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31.
Prof. Dr. Hilmar Schumann 《Contributions to Mineralogy and Petrology》1954,4(1-2):198-206
Zusammenfassung Konoskopische Interferenzfiguren können an durchsichtigen, doppelbrechenden Kristallen auch im Auflicht erhalten werden, wofern es gelingt, eine Reflexion im Innern des Kristalls an einer (natürlichen oder künstlichen) Begrenzungsfläche —allenfalls auch an einem kristallographisch begrenzten oder zufällig regellosen Spalt — zu erzeugen. Ebenheit und Glätte sind keine unbedingten Voraussetzungen für das Zustandekommen der Effekte. Die Reflexion ist am stärksten an Grenzflächen gegen Luft, doch ist auch dies keine grundsatzliche Bedingung. Besonders günstig ist es, wenn eine optisch ausgezeichnete Richtung (optische Achse, Bisektrix) in der Nähe der Normalen der Einstrahlungsfläche liegt. Ist dies nicht der Fall, so kann man unter Benutzung eines Drehtisches (mit dem oberen Segment oder ohne ein solches) die interessierenden Richtungen der Tubusachse parallel stellen. Als Apparatur können normale mineralogische Polarisationsmikroskope, bzw. wo starke Vergrößerungen nötig sind, Erzmikroskope verwendet werden. Grundsätzlich neu ist nur ein leicht zu improvisierender Spezialkollimator mit großem Öffnungswinkel und eingebautem Polarisator. Dies Verfahren hat Bedeutung für die Untersuchung aufgewachsener oder in einer künstlichen Fassung befindlicher Kristalle.Herrn Professor Dr.Carl W. Correns zum 60. Geburtstag gewidmet. 相似文献
32.
Towards a Higher Comparability of Geothermometric Data Obtained by Raman Spectroscopy of Carbonaceous Material. Part 2: A Revised Geothermometer 下载免费PDF全文
N. Keno Lünsdorf István Dunkl Burkhard C. Schmidt Gerd Rantitsch Hilmar von Eynatten 《Geostandards and Geoanalytical Research》2017,41(4):593-612
The estimation of the peak metamorphic temperature by Raman spectroscopy of carbonaceous material (RSCM) is influenced by several bias sources grouped in measuring conditions, spectral processing and sample heterogeneity. The measuring conditions (selected excitation wavelength) and the operator bias during spectral processing have a pronounced impact on the temperature estimate and thus on the comparability and portability of thermometric data obtained by RSCM. Several calibration lines of RSCM geothermometers are published already, but no standardised approach exists. Samples of carbonaceous material bearing metasediments with well‐established metamorphic conditions of the central and western Alps compile a reference series. By applying an automated, iterative and randomised curve‐fitting approach, a consistent and user input‐independent RSCM geothermometer is presented, which covers peak metamorphic temperatures from ca. 160 to 600 °C. The method is hardware independent because the measuring conditions bias is excluded by the use of the reference series and the automated curve‐fitting approach reduces the spectral processing bias effectively, increasing the method's comparability and portability. By distributing the reference series and the automated curve‐fitting software, a laboratory will be able to derive a laboratory specific calibration line for the RSCM geothermometer. 相似文献
33.
Superposition of burial and hydrothermal events: post‐Variscan thermal evolution of the Erzgebirge,Germany 下载免费PDF全文
Reinhard Wolff István Dunkl Jan‐Michael Lange Christian Tonk Thomas Voigt Hilmar von Eynatten 《地学学报》2015,27(4):292-299
The post‐Variscan thermal history of the Erzgebirge (Germany) is the result of periods of sedimentary burial, exhumation and superimposed hydrothermal activity. The timing and degree of thermal overprint have been analysed by zircon and apatite (U–Th)/He and apatite fission track thermochronology. The present‐day surface of the Erzgebirge was exhumed to a near‐surface position after the Variscan orogeny. Thermal modelling reveals Permo‐Mesozoic burial to temperatures of up to 80–100 °C, although the sedimentary cover thins out towards the north resulting in maximum burial temperatures of less than 40 °C. This thermal pattern was locally modified by Cretaceous hydrothermal activity that reset the zircon (U–Th)/He thermochronometer along ore veins. The thermal models show no significant regional exhumation during Cenozoic times, indicating that the peneplain‐like morphology of the basement is a Late Cretaceous feature. 相似文献
34.
Silke Triebold George Luiz Luvizotto Raimon Tolosana-Delgado Thomas Zack Hilmar von Eynatten 《Contributions to Mineralogy and Petrology》2011,161(4):581-596
Investigation by Raman spectroscopy of samples from different geological settings shows that the occurrence of TiO2 polymorphs other than rutile can hardly be predicted, and furthermore, the occurrence of anatase is more widespread than
previously thought. Metamorphic pressure and temperature, together with whole rock chemistry, control the occurrence of anatase,
whereas variation of mineral assemblage characteristics and/or fluid occurrence or composition takes influence on anatase
trace element characteristics and re-equilibration of relict rutiles. Evaluation of trace element contents obtained by electron
microprobe in anatase, brookite, and rutile shows that these vary significantly between the three TiO2 phases. Therefore, on the one hand, an appropriation to source rock type according to Nb and Cr contents, but as well application
of thermometry on the basis of Zr contents, would lead to erroneous results if no phase specification is done beforehand.
