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111.
The Apuseni–Banat–Timok–Srednogorie magmatic–metallogenic belt (ABTS belt), forms a substantial metallogenic province in the Balkan-South Carpathian system in southeastern Europe. The belt hosts porphyry, skarn, and epithermal deposits mined since pre-Roman times. Generally, the deposits, prospects, and occurrences within the belt are linked to magmatic centers of calc-alkaline affinity. Fifty-one rhenium-osmium (Re–Os) ages and Re concentration data for molybdenites define systematic geochronologic trends and constrain the geochemical-metallogenic evolution of the belt in space and time. From these data and additional existing geologic-geochemical data, a general tectonic history for the belt is proposed. Mineralization ages in Apuseni-Banat, Timok, and Panagyurishte (the central district of the larger E–W Srednogorie Zone) range from 72–83, 81–88, and 87–92 Ma, respectively, and clearly document increasing age from the northwestern districts to the southeastern districts. Further, Re–Os ages suggest rapidly migrating pulses of Late Cretaceous magmatic–hydrothermal activity with construction of deposits in ~1 m.y., districts in ~10 m.y., and the entire 1,500 km belt in ~20 m.y. Ages in both Timok and Panagyurishte show systematic younging, while deposit ages in Banat and Apuseni are less systematic reflecting a restricted evolution of the tectonic system. Systematic differences are also observed for molybdenite Re concentrations on the belt scale. Re concentrations generally range from hundreds to thousands of parts per million, typical of subduction-related Cu–Au–Mo–(PGE) porphyry systems associated with the generation of juvenile crust. The geochronologic and geochemical trends are compatible with proposed steepening of subducting oceanic slab and relaxation of upper continental plate compression. Resulting influx of sub-continental mantle lithosphere (SCML) and asthenosphere provide a fertile metal source and heat, while the subducting slab contributes connate and mineral dehydration fluids, which facilitate partial melting and metal leaching of SCML and asthenosphere. Cu–Au–Mo–(PGE) porphyry deposits may develop where melts are trapped at shallow crustal levels, often with associated volcanism and epithermal-style deposits (South Banat, Timok, and Panagyurishte). Mo–Fe–Pb–Zn skarn deposits may develop where felsic melts are trapped adjacent to Mesozoic limestones at moderate crustal levels (North Banat and Apuseni). Systematic spatial variations in deposit style, commodity enrichment, Re–Os ages, and Re concentrations support specific tectonic processes that led to ore formation. In a post-collisional setting, subduction of Vardar oceanic crust may have stalled, causing slab steepening and rollback. The slab rollback relaxes compression, facilitating and enhancing orogenic collapse of previously thickened Balkan-South Carpathian crust. The progression of coupled rollback-orogenic collapse is evidenced by the width of Late Cretaceous extensional basins and northward younging of Re–Os ages, from Panagyurishte (~60 km; 92–87 Ma) to Timok (~20 km; 88–81 Ma) to Apuseni-Banat (~5 km; 83–72 Ma). Generation of a well-endowed mineral belt, such as the ABTS, requires a temporally and spatially restricted window of magmatic–hydrothermal activity. This window is quickly opened as upper plate compression relaxes, thereby inducing melt generation and ingress of melt to higher crustal levels. The window is just as quickly closed as upper plate compression is reinstated. The transient tectonic state responsible for economic mineralization in the ABTS belt may be a paleo-analogue to transient intervals in the present subduction tectonics of SE Asia where much mineral wealth has been created in the last few million years.  相似文献   
112.
