Assessment of ERA5 and ERA-Interim in Reproducing Mean and Extreme Climates over West Africa     

Imoleayo Ezekiel GBODE  Toju Esther BABALOLA  Gulilat Tefera DIRO  Joseph Daniel INTSIFUL 《大气科学进展》2023,40(4):570-586

In situ data in West Africa are scarce, and reanalysis datasets could be an alternative source to alleviate the problem of data availability. Nevertheless, because of uncertainties in numerical prediction models and assimilation methods, among other things, existing reanalysis datasets can perform with various degrees of quality and accuracy. Therefore, a proper assessment of their shortcomings and strengths should be performed prior to their usage. In this study, we examine the performance of E...  相似文献   

Dehydroxylation mechanisms in Al/Fe dioctahedral phyllosilicates by quantum mechanical methods with cluster models     

Esther Molina-Montes  Alfonso Hernández-laguna 《Geochimica et cosmochimica acta》2008,72(16):3929-3938

Atomic models involving the dehydroxylation process of dioctahedral phyllosilicates without interlayer charge were used to calculate energies and explore the reaction paths of the possible mechanisms of this reaction at a quantum mechanical level. The geometrical features and electronic structure of a molecular cluster model of two edge-sharing octahedrally coordinated cations coupled to a ring of six silicate tetrahedra was evaluated by ab initio molecular orbital calculations with Hartree-Fock approximation. Two dehydroxylation mechanisms are considered. One mechanism involves two contiguous hydroxyl that are on an octahedron shared edge that joins a pair of octahedral cations. The other model considered involves OH loss from across an octahedral vacant. The substitution effect of Al³⁺ by Fe³⁺ in the octahedral sheet on the activation energy and structural transformations is compared by minimization of the critical points of the Potential Energy Surface (PES) for the reactant, transition state and product along the reaction path of the dehydroxylation process. The calculated energy differences and vibration frequencies are according to previous experimental results. The dehydroxylation mechanism involving OH across the octahedral hole, is less energetically favorable and is endothermic.  相似文献   

Spatial variability of soil erodibility and its correlation with soil properties in semi-arid mountainous watershed,Saudi Arabia   总被引：2，自引：0，他引：2  

Javed Mallick  Hussein Al-Wadi  Atiqur Rahman  Mohd Ahmed  Roohul Abad Khan 《国际地球制图》2016,31(6):661-681

Soil erodibility values are best estimated from long-term direct measurements on runoff-plots; however, in lack of field tests, these values can be estimated using relationships based on physico-chemical soil properties. The study objective was to assess the erodibility and its correlation with soil properties. The average erodibility value was estimated 0.043 t ha h ha^?1 MJ^?1 mm^?1. The areas with heavy textured soil and low organic matter content had the lowest values of erodibility. The erodibility decreases as the sand content increases, whereas silt showed a positive correlation. The erodibility factors and its relation to soil properties were evaluated using multiple regression analysis. Results revealed that sand and organic matter content of soil combinedly explained 78% of variation. Altitudinal increases also seem to affect the soil texture. This study has demonstrated that soil properties and erodibility values can be used as assistance for soil conservation practices and modelling of landscape processes.  相似文献   

Assessment of toxicological status of a SW Mediterranean segment population of striped dolphin (Stenella coeruleoalba) using skin biopsy     

M. Cristina Fossi  Letizia Marsili  Giancarlo Lauriano  Caterina Fortuna  Simone Canese  Stefania Ancora  Claudio Leonzio  Teresa Romeo  Ruben Merino  Esteban Abad  Begoa Jimnez 《Marine environmental research》2004,58(2-5):269

