The effects of phase fractionation on the composition of oils, condensates and gases   总被引：1，自引：0，他引：1  

Ger W. van Graas  Ann Elin Gilje  Timothy P. Isom  Liv Aase Tau 《Organic Geochemistry》2000,31(12)

The effects of phase fractionation on the composition of oils, condensates and gases have been studied in the laboratory by a differential evaporation experiment. The experiment was designed to simulate the behaviour of a single-charge petroleum during (upward) migration or in a reservoir undergoing uplift, scenarios thought to be typical for the Norwegian continental shelf. After each pressure reduction step, samples from all phases (oil, condensate, free and associated gas) were collected and analysed. The results show that, in general, small molecules are preferentially enriched in the gas phase, both at elevated pressure and temperature and under standard conditions (15°C, 1 bar). The solvent power of the gas phase for large molecules is drastically reduced at lower pressures (here below approx. 300 bar). Carbon isotope ratios of individual compound are not affected, while variations in isotope ratios of fractions can be explained by changes in the fraction compositions. Individual geochemical parameters behave as can be expected based on the molecular size and structure of the compounds involved. However, a generally valid, quantitative prediction of how geochemical parameters vary as a result of phase fractionation is very difficult, as this will depend not only on the pressure and temperature of fractionation, but also on the composition and amounts of the oil and gas that are involved. The observations from this study confirm the importance of phase fractionation as an important process to consider when interpreting geochemical data for both condensates and oils.  相似文献   

Melt‐bearing impactites (suevite and impact melt rock) within the Gardnos structure,Norway     

Elin KALLESON  Henning DYPVIK  Odd NILSEN 《Meteoritics & planetary science》2010,45(5):798-827

Abstract– Melt‐bearing impactites dominated by suevite, and with a minor content of clast‐rich impact melt rock, are found within the central part of the Gardnos structure. They are preserved as the eroded remnants in the relatively small complex impact structure with a present diameter of 5 km. These rocks have been mapped in the field and in the Branden drill core, and described according to mineralogy/petrology, including matrix, litho clast, and melt content, as well as geochemistry. Based on our extensive field mapping, a simple 3‐D model of the original crater was constructed to estimate tentative volumes for the melt‐bearing impactites. The variations in lithic and melt fragment content and chemistry of suevite matrix can mostly be explained by incorporation of mafic rocks into a dominant mixture of granitic, gneissic, and quartzitic target rocks, reflecting mixing of material from different parts of the crater. Melt fragments within suevite occur with a variety of shapes and textures, probably related to different original target rock composition, to the various temperatures the individual fragments were subjected to during the impact event and deposition processes. This study discusses the impact‐related deposits based on a sedimentological approach. Their overall composition and structures indicate dominating gravity flow processes in the final transportation and deposition of the suevite.  相似文献   

A non-magmatic iron projectile for the Gardnos impact event     

Steven Goderis  Elin Kalleson  Roald Tagle  Henning Dypvik  Ralf-Thomas Schmitt  Jörg Erzinger  Philippe Claeys 《Chemical Geology》2009,258(3-4):145-156

The goal of this study is to identify the type of projectile responsible for the formation of the late Precambrian Gardnos impact structure in Norway. Fifteen impactite samples, predominantly impact breccias and suevites from the central and northeastern part of the structure, were analyzed for platinum group elements (PGE) and Au using nickel-sulfide fire assay combined with inductively coupled plasma mass spectrometry (ICP-MS). Major and trace elements were measured in the same samples using X-ray fluorescence (XRF). In addition, the concentrations of siderophile elements Ni, Cr, and Co were determined by ICP-MS after acid digestion. The samples collected at the contact between suevite and the sedimentary infill yielded the highest PGE concentrations (Ir = 1.926 ng/g, Ru = 3.494 ng/g, Pt = 4.716 ng/g, Rh = 0.766 ng/g, Pd = 2.842 ng/g for GC6). The CI-normalized PGE patterns are characterized by Ru and Rh enrichments suggesting a non-chondritic impactor. Concentration plots of the different PGE display an excellent correlation (R > 0.99), indicative of a single source for the PGE enrichment. The Ni/Cr ratio of the Gardnos impactor (2.56 ± 0.20) agrees with that of chondrites (2 to 7), whereas Ir is depleted relative to Ni in this projectile (Ni/Ir ratio of 92 000 ± 8000 compared to an average Ni/Ir ratio of 23 150 ± 4250 for chondrites). There is no clear indication of selective post-depositional remobilization of the characteristic highly siderophile elements. The Ni/Ir and Cr/Ir data combined with the non-chondritic PGE ratios probably indicate a differentiated projectile. Based on (1) the similarity of the inter-element ratios of the impactor with the iron phase of non-magmatic iron meteorites and (2) the presence of characteristics of both chondrites and iron meteorites (Ni/Cr and Ni/Ir ratios), an IA or IIIC non-magmatic iron meteorite is a very plausible impactor.  相似文献   

