Rare Earth Element Determination in Olivine by Laser Ablation‐Quadrupole‐ICP‐MS: An Analytical Strategy and Applications          下载免费PDF全文

Clare V. Stead  Emma L. Tomlinson  Balz S. Kamber  Michael G. Babechuk  Cora A. McKenna 《Geostandards and Geoanalytical Research》2017,41(2):197-212

Olivine offers huge, largely untapped, potential for improving our understanding of magmatic and metasomatic processes. In particular, a wealth of information is contained in rare earth element (REE) mass fractions, which are well studied in other minerals. However, REE data for olivine are scarce, reflecting the difficulty associated with determining mass fractions in the low ng g^?1 range and with controlling the effects of LREE contamination. We report an analytical procedure for measuring REEs in olivine using laser ablation quadrupole‐ICP‐MS that achieved limits of determination (LOD) at sub‐ng g^?1 levels and biases of ~ 5–10%. Empirical partition coefficients (D values) calculated using the new olivine compositions agree with experimental values, indicating that the measured REEs are structurally bound in the olivine crystal lattice, rather than residing in micro‐inclusions. We conducted an initial survey of REE contents of olivine from mantle, metamorphic, magmatic and meteorite samples. REE mass fractions vary from 0.1 to double‐digit ng g^?1 levels. Heavy REEs vary from low mass fractions in meteoritic samples, through variably enriched peridotitic olivine to high mass fractions in magmatic olivines, with fayalitic olivines showing the highest levels. The variable enrichment in HREEs demonstrates that olivine REE patterns have petrological utility.  相似文献   

Hydraulic,physical and rheological characteristics of rain‐triggered lahars at Semeru volcano,Indonesia     

Céline Dumaisnil  Jean‐Claude Thouret  Guillaume Chambon  Emma E. Doyle  Shane J. Cronin  Surono 《地球表面变化过程与地形》2010,35(13):1573-1590

Lahars (volcanic debris flows) have been responsible for 40% of all volcanic fatalities over the past century. Mount Semeru (East Java, Indonesia) is a persistently active composite volcano that threatens approximately one million people with its lahars and pyroclastic flows. Despite their regularity, the behaviour and the propagation of these rain‐triggered lahars are poorly understood. In situ samples were taken from lahars in motion at two sites in the Curah Lengkong River, on the southeast flank of Semeru, providing estimates of the particle concentration, grain size spectrum, grain density and composition. This enables us to identify flow sediment from three categories of lahars: (a) hyperconcentrated flow, (b) non‐cohesive, clast‐ and matrix‐supported debris flow, and (c) muddy flood. To understand hyperconcentrated flow sediment transport processes, it is more appropriate to sample the active flows than the post‐event lahar deposits because in situ sampling retains the full spectrum of the grain‐size distribution. Rheometrical tests on materials sampled from moving hyperconcentrated flows were carried out using a laboratory vane rheometer. Despite technical difficulties, results obtained on the <63, <180, and <400 µm fractions of the sampled sediment, suggest a purely frictional behaviour. Importantly, and contrary to previous experiments conducted with monodisperse suspensions, our results do not show any transition towards a viscous behaviour for high shear rates. These data provide important constraints for future physical and numerical modelling of lahar flows. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

Sylvia Chant and Cathy McIlwaine, Geographies of Development in the 21st Century: An Introduction to the Global South     

Emma Mawdsley 《Singapore journal of tropical geography》2010,31(1):134-135

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Multilevel samplers as microcosms to assess microbial response to biostimulation     

Baldwin BR  Peacock AD  Park M  Ogles DM  Istok JD  McKinley JP  Resch CT  White DC 《Ground water》2008,46(2):295-304

