Assessment of alternative adsorption models and global sensitivity analysis to characterize hexavalent chromium loss from soil to surface runoff          下载免费PDF全文

Chuan‐An Xia  Juxiu Tong  Bill X. Hu  Xiujie Wu  Alberto Guadagnini 《水文研究》2018,32(20):3140-3157

We investigate our ability to assess transfer of hexavalent chromium, Cr(VI), from the soil to surface runoff by considering the effect of coupling diverse adsorption models with a two‐layer solute transfer model. Our analyses are grounded on a set of two experiments associated with soils characterized by diverse particle size distributions. Our study is motivated by the observation that Cr(VI) is receiving much attention for the assessment of environmental risks due to its high solubility, mobility, and toxicological significance. Adsorption of Cr(VI) is considered to be at equilibrium in the mixing layer under our experimental conditions. Four adsorption models, that is, the Langmuir, Freundlich, Temkin, and linear models, constitute our set of alternative (competing) mathematical formulations. Experimental results reveal that the soil samples characterized by the finest grain sizes are associated with the highest release of Cr(VI) to runoff. We compare the relative abilities of the four models to interpret experimental results through maximum likelihood model calibration and four model identification criteria (i.e., the Akaike information criteria [AIC and AIC_C] and the Bayesian and Kashyap information criteria). Our study results enable us to rank the tested models on the basis of a set of posterior weights assigned to each of them. A classical variance‐based global sensitivity analysis is then performed to assess the relative importance of the uncertain parameters associated with each of the models considered, within subregions of the parameter space. In this context, the modelling strategy resulting from coupling the Langmuir isotherm with a two‐layer solute transfer model is then evaluated as the most skilful for the overall interpretation of both sets of experiments. Our results document that (a) the depth of the mixing layer is the most influential factor for all models tested, with the exception of the Freundlich isotherm, and (b) the total sensitivity of the adsorption parameters varies in time, with a trend to increase as time progresses for all of the models. These results suggest that adsorption has a significant effect on the uncertainty associated with the release of Cr(VI) from the soil to the surface runoff component.  相似文献   

ANALYSIS OF DRIVING FORCES ON THE CHANGE OF HISTORICAL FARMLAND USE IN SHANDONG PROVINCE DURING THE QING DYNASTY (1644-1911)     

ZHANG Xue-in  GE Quan-heng  ZHENG Jing-un 《中国地理科学(英文版)》2003,13(3)

1INTRODUCTIONTheIGBP-IHDP(InternationalGeosphere-BiosphereProgramme,andInternationalHumanDimensionPro-gramme)jointproject—LUCC(landuse/coverchange)isaninterdisciplinaryprogramdesignedtoimprovetheunderstandingofthedynamicsofland-useandland-coverchangeasinputstoandconsequencesofglobalenvironmentalchangeandsustainabledevelopment(CHARLOTTE,2002).Inparticularthedifferentbio-geochemicalmodeling(e.g.theglobalcarboncycle)ac-tivitiesandcomparativestudies,suchasthoseconduct-edbyIGBP-G…  相似文献   

CHARACTERIZATION OF LACTATE DEHYDROGENASE ISOZYME PATTERN AND MORPHOLOGY OF THREE MARINE FISH CELL LINES     

郭华荣  张士璀  李红岩  童裳亮  相建海 《中国海洋湖沼学报》2002,20(3):226-231

Three continuous marine fish cell lines of FG (i. e., Hounder Gill) from flounder (Paralichthys olivaceus) gill, SPH (i. e. , Sea Perch Heart) from sea perch (Lateolabrax japonicus) heart and RSBF (i.e., Red Sea Bream Fin) from red sea bream (Pagrosomus major) fin, were characterized by lactate dehydrogenase (LDH) isozyme and morphological analysis. The LDH isozyme patterns of these three cell lines and their corresponding tissues of origin were investigated and compared. The results showed: (1) No difference was found in the LDH isozyme patterns of FG and flounder gill tissue. However, the LDH isozyme patterns of SPH and RSBF were significantly different from their corresponding tissues of origin; (2) LDH isozyme patterns of FG, SPH and RSBF were markedly different from each other and could serve as genetic markers for species identification and detection of cross contamination. Morphological change analysis of these three cell lines in comparison to their original tissues indicated that FG cells still appeared epithelioid without morphological transformation. However, morphological changes were found in SPH and RSBF compared to their original tissues. Therefore, the cellular morphology was still plastic in the relatively stable culture conditions, and it was possible that change of LDH patterns wasrelated to morphological changes of fish cells in vitro.  相似文献   

射电源0420—014,1334—127和2345—167中的视超光速运动     

沈志强  万同山  洪晓瑜 《中国天文和天体物理学报》1997,(1)

本文叙述南天区 5GHzVLBI普查中新发现的视超光速射电源 ,0 4 2 0— 0 1 4,1 334—1 2 7和 2 345— 1 67,这些结果尚待进一步的观测加以证实  相似文献   

