximation technique to address the problem of fitting a surface to a given set of curves. The originality of the method lies in its ability to take into account the continuous aspect of the data, and also in the possibility to arbitrarily select the regularity (C0, C1, or higher) of the approximant obtained. We demonstrate the efficiency of the approach by constructing a bathymetry map of the Marianas trench based upon a set of SONAR (SOnic Navigation And Ranging) bathymetry ship track data.  相似文献   
100.
We introduce a surface approximation technique to address the problem of fitting a surface to a given set of curves. The originality of the method lies in its ability to take into account the continuous aspect of the data, and also in the possibility to arbitrarily select the regularity (C0, C1, or higher) of the approximant obtained. We demonstrate the efficiency of the approach by constructing a bathymetry map of the Marianas trench based upon a set of SONAR (SOnic Navigation And Ranging) bathymetry ship track data.  相似文献   
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