Passive multilevel samplers (MLS) containing a solid matrix for microbial colonization were used as in situ microcosms in conjunction with a push-pull biostimulation experiment designed to promote biological U(VI) and Tc(VII) reduction. MLS were deployed at 24 elevations in the injection well and two downgradient wells to investigate the spatial variability in microbial community composition and growth prior to and following biostimulation. The microbial community was characterized by real-time quantitative polymerase chain reaction (Q-PCR) quantification of bacteria, NO(3)(-)-reducing bacteria (nirS and nirK), delta-proteobacteria, Geobacter sp., and methanogens (mcrA). Pretest cell densities were low overall but varied substantially with significantly greater bacterial populations detected at circumneutral pH (t-test, alpha= 0.05), suggesting carbon substrate and low pH limitations of microbial activity. Although pretest cell densities were low, denitrifying bacteria were dominant members of the microbial community. Biostimulation with an ethanol-amended ground water resulted in concurrent NO(3)(-) and Tc(VII) reduction, followed by U(VI) reduction. Q-PCR analysis of MLS revealed significant (1 to 2 orders of magnitude, Mann-Whitney U-test, alpha= 0.05) increases in cell densities of bacteria, denitrifiers, delta-proteobacteria, Geobacter sp., and methanogens in response to biostimulation. Traditionally, characterization of sediment samples has been used to investigate the microbial community response to biostimulation; however, collection of sediment samples is expensive and not conducive to deep aquifers or temporal studies. The results presented demonstrate that push-pull tests with passive MLS provide an inexpensive approach to determine the effect of biostimulation on contaminant concentrations, geochemical conditions, and the microbial community composition and function.  相似文献   

Thank you to 2022 Ocean Dynamics reviewers     

Ezer  Tal  Carniel  Sandro  Amin  Chabchoub  de Camargo  Ricardo  Estrada-Allis  Sheila N.  Gao  Guoping  Greatbatch  Richard J.  Lermusiaux  Pierre F. J.  Liu  Zhiyu  Miyazawa  Yasumasa  Forster  Alejandro Orfila  Panickal  Swapna  Phillips  Helen  Pinones  Andrea  Stanev  Emil  Volker  Christoph  Xu  Fanghua  Young  Emma 《Ocean Dynamics》2023,73(1):35-38

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Late Quaternary environmental change in the Southern Cape,South Africa,from stable carbon and oxygen isotopes in faunal tooth enamel from Boomplaas Cave          下载免费PDF全文

Judith Sealy  Julia Lee‐Thorp  Emma Loftus  J. Tyler Faith  Curtis W. Marean 《第四纪科学杂志》2016,31(8):919-927

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Pressure-temperature paths from P-T pseudosections and zoned garnets: potential, limitations and examples from the Zanskar Himalaya, NW India     

Derek Vance  Emma Mahar 《Contributions to Mineralogy and Petrology》1998,132(3):225-245

The extraction of P-T histories from metamorphic rocks provides a valuable dataset for the elucidation of the tectonic mechanisms for orogeny. While continued re-equilibration frequently obliterates early information, garnet zonation and inclusion assemblages can often surmount this problem. The task is more difficult in high variance assemblages or if inclusions are not preserved, but one approach is to use pseudosections that are specific to the bulk composition of a given rock. In the latter case, the compositions and abundances of all the minerals are fixed at a given P-T point such that, if the effective bulk composition is known, the garnet composition alone can be used to reconstruct the history. Here, we explore this approach using examples from the Zanskar Himalaya, NW India. Pseudosections have been calculated for four pelitic to semipelitic rocks from the Zanskar Himalaya and have been contoured for garnet composition. The calculations adequately model the mineral assemblages in the rocks and predict the presence of chlorite in the early assemblage where chlorite is found as inclusions within garnet. Moreover, the pseudosections successfully model the garnet core compositions, with all three independent compositional contours overlapping at a single pressure and temperature. This occurs at ∼550 °C and at pressures varying from 3–7 kbar for the four rocks studied. We have been less successful, however, at modelling garnet compositions beyond the cores because fractionation of the effective bulk composition is caused by garnet growth itself. However, in this case, a combination of the␣pseudosection and conventional thermobarometry using␣Fe-Ti inclusions and matrix phases allows us to reconstruct␣the entire P-T history. The resulting P-T paths record burial of 3–5 kbar without significant temperature increase followed by isobaric heating of 50–100 °C. This evolution is consistent with Himalayan collision in the early Tertiary but a combination of the P-T data presented here and published geochronological data suggests renewed thrusting south of the suture zone in the Oligocene. In addition, the data demonstrate that no extra heat source is required to cause melting of the Himalayan crust in the Miocene. While melting could have occurred both by dehydration during decompression or in the presence of a fluid, the lack of garnet resorption does suggest decompression was rapid and followed quickly by cooling. This scenario favours melting by decompression. Received: 17 July 1997 / Accepted: 6 April 1998  相似文献   