Middle Paleozoic to Middle Jurassic terrane assemblies in the Klamaths and Sierran Foothills consist of mafic–ultramafic complexes + fine‐grained terrigenous strata derived from previously accreted continental‐margin belts. Sutured oceanic terranes reflect c. 230 Myr of margin‐parallel slip involving chiefly transtension and transpression. Quartzofeldspathic clastic rocks and blueschists ± eclogites are very rare. Little devolatilization occurred at magmagenic depths; hence, coeval hydrothermal ore deposits and granitoids are uncommon. In contrast, nearly head‐on Cretaceous subduction of the Farallon plate generated the massive Klamath–Sierra Nevada volcanic–plutonic arc, reflecting dewatering of the eastward descending oceanic lithosphere in the magmagenic zone. Immature Great Valley forearc and Franciscan trench deposits shed from the arc record c. 70 Myr. of rapid crustal growth. Au‐bearing solutions rising from magmagenic depths, exsolved from plutons, and expelled from heated wall rocks were mobilized attending arc construction. Precipitation of gold‐bearing quartz veins occurred where H2O + CO2‐bearing fluids encountered major geochemical discontinuities in the wall rocks.  相似文献   
113.
This study examined two shallow‐water, offshore oil facilities and their surroundings in the Umm Al Dalkh and Zakum oilfields [United Arab Emirates, Persian (Arabian) Gulf]. The focus was on sediment contamination levels and the detection of disturbance based on two representative invertebrate components of the benthos: molluscs and polychaetes. We tested the hypothesis that significant disturbance to the community has occurred, by examining whether distance from the platform or variation in contaminants explains among‐site variation in the composition of benthic communities. Moreover, we also tested the hypothesis that organic enrichment because of oil input has modified the feeding guild structure by examining whether the relative abundances of filter‐feeders, deposit‐feeders and omnivores are correlated with distance from the platform or with contamination by hydrocarbons. The contamination levels and their spatial distribution in the sediments differed significantly between the two fields, as did their mollusc and polychaete communities. The within‐field variability, however, was much lower: no clear structuring of contamination values and species composition and abundance was detectable in relation to distance from the oil platform. Contamination levels were low, often below detection levels or international guideline values. Variation in contaminant concentrations did not explain variation in taxonomic composition and abundance. The relative abundance of the above‐mentioned feeding guilds did not correlate with either distance from the platform or with contaminant concentrations. These patterns may reflect the long time that has elapsed since drilling (15–20 years), which appears to have allowed contaminants to disperse and degrade and assemblages to recover from the impact, if indeed such a disturbance ever occurred. In contrast to low values of barium and total petroleum hydrocarbons, associated with well drilling, some metals were at their highest concentrations beneath the central platforms. This suggests that production‐related activities (including platform cleaning and maintenance) are currently a more relevant contamination source.  相似文献   
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115.
The abundances, distributions, enantiomeric ratios, and carbon isotopic compositions of amino acids in two fragments of the Aguas Zarcas CM2 type carbonaceous chondrite fall and a fragment of the CM2 Murchison meteorite were determined via liquid chromatography time‐of‐flight mass spectrometry and gas chromatography isotope ratio mass spectrometry. A suite of two‐ to six‐carbon aliphatic primary amino acids was identified in the Aguas Zarcas and Murchison meteorites with abundances ranging from ~0.1 to 158 nmol/g. The high relative abundances of α‐amino acids found in these meteorites are consistent with a Strecker‐cyanohydrin synthesis on these meteorite parent bodies. Amino acid enantiomeric and carbon isotopic measurements in both fragments of the Aguas Zarcas meteorites indicate that both samples experienced some terrestrial protein amino acid contamination after their fall to Earth. In contrast, similar measurements of alanine in Murchison revealed that this common protein amino acid was both racemic (D ≈ L) and heavily enriched in 13C, indicating no measurable terrestrial alanine contamination of this meteorite. Carbon isotope measurements of two rare non‐proteinogenic amino acids in the Aguas Zarcas and Murchison meteorites, α‐aminoisobutyric acid and D‐ and L‐isovaline, also fall well outside the typical terrestrial range, confirming they are extraterrestrial in origin. The detections of non‐terrestrial L‐isovaline excesses of ~10–15% in both the Aguas Zarcas and Murchison meteorites, and non‐terrestrial L‐glutamic acid excesses in Murchison of ~16–40% are consistent with preferential enrichment of circularly polarized light generated L‐amino acid excesses of conglomerate enantiopure crystals during parent body aqueous alteration and provide evidence of an early solar system formation bias toward L‐amino acids prior to the origin of life.  相似文献   
116.
