The use of a non-lethal tool for evaluating toxicological hazard of organochlorine contaminants in Mediterranean cetaceans: new data 10 years after the first paper published in MPB     

Fossi MC  Marsili L  Neri G  Natoli A  Politi E  Panigada S 《Marine pollution bulletin》2003,46(8):972-982

In the Mediterranean Sea, top predators, and particularly cetacean odontocetes, accumulate high concentrations of organochlorine contaminants and toxic metals, incurring high toxicological risk. In this paper we investigate the use of the skin biopsies as a non-lethal tool for evaluating toxicological hazard of organochlorines in Mediterranean cetaceans, presenting new data 10 years after the paper published by Fossi and co-workers [Mar. Poll. Bull. 24 (9) (1992) 459] in which this new methodology was first presented. Some organochlorine compounds, now with worldwide distribution, are known as endocrine disrupting chemicals (EDCs). Here the unexplored hypothesis that Mediterranean cetaceans are potentially at risk due to organochlorines with endocrine disrupting capacity is investigated. High concentrations of DDT metabolites and PCB congeners (known as EDCs) were found in the different Mediterranean species (Stenella coeruleoalba, Delphinus delphis, Tursiops truncatus and Balaenoptera physalus). In this paper we also propose benzo(a)pyrene monooxygenase (BPMO) activity in marine mammal skin biopsies (non-lethal biomarker) as a potential indicator of exposure to organochlorines, with special reference to the compounds with endocrine disrupting capacity. A statistically significant correlation was found between BPMO activity and organochlorine levels (DDTs, pp(')DDT, op(')DDT, PCBs and PCB99) in skin biopsies of males of B. physalus. Moreover a statistical correlation was also found between BPMO activity and DDT levels in skin biopsies of the endangered Mediterranean population of D. delphis. These results suggest that BPMO induction may be an early sign of exposure to organochlorine EDCs and can be used for periodic monitoring of Mediterranean marine mammal toxicological status.  相似文献   

Uncertainty Estimate in Resources Assessment: A Geostatistical Contribution   总被引：2，自引：0，他引：2  

de Souza  Luis Eduardo  Costa  João Felipe C. L.  Koppe  Jair C. 《Natural Resources Research》2004,13(1):1-15

For many decades the mining industry regarded resources/reserves estimation and classification as a mere calculation requiring basic mathematical and geological knowledge. Most methods were based on geometrical procedures and spatial data distribution. Therefore, uncertainty associated with tonnages and grades either were ignored or mishandled, although various mining codes require a measure of confidence in the values reported. Traditional methods fail in reporting the level of confidence in the quantities and grades. Conversely, kriging is known to provide the best estimate and its associated variance. Among kriging methods, Ordinary Kriging (OK) probably is the most widely used one for mineral resource/reserve estimation, mainly because of its robustness and its facility in uncertainty assessment by using the kriging variance. It also is known that OK variance is unable to recognize local data variability, an important issue when heterogeneous mineral deposits with higher and poorer grade zones are being evaluated. Altenatively, stochastic simulation are used to build local or global uncertainty about a geological attribute respecting its statistical moments. This study investigates methods capable of incorporating uncertainty to the estimates of resources and reserves via OK and sequential gaussian and sequential indicator simulation The results showed that for the type of mineralization studied all methods classified the tonnages similarly. The methods are illustrated using an exploration drill hole data sets from a large Brazilian coal deposit.  相似文献   

Rapid morphological changes at the summit of an active volcano: reappraisal of the poorly documented 1964 eruption of Mount Etna (Italy)     

Boris Behncke  Marco Neri  Giovanni Sturiale   《Geomorphology》2004,63(3-4):203-218

While the eruptive record of Mount Etna is reasonably complete for the past 400 years, the activity of the early and late 1960s, which took place at the summit, is poorly documented in the scientific literature. From 1955 to 1971, the Central and Northeast Craters were the sites of long-lived mild Strombolian and effusive activity, and numerous brief episodes of vigorous eruptive activity, which led to repeated overflows of lava onto the external flanks of the volcano. A reconstruction of the sequence of the more important of these events based on research in largely obscure and nearly inaccessible sources permits a better understanding of the eruption dynamics and rough estimates of erupted volumes and of the changes to the morphology of the summit area. During the first half of 1964, the activity culminated in a series of highly dynamic events at the Central Crater including the opening of a fissure on the E flank of the central summit cone, lava fountains, voluminous tephra emission, prolonged strong activity with continuous lava overflows, and growth of large pyroclastic intracrater cones. Among the most notable processes during this eruption was the breaching of a section of the crater wall, which was caused by lateral pressure of lava ponding within the crater. Comparison with the apparently similar summit activity of 1999 allows us to state that (a) lava overflows from large pit craters at the summit are often accompanied by breaching of the crater walls, which represents a significant hazard to nearby observers, and that (b) eruptive activity in 1999 was much more complex and voluminous than in 1964. For 1960s standards however, the 1964 activity was the most important summit eruption in terms of intensity and output rates for about 100 years, causing profound changes to the summit morphology and obliterating definitively the former Central Crater.  相似文献   

