Chemical Procedures for Rhenium Extraction from Geological Samples: Optimising the Anion Resin Bead Clean‐up Step     

Gang Yang  Aaron Zimmerman  Nicole C. Hurtig  Svetoslav V. Georgiev  Vineet Goswami  Judith L. Hannah  Holly J. Stein 《Geostandards and Geoanalytical Research》2020,44(2):231-242

Rhenium–osmium geochronometry for samples with low Re and complex matrices requires improved Re extraction methods. Here, we investigate plausible controls on efficiency and efficacy of Re extraction during our anion resin bead purification. Four different protocols are compared, each isolating a single variable to test. Rhenium concentrations for solutions at each step of each protocol document differences in chemical recovery/yield. The negative‐thermal ionisation mass spectrometry (N‐TIMS) signal intensity serves as a proxy for Re yield and purity. These data document correlations between the N‐TIMS signal intensity and (a) the duration of anion resin bead conditioning prior to loading with Re‐bearing solution, and (b) both duration and strength of nitric acid used during rinsing of the Re‐loaded anion resin bead. The optimal protocol improved Re signal intensity around fourteen times compared with our current Re extraction protocol, an aggregate of 2.4 times improvement in chemical recovery (yield) and 5.8 times improvement in emission efficiency (purity). Repeated N‐TIMS isotopic measurements on our in‐house Re standard solution (1407) verify that our optimal protocol‐3 does not fractionate Re isotopes. The improved anion resin bead method considerably lowers the Re detection limit and allows Re‐Os isotopic analysis of picogram‐level Re hosted in geological samples with complex matrices.  相似文献   

The spawning and early life-history of a New Zealand endemic amphidromous eleotrid,bluegill bully (Gobiomorphus hubbsi)     

Matt G. Jarvis  Hannah A. Harland  Manna L. Warburton  Gerard P. Closs 《新西兰海洋与淡水研究杂志》2018,52(1):55-68

The larval stage of fishes is critical in determining their dispersal, survival and recruitment, but little is known of the larval behaviours and tolerances of amphidromous fishes, particularly in New Zealand. We report the results of a series of observational and experimental studies on bluegill bully (Gobiomorphus hubbsi), including spawning sites and behaviours, larval characteristics at hatch, phototactic responses of larvae, and larval survival at different salinity levels. Spawning primarily occurred in the lower reaches of the river, and larvae from different nests exhibited marked differences in, and trade-offs between, larval characteristics at hatch, potentially affecting larval success. Larvae were positively phototactic to intense light, an unexpected result based on diel drift patterns and international research. Finally, larvae exhibited markedly higher survival rates when reared at intermediate salinities compared to freshwater or seawater, suggesting estuaries may play an important role as nursery grounds for bluegill bully and other amphidromous fish.  相似文献   

Water source dynamics of high Arctic river basins          下载免费PDF全文

Phillip J. Blaen  David M. Hannah  Lee E. Brown  Alexander M. Milner 《水文研究》2014,28(10):3521-3538

Arctic river basins are amongst the most vulnerable to climate change. However, there is currently limited knowledge of the hydrological processes that govern flow dynamics in Arctic river basins. We address this research gap using natural hydrochemical and isotopic tracers to identify water sources that contributed to runoff in river basins spanning a gradient of glacierization (0–61%) in Svalbard during summer 2010 and 2011. Spatially distinct hydrological processes operating over diurnal, weekly and seasonal timescales were characterized by river hydrochemistry and isotopic composition. Two conceptual water sources (‘meltwater’ and ‘groundwater’) were identified and used as a basis for end‐member mixing analyses to assess seasonal and year‐to‐year variability in water source dynamics. In glacier‐fed rivers, meltwater dominated flows at all sites (typically >80%) with the highest contributions observed at the beginning of each study period in early July when snow cover was most extensive. Rivers in non‐glacierized basins were sourced initially from snowmelt but became increasingly dependent on groundwater inputs (up to 100% of total flow volume) by late summer. These hydrological changes were attributed to the depletion of snowpacks and enhanced soil water storage capacity as the active layer expanded throughout each melt season. These findings provide insight into the processes that underpin water source dynamics in Arctic river systems and potential future changes in Arctic hydrology that might be expected under a changing climate. Copyright © 2013 John Wiley & Sons, Ltd.  相似文献   