The stream hydrograph is an integration of spatial and temporal variations in water input, storage and transfer processes within a catchment. For glacier basins in particular, inferences concerning catchment‐scale processes have been developed from the varying form and magnitude of the diurnal hydrograph in the proglacial river. To date, however, such classifications of proglacial diurnal hydrographs have developed in a relatively subjective manner. This paper develops an objective approach to the classification of diurnal discharge hydrograph ‘shape’ and ‘magnitude’ using a combination of principal components analysis and cluster analysis applied to proglacial discharge time‐series and to diurnal bulk flow indices. The procedure is applied to discharge time‐series from two different glacier basins and four separate ablation seasons representing a gradient of increasing hydrological perturbation as a result of (i) variable water inputs generated by rainstorm activity and (ii) variable location and response of hydrological stores through a systematic decrease in catchment glacierized area. The potential of the technique for application in non‐glacial hydrological contexts is discussed. Copyright © 2000 John Wiley & Sons, Ltd.  相似文献   
117.
118.
Previous work on identifying opportunities for Pacific Island countries to improve the economic returns from their tuna resources in the Western and Central Pacific Ocean (WCPO) has not generally included articulation of aspirations from Islanders themselves. However, generating such an understanding is increasingly important as these countries assert their positions in regional fisheries policy making. This study analyses the self-identified aspirations of industry and government representatives from six Pacific Island countries and finds a wider diversity of attitudes, strategies and success than is generally recognised. Implications for negotiations in the WCPFC are then discussed.  相似文献   
119.
Evaluating the water‐soluble organic composition of carbonaceous chondrites is key to understanding the inventory of organic matter present at the origins of the solar system and the subsequent processes that took place inside asteroid parent bodies. Here, we present a side‐by‐side analysis and comparison of the abundance and molecular distribution of aliphatic amines, aldehydes, ketones, mono‐ and dicarboxylic acids, and free and acid‐releasable cyanide species in the CM2 chondrites Aguas Zarcas and Murchison. The Aguas Zarcas meteorite is a recent fall that occurred in central Costa Rica and constitutes the largest recovered mass of a CM‐type meteorite after Murchison. The overall content of organic species we investigated was systematically higher in Murchison than in Aguas Zarcas. Similar to previous meteoritic organic studies, carboxylic acids were one to two orders of magnitude more abundant than other soluble organic compound classes investigated in both meteorite samples. We did not identify free cyanide in Aguas Zarcas and Murchison; however, cyanide species analyzed after acid digestion of the water‐extracted meteorite mineral matrix were detected and quantified at slightly higher abundances in Aguas Zarcas compared to Murchison. Although there were differences in the total abundances of specific compound classes, these two carbonaceous chondrites showed similar isomeric distributions of aliphatic amines and carboxylic acids, with common traits such as a complete suite of structural isomers that decreases in concentration with increasing molecular weight. These observations agree with their petrologic CM type‐2 classification, suggesting that these meteorites experienced similar organic formation processes and/or conditions during parent body aqueous alteration.  相似文献   
120.
Using a mixed set of ethnographic methods including interviews and a structured survey, we evaluate local perceptions about the sustainability of salmon fisheries among fishers of the Cook Inlet region of Alaska. A majority of residents report participating in these fisheries, but we find significant disagreement about their sustainability. Household income and the types of fishing practiced both influence people's responses, and many implicated specific user groups for overharvesting and/or for receiving unfair catch allocations. Drawing on the theoretical areas of information theory and political ecology, we argue that these findings reveal a complex interplay among the practical, social, and political aspects of how local resource users, or “local experts,” develop and communicate their assessments of ecological conditions in a context of conflict. We conclude with notes on future research as it relates to the successful design of local-management and co-management solutions, especially in settings where resources are contested by stakeholders.  相似文献   
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