Water-level variations in Lake Nhauhache, Mozambique, during the last 2,300?years     

Karin Holmgren  Jan Risberg  Johan Freudendahl  Mussa Achimo  Anneli Ekblom  Joao Mugabe  Elin Norstr?m  Sandra Sitoe 《Journal of Paleolimnology》2012,48(2):311-322

Stratigraphic variations in diatom composition and phytolith abundance in a sediment core from a small, hydrologically isolated waterbody, Lake Nhauhache, Mozambique, provide evidence of water-level fluctuations over the past ~2,300?years. Ten AMS radiocarbon dates on bulk sediment samples show that the lake came into existence about 2,300?years ago and that it has dried out since then, but only for brief time periods. Changes in the diatom assemblage composition indicate that lake level fluctuated in response to shifting humidity conditions. The changes reflect wetter conditions ca. 300 BC?CAD 800, more variable conditions between AD 800 and 1150, a distinct dry phase within the time span AD 1150?C1700 and a return thereafter to more humid conditions until present. There is general agreement between the Lake Nhauhache record and other records from the Southern Hemisphere summer rainfall region. This suggests that sediments from small interdunal lakes, which are abundant along the coast of southern Africa, provide reliable, regional paleoenvironmental information about an area from which more such data are needed.  相似文献   

Real-time mapping of earthquake-induced landslides     

Amir M. Kaynia  Elin Skurtveit  Gokhan Saygili 《Bulletin of Earthquake Engineering》2011,9(4):955-973

Rigid sliding block analysis is a common analytical procedure used to predict the potential for earthquake-induced landslides for natural slopes. Currently, predictive models provide the expected level of displacement as a function of the characteristics of the slope (e.g., geometry, strength, yield acceleration) and the characteristics of earthquake shaking (e.g., peak ground acceleration, peak ground velocity). These predictive models are used for developing seismic landslide hazard maps which identify zones with risk of earthquake-induced landslides. Alternatively, these models can be combined with Shakemaps to generate “near-real-time” Slidemaps which could be used, among others, as a tool in disaster management. Shakemaps (a publicly available free service of the United States Geological Survey, USGS) provide near-real-time ground motion conditions during the time of an earthquake event. The ground motion parameters provided by a Shakemap are very useful for the development of Slidemaps. By providing ground motion parameters from an actual earthquake event, Shakemaps also serve as a tool to decouple the uncertainty of the ground motion in sliding displacements prediction. Campania region in Italy is studied for assessing the applicability of using Shakemaps for regional landslide-risk assessment. This region is selected based on the availability of soil shear strength parameters and the proximity to the 1980 Irpina (M _w  = 6.9) Earthquake.  相似文献   

Prospects for Detecting the 326.5 MHz Redshifted 21-cm HI Signal with the Ooty Radio Telescope (ORT)     

Sk. Saiyad Ali  Somnath Bharadwaj 《Journal of Astrophysics and Astronomy》2014,35(2):157-182

Observations of the redshifted 21-cm HI fluctuations promise to be an important probe of the post-reionization era (z≤ 6). In this paper we calculate the expected signal and foregrounds for the upgraded Ooty Radio Telescope (ORT) which operates at frequency ν _o = 326.5 MHz which corresponds to redshift z = 3.35. Assuming that the visibilities contain only the HI signal and system noise, we show that a 3 σ detection of the HI signal (～1 mK) is possible at angular scales 11^′ to 3^° with ≈1000 h of observation. Foreground removal is one of the major challenges for a statistical detection of the redshifted 21 cm HI signal. We assess the contribution of different foregrounds and find that the 326.5 MHz sky is dominated by the extragalactic point sources at the angular scales of our interest. The expected total foregrounds are 10⁴?10⁵ times higher than the HI signal.  相似文献   

Adaptation to climate change impacts on urban storm water: a case study in Arvika, Sweden   总被引：1，自引：0，他引：1  

Jonas Olsson  Hideo Amaguchi  Elin Alsterhag  Maria Dåverhög  Per-Erik Adrian  Akira Kawamura 《Climatic change》2013,116(2):231-247