For the elements Cr, V, Fe, and Nb, variation between the polymorphs is systematic and can be used for discrimination on the
basis of a linear discriminant analysis. Using phase group means and coefficients of linear discriminants obtained from a
compilation of analyses from samples with well-defined phase information together with prior probabilities of groupings from
a natural sample compilation, one is able to calculate phase grouping probabilities of any TiO2 analysis containing at least the critical elements Cr, V, Fe, and Nb. An application of this calculation shows that for the
appropriation to the phase rutile, a correct-classification rate of 99.5% is obtained. Hence, phase specification by trace
elements proves to be a valuable tool besides Raman spectroscopy. 相似文献
35.
Hilmar W. Duerbeck 《Astrophysics and Space Science》2002,279(1-2):5-14
The optical photometric evolution of the final helium flash object V4334 Sgr from 1994 to 2001 is described. The rise to optical maximum (1994–1996) is characterized by a continuous increase of colour indices, indicating a slowly expanding, cooling pseudo-photosphere. This photosphere became stationary in 1997. In the following years, the object underwent brightnessdeclines of increasing strength, which are similar in character to the `reddeclines' of RCB stars. The fading of V4334 Sgr is more dramatic than anybrightness decline of an RCB star: at present, only 10-5 of the visual light reaches the observer. Most short-wavelength radiation is absorbed by a dust envelopethat completely surrounds the star, and is re-radiated in the infrared. The sparse optical data of 2000–2001 show that the obscuration has not increased in strength any more. The light curve of V4334 Sgr is similar to that of the final helium flash object V605 Aql which erupted in 1919. 相似文献
36.
Provenance of Palaeo‐Rhine sediments from zircon thermochronology,geochemistry, U/Pb dating and heavy mineral assemblages 下载免费PDF全文
Sediments deposited in the Late Cenozoic basins of the Central European Rift System, including the Upper Rhine Graben (URG) and the Lower Rhine Embayment (LRE), document the drastic extension of the Rhine's catchment towards the Central Alps in the Late Pliocene by distinct heavy mineral assemblages. This outstanding change in principal sediment sources should be accompanied by a change towards distinctly younger (i.e. Tertiary) detrital mineral cooling ages. Therefore, it provides a particularly well‐suited framework to explore the thermochronological provenance record in relation to heavy mineral assemblages. In this multi‐proxy approach we (i) exploit and elaborate detrital zircon (U–Th)/He thermochronology (ZHe) for sediment provenance surveys, (ii) document shortcomings if only a single geochronological method is employed, and (iii) obtain tighter constraints on the sources of Paleo‐Rhine sediments. Our results are based on Pliocene and Pleistocene sediment samples from the northern URG (drill core Ludwigshafen P36) and the LRE (lignite mine Hambach). In a Late Pliocene URG sample, Variscan and Permo‐Triassic cooling ages dominate the age spectra of the ZHe and Zircon fission track (ZFT) thermochronometers. The youngest ages are Late Cretaceous and these zircons show rare earth element signatures that suggest derivation from hydrothermally affected basement rocks of the URG margins. In contrast, a Lower Pleistocene URG sample contains significant Tertiary age components that unequivocally indicate Alpine sources. This cardinal difference coincides well with a significant change in the heavy mineral assemblage. The extension of the catchment of the Rhine towards the Central Alps is considered to occur no earlier than the latest Pliocene (i.e. after ~3.0 Ma). Despite strongly contrasting heavy mineral compositions, the Pliocene and Pleistocene samples from the LRE show largely similar ZHe and ZFT age distributions dominated by Permo‐Triassic and Variscan ages. Admixture of zircon‐dominated, but overall heavy mineral‐poor sediment derived from local drainages of the Rhenish Massif likely explains this apparent contradiction in sediment provenance proxies. Tertiary cooling ages occur in both Pliocene and Pleistocene LRE samples. Zircon Th/U ratios and U/Pb ages reveal that the young age component in Late Pliocene sediments from the LRE is not derived from the Alps but from Oligocene trachytic members of the Central European volcanic centres of the Vogelsberg, Westerwald, and/or Siebengebirge. The integration of ZHe and ZFT techniques with zircon geochemistry and U/Pb geochronology adds the respective advantages of each method and allows for a very detailed picture of detrital zircon provenance. 相似文献
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Hilmar von Eynatten Carles Barceló-Vidal Vera Pawlowsky-Glahn 《Mathematical Geology》2003,35(3):231-251
Perturbation on the simplex is an operation which can be used to numerically describe changes in the composition of, for example, soils, sediments, or rocks. The combination of perturbation and power transformation provides a strong tool for analyzing compositional linear processes in the simplex. When the process is constrained in the sense of a well-known starting (or final) composition, noncentred principal component analysis can be used to estimate the leading perturbation vector of the process. Applying these mathematical tools to chemical major element data from a weathering profile developed on granitoid rocks allows us to model the compositional changes associated with the process of chemical weathering. The comparison of these results with the compositional linear trend defined by erosional products of several of the world's major drainage systems yields close similarities. The latter observation allows for a mathematical formulation of a global mean weathering trend within the system Al2O3–CaO– Na2O– K2O. We further demonstrate the usefulness of the approach for validating processes behind individual trends and for combining the effects of different processes which modify the composition of soils, sediments, and rocks. Alternatives to the Chemical Index of Alteration (CIA) are discussed to obtain a translation-invariant scale for the process of chemical weathering. 相似文献