Petrogenesis of the Eocene and Mio–Pliocene alkaline basaltic magmatism in Meseta Chile Chico, southern Patagonia, Chile: Evidence for the participation of two slab windows     

Felipe Espinoza  Diego Morata  Ewan Pelleter  Ren  C. Maury  Manuel Su  rez  Yves Lagabrielle  Mireille Polv    Herv  Bellon  Joseph Cotten  Rita De la Cruz  Christelle Guivel 《Lithos》2005,82(3-4):315-343

The Meseta Chile Chico (MCC, 46.4°S) is the westernmost exposure of Eocene (lower basaltic sequence, LBS; 55–40 Ma, K–Ar ages) and Mio–Pliocene (upper basaltic sequence, UBS; 16–4 Ma, K–Ar ages) flood basalt volcanism in Patagonia. The MCC is located south of the Lago General Carrera-Buenos Aires (LGCBA), southeast from the present day Chile Triple Junction (CTJ), east of the actual volcanic gap between Southern South Volcanic Zone and Austral Volcanic Zone (SSVZ and AVZ, respectively) and just above the inferred location of the South Chile Ridge segment subducted at 6 Ma (SCR-1). Erupted products consist of mainly ne-normative olivine basalt with minor hy-normative tholeiites basalt, trachybasalt and basanite. MCC lavas are alkaline (42.7–53.1 wt.% SiO₂, 3–8 wt.% Na₂O+K₂O) and relatively primitive (Ni: 133–360 ppm, Cr: 161–193 ppm, Co: 35–72 ppm, 4–16.5 MgO wt.%). They have a marked OIB-like signature, as shown by their isotopic compositions (⁸⁷Sr/⁸⁶Sr_o=0.70311–0.70414 and εNd=+4.7–+5.1) and their incompatible trace elements ratios (Ba/La=10–20, La/Nb=0.46–1.09, Ce/Pb=15.52–27.5, Sr/La<25), reflecting deep mantle origin. UBS-primitive lavas have characteristics similar to those of the Eocene LBS basalts, while UBS-intermediate lavas show geochemical imprints (La/Nb>1, Sr/La>25, low Ce/Pb, Nb/U) compatible with contamination by arc/slab-derived and/or crustal components. We propose that the genesis and extrusion of magmas is related to the opening of two slab windows due to the subduction of two active ridge segments beneath Patagonia during Eocene and Mio–Pliocene.  相似文献   

On the numerical simulation of waterflooding of heterogeneous petroleum reservoirs     

Jim Douglas Jr.  Frederico Furtado  Felipe Pereira 《Computational Geosciences》1997,1(2):155-190

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A parallelizable method for two‐phase flows in naturally‐fractured reservoirs     

Jim Douglas Jr.  Felipe Pereira  Li‐Ming Yeh 《Computational Geosciences》1997,1(3-4):333-368

A parallelizable, semi‐implicit numerical method is proposed for the study of naturally‐fractured reservoir systems. It has proved to be computationally efficient in producing accurate numerical solutions for the dual‐porosity model for immiscible, two‐phase flow in such reservoirs. The method combines hybridized mixed finite elements, a new version of the modified method of characteristics, a sophisticated operator‐splitting procedure for separating the pressure calculation in the fractures from that of the saturation, another operator splitting to handle the interaction of the matrix blocks and the fractures, and domain decomposition iterative procedures for both the pressure and the saturation. It permits moderately long time steps for the pressure and the saturation in the fractures and matrix blocks by using short, inexpensive microsteps to treat the transport portion of the saturation equation in the fractures. This paper is devoted to the formulation of the method and a discussion of numerical results for five‐spot and vertical cross‐section examples.  相似文献   

An analysis of the earthquake time series at Mount St. Helens, Washington, in the framework of recent volcanic activity     