Collaborative Governance and Conflict Management: Lessons Learned and Good Practices from a Case Study in the Amazon Basin     

Joshua Fisher  Hannah Stutzman  Mariana Vedoveto  Debora Delgado  Ramon Rivero  Walter Quertehuari Dariquebe 《社会与自然资源》2020,33(4):538-553

Abstract

Given the linkages between natural resources and social conflicts, evidence increasingly shows that successful natural resource management requires conflict mitigation and prevention. However, there may be a gap in practice between knowing what processes and tools need to be used to manage conservation conflicts and how to actually implement them. We present learning from a practice-based case study of conflict management in the Amarakaeri Communal Reserve in the Peruvian Amazon that aimed to develop natural resource governance institutions and build stakeholder capacity, including of indigenous groups, to navigate existing conflict resolution mechanisms. Through applying good practices in conservation conflict management and collaborative governance, we generated important lessons on the practical considerations involved in collaborative conservation. These lessons, while specific to our case, could be applied to a variety of protected areas facing complex social-ecological systems dynamics and wicked problems.  相似文献   

Fraile Detection of Solar $$-Modes by Fossat et al.     

Hannah Schunker  Jesper Schou  Patrick Gaulme  Laurent Gizon 《Solar physics》2018,293(6):95

The internal gravity modes of the Sun are notoriously difficult to detect, and the claimed detection of gravity modes presented by Fossat et al. (Astron. Astrophys.604, A40, 2017) is thus very exciting. Given the importance of these modes for understanding solar structure and dynamics, the results must be robust. While Fossat et al. described their method and parameter choices in detail, the sensitivity of their results to several parameters was not presented. Therefore, we test the sensitivity of the results to a selection of the parameters. The most concerning result is that the detection vanishes when we adjust the start time of the 16.5-year velocity time-series by a few hours. We conclude that this reported detection of gravity modes is extremely fragile and should be treated with utmost caution.  相似文献   

Simulation of Quiet-Sun Hard X-Rays Related to Solar Wind Superhalo Electrons     

Wen Wang  Linghua Wang  Säm Krucker  Iain Hannah 《Solar physics》2016,291(5):1357-1367

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Policy options to streamline the carbon market for agricultural nitrous oxide emissions     

Meredith T. Niles  Hannah Waterhouse  Robert Parkhurst  Eileen L. McLellan  Sara Kroopf 《Climate Policy》2019,19(7):893-907

The majority of emissions of nitrous oxide – a potent greenhouse gas (GHG) – are from agricultural sources, particularly nitrogen fertilizer applications. A growing focus on these emission sources has led to the development in the United States of GHG offset protocols that could enable payment to farmers for reducing fertilizer use or implementing other nitrogen management strategies. Despite the development of several protocols, the current regional scope is narrow, adoption by farmers is low, and policy implementation of protocols has a significant time lag. Here we utilize existing research and policy structures to propose an ‘umbrella’ approach for nitrogen management GHG emissions protocols that has the potential to streamline the policy implementation and acceptance of such protocols. We suggest that the umbrella protocol could set forth standard definitions common across multiple protocol options, and then modules could be further developed as scientific evidence advances. Modules could be developed for specific crops, regions, and practices. We identify a policy process that could facilitate this development in concert with emerging scientific research and conclude by acknowledging potential benefits and limitations of the approach.

Key policy insights

• Agricultural greenhouse gas market options are growing, but are still underutilized

• Streamlining protocol development through an umbrella process could enable quicker development of protocols across new crops, regions, and practices

• Effective protocol development must not compromise best available science and should follow a rigorous pathway to ensure appropriate implementation

  相似文献   

Effect of polychromatic X‐ray microtomography imaging on the amino acid content of the Murchison CM chondrite     

Jon M. Friedrich  Hannah L. McLain  Jason P. Dworkin  Daniel P. Glavin  W. Henry Towbin  Morgan Hill  Denton S. Ebel 《Meteoritics & planetary science》2019,54(1):220-228

