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111.
Present day inertial surveys are limited to single traverse runs in which the number of unknown system parameters to be determined are few, depending on the number of control points available along the traverse. Further, conventional inertial surveys are generally restricted to the determination of coordinates with no possibility for a rigorous post-mission adjustment of the observations. The consequence is the continued presence of systematic trends in the residuals, even after the use of error models such as those proposed by Ball, Gregerson or Kouba. Future work aiming at higher accuracies obviously requires more comprehensive models and rigorous adjustment procedures. These can be accomplished by the development of such error models and by the use of “area surveys”, instead of the single traverses, together with rigorous adjustment procedures suitable for the network of criss-crossing lines inertially surveyed. In such a network the cross-over points serve as constraints for the geodetic parameters (latitude, longitude, height, gravity anomaly, deflection components) and allow the addition of hardware and software related error parameters. Thus an opportunity is provided to effectively self-calibrate the system—a concept successfully used, for example, in photogrammetry or in satellite tracking. The number and the strength of such parameters depend on the number of control and cross-over points. The adjustment, of course, also provides the necessary statistical information on the adjusted parameters, such as their precision and the correlation between them. The presentation will describe current work at OSU in this area. Presented at the Second International Symposium on Inertial Technology for Surveying and Geodesy, Banff, Canada, June 1–5, 1981.  相似文献   
112.
A double spike for osmium analysis of highly radiogenic samples   总被引:1,自引:0,他引:1  
Geologic samples containing highly radiogenic Os (molybdenites and low-level, highly radiogenic (LLHR) samples) have no internal means by which to correct for mass fractionation during isotopic measurement by mass spectrometry. We describe a double spike for use with highly radiogenic samples, created by combining isotopically enriched 188Os and 190Os. Spiking molybdenite and other highly radiogenic minerals with this tracer allows for a fractionation correction, as well as a more reliable determination of common Os relative to analysis using single spikes.

The precise isotopic composition of the double spike is determined by a calibration against natural Os, in which two separate measurements are necessary: one each for the pure double spike and the spike–standard mixture. An estimate of the true composition of the spike is obtained by least squares approximation, and the errors are obtained by Monte Carlo methods. Sample analyses are then much more straightforward than the calibration because isotopic compositions of all components are known a priori.

Results obtained with a mixed Re-double Os spike demonstrate an improved reproducibility over individual 185Re and 190Os spikes. For an Archean in-house molybdenite standard we now observe a reproducibility of 0.08%. The ability to make a fractionation correction is essential for Os measurements made by ion counting. With the double Os spike, young samples and those with low Re contents (i.e., LLHR) can now be accurately analyzed. The 188Os–190Os double spike also allows a determination of the common Os contents of highly radiogenic samples. Common Os is poorly determined for ancient samples with high concentrations of 187Os, which fortunately are not sensitive to estimates of common Os. Common Os can be reasonably well determined for younger samples and those with low Re contents. We report a common Os concentration of 0.4±0.1 ppb for an 11 Ma molybdenite. Consideration of common Os content is important for age determination of young samples and LLHR samples, and is not possible by other published means of Os analysis.  相似文献   

