Chemical Procedures for Rhenium Extraction from Geological Samples: Optimising the Anion Resin Bead Clean‐up Step     

Gang Yang  Aaron Zimmerman  Nicole C. Hurtig  Svetoslav V. Georgiev  Vineet Goswami  Judith L. Hannah  Holly J. Stein 《Geostandards and Geoanalytical Research》2020,44(2):231-242

Rhenium–osmium geochronometry for samples with low Re and complex matrices requires improved Re extraction methods. Here, we investigate plausible controls on efficiency and efficacy of Re extraction during our anion resin bead purification. Four different protocols are compared, each isolating a single variable to test. Rhenium concentrations for solutions at each step of each protocol document differences in chemical recovery/yield. The negative‐thermal ionisation mass spectrometry (N‐TIMS) signal intensity serves as a proxy for Re yield and purity. These data document correlations between the N‐TIMS signal intensity and (a) the duration of anion resin bead conditioning prior to loading with Re‐bearing solution, and (b) both duration and strength of nitric acid used during rinsing of the Re‐loaded anion resin bead. The optimal protocol improved Re signal intensity around fourteen times compared with our current Re extraction protocol, an aggregate of 2.4 times improvement in chemical recovery (yield) and 5.8 times improvement in emission efficiency (purity). Repeated N‐TIMS isotopic measurements on our in‐house Re standard solution (1407) verify that our optimal protocol‐3 does not fractionate Re isotopes. The improved anion resin bead method considerably lowers the Re detection limit and allows Re‐Os isotopic analysis of picogram‐level Re hosted in geological samples with complex matrices.  相似文献   

Low resolution spectroscopy of selected Algol systems     

Shanti Priya Devarapalli  Rukmini Jagirdar  M. Parthasarathy  D. K. Sahu  Vijay Mohan  B. C. Bhatt  Vineet S. Thomas 《Astrophysics and Space Science》2018,363(4):69

The analysis of spectroscopic data for 30 Algol-type binaries is presented. All these systems are short period Algols having primaries with spectral types B and A. Dominant spectral lines were identified for the spectra collected and their equivalent widths were calculated. All the spectra were examined to understand presence of mass transfer, a disk or circumstellar matter and chromospheric emission. We also present first spectroscopic and period study for few Algols and conclude that high resolution spectra within and outside the primary minimum are needed for better understanding of these Algol type close binaries.  相似文献   

Holocene climate forcings and lacustrine regime shifts in the Indian summer monsoon realm     

Sushma Prasad  Norbert Marwan  Deniz Eroglu  Bedartha Goswami  Praveen K. Mishra  Birgit Gaye  A. Anoop  N. Basavaiah  Martina Stebich  Arshid Jehangir 《地球表面变化过程与地形》2020,45(15):3842-3853

Extreme climate events have been identified both in meteorological and long-term proxy records from the Indian summer monsoon (ISM) realm. However, the potential of palaeoclimate data for understanding mechanisms triggering climate extremes over long time scales has not been fully exploited. A distinction between proxies indicating climate change, environment, and ecosystem shift is crucial for enabling a comparison with forcing mechanisms (e.g. El-Niño Southern Oscillation). In this study we decouple these factors using data analysis techniques [multiplex recurrence network (MRN) and principal component analyses (PCA)] on multiproxy data from two lakes located in different climate regions – Lonar Lake (ISM dominated) and the high-altitude Tso Moriri Lake (ISM and westerlies influenced). Our results indicate that (i) MRN analysis, an indicator of changing environmental conditions, is associated with droughts in regions with a single climate driver but provides ambiguous results in regions with multiple climate/environmental drivers; (ii) the lacustrine ecosystem was ‘less sensitive’ to forcings during the early Holocene wetter periods; (iii) archives in climate zones with a single climate driver were most sensitive to regime shifts; (iv) data analyses are successful in identifying the timing of onset of climate change, and distinguishing between extrinsic and intrinsic (lacustrine) regime shifts by comparison with forcing mechanisms. Our results enable development of conceptual models to explain links between forcings and regional climate change that can be tested in climate models to provide an improved understanding of the ISM dynamics and their impact on ecosystems. © 2020 John Wiley & Sons, Ltd.  相似文献   

Correction to: Application of 1D and 2D hydrodynamic modeling to study glacial lake outburst flood (GLOF) and its impact on a hydropower station in Central Himalaya     

Sattar  Ashim  Goswami  Ajanta  Kulkarni  Anil V. 《Natural Hazards》2019,98(2):817-817

Natural Hazards - The article was published with the citation “Worni et al. (2012)”. The author group of the article would like readers to know that this information should instead...  相似文献   

Erratum to: Changes in western disturbances over the Western Himalayas in a warming environment     