X‐ray microcomputed tomography (μCT) is a useful means of characterizing cosmochemical samples such as meteorites or robotically returned samples. However, there are occasional concerns that the use of μCT may be detrimental to the organic components of a chondrite. Small organic compounds such as amino acids comprise up to ~10% of the total solvent extractable carbon in CM carbonaceous chondrites. We irradiated three samples of the Murchison CM carbonaceous chondrite under conditions akin to and harsher than those typically used during typical benchtop X‐ray μCT imaging experiments to determine if detectable changes in the amino acid abundance and distribution relative to a nonexposed Murchison control sample occurred. After subjecting three meteorite samples to ionizing radiation dosages between ~300 Gray (Gy) and 3 kGy with bremstrahlung X‐rays, we analyzed the amino acid content of each sample. Within sampling and analytical errors, we cannot discern differences in the amino acid abundances and amino acid enantiomeric ratios when comparing the control samples (nonexposed Murchison) and the irradiated samples. We conclude that a polychromatic X‐ray μCT experiment does not alter the abundances of amino acids to a degree greater than how well those abundances are measured with our techniques and therefore any damage to amino acids is minimal.  相似文献   

Cartograms for Use in Forecasting Weather-Driven Natural Hazards     

Florian Pappenberger  Hannah L. Cloke  Calum A. Baugh 《The Cartographic journal》2019,56(2):134-145

This paper evaluates the potential of using cartograms for visualizing and interpreting forecasts of weather-driven natural hazards in the context of global weather forecasting and early warning systems. The use of cartograms is intended to supplement traditional cartographic representations of the hazards in order to highlight the severity of an upcoming event. Cartogrammetric transformations are applied to forecasts of floods, heatwaves, windstorms and snowstorms taken from the European Centre for Medium-range Weather Forecasts (ECMWF) forecast archive. Key cartogram design principles in standard weather forecast visualization are tested. Optimal cartogram transformation is found to be dependent on geographical features (such as coastlines) and forecast features (such as snowstorm intensity). For highly spatially autocorrelated weather variables used in analysing several upcoming natural hazards such as 2m temperature anomaly, the visualization of the distortion provides a promising addition to standard forecast visualizations for highlighting upcoming weather-driven natural hazards.  相似文献   

Holocene hydrological variability of Lake Ladoga,northwest Russia,as inferred from diatom oxygen isotopes     

Svetlana S. Kostrova  Hanno Meyer  Hannah L. Bailey  Anna V. Ludikova  Raphael Gromig  Gerhard Kuhn  Yuri A. Shibaev  Anna V. Kozachek  Alexey A. Ekaykin  Bernhard Chapligin 《Boreas: An International Journal of Quaternary Research》2019,48(2):361-376

This article presents a new comprehensive assessment of the Holocene hydrological variability of Lake Ladoga, northwest Russia. The reconstruction is based on oxygen isotopes of lacustrine diatom silica (δ¹⁸O_diatom) preserved in sediment core Co 1309, and is complemented by a diatom assemblage analysis and a survey of modern isotope hydrology. The data indicate that Lake Ladoga has existed as a freshwater reservoir since at least 10.8 cal. ka BP. The δ¹⁸O_diatom values range from +29.8 to +35.0‰, and relatively higher δ¹⁸O_diatom values around +34.7‰ between c. 7.1 and 5.7 cal. ka BP are considered to reflect the Holocene Thermal Maximum. A continuous depletion in δ¹⁸O_diatom since c. 6.1 cal. ka BP accelerates after c. 4 cal. ka BP, indicating Middle to Late Holocene cooling that culminates during the interval 0.8–0.2 cal. ka BP, corresponding to the Little Ice Age. Lake‐level rises result in lower δ¹⁸O_diatom values, whereas lower lake levels cause higher δ¹⁸O_diatom values. The diatom isotope record gives an indication for a rather early opening of the Neva River outflow at c. 4.4–4.0 cal. ka BP. Generally, overall high δ¹⁸O_diatom values around +33.5‰ characterize a persistent evaporative lake system throughout the Holocene. As the Lake Ladoga δ¹⁸O_diatom record is roughly in line with the 60°N summer insolation, a linkage to broader‐scale climate change is likely.  相似文献