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171.
Small eruptive centres (SECs) representing short-lived, isolated eruptions are effective samples of mantle heterogeneity over a given area, as they are generally of basaltic composition and show evidence of little magmatic processing. This is particularly powerful in volcanic arcs where the original melting process generating stratovolcanoes is often obscured by additions from the down-going slab (fluids and sediments) and the overlying crust. The Pucón area of southern Chile contains active and dormant stratovolcanoes, Holocene, basaltic SECs and an arc-scale strike-slip fault (the Liquiñe Ofqui Fault System: LOFS). The SECs show unexpected compositional heterogeneity considering their spatial proximity. We present a detailed study of these SECs combining whole rock major and trace element concentrations, U-Th isotopes and olivine-hosted melt inclusion major element and volatile contents to highlight the complex inter-relations in this small but active area. We show that heterogeneity preserved at individual SECs relates to different processes: some start in the melting region with the input of slab-derived fluids, whilst others occur later in a centre’s magmatic history with the influence of crustal contamination prior to olivine crystallisation. These signals are deduced through the combination of the different geochemical tools used in this study. We show that there is no correlation between composition and distance from the arc front, whilst the local tectonic regime has an effect on melt composition: SECs aligned along the LOFS have either equilibrium U-Th ratios or small Th-excesses instead of the large—fluid influenced—U-excesses displayed by SECs situated away from this feature. One of the SECs is modelled as being generated from fluid-enriched depleted mantle, a source which it may share with the stratovolcano Villarrica, whilst another SEC with abundant evidence of crustal contamination may share its plumbing system with its neighbouring stratovolcano Quetrupillán, showing that polygenetic–monogenetic connections are unpredictable. Such marked preservation of individual magmatic histories highlights the isolation of individual melting events even in complex and highly volcanically active areas.  相似文献   
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Historical gold mining operations in Nova Scotia, Canada, resulted in numerous deposits of publicly accessible, arsenic (As)-rich mine waste that has weathered in situ for 75–150 years, resulting in a wide range of As-bearing secondary minerals. The geochemical heterogeneity of this mine waste creates a challenge for identifying a single remediation approach that will limit As mobility. A 30-cm-thick, low-organic content soil cover was evaluated in a laboratory leaching experiment where, to simulate natural conditions, the equivalent of 2 years of synthetic rainwater was leached through each column and two dry seasons were incorporated into the leaching protocol. Each column was a stratigraphic representation of the four major tailings types found at the historical Montague and Goldenville gold mine districts: hardpan tailings, oxic tailings, wetland tailings, and high Ca tailings. Hardpan tailings released acidic, As-rich waters (max 12 mg/L) under the soil cover but this acidity was buffered by surrounding oxic tailings. Leachate from the oxic tailings was circumneutral, with average As concentrations between 4.4 and 9.7 mg/L throughout the experiment. The presence of carbonates in the high Ca tailings resulted in near-neutral to weakly alkaline leachate pH values and average As concentrations between 2.1 and 6.1 mg/L. Oxidation of sulfides in the wetland tailings led to acidic leachate over time and a decrease in As concentrations to values that were generally less than 1 mg/L. This study shows that the use of a low-organic content soil cover does not create reducing conditions that would destabilize oxidized, As-bearing secondary phases in these tailings. However, oxygen penetration through the cover during dry seasons would continue to release As to tailings pore waters via sulfide oxidation reactions.  相似文献   
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Natural Hazards - To investigate the propagation of meteorological droughts to agricultural and hydrological droughts, the relationship between droughts was analyzed using observed precipitation...  相似文献   
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The post-Mesoproterozoic tectonometamorphic history of the Musgrave Province, central Australia, has previously been solely attributed to intracontinental compressional deformation during the 580 -520 Ma Petermann Orogeny. However, our new structurally controlled multi-mineral geochronology results,from two north-trending transects, indicate protracted reactivation of the Australian continental interior over ca. 715 million years. The earliest events are identified in the hinterland of the orogen along the western transect. The first tectonothermal event, at ca. 715 Ma, is indicated by40 Ar/39 Ar muscovite and U e Pb titanite ages. Another previously unrecognised tectonometamorphic event is dated at ca. 630 Ma by Ue Pb analyses of metamorphic zircon rims. This event was followed by continuous cooling and exhumation of the hinterland and core of the orogen along numerous faults, including the Woodroffe Thrust,from ca. 625 Ma to 565 Ma as indicated by muscovite, biotite, and hornblende40 Ar/39 Ar cooling ages. We therefore propose that the Petermann Orogeny commenced as early as ca. 630 Ma. Along the eastern transect,40 Ar/39 Ar muscovite and zircon(Ue Th)/He data indicate exhumation of the foreland fold and thrust system to shallow crustal levels between ca. 550 Ma and 520 Ma, while the core of the orogen was undergoing exhumation to mid-crustal levels and cooling below 600-660℃. Subsequent cooling to 150 -220℃ of the core of the orogen occurred between ca. 480 Ma and 400 Ma(zircon [Ue Th]/He data)during reactivation of the Woodroffe Thrust, coincident with the 450 -300 Ma Alice Springs Orogeny.Exhumation of the footwall of the Woodroffe Thrust to shallow depths occurred at ca. 200 Ma. More recent tectonic activity is also evident as on the 21 May, 2016(Sydney date), a magnitude 6.1 earthquake occurred, and the resolved focal mechanism indicates that compressive stress and exhumation along the Woodroffe Thrust is continuing to the present day. Overall, these results demonstrate repeated amagmatic reactivation of the continental interior of Australia for ca. 715 million years, including at least 600 million years of reactivation along the Woodroffe Thrust alone. Estimated cooling rates agree with previously reported rates and suggest slow cooling of 0.9 -7.0℃/Ma in the core of the Petermann Orogen between ca. 570 Ma and 400 Ma. The long-lived, amagmatic, intracontinental reactivation of central Australia is a remarkable example of stress transmission, strain localization and cratonization-hindering processes that highlights the complexity of Continental Tectonics with regards to the rigid-plate paradigm of Plate Tectonics.  相似文献   
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Acoustic backscatter from an active sonar system (TAPS-6) over a range of six frequencies between 265 kHz and 3 MHz revealed characteristics of emergence and reentry events within 1 h of sunset and sunrise, respectively, at a site 10 m deep in the Damariscotta River estuary, Maine. Emergence traps indicated that the mysid shrimpNeomysis americana was the dominant migrator. Daily fluctuation in irradiance influenced the timing of dusk emergence. Local variability in irradiance apparently caused populations to emerge occasionally before sunset or to leave the surface after the beginning of nautical twilight near dawn. Emergence before sunset was marked by slower-than-average ascent, and departure from the surface after initiation of nautical twilight was marked by faster-than-average descent. This pattern would be expected for populations avoiding visual predators by concealment in dark water. Mean ascent (0.29 ± 0.03 cm s−1 [±1 SE]) and descent (−0.26 ± 0.02 cm s−1) velocities showed little difference in magnitude, suggesting that a similar mechanism controls both. Ascent initiation times for the first such event of the night were consistent with a cue based on relative rate of change in light intensity and inconsistent with either the progress of isolumes or with absolute rate of change in light intensity.  相似文献   
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