R. K. Madhura  R. Krishnan  J. V. Revadekar  M. Mujumdar  B. N. Goswami 《Climate Dynamics》2015,44(3-4):1169-1169

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Simulation of heavy rainfall events over Indian region: a benchmark skill with a GCM     

Prashant Goswami  B. Kantha Rao 《Climate Dynamics》2015,45(7-8):1899-1911

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Pressure and temperature conditions for crystallization of metamorphic allanite and monazite in metapelites: a case study from the Miyar Valley (high Himalayan Crystalline of Zanskar,NW India)          下载免费PDF全文

S. Goswami‐Banerjee  M. Robyr 《Journal of Metamorphic Geology》2015,33(5):535-556

The textural and chemical evolution of allanite and monazite along a well‐constrained prograde metamorphic suite in the High Himalayan Crystalline of Zanskar was investigated to determine the P–T conditions for the crystallization of these two REE accessory phases. The results of this study reveals that: (i) allanite is the stable REE accessory phase in the biotite and garnet zone and (ii) allanite disappears at the staurolite‐in isograd, simultaneously with the occurrence of the first metamorphic monazite. Both monazite and allanite occur as inclusions in staurolite, indicating that the breakdown of allanite and the formation of monazite proceeded during staurolite crystallization. Staurolite growth modelling indicates that staurolite crystallized between 580 and 610 °C, thus setting the lower temperature limit for the monazite‐forming reaction at ~600 °C. Preservation of allanite and monazite inclusions in garnet (core and rim) constrains the garnet molar composition when the first monazite was overgrown and subsequently encompassed by the garnet crystallization front. Garnet growth modelling and the intersection of isopleths reveal that the monazite closest to the garnet core was overgrown by the garnet advancing crystallization front at 590 °C, which establishes an upper temperature limit for monazite crystallization. Significantly, the substitution of allanite by monazite occurs in close spatial proximity, i.e. at similar P–T conditions, in all rock types investigated, from Al‐rich metapelites to more psammitic metasedimentary rocks. This indicates that major silicate phases, such as staurolite and garnet, do not play a significant role in the monazite‐forming reaction. Our data show that the occurrence of the first metamorphic monazite in these rocks was mainly determined by the P–T conditions, not by bulk chemical composition. In Barrovian terranes, dating prograde monazite in metapelites thus means constraining the time when these rocks reached the 600 °C isotherm.  相似文献   

Geotechnical properties of the bank sediments along the Dhansiri River channel, Assam     

P. Kotoky  M. K. Dutta  R. Goswami  G. C. Borah 《Journal of the Geological Society of India》2011,78(2):175-183

The bank sediments along the extremely meandered Dhansiri River channel, a south bank tributary of the mighty Brahmaputra River, with erosion potentiality have been investigated to evaluate its certain geotechnical characteristics. The study has shown that the bank sediments are basically composed of CL and ML types of soil. These types of sediments are very much prone to liquefaction which in turn related to erosion susceptibility. The bank stability analysis has differentiated the studied stretch into unstable, at risk and stable zones. Most of the erosion affected zones along the channel reach under study are located within the unstable or at risk zones. The field study around Butalikhowa, Barguriagaon, Golaghat and Duchmuagaon areas along the channel with active erosion activity has supported our contention and practical utility of the present study. It is expected that such type of study will help in providing certain inevitable baseline information for various channel management practices for this extremely flood prone areas of Northeast India.  相似文献   

Analysis and quantification of contrasts in observed meteorological fields for foggy and non-foggy days   总被引：1，自引：0，他引：1  

Prashant Goswami  Sumana Sarkar 《Meteorology and Atmospheric Physics》2015,127(5):605-623

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Use of SARAL/AltiKa Observations for Modeling River Flow     

Praveen Gupta  Amit Kumar Dubey  Nandita Goswami  Raghvendra Pratap Singh  Prakash Chauhan 《Marine Geodesy》2015,38(3):614-625

In the absence of many gauging stations in the major and mighty river systems, there is a need for satellite-based observations to estimate temporal variations in the river water storage and associated water management. In this study, SARAL/AltiKa application for setting up hydraulic model (HEC-RAS) and river flow simulations over Tapi River India has been discussed. Waveform data of 40 Hz from Ka band altimeter has been used for water levels retrieval in the Tapi river. SARAL/AltiKa retrieved water levels were converted to discharge in the upstream location (track-926) using the rating curve available for the nearby gauging site and using linear spatial interpolation technique. Steady state simulations were done for various flow conditions in the upstream. Validation of river flow model was done in the downstream location (track-367) by comparing simulated and altimeter retrieved water levels (RMSE 0.67 m). Validated model was used to develop rating curve between water levels and simulated discharge for the downstream location which enables to monitor discharge variations from satellite platform in the absence of in situ observations. It has been demonstrated that SARAL/AltiKa data has potential for river flow monitoring and modeling which will feed for flood disaster forecasting, management and planning.  相似文献