流体包裹体成分测定的低温相变和显微拉曼光谱分析技术研究进展   总被引：2，自引：1，他引：1  

葛云锦  陈勇  周瑶琪 《岩矿测试》2008,27(3):207-210

论述了包裹体低温分析技术的原理以及进展。传统的流体包裹体低温分析技术是以显微冷冻测温测定无机盐体系为主,目前已发展到应用低温原位拉曼光谱技术对包裹体中的阳离子和阴离子进行定量-半定量分析。油气包裹体原位低温分析技术也取得了较大的突破,对不同成分油气包裹体低温下的相变过程取得了一定的认识,据此对油气包裹体进行分类,推测其主要成分,为油气包裹体计算提供基础参数。  相似文献   

徐州土壤多环芳烃的环境地球化学迁移特征   总被引：1，自引：1，他引：0  

葛晓立  焦杏春  袁欣  李奇  罗松光  孙玮琳 《岩矿测试》2008,27(6):409-412

选择江苏徐州黄棕壤进行不同深度层位多环芳烃含量的定量分析,研究并探讨了多环芳烃在土壤深度剖面中的地球化学迁移特征。研究结果显示,多环芳烃在徐州土壤剖面中主要集中在地表0~20 cm内。其中低环多环芳烃化合物的迁移能力较强,4~6环等高环化合物相对较难迁移,主要残留于地表生态系统环境中。  相似文献   

人工合成烃类包裹体研究进展   总被引：4，自引：0，他引：4  

陈勇  葛云锦 《地质论评》2008,54(6):807-813

人工合成烃类包裹体不仅可以作为分析仪器校正的标样,还可以增进人们对烃类包裹体形成机制和水—岩作用机理的认识。人工合成包裹体的方法主要有三种：人工晶体生长法、焊封石英管法和金刚石压腔法,其中利用愈合人工石英(水晶)单晶裂隙合成流体包裹体技术已成为标准的合成技术。目前人工合成烃类包裹体主要利用晶体生长法合成,包括高温高压利用石英（或方解石）晶体生长愈合裂缝形成流体包裹体和低温下采用过饱和溶液重结晶形成流体包裹体。由于高温高压条件下烃类可能发生裂解,母液保真是成功实现人工合成烃类包裹体的重要前提条件。国外在人工合成烃类包裹体研究方面已经取得了一些重要的认识,但远不及人工合成无机体系流体包裹体研究那样系统和完善。国内关于人工合成烃类包裹体研究尚处于起步阶段,迫切需要开展这方面的研究工作。  相似文献   

青藏铁路多年冻土区保温护道路基温度场数值模拟研究   总被引：1，自引：0，他引：1  

葛建军 《冰川冻土》2008,30(2):274-279

多年冻土区路基铺设保温护道的目的在于削弱边坡热侵蚀作用对路基下多年冻土温度状况的影响,防止多年冻土上限特别是阳坡侧冻土上限下降,减少人为活动对路堤坡脚及附近天然地表的破坏;防止路侧地表积水渗入基底;对边坡产生反压,防止路肩滑塌,以保证路基的稳定.结合试验工程监测资料,采用数值模拟方法分析了青藏铁路多年冻土区路基保温护道的效果,结果表明:保温护道并没有达到设计的目的,由于路基和护道几何形状对空气对流和太阳辐射的影响,不仅达不到保护冻土地基的目的,反而加大阴阳坡温度差异,导致路基病害的发生.  相似文献   

浅论双重管理体制下无锡市水文站网规划设计     

戈礼宾 《水文》2008,28(4)

无锡市机构编制委员会在江苏省率先正式批复江苏省水文水资源勘测局无锡分局增挂“无锡市水文局”牌子,实行省市双重领导,以省为主管理体制,并明确了无锡市水文局为地方服务的七项职责。无锡水文在新的历史发展时期下,水文站网规划设计应该紧紧围绕无锡水利、服务无锡水利、融入无锡水利,才能发挥水文体制省市双重领导、以省为主管理的最大效益。  相似文献   

电子探针Th-U-Pb微区测年方法及其在铀矿地质研究中的应用前景   总被引：6，自引：0，他引：6  

葛祥坤 《铀矿地质》2008,24(3):175-180

电子探针Th-U-Pb微区测年方法是新近发展起来的一项测年技术.该技术以放射性核素的衰变理论为基础,在一定条件下通过电子探针测量矿物中的Th、U、Pb含量,经过数据处理,最终计算出矿物的年龄.由于该项技术具有省时、费用低、不破坏样品等优点,现已广泛地应用于独居石、锆石的年龄研究中.在晶质铀矿年龄研究中的应用仅有零星报道,但由于该技术的高空间分辨率,将对不同产出状态的微小晶质铀矿颗粒的定年研究大有裨益.  相似文献