113.
Quartz phenocrysts from 31 granitoid stocks in the Colorado Mineral Belt yield 18O values less than 10.4, with most values between 9.3 and 10.4. An average magmatic value of about 8.5 is suggested. The stocks resemble A-type granites; these data support magma genesis by partial melting of previously depleted, fluorine-enriched, lower crustal granulites, followed by extreme differentiation and volatile evolution in the upper crust.Subsolidus interaction of isotopically light water with stocks has reduced most feldspar and whole rock 18O values. Unaltered samples from Climax-type molybdenumbearing granites, however, show no greater isotopic disturbance than samples from unmineralized stocks. Although meteoric water certainly played a role in post-mineralization alteration, particularly in feldspars, it is not required during high-temperature mineralization processes. We suggest that slightly low 18O values in some vein and replacement minerals associated with molybdenum mineralization may have resulted from equilibration with isotopically light magmatic water and/or heavy isotope depletion of the ore fluid by precipitation of earlier phases.Accumulation of sufficient quantities of isotopically light magmatic water to produce measured depletions of 18O requires extreme chemical stratification in a large magma reservoir. Upward migration of a highly fractionated, volatile-rich magma into a small apical Climax-type diapir, including large scale transport of silica, alkalis, molybdenum, and other vapor soluble elements, may occur with depression of the solidus temperature and reduction of magma viscosity by fluorine. Climax-type granites may provide examples of 18O depletion in magmatic systems without meteoric water influx.  相似文献   
114.
115.
The abundances, distributions, enantiomeric ratios, and carbon isotopic compositions of amino acids in two fragments of the Aguas Zarcas CM2 type carbonaceous chondrite fall and a fragment of the CM2 Murchison meteorite were determined via liquid chromatography time‐of‐flight mass spectrometry and gas chromatography isotope ratio mass spectrometry. A suite of two‐ to six‐carbon aliphatic primary amino acids was identified in the Aguas Zarcas and Murchison meteorites with abundances ranging from ~0.1 to 158 nmol/g. The high relative abundances of α‐amino acids found in these meteorites are consistent with a Strecker‐cyanohydrin synthesis on these meteorite parent bodies. Amino acid enantiomeric and carbon isotopic measurements in both fragments of the Aguas Zarcas meteorites indicate that both samples experienced some terrestrial protein amino acid contamination after their fall to Earth. In contrast, similar measurements of alanine in Murchison revealed that this common protein amino acid was both racemic (D ≈ L) and heavily enriched in 13C, indicating no measurable terrestrial alanine contamination of this meteorite. Carbon isotope measurements of two rare non‐proteinogenic amino acids in the Aguas Zarcas and Murchison meteorites, α‐aminoisobutyric acid and D‐ and L‐isovaline, also fall well outside the typical terrestrial range, confirming they are extraterrestrial in origin. The detections of non‐terrestrial L‐isovaline excesses of ~10–15% in both the Aguas Zarcas and Murchison meteorites, and non‐terrestrial L‐glutamic acid excesses in Murchison of ~16–40% are consistent with preferential enrichment of circularly polarized light generated L‐amino acid excesses of conglomerate enantiopure crystals during parent body aqueous alteration and provide evidence of an early solar system formation bias toward L‐amino acids prior to the origin of life.  相似文献   
116.
The stream hydrograph is an integration of spatial and temporal variations in water input, storage and transfer processes within a catchment. For glacier basins in particular, inferences concerning catchment‐scale processes have been developed from the varying form and magnitude of the diurnal hydrograph in the proglacial river. To date, however, such classifications of proglacial diurnal hydrographs have developed in a relatively subjective manner. This paper develops an objective approach to the classification of diurnal discharge hydrograph ‘shape’ and ‘magnitude’ using a combination of principal components analysis and cluster analysis applied to proglacial discharge time‐series and to diurnal bulk flow indices. The procedure is applied to discharge time‐series from two different glacier basins and four separate ablation seasons representing a gradient of increasing hydrological perturbation as a result of (i) variable water inputs generated by rainstorm activity and (ii) variable location and response of hydrological stores through a systematic decrease in catchment glacierized area. The potential of the technique for application in non‐glacial hydrological contexts is discussed. Copyright © 2000 John Wiley & Sons, Ltd.  相似文献   
117.
118.
Evaluating the water‐soluble organic composition of carbonaceous chondrites is key to understanding the inventory of organic matter present at the origins of the solar system and the subsequent processes that took place inside asteroid parent bodies. Here, we present a side‐by‐side analysis and comparison of the abundance and molecular distribution of aliphatic amines, aldehydes, ketones, mono‐ and dicarboxylic acids, and free and acid‐releasable cyanide species in the CM2 chondrites Aguas Zarcas and Murchison. The Aguas Zarcas meteorite is a recent fall that occurred in central Costa Rica and constitutes the largest recovered mass of a CM‐type meteorite after Murchison. The overall content of organic species we investigated was systematically higher in Murchison than in Aguas Zarcas. Similar to previous meteoritic organic studies, carboxylic acids were one to two orders of magnitude more abundant than other soluble organic compound classes investigated in both meteorite samples. We did not identify free cyanide in Aguas Zarcas and Murchison; however, cyanide species analyzed after acid digestion of the water‐extracted meteorite mineral matrix were detected and quantified at slightly higher abundances in Aguas Zarcas compared to Murchison. Although there were differences in the total abundances of specific compound classes, these two carbonaceous chondrites showed similar isomeric distributions of aliphatic amines and carboxylic acids, with common traits such as a complete suite of structural isomers that decreases in concentration with increasing molecular weight. These observations agree with their petrologic CM type‐2 classification, suggesting that these meteorites experienced similar organic formation processes and/or conditions during parent body aqueous alteration.  相似文献   
119.
Previous work on identifying opportunities for Pacific Island countries to improve the economic returns from their tuna resources in the Western and Central Pacific Ocean (WCPO) has not generally included articulation of aspirations from Islanders themselves. However, generating such an understanding is increasingly important as these countries assert their positions in regional fisheries policy making. This study analyses the self-identified aspirations of industry and government representatives from six Pacific Island countries and finds a wider diversity of attitudes, strategies and success than is generally recognised. Implications for negotiations in the WCPFC are then discussed.  相似文献   
120.
Using a mixed set of ethnographic methods including interviews and a structured survey, we evaluate local perceptions about the sustainability of salmon fisheries among fishers of the Cook Inlet region of Alaska. A majority of residents report participating in these fisheries, but we find significant disagreement about their sustainability. Household income and the types of fishing practiced both influence people's responses, and many implicated specific user groups for overharvesting and/or for receiving unfair catch allocations. Drawing on the theoretical areas of information theory and political ecology, we argue that these findings reveal a complex interplay among the practical, social, and political aspects of how local resource users, or “local experts,” develop and communicate their assessments of ecological conditions in a context of conflict. We conclude with notes on future research as it relates to the successful design of local-management and co-management solutions, especially in settings where resources are contested by stakeholders.  相似文献   
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