Already today, the functionality of many sewer and storm water systems are not up to the required standards and consequently flooding problems are experienced in case of heavy storms. System upgrades are required, which are however complicated by the expected future increase in short-term rainfall intensities as a result of climate change. In this case study, focusing on the town of Arvika, Sweden, this issue is investigated in three main steps. In the first, extreme value analyses of 30-min rainfall from an ensemble of climate projections are carried out to estimate the future increase and generate a future design storm. In the second, the existing system’s response to both today’s and future design storms are simulated by a coarse sewer model setup (MOUSE) and a detailed coupled surface-sewer model setup (TSR). In the third and final step, system upgrades are designed and evaluated by both models. The results indicate an increase by 10–30 % of today’s short-term rainfall extremes by the end of the century. Upgrading the system to achieve a satisfactory performance for the future design storm would cost approximately twice as much as an upgrade based on today’s design storm.  相似文献   

Long-term seismic observations along Myanmar–Sunda subduction margin: insights for 2004 Mw > 9.0 earthquake     

Khan  Prosanta Kumar  Banerjee  Jayashree  Shamim  Sk  Mohanty  Manoranjan 《International Journal of Earth Sciences》2018,107(7):2383-2392

International Journal of Earth Sciences - The present study investigates the temporal variation of few seismic parameters between the Myanmar (Zone I), Andaman–Nicobar–Northwest Sumatra...  相似文献   

Social–ecological traps and transformations in dryland agro-ecosystems: Using water system innovations to change the trajectory of development     

Elin Enfors 《Global Environmental Change》2013,23(1):51-60

Recent efforts to achieve a much needed productivity increase in farming systems across semi-arid and dry sub-humid sub-Saharan Africa have highlighted the potential of small-scale water system innovations (SWSIs). This paper takes a social–ecological resilience approach to investigate how this type of water management technology would influence agro-ecosystem dynamics, using a catchment in northeastern Tanzania as an example. The analysis finds that three external drivers (increasing dryspell frequency, population growth, and institutional changes) have interacted with a set of key variables in the studied system to shape a development trajectory over the past half-century where off-farm ecosystem services are being degraded while agricultural yields remain low and people remain poor. The analysis further finds that the evaluated SWSIs have the potential to destabilize feedbacks maintaining this social–ecological trap through several different mechanisms, and thereby open up for new development trajectories. A concluding discussion identifies a number of challenges to this type of transformation in sub-Saharan Africa, and outlines the type of investment approaches that would be needed to go from potential to reality.  相似文献   

Effects of resuspension on benthic fluxes of oxygen,nutrients, dissolved inorganic carbon,iron and manganese in the Gulf of Finland,Baltic Sea     

Elin Almroth  Anders Tengberg  Johan H. Andersson  Svetlana Pakhomova  Per O.J. Hall 《Continental Shelf Research》2009,29(5-6):807-818

The effect of resuspension on benthic fluxes of oxygen (O₂), ammonium (NH₄⁺), nitrate (NO₃^?), phosphate (PO₄^3?), silicate (Si(OH)₄), dissolved inorganic carbon (DIC), total dissolved iron (Fe) and total dissolved manganese (Mn) was studied at three different stations in the Gulf of Finland (GoF), Baltic Sea during three cruises in June–July 2003, September 2004 and May 2005. The stations were situated on different bottom types in the western, central and eastern part, respectively, of the open GoF. The fluxes were measured in-situ using the autonomous Göteborg benthic lander. To simulate resuspension events, the stirring speed was increased in two of the four chambers of the lander after approximately half of the incubation time. The other two chambers were used as control chambers. Clear effects of resuspension were observed on the oxygen fluxes where an increase of the consumption was observed in 88% of the cases and on average with 59% (stdev=53). The NH₄⁺ fluxes were affected in 50% of the cases (4 out of 8 incubations) at stations with low bottom water oxygen concentrations, but in no cases where the bottom water was oxygenated (0 out of 9 incubations). The NH₄⁺ fluxes decreased by 26±27% in 2005 and by 114±19% in 2003. There was no clear effect of resuspension on the fluxes of any of the other solutes in this study. Thus, resuspension events did not play a significant role in release/uptake of NO₃^?, PO₄^3?, Si(OH)₄, DIC, Fe and Mn in GoF sediments. However, increased oxygen consumption as a result of resuspension may lead to spreading of anoxic/suboxic bottom water conditions, and thus indirectly to increased benthic release of phosphate, ammonium and iron.  相似文献