Biogeochemical effects of disturbance in shallow water sediment by macroalgae harvesting boats     

Lenzi M  Finoia MG  Persia E  Comandi S  Gargiulo V  Solari D  Gennaro P  Porrello S 《Marine pollution bulletin》2005,50(5):512-519

In the shallow water of Orbetello lagoon, macroalgae harvesting boats produce sediment disturbance. To evaluate the effect of this, during 2001-2002, a trial study was carried out in the lagoon in order to: verify seasonal and diurnal trends in nutrients and estimate the quantity of resuspended organic sediment. An unbalanced and balanced ANOVA (one and two way) analysis was applied. The disturbance did not produce strong and lasting eutrophication effects. In the seasonal survey, dissolved inorganic nitrogen (DIN) and soluble reactive phosphorus (SRP) showed significant decreases in disturbed areas at the end of the trial, while the control area showed a constant, significant increase. Dissolved organic nitrogen (DON) and phosphorus (DOP) significantly increased everywhere. In disturbed areas, sediment redox (Eh((NHE))) increased and porosity values decreased, contrary to the control area. Total organic carbon (TOC) remained unchanged in disturbed areas, but increased in the control area, where the C:P ration increased. The fall-out of sedimentary material resuspended by boat action for as far as 50 m from the boat route, was 189 g(dw)m(-2) made up mainly of organic matter. This disturbance could be the cause of change in vegetation in the lagoon.  相似文献   

Global civil society? The Johannesburg World Summit on Sustainable Development     

D.L. Carr  Emma S. Norman 《Geoforum》2008,39(1):358-371

In the face of mounting environmental degradation and persistent poverty over the previous decade, Johannesburg’s World Summit on Sustainable Development (WSSD) of August and September 2002 inherited a number of unmet accords from the 1992 Rio de Janeiro Earth Summit. Consequently, the United Nations Stakeholder Forum Implementation Conference (IC) was convened to integrate civil society stakeholders into global deliberations on sustainable development and to marshal their forces in the implementation of WSSD accords. Given the importance of the IC as the first civil society forum at a major global summit on environment and poverty, intriguing questions emerge as to its effectiveness in achieving civil society objectives. As a first attempt in exploring this topic, we examine three fundamental aspects of the IC. Specifically, we examine the relative “civility” of the IC forum in terms of (a) fidelity of representation of the community of global environment and development stakeholders; (b) autonomy of the IC agenda from state and institutional interests; and (c) interpretations of space and place as reflected in deliberative processes and outcomes. The paper begins with a review of the civil society literature with a particular emphasis on civil society representation in UN meetings since Rio. The paper concludes with a discussion of IC participation at the Johannesburg summit, and considers implications for future civil society participation in global decision-making forums.  相似文献   

Arsenic mobilisation in a new well field for drinking water production along the Red River,Nam Du,Hanoi     

Jenny Norrman  Charlotte J. Sparrenbom  Michael Berg  Dang Duc Nhan  Pham Quy Nhan  Håkan Rosqvist  Gunnar Jacks  Emma Sigvardsson  David Baric  Johanna Moreskog  Peter Harms-Ringdahl  Nguyen Van Hoan 《Applied Geochemistry》2008

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