In Situ Determination of First‐Row Transition Metal,Ga and Ge Abundances in Geological Materials via Medium‐Resolution LA‐ICP‐MS     

Ricardo Arevalo Jr  William F. McDonough  Philip M. Piccoli 《Geostandards and Geoanalytical Research》2011,35(2):253-273

An in situ, medium‐resolution LA‐ICP‐MS method was developed to measure the abundances of the first‐row transition metals, Ga and Ge in a suite of geological materials, namely the MPI‐DING reference glasses. The analytical protocol established here hinged on maximising the ablation rate of the ultraviolet (UV) laser system and the sensitivity of the ICP‐MS, as well minimising the production of diatomic oxides and argides, which serve as the dominant sources of isobaric interferences. Non‐spectral matrix effects were accounted for by using multiple external calibrators, including NIST SRM 610 and the USGS basaltic glasses BHVO‐2G, BIR‐1G and BCR‐2G, and utilising ⁴³Ca as an internal standard. Analyses of the MPI‐DING reference glasses, which represent geological matrices ranging from basaltic to rhyolitic in composition, included measurements of concentrations as low as < 10⁰ μg g^?1 and as high as > 10⁴ μg g^?1. The new data reported here were found to statistically correlate with the ‘preferred’ reference values for these materials at the 95% confidence level, though with significantly better precision, typically on the order of ≤ 3% (2s_m). This analytical method may be extended to any matrix‐matched geological sample, particularly oceanic basalts, silicate minerals and meteoritic materials.  相似文献   

Regional decoupling between NW Atlantic barnacle recruit and adult density is related to changes in pelagic food supply and benthic disturbance     

Stephen W.B. Cole  Ricardo A. Scrosati  Jamie C. Tam  Andrea V. Sussmann 《Journal of Sea Research》2011,65(1):33-37

We investigated the regional variation in barnacle (Semibalanus balanoides) recruit and adult abundance on the NW Atlantic coast. At the end of the recruitment season (June–July), we sampled wave-exposed rocky intertidal sites in two regions on the open Atlantic coast (Maine, AM, and Nova Scotia, AN) and in two regions on the Gulf of St. Lawrence coast (Northumberland Strait, GN, and Cape Breton Island, GC). Recruit density was highest in the southernmost region (AM), followed by GN and, then, by AN and GC. Regional values of nearshore primary productivity (satellite data of chlorophyll-a concentration, a surrogate for phytoplankton abundance) were highest for AM and GN, suggesting that food supply (barnacles are filter feeders) is an important factor determining regional recruitment patterns. Adult barnacle density was regionally decoupled from recruit density. Adults occurred in very low abundances on the Gulf of St. Lawrence coast (GN and GC) and were relatively abundant on the Atlantic coast (AM and AN), although always in much lower abundances than recruits. The low adult densities on the Gulf of St. Lawrence coast seem to result mainly from intense ice scour, as this coast freezes extensively every winter, as opposed to the ice-free Atlantic coast. Ice scour thus appears to override regional recruitment differences in determining adult density. Therefore, our data suggest that both pelagic food supply and benthic disturbance contribute to setting regional patterns in barnacle population structure on the NW Atlantic coast.  相似文献   

Depositional processes on oceanic island shelves – Evidence from storm‐generated Neogene deposits from the mid‐North Atlantic     

Ricardo P. Meireles  Rui Quartau  Ricardo S. Ramalho  Ana C. Rebelo  José Madeira  Vittorio Zanon  Sérgio P. Ávila 《Sedimentology》2013,60(7):1769-1785

Oceanic islands – such as the Azores in the mid‐North Atlantic – are periodically exposed to large storms that often remobilize and transport marine sediments along coastlines, and into deeper environments. Such disruptive events create deposits – denominated tempestites – whose characteristics reflect the highly dynamic environment in which they were formed. Tempestites from oceanic islands, however, are seldom described in the literature and little is known about storm‐related sediment dynamics affecting oceanic island shelves. Therefore, the geological record of tempestite deposits at oceanic islands can provide invaluable information on the processes of sediment remobilization, transport and deposition taking place on insular shelves during and after major storms. In Santa Maria Island (Azores), a sequence of Neogene tempestite deposits was incorporated in the island edifice by the ongoing volcanic activity (thus preserved) and later exposed through uplift and erosion. Because it was overlain by a contemporary coastal lava delta, the water depth at the time of deposition could be inferred, constituting an excellent case‐study to gain insight on the still enigmatic processes of insular shelf deposition. Sedimentological, palaeontological, petrographic and palaeo‐water depth information allowed the reconstruction of the depositional environment of these sediments. The sequence typifies the characteristics of a tempestite (or successive tempestites) formed at ca 50 m depth, in a steep, energetic open insular shelf, and with evidence for massive sediment remobilization from the nearshore to the middle or outer shelf. The authors claim that cross‐shelf transport induced by storm events is the main process of sediment deposition acting on steep and narrow shelves subjected to high‐energetic environments, such as the insular shelves of open‐sea volcanic islands.  相似文献   

