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181.
182.
Extremely alkaline ground water has been found underneath many shuttered steel mills and slag dumps and has been an impediment to the cleanup and economic redevelopment of these sites because little is known about the geochemistry. A large number of these sites occur in the Lake Calumet region of Chicago, Illinois, where large-scale infilling of the wetlands with steel slag has created an aquifer with pH values as high as 12.8. To understand the geochemistry of the alkaline ground water system, we analyzed samples of ground water and the associated slag and weathering products from four sites. We also considered several potential remediation schemes to lower the pH and toxicity of the water. The principal cause of the alkaline conditions is the weathering of calcium silicates within the slag. The resulting ground water at most of the sites is dominated by Ca2+ and OH- in equilibrium with Ca(OH)2. Where the alkaline ground water discharges in springs, atmospheric CO2 dissolves into the water and thick layers of calcite form. Iron, manganese, and other metals in the metallic portion of the slag have corroded to form more stable low-temperature oxides and sulfides and have not accumulated in large concentrations in the ground water. Calcite precipitated at the springs is rich in a number of heavy metals, suggesting that metals can move through the system as particulate matter. Air sparging appears to be an effective remediation strategy for reducing the toxicity of discharging alkaline water. 相似文献
183.
Geotechnical properties of municipal sewage sludge 总被引:3,自引:0,他引:3
Brendan C. O’Kelly 《Geotechnical and Geological Engineering》2006,24(4):833-850
The geotechnical properties of municipal sewage sludge, in particular those pertinent to the handling and landfilling of the
material, are presented. Index, drying, compaction, shear strength and consolidation tests were conducted on the material
at different states of biodegradation. The organic content and specific gravity of solids were found to be inversely related,
with typical organic contents of 50–70% and specific gravity of solids values of 1.55–1.80. The density of the compacted material
was low in comparison with mineral soils. Standard Proctor compaction yielded a maximum dry density of 0.56 tonne/m3 at 85% water content. Laboratory vane-shear and triaxial compression tests indicated that, below about 180% water content,
the shear strength of the sludge material increased exponentially with reducing water content. Consolidated-undrained triaxial
compression tests on the pasteurised sludge material indicated an effective angle of shearing resistance of 32° for the moderately
degraded material and 37° for the strongly degraded material. Biogas was produced at rates of up to 0.33 L/day/kg slurry due
to ongoing biodegradation and the resulting pore pressure response must be taken into account in any stress analysis. Consolidation
tests using the hydraulic consolidation cell, oedometer and triaxial apparatus indicated that the sludge material was highly
compressible although practically impermeable, for example the coefficient of permeability for the moderately degraded slurry
was of the order of 10−9m/s. However, creep deformation was significant with typical coefficient of secondary compression values of 0.02–0.08 for
the compacted material. A more free-draining material was produced at higher states of biodegradation. 相似文献
184.
185.
J. Allington-Smith P. Bettess E. Chadwick R. Content R. Davies G. Dodsworth R. Haynes D. Lee I. Lewis J. Webster E. Atad S. Beard R. Bennett J. Harris P. Hastings D. Kelly T. Paul M. Strachan P. Williams T. Bond D. Crampton T. Davidge B. Leckie C. Morbey R. Murowinski S. Roberts L. Saddlemyer J. Sebesta J. Stilburn K. Szeto 《Experimental Astronomy》1997,7(4):293-299
186.
187.
Joan D. Willey Robert J. Kieber Kelly H. Williams Jamie S. Crozier Stephen A. Skrabal G. Brooks Avery Jr. 《Journal of Atmospheric Chemistry》2000,37(2):185-205
Iron occurs in rain as particulateand dissolved Fe and includes both Fe(II) and Fe(III)species. Model calculations and correlation analysisindicate Fe(II)(aq) occurs almost exclusively as thefree ion whereas Fe(III)(aq) occurs as both ironoxalate and Fe(OH)2
+(aq) with largevariations over the pH range from 4.0 to 5.0. Complexation with humic-like compounds may also beimportant for Fe(III)(aq); however, the concentrationand structural characteristics of these compounds haveyet to be determined. 112 rain samples were collectedfor iron analysis in Wilmington, North Carolina,between 1 July 1997, and 30 June 1999. Total iron,particulate iron and Fe(III)(aq) were higher inconcentration in summer and spring rain relative towinter and autumn rain. Fe(II)(aq) concentrations, incontrast, did not vary seasonally. Particulate iron,which was approximately half the total rainwater iron,was highest between noon and 6 p.m. (EST), probably dueto more intense regional convection including land-seabreezes during that time. The ratio ofFe(II)(aq)/Fe(III)(aq) was also highest in rainreceived between noon and 6 p.m., which most likelyreflects photochemical reduction of Fe(III)(aq)complexes to form Fe(II)(aq). A conceptual modeldepicting the interplay between iron species, lightintensity and organic ligands in rainwater ispresented. 相似文献
188.
Summary In this paper we use the example of Singapore to make two theoretical contributions to the geographical literature on local labour markets. Firstly, we suggest that the local labour market should be conceived of as an extended 'network space' that is constituted by extra-local linkages and flows as well as local interactions. The importance of certain kinds of foreign 'workers' and 'talent' in Singapore can be used to illustrate this argument. Secondly, we contend that locally constructed discourses can actively shape labour market dynamics, exemplified here by the rise of 'knowledge-based economy' rhetoric in Singapore. 相似文献
189.
190.