G. Neri  S.D. Malone 《Journal of Volcanology and Geothermal Research》1989,38(3-4)

The analysis of the earthquake time distribution at Mount St. Helens reveals a good correlation between the physical state of the volcano and statistical parameters of earthquake sequence. There are three main seismic phases in the whole 1980–1986 period. The first one precedes the main eruption of May 18, 1980. It begins with a sudden increase of the seismicity level in late March and continues with an Utsu (1961) type decay of the seismic occurrence rate, characterized by a small value of the decay coefficient, β. The second phase lasts from the cataclysmic eruption on May 18, 1980 until the continuous dome building episode in 1983 and is characterized by a very slow exponential increase of the background level of seismicity. The third phase covers the remaining part of the sample and is characterized by a stationary earthquake clustering process episodically interrupted by peaks of activity related to eruptions. The trends in seismic occurrence rate within each phase, as well as the statistical parameter variations at each transition, are analyzed and discussed in the framework of volcanic activity. This leads to the conclusion that statistical techniques may give a significant contribution in understanding changes in volcanic processes such as those at Mount St. Helens.  相似文献   

The non‐stationary cross‐correlation coefficients in the seismic analysis of MDOF structural systems     

Giovanni Falsone  Fabio Neri 《地震工程与结构动力学》2003,32(14):2289-2299

A method concerning the evaluation, in a very compact form, of the non‐stationary modal cross‐correlation coefficients of MDOF structural systems subjected to seismic excitations is presented. It is available both in the case when the excitation is considered as a white‐noise process and when it is considered as a filtered process. The evaluation of these coefficients is required when a transient seismic analysis is performed by the use of the modal response spectrum approach. This is necessary when the strong‐motion phase of the earthquake is significantly short with respect to the fundamental period of the structure. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   

Structure of the Mérida Andes, Venezuela: relations with the South America–Caribbean geodynamic interaction     

Felipe E. Audemard  Franck A. Audemard   《Tectonophysics》2002,345(1-4)

For over 50 years, several models based on diverse geologic concepts and variable quality of data have been proposed to explain the major structure and history of the Mérida Andes (MA), in western Venezuela. Lately, this chain growth and associated flexural basins deepening have been related to incipient type-A subductions of either polarity, accounting for the across-chain asymmetry. However, these recent models have not well integrated the present tectonically active setting driven by neighboring major plate interactions. At present, this chain exhibits ongoing strain partitioning where cumulative right-lateral slip along chain axis is as much as half of, or about the same, as the transverse shortening since late Miocene, thus implying that the NNE-directed Maracaibo block extrusion with respect to the South America (SA) plate is not a secondary feature. Consequently, this paper discusses some limitations exhibited by the SE-directed continental subduction models—Maracaibo crust underthrusting the Mérida Andes—in the light of available geological and geophysical data. Besides, it is herein proposed that the Mérida Andes structuration is related to a NW-directed, gently dipping, incipient type-A subduction, where chain growth and evolution are similar to those of a sedimentary accretionary wedge (i.e., Barbados), but at crustal scale and with ongoing strain partitioning. This continental subduction is the SE portion of a major orogenic float that also comprises the Perijá range and the Santa Marta block.  相似文献   

Decadal-scale changes in suspended wood after riparian recruitment in managed stands in headwater streams of coastal British Columbia,Canada     

Felipe Rossetti de Paula  John S. Richardson  Alex C.Y. Yeung  Stephen J. Mitchell  Devesh Bahuguna 《地球表面变化过程与地形》2020,45(9):1974-1989

Large wood (LW) affects several ecological and hydrogeomorphic processes in streams. The main source of LW is riparian trees falling inside channels. However, in confined valley floors, falling trees are more likely to be suspended above the channel. Eventually, these suspended trees will decompose and break to finally fall into the channel to better provide functions for streams. We evaluated changes in wood decay, length, diameter, and suspended status (suspended or non-suspended) 17 years post-harvest and nine years after the first sampling occurred in 2006 in 12 headwater streams of coastal British Columbia, Canada. We also evaluated whether changes differed among riparian management treatments (no-harvest buffers of 10 and 30 m in width, thinning, and unharvested reference sites), and identified the factors affecting wood changes and suspended status. Wood pieces advanced in decay, became shorter, and 34% of them (n = 108) changed status from suspended to non-suspended. Non-suspended wood pieces were more decayed and shorter than suspended wood. Suspended wood was longer, thicker, less decayed, and represented 46.5% (n = 147) of the wood sampled in 2006. Our findings revealed limited influences of riparian management on many aspects of wood changes considered in this study. Changes in wood characteristics were more likely for pieces that were smaller in diameter, longer, and suspended closer to the water. The transition from suspended to non-suspended LW can be a long-term process that can increase wood residence time and reduce LW in-stream functions particularly in confined stream valleys. The suspended stage is also an important mechanism underlying time lags in stream ecosystem responses to riparian tree fall. © 2020 John Wiley & Sons, Ltd.  相似文献