In situ U/Pb dating of impact‐produced zircons from the Vargeão Dome (Southern Brazil)     

Anne Nédélec  Jean‐Louis Paquette  Elder Yokoyama  Ricardo I. F. Trindade  Thierry Aigouy  David Baratoux 《Meteoritics & planetary science》2013,48(3):420-431

The Vargeão impact structure was formed in the Serra Geral basaltic and rhyodacitic to rhyolitic lava flows of southern Brazil, that belong to the Paraná‐Etendeka large igneous province. The Chapecó‐type rhyodacites contain small baddeleyite crystals recently dated at 134.3 (±0.8) Ma, which is regarded as the age of this acid volcanism coeval to the flood basalt eruption. Inside the impact structure, a brecciated rhyodacitic sample displays fine veinlets containing numerous lithic fragments in a former melt. This impact breccia contains newly formed zircons, either in the veins or at the contact between a vein and the volcanic matrix. The zircons are 10–50 μm in length, clear and nearly unzoned. In situ laser‐ablation dating of the zircons provides a concordant Early Aptian age of 123.0 ± 1.4 Ma that is regarded as the age of the impact event. As in situ age determination ensures the best possible selection of the analyzed mineral grains, the methodology employed in this study also represents a promising method for dating other impact structures.  相似文献   

Seasonal Diet Shifts and Overlap Between Two Sympatric Catfishes in an Estuarine Nursery     

David Valença Dantas  Mario Barletta  Jonas de Assis Almeida Ramos  André Ricardo Araújo Lima  Monica Ferreira da Costa 《Estuaries and Coasts》2013,36(2):237-256

This study describes the seasonal feeding habits of different size classes of Cathorops spixii and Cathorops agassizii along an estuarine ecocline and the food overlap when different size classes occur together. These species were essentially zoobenthivorous, feeding mainly on Polychaeta Nereis sp., Copepoda Pseudodiaptomus acutus, Ostracoda Asterope sp., Gastropoda: Littorinidae, and Bivalvia Mytilus sp. and Anomalocardia brasiliana. However, during their life cycle and between different habitats and seasons, their trophic guild can change to zooplanktivore. The competition for resources was observed among C. spixii and C. agassizii, but was significantly reduced due to the seasonal diference in habitat use by different ontogenetic phases in the main channel of the estuary. The food niche separation was strongly influenced by environmental fluctuations, principally of salinity, resulting from rainfall and river inflow. High abundance of some preys, such as P. acutus (all estuary), Asterope sp. (upper and middle estuary), and Littorinidae (upper and lower estuary), could influence the significant diet overlap, principally during the rainy season, and call for more detailed studies of the benthic community structure. Moreover, dietary overlap was observed mainly between smaller sizes (intraspecific and/or interspecific) or between corresponding ontogenetic phases (interspecific), suggesting some differentiation in the diet in relation to the size class. Differences in prey type and size between the different ontogenetic phases of these ariids, principally among juveniles and adults, could be related to the size of the mouth, since adults are able to successfully capture larger preys or larger quantities of particular items.  相似文献   

Water quality and risk assessment of dug wells: a case study for a poor community in the city of São Paulo, Brazil     

Alexandra V. Suhogusoff  Ricardo Hirata  Luiz Carlos K. M. Ferrari 《Environmental Earth Sciences》2013,68(3):899-910

Sparsely populated areas, or peripheral communities commonly lack access to a public water supply and sewerage systems. The inhabitants of these areas must make use of excavated wells to provide their water needs, and cesspits for domestic wastewater disposal. These on-site sanitation systems can release pathogens and nutrients into shallow groundwater. These poor communities urgently require cheap and efficient techniques for the detection of sanitary conditions, in order to prevent contamination of the water resources supplied by dug wells. The sanitary risk assessment methodology, applied in an irregular settlement south of the city of São Paulo, was based on a questionnaire with yes/no questions (risk factors), which allowed the identification of problems related to the well construction and operation, and the presence of potential contamination sources in its vicinity. These risk factors were compared against nitrate and bacterial analysis using the clustering statistical method, to verify the relationship between contamination and certain aspects surveyed in the questionnaire. Questions that were more related to contaminated wells were those concerning the presence of cover and its integrity; gaps between mouth and cover; the surrounding pavement and presence of ground irregularities; infiltration in the well casing; water-suspended materials; and proximity to contamination sources. Contamination models based on variograms allowed to observe that bacterial contamination presented a strong localized component, which was associated frequently with the way residents handled the wells, whereas nitrate contamination was related more to a regional (spatial) component; that is, the distance between wells and cesspits.  相似文献   

Evaluation of pile foundation response to lateral spreading   总被引：7，自引：0，他引：7  

Tarek Abdoun  Ricardo Dobry 《Soil Dynamics and Earthquake Engineering》2002,22(9-12):1051-1058

The effects of liquefaction on deep foundations are very damaging and costly, and they keep recurring in many earthquakes. The first part of the paper reviews the field experience of deep foundations affected by liquefaction during earthquakes in the last few decades, as well as the main lessons learned. The second part of the paper presents results of physical modeling of deep foundations in the presence of liquefaction conducted by the authors and others at the 100g-ton RPI centrifuge. In the last decade centrifuge modeling has been identified as a key tool to identify and quantify mechanisms, calibrate analyses and evaluate retrofitting strategies for pile foundations. Results are presented of centrifuge models of instrumented pile foundations subjected to lateral spreading, including single pile and pile groups, 2- and 3-layer soil profiles, mass and stiffening elements above ground to incorporate the effect of the superstructure, and evaluation of proposed retrofitting strategies. Interpretations of these centrifuge experiments and their relation to field observations and soil properties.  相似文献   

A frequency criterion for optimal node selection in smoothing with cubic splines     

Jörg Schleicher  Ricardo Biloti 《Geophysical Prospecting》2008,56(2):229-237

When smoothing a function with high‐frequency noise by means of optimal cubic splines, it is often not clear how to choose the number of nodes. The more nodes are used, the closer the smoothed function will follow the noisy one. In this work, we show that more nodes mean a better approximation of Fourier coefficients for higher frequencies. Thus, the number of nodes can be determined by specifying a frequency up to which all Fourier coefficients must be preserved and increasing the number of nodes until this criterion is met. A comparison of the corresponding smoothing results with those obtained by filtering using moving average and moving median filters of corresponding length and a low pass with corresponding high‐cut frequency shows that optimal cubic splines yield better results as they preserve not only the desired low‐frequency band but also important high‐frequency characteristics.  相似文献   

Temporal and spatial changes of total and labile metal concentration in the surface sediments of the Vigo Ria (NW Iberian Peninsula): influence of anthropogenic sources     

Prego R  Filgueiras AV  Santos-Echeandía J 《Marine pollution bulletin》2008,56(5):1031-1042

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Effects of the 'Prestige' oil spill on macroalgal assemblages: large-scale comparison     

Lobón CM  Fernández C  Arrontes J  Rico JM  Acuña JL  Anadón R  Monteoliva JA 《Marine pollution bulletin》2008,56(6):1192-1200

An assessment of the effects of the 'Prestige' oil spill on intertidal, macroalgal assemblages was carried out comparing abundance data obtained before and after the spill. Four zones in the North and Northwest coast of Spain were sampled, one of them located at the immediate vicinity of the spill, the zone most heavily oiled. Macroalgal assemblages had similar structure between years. Neither critical decrease in abundance of the dominant macroalgae, nor increase in opportunistic species were found. Some differences in abundance were observed, but they did not show any pattern, being more likely the result of the natural variability of the assemblage. Extensive, but not intense fuel deposition on the shores and a limited use of aggressive cleanup methods are suggested as possible causes for the lack of the effects in these assemblages after the 'Prestige' oil spill.  相似文献