Various studies have revealed high concentrations of contaminants such as organochlorines (OCs) and heavy metals in Mediterranean cetaceans. A geographical trend of contamination (PCBs and DDTs) has been found for striped dolphin (Stenella coeruleoalba). In this study we used a non-lethal approach (skin biopsy) to investigate bioaccumulation of OCs, including polychlorobiphenyls (PCBs), DDTs, polychlorodibenzo-p-dioxins (PCDDs), polychlorodibenzofurans (PCDFs), trace elements (Hg, Cd, Pb) and CYP1A activity (BPMO) in nine striped dolphins sampled in the Aeolian area (Sicily – Italy) in summer 2002. The arithmetic mean value of BPMO activity in this group was 43.46 AUF/g tissue/h. This value is approximately 3 times and 5 times lower, respectively, than the value found in the Ionian and in the Ligurian groups. Skin biopsies of striped dolphins emerged as a suitable material for assessing the toxicological status of the various Mediterranean groups.  相似文献   

Evidence for Amazonian acidic liquid water on Mars—A reinterpretation of MER mission results     

Alberto G. Fairén  Dirk Schulze-Makuch  Wolfgang Fink  Esther R. Uceda  Ricardo Amils 《Planetary and Space Science》2009,57(3):276-318

The Mars Exploration Rover (MER) missions have confirmed aqueous activity on Mars. Here we review the analyses of the field-based MER data, and conclude that some weathering processes in Meridiani Planum and Gusev crater are better explained by late diagenetic water-rock interactions than by early diagenesis only. At Meridiani, the discovery of jarosite by MER-1 Opportunity indicates acidic aqueous activity, evaporation, and desiccation of rock materials. MER-based information, placed into the context of published data, point to local and limited aqueous activity during geologically recent times in Meridiani. Pre-Amazonian environmental changes (including important variations in the near-surface groundwater reservoirs, impact cratering, and global dust storms and other pervasive wind-related erosion) are too extreme for pulverulent jarosite to survive over extended time periods, and therefore we argue instead that jarosite deposits must have formed in a climatically more stable period. Any deposits of pre-existent concretionary jarosite surviving up to the Amazonian would not have reached completion in the highly saline and acidic brines occurring at Meridiani. MER-2 Spirit has also revealed evidence for local and limited Amazonian aqueous environmental conditions in Gusev crater, including chemical weathering leading to goethite and hematite precipitation, rock layering, and chemical enhancement of Cl, S, Br, and oxidized iron in rocks and soils. The estimated relative age of the impact crater materials in Gusev indicates that these processes have taken place during the last 2 billion years. We conclude that minor amounts of shallow acidic liquid water have been present on the surface of Mars at local scales during the Amazonian Period.  相似文献   

The Southern Westerlies during the last glacial maximum in PMIP2 simulations   总被引：1，自引：1，他引：0  

Maisa Rojas  Patricio Moreno  Masa Kageyama  Michel Crucifix  Chris Hewitt  Ayako Abe-Ouchi  Rumi Ohgaito  Esther C. Brady  Pandora Hope 《Climate Dynamics》2009,32(4):525-548

The Southern Hemisphere westerly winds are an important component of the climate system at hemispheric and global scales. Variations in their intensity and latitudinal position through an ice-age cycle have been proposed as important drivers of global climate change due to their influence on deep-ocean circulation and changes in atmospheric CO₂. The position, intensity, and associated climatology of the southern westerlies during the last glacial maximum (LGM), however, is still poorly understood from empirical and modelling standpoints. Here we analyse the behaviour of the southern westerlies during the LGM using four coupled ocean-atmosphere simulations carried out by the Palaeoclimate Modelling Intercomparison Project Phase 2 (PMIP2). We analysed the atmospheric circulation by direct inspection of the winds and by using a cyclone tracking software to indicate storm tracks. The models suggest that changes were most significant during winter and over the Pacific ocean. For this season and region, three out four models indicate decreased wind intensities at the near surface as well as in the upper troposphere. Although the LGM atmosphere is colder and the equator to pole surface temperature gradient generally increases, the tropospheric temperature gradients actually decrease, explaining the weaker circulation. We evaluated the atmospheric influence on the Southern Ocean by examining the effect of wind stress on the Ekman pumping. Again, three of the models indicate decreased upwelling in a latitudinal band over the Southern Ocean. All models indicate a drier LGM than at present with a clear decrease in precipitation south of 40°S over the oceans. We identify important differences in precipitation anomalies over the land masses at regional scale, including a drier climate over New Zealand and wetter over NW Patagonia.  相似文献   

Ostracods as tsunami tracers in Holocene sequences     

Francisco Ruiz  Manuel Abad  Joaquín Rodríguez Vidal  Manuel Pozo 《Quaternary Research》2010,73(1):130-239

This review analyses the ostracod record in Holocene tsunami deposits, using an overview of the 2004 Indian Ocean tsunami impact on its recent populations and the associated tsunamigenic deposits, together with results from numerous investigations of other Holocene sequences. Different features such as the variability of the local assemblages, population density, species diversity, age population structure (e.g., percentages of adults and juvenile stages) or taphonomical signatures suggest that these microorganisms may be included amongst the most promising tracers of these high-energy events in marshes, lakes, lagoons or shallow marine areas.  相似文献   

Identification and definition of primary and reworked tephra in Late Glacial and Holocene marine shelf sediments off North Iceland     

Esther Ruth Gudmundsdóttir  Jón Eiríksson  Gudrún Larsen 《第四纪科学杂志》2011,26(6):589-602

Nine tephra layers in marine sediment cores (MD99‐2271 and MD99‐2275) from the North Icelandic shelf, spanning the Late Glacial and the Holocene, have been investigated to evaluate the effectiveness of methods to detect tephra layers in marine environments, to pinpoint the stratigraphic level of the time signal the tephra layers provide, and to discriminate between primary and reworked tephra layers in a marine environment. These nine tephra layers are the Borrobol‐like tephra, Vedde Ash, Askja S tephra, Saksunarvatn ash, and Hekla 5, Hekla 4, Hekla 3, Hekla 1104 and V1477 tephras. The methods used were visual inspection, magnetic susceptibility, X‐ray photography, mineralogical counts, grain size and morphological measurements, and microprobe analysis. The results demonstrate that grain size measurements and mineralogical counts are the most effective methods to detect tephra layers in this environment, revealing all nine tephra layers in question. Definition of the tephra layers revealed a 2–3 cm diffuse upper boundary in eight of the nine tephra layers and 2–3 cm diffuse lower boundary in two tephra layers. Using a multi‐parameter approach the stratigraphic position of a tephra layer was determined where the rate of change of the parameters tested was the greatest compared with background values below the tephra. The first attempt to use grain morphology to distinguish between primary and reworked tephra in a marine environment suggests that this method can be effective in verifying whether a tephra layer is primary or reworked. Morphological measurements and microprobe analyses in combination with other methods can be used to identify primary tephra layers securely. The study shows that there is a need to apply a combination of methods to detect, define (the time signal) and discriminate between primary and reworked tephra in marine environments. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Bioaccumulation and histopathological effects of oil on a stony coral     

Esther C. Peters  Philip A. Meyers  Paul P. Yevich  Norman J. Blake 《Marine pollution bulletin》1981,12(10):333-339

Colonies of the shallow-water Caribbean coral Manicina areolata incorporated petroleum hydrocarbons into their tissues during exposure to water accommodated fractions of No. 2 fuel oil for three months. This contamination was not removed after depuration periods of up to two weeks. Although these corals remained alive, evidence of pathological responses was found which included impaired development of reproductive tissues, degeneration and loss of symbiotic zooxanthellae, and atrophy of mucous secretory cells and muscle bundles.  相似文献   

A Note on Second Species Solutions Generated from p–q Resonant Orbits     

Esther Barrabés  Gerard Gómez 《Celestial Mechanics and Dynamical Astronomy》2004,88(3):229-244

The first image under the flow of the restricted three-body problem of the p—q resonant strips — that appear in the study of the p—q resonant orbits — do not have, in general, intersection with the strip. In this paper we show some particular situations in which the above intersections exist for some very simple p—q resonant orbits which, at the same time, are periodic second species solutions.This revised version was published online in October 2005 with corrections to the